Collisional solute release from thermally activated lipid particles

Solid lipid particles were evaluated for their potential as a thermo-activated drug delivery system. Submicron-sized diphenylhexatriene (DPH)/myristyl alcohol particles were produced by an atomization/drying process and the release rate of DPH into sodium dodecyl sulfate (SDS) micellar solutions was measured. The results showed that the presence of micelles and thermal activation was necessary and sufficient for the release of DPH. The initial rate of DPH release was linear for most systems. However, nonlinearity was noted at low micelle concentrations where the rate decreased with time due to the loss of sink conditions with the rising concentration of DPH in the micellar solution. Also at high micelle and particle concentrations, the rate increased with time, which may be due to a loss of particle integrity. Analyzing the data from a design study, the release rate was found to be linearly proportional to particle concentration. In contrast, the rate of release increased with micelle concentration in a nonlinear manner and appeared to approach a plateau at high micelle concentrations. The decrease in rate as the micelle concentration increased is suggestive of a saturable process and may involve a collision-based mechanism.     

Turbulence modulation by large ellipsoidal particles: concentration effects

We use laboratory measurements to study how suspended ellipsoidal particles affect the velocity statistics of a turbulent flow. The ellipsoids have size, time, and velocity scales corresponding to the inertial subrange of the turbulence and are nearly neutrally buoyant. These characteristics make them likely candidates for two-way interactions with the fluid (i.e., they influence the flow and are influenced by it). We vary the volume fraction of suspended ellipsoids and observe the effects on one- and two-point velocity statistics in the fluid phase. Measurements at two different heights indicate that particle buoyancy (0.5 % denser than the ambient fluid) significantly changes volume fraction. We see that particles’ effect on turbulent kinetic energy is a non-monotonic function of the volume fraction. We also find that particles’ presence causes a redistribution of velocity variance from large scales to small scales within the inertial subrange, i.e., the slope of power spectra is flatter than in the single-phase case.     

Light scattering by optically soft large particles of arbitrary shape

Light scattering by chaotically oriented optically soft large particles of arbitrary shape is considered within the framework of the Rayleigh-Gans approximation. It has been shown that outside the forward direction, the scattering pattern has the dependence of Δk??(1+cos2θ), where is an average particle surface area, Δk is the difference between scattered and initial wave vectors, θ is the scattering angle, and this pattern is independent of particle shape. A simple approximating formula is suggested, which correctly describes the scattering pattern in the entire range of scattering angles. This formula is compared to the particular case of size-distributed spherical particles and is shown to have high accuracy. Also, it is shown that the inherent optical properties, as total, transport, and backward scattering coefficients, are determined by the specific particle surface area and the effective particle size.     

Photophoresis of large sublimating aerosol particles

The paper deals with photophoresis of a large solid spherical aerosol particle on whose surface a phase transition occurs in the form of evaporation (sublimation) of the particle matter. A formula is derived for the rate of photophoresis, which generalizes the known relation for the rate of photophoresis of a nonvolatile particle. It is demonstrated that the inclusion of the evaporation coefficient may introduce a significant correction to the value of the rate of photophoresis.     

Boosting energy density by frustration

<正>Energy storage units are essential in electronic and electric devices as sources to supply energy for circuits.The most widely used ones are electrochemical batteries with high energy density,for example,in renewable energy generation and electric vehicles.However,the electrochemical batteries cannot suffer highpower energy input/output,     

Theory of centrifugal sedimentation of large particles

The motion of particles of finite size in rotating viscous liquids is investigated. On the basis of the properties of centrifugal sedimentation described, its possible technical applications are discussed.Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 32, No. 5, pp. 865–869, May, 1977.     

Electroosmotic fluid motion and late-time solute transport for large zeta potentials

Analytical and numerical methods are employed to determine the electric potential, fluid velocity, and late-time solute distribution for electroosmotic flow in a tube and channel at zeta potentials that are not necessarily small. The electric potential and fluid velocity are in general obtained by numerical means. In addition, new analytical solutions are presented for the velocity in a tube and channel in the extremes of large and small Debye layer thickness. The electroosmotic fluid velocity is used to analyze late-time transport of a neutral nonreacting solute. Zero- and first-order solutions describing axial variation of the solute concentration are determined analytically. The resulting expressions contain eigenvalues representing the dispersion and skewness of the axial concentration profiles. These eigenvalues and the functions describing transverse variation of the concentration field are determined numerically using a shooting technique. Results are presented for both tube and channel geometries over a wide range of the normalized Debye layer thickness and zeta potential. Simple analytical approximations to the eigenvalues are also provided for the limiting cases of large and small values of the Debye layer thickness.     

Scattering matrices for large ice crystal particles

The problem of light scattering by ice crystal particles whose sizes are essentially larger than the incident wavelength is divided into two parts. First, the scattered field is represented as a set of plane-parallel outgoing beams in the near zone of the particle. Then, in the far zone the scattered field is represented as a result of both diffraction and interference of these beams within the framework of physical optics. A proper ray-tracing algorithm for calculation of the amplitude (Jones) scattering matrix is developed and applied. For large particles, a number of reduced Mueller matrices are introduced and discussed, since the pure Mueller matrix obtained from the Jones matrix becomes a rather cumbersome and quickly oscillating value. Backscattering by hexagonal ice crystals, including polarization properties, is considered in detail.     

Control of surface migration of gold particles on Si nanowires

On the surface of silicon nanowires (SiNWs) synthesized by gold (Au)-catalyzed chemical vapor deposition (CVD), Au particles 5-20 nm in diameter are formed if the growth conditions are within a specific range. We studied the mechanism of Au particle formation by growing SiNWs under different conditions, specifically by dynamically changing the growth parameters during the growth process. We show that insufficient supply of Si source to the Au-Si eutectic on top of the SiNWs enhances the migration of Au atoms on the surface of SiNWs in the form of Au-Si eutectic, which is precipitated on the surface as Au particles during cooling. We also show that using Au-Si eutectic on the surface of SiNWs as a catalyst enables one-step growth of branched SiNWs.     

Accuracy of calculating flows upon disappearance of discontinuity by the method of large particles

The numerical solution of the problem of disappearance of discontinuity is compared in the univariate case with the accurate solution for the discontinuity of an arbitrary amplitude and with the calculation in Lagrange coordinates, and in the spatial case with the calculations on grids that differ in details.Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 40, No. 4, pp. 690–695, April, 1981.     

Times of capture of moderately large nonvolatile aerosol particles by growing or evaporating drops

The time of the total clearing of particles from a given volume around growing or evaporating drops is calculated on the basis of the theory of motion of moderately large nonvolatile aerosol particles in binary gas mixtures which are nonuniform in temperature and concentration.     

Laser-induced migration of oil particles suspended in a water matrix

The thermoconvective flow induced in oil samples and oil-in-water emulsions by irradiation with a laser beam is studied experimentally. The samples are irradiated by He-Ne and CO2 lasers at different power levels. Time-resolved records of temperature and surface waves that propagate in a liquid surface are presented. In laser-heated emulsions the thermoconvective flow leads the dispersed oil droplets to the water-free surface where they agglomerate to form a floating oil layer. The reflected light beam is formed by a speckle pattern whose intensity and contrast show a spiking, quasi-periodic time variation. A theoretical model is proposed to explain this phenomenon.     

Finite-difference time-domain solution of light scattering by dielectric particles with large complex refractive indices

The finite-difference time-domain (FDTD) technique is examined for its suitability for studying light scattering by highly refractive dielectric particles. It is found that, for particles with large complex refractive indices, the FDTD solution of light scattering is sensitive to the numerical treatments associated with the particle boundaries. Herein, appropriate treatments of the particle boundaries and related electric fields in the frequency domain are introduced and examined to improve the accuracy of the FDTD solutions. As a result, it is shown that, for a large complex refractive index of 7.1499 + 2.914i for particles with size parameters smaller than 6, the errors in extinction and absorption efficiencies from the FDTD method are generally less than ~4%. The errors in the scattering phase function are less than ~5%. We conclude that the present FDTD scheme with appropriate boundary treatments can provide a reliable solution for light scattering by nonspherical particles with large complex refractive indices.     

Geometrical optics calculation of inelastic scattering on large particles

A geometrical optics approximation was used for calculations of inelastic (Raman and fluorescent) scattering on particles with large size parameters. The inelastic part of the radiation was obtained by use of the principle of ray reversibility. The technique presented simplifies the computations and provides a geometric interpretation of how far-field patterns can be calculated by use of the internal field distributions. The numerical results for homogeneous spherical particles are compared with the classic dipole solution.     

Biomineralization of large hydroxyapatite particles using ovalbumin as biosurfactant

Hydroxyapatite (HA) is synthesized via a biomineralizing route by using ovalbumin as natural biosurfactant. The product material is characterized by means of X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and transmission electron microscopy (TEM). It shows that large HA spindle-like particles measured at 0.8 mm in length are aggregates from the needle-like nanocrystals. Furthermore, it is proved that there are superfluous positive charges on the surface of HA particles by using the electrophoretic method. It shows that the large particles are self-assembled from large amounts of HA nanocrystals with ovalbumin as biosurfactant. The interactions between ovalbumin and HA crystals have great effects on the formation of large HA particles and the positive charges on the surface of the particles.     

Preparation of mesoporous alumina particles by spray pyrolysis and application to double bond migration of 2-butene

The objective of the present study is to investigate the catalytic performance of mesoporous alumina that were prepared via spray pyrolysis for double bond migration from 2-butene to 1-butene. The mesoporous alumina particles were prepared via spray pyrolysis by changing the types of organic surfactants and Al precursors. The texture and acidic properties of mesoporous alumina were analyzed through N2 adsorption, SEM, ammonia-temperature programmed desorption, and FT-IR of adsorbed pyridine. The morphologies and texture properties of the mesoporous alumina were found to have been strongly influenced by the combination of the Al precursor and the structure-directing agents. The mesoporous alumina samples had two kinds of acidic sites: a Lewis acid site and a H-bonded weak acid site. 1-Butene was produced selectively through double bond migration of 2-butene over all of the mesoporous alumina catalysts. The catalyst prepared by using a chloride compound as an aluminium precursor and CTAC as a structure-directing agent showed the highest activity in the double bond migration of 2-butene, which was attributed to its large surface area and an overall high amount of acid sites.     

Integral light-scattering and absorption characteristics of large, nonspherical particles

We obtain and analyze simple analytical formulas for asymmetry parameters and absorption cross sections of large, nonspherical particles. The formulas are based on the asymptotic properties of these characteristics at strong and weak absorption of radiation inside particles. The absorption cross section depends on parameter phi, which determines the value of the light-absorption cross section for weakly absorbing particles. It is larger for nonspherical scatterers. The asymmetry parameter depends on two parameters. The first is the asymmetry parameter g(0) of a nonspherical, transparent particle with the same shape as an absorbing one. The second parameter, beta, determines the strength of the influence of light absorption on the value of the asymmetry parameter. Parameter beta is larger for nonspherical particles. One can find these three parameters (phi, g(0), and beta) using a ray-tracing code (RTC) for nonabsorbing and weakly absorbing particles. The RTC can then be used to check the accuracy of the equations at any absorption for hexagonal cylinders and spheroids. It is found that the error of computing the absorption cross section and 1 - g (g is the asymmetry parameter) is less than 20% at the refractive index of particles n = 1.333. Values for asymmetry parameters of large, nonabsorbing, spheroidal particles with different aspect ratios are tabulated for the first time to our knowledge. They do not depend on the size of particles and can serve as an independent check of the accuracy of T-matrix codes for large parameters.     

An experimental study on the influence of particles on grain boundary migration

The pinning effect of particles on grain boundary migration was studied in a Fe–20 mass% Cr alloy deoxidised with Ti and Zr. The different nitrogen contents (65, 248 and 490 ppm) were used to vary the number of precipitated inclusions. The specimens from equiaxed zones of metal samples with different particle densities were examined by in situ observations during a 60-min holding time at 1200 and 1400 °C in a Confocal Scanning Laser Microscope. The change of particles pinning effect on the grain growth was described by an average grain size, [`(D)]_textA bar{D}_{text{A}} , and the ratio between the perimeter and area of grains, P _GB/A _G. It was found that the pinning effect of particles (mostly complex Ti–Zr oxynitrides) on grain growth decreased with a decreased nitrogen content in the metal. Furthermore, the effect of particles decreased with an increased temperature of treatment, due to the reduction of the number of particles on the grain boundaries.