Experimental study on the external electrical thermal and dynamic power characteristics of alkaline water electrolyzer

As hydrogen production with a water electrolyzer is an effective way for renewable energy consumption, understanding the external electrical characteristics of water electrolyzer is of great significance for the modeling and simulation, system configuration, and control strategy of the system for hydrogen production by renewable energy. However, there are relatively fewer studies in this area. This paper presents the establishment of an experimental platform to conduct an experimental study on the static and dynamic voltage‐current characteristics and analyze the adjustability of the electric power of the traditional alkaline water electrolyzer, the relationship between the electrical characteristics and the electrolyte temperature, and operating point of the alkaline water electrolyzer. In addition, the mathematical fitting problem of the electrical characteristics of the alkaline water electrolyzer is discussed. The work could supply a reference to alkaline water electrolyzer intergrated application in renewable energy.     

Influence of wind turbine power curve and electrolyzer operating temperature on hydrogen production in wind-hydrogen systems

Current simulation tools used to analyze, design and size wind-hydrogen hybrid systems, have several common characteristics: all use manufacturer wind turbine power curve (obtained from UNE 61400-12) and always consider electrolyzer operating in nominal conditions (not taking into account the influence of thermal inertia and operating temperature in hydrogen production). This article analyzes the influence of these parameters. To do this, a mathematical wind turbine model, that represents the manufacturer power curve to the real behaviour of the equipment in a location, and a dynamic electrolyzer model are developed and validated. Additionally, hydrogen production in a wind-hydrogen system operating in “wind-balance” mode (adjusting electricity production and demand at every time step) is analyzed. Considering the input data used, it is demonstrated that current simulation tools present significant errors in calculations. When using the manufacturer wind turbine power curve: the electric energy produced by the wind turbine, and the annual hydrogen production in a wind-hydrogen system are overestimated by 25% and 33.6%, respectively, when they are compared with simulation results using mathematical models that better represent the real behaviour of the equipments. Besides, considering electrolyzer operating temperature constant and equal to nominal, hydrogen production is overestimated by 3%, when compared with the hydrogen production using a dynamic electrolyzer model.     

Modeling of hydrogen and electrical energy storages in wind/PV energy system on the Lake Baikal coast

The paper presents a research on a green power supply system (producing no carbon dioxide and other harmful emissions) in the area of Baikal Lake, for the maximum loads of 10 kW and 100 kW. The system includes photovoltaic converters, wind turbines, batteries for electric energy storage and a system for hydrogen production, storage and energy use. Calculations based on the optimization mathematical model demonstrated the efficiency of the combined use of wind and solar energy in the considered areas, as well as the simultaneous storage of electric energy and hydrogen. The electric energy storage is most efficient for short-term time intervals whereas an increase in the duration of continuous energy “standstills” up to several days makes the storage of hydrogen more cost-effective.     

The coupling factor: A new metric for determining and controlling the efficiency of solar photovoltaic power utilization

The production of electricity and hydrogen in a renewable fashion, such as using solar energy, can provide a clean and sustainable energy source for electric-powered vehicles, including fuel-cell and battery-electric vehicles. Our research on generating hydrogen and charging batteries using renewable solar photovoltaic (PV) electricity has led to the development of a simple and convenient new metric called the coupling factor that describes the fraction of the maximum PV power transferred to electrical loads. The keystone of the coupling factor concept is a regression model to calculate the maximum PV voltage, current, and power as a function of the instantaneous incident solar irradiance and the photovoltaic module temperature. The coupling factor can range from zero to one, i.e., no transfer of power from the PV system to the load, to complete transfer of the PV power. We describe the derivation of regression models to compute important PV electrical output variables, such as the open circuit voltage, the short circuit current, the maximum power point voltage, the maximum power point current, and the coupling factor as a function of the fundamental measured variables affecting those quantities. The models are derived for PV modules used in our previous research to power an electrolyzer and charge high-voltage batteries. In addition, we develop models for other modules using PV cell technologies different from those used in our PV system. Some of the calculated quantities are compared to measurements for our PV system. The usefulness of these quantities, and especially the coupling factor, in rating the transfer of PV power to electrolyzer and battery loads, is illustrated. Finally, we discuss how the predicted maximum power point voltage can be used for real-time control and efficiency optimization of a dynamic PV-load system.     

Simulation of the operation of a gas turbine installation of a thermal power plant with a hydrogen fuel production system

The growth in demand for the production of heat and electricity requires an increase in fuel consumption by power equipment. At the moment, the most demanded thermal equipment for construction and modernization is gas turbine units. Gas turbines can burn a variety of fuels (natural gas, synthesis gas, methane), but the main fuel is natural gas of various compositions. The use of alternative fuels makes it possible to reduce CO₂ and NO_x emissions during the operation of a gas turbine. Under conditions of operation of thermal power plants at the wholesale power market, it becomes probable that combined cycle power units, designed to carry base load, will start to operate in variable modes. Variable operation modes lead to a decrease in the efficiency of power equipment. One way to minimize or eliminate equipment unloading is to install an electrolysis unit to produce hydrogen.In this article the technology of “Power to gas” production with the necessary pressure at the outlet of 30 kgf/cm² (this pressure is necessary for stable operation of the fuel preparation system of the gas turbine) is considered. High cost of hydrogen fuel during production affects the final cost of heat and electric energy, therefore it is necessary to burn hydrogen in mixture with natural gas. Burning a mixture of 5% hydrogen fuel and 95% natural gas requires minimal changes in the design of the gas turbine, it is necessary to supplement the fuel preparation system (install a cleaning system, compression for hydrogen fuel). In addition, the produced hydrogen can be stored, transported to the consumer. For the possibility of combustion of a mixture of natural gas and hydrogen fuel in a gas turbine the methodology of calculation of thermodynamic properties of working bodies developed by a team of authors under the guidance of Academician RAS (the Russian Academy of Sciences) V.E. Alemasov has been adapted, resulting in a program that allows to obtain an adequate mathematical model of the gas turbine. The permissible range of the working body temperature is limited to 3000 K. This paper presents the developed all-mode mathematical model of a gas turbine.On the basis of mathematical modeling of a gas turbine, a change in the main energy and environmental characteristics is shown depending on the composition of the fuel gas. Adding 5% hydrogen to natural gas has little effect on the gas turbine air treatment system, the flow rate remains virtually unchanged. CO₂ emissions decrease, but there is an increase in the amount of H₂O in the turbine exhaust gases.     

Continuous operation in an electric and hydrogen hybrid energy storage system for renewable power generation and autonomous emergency power supply

Under the background of extensive improvement of renewable resources and demand for reliable emergency power supply, we proposed a hybrid energy storage system including an electric double-layer capacitor bank and a hydrogen system which is composed of fuel cell, electrolyzer, gas tank and metal hydride tank. Through its integration with photovoltaic power sources in a local direct current grid, we expect to obtain both of stable energy source at ordinary times and long-time reliable autonomous emergency power supply when outages happen. A three-day demonstration of the proposed system was performed. The fluctuation compensation performance of the components and the long-time stable power supply obtained by the entire system were evaluated at first, hence the configuration and the management methods of the proposed system were verified in the autonomous emergency power supply application. Meanwhile, the performance of the hybrid use of the gas tank and the metal hydride tank in the system was preliminarily evaluated, for its effectiveness verification on reducing auxiliary power for temperature condition of the metal hydride tank. Moreover, we investigated the distribution characteristics of the power and energy loss in the electric double-layer capacitor, electrolyzer and fuel cell, and their correlation to the efficiency characteristics under different conditions during the operation. The investigation results showed that the continual low-load-ratio state of the electrolyzer and fuel cell led to the low efficiency, the rare high-power occurrence of the electrolyzer and fuel cell led their demanded excessive power capacity. Thus, we proposed a solution method of shifting the electrolyzer and fuel cell's load to the EDLC, when the electrolyzer and fuel cell are in low-load-ratio and excessive high-power state, in order for efficiency increase and facility capacity reduction.     

Increasing the stability of hydrogen production in the wind energy-hydrogen system through the use of synthetic inertia of the wind turbine

One of the trends in the development of the electric power industry in the world is the use of renewable resources. In recent years, the development of hydrogen energy has been widely discussed, which, when combined with renewable energy sources, makes it possible to obtain “green” hydrogen. One of the promising solutions for obtaining green hydrogen is the development of wind energy-hydrogen systems. However, one of the limiting factors, in addition to economic aspects, are technical limitations. Sustainable hydrogen production is complicated by the variability of wind energy. In addition, energy systems with a predominant share of wind power units have a low total inertia value. Consequently, such systems become more sensitive to changes in load modes in the grid and become less stable in emergency modes. Together, these facts reduce the reliability of wind energy-hydrogen system. The paper proposes to increase the stability of wind energy-hydrogen system and power system as a whole to apply synthetic inertia for wind power plants. It is shown that by adjusting the parameters of synthetic inertia can provide not only the required inertial response, but also increase the dynamic stability of the power system and as a consequence wind energy-hydrogen system. The influence of the measurement window time and calculation of the frequency change rate, which is important in certain modes, is also investigated.     

开关磁阻风电制氢动力传动系统机电耦合动力学分析

为揭示开关磁阻风电制氢动力传动系统的机电耦合作用规律,考虑齿轮系统的详细特性和制氢装置非线性物理细节以及发电机电磁特性,建立包含风轮、齿轮传动系统、开关磁阻发电机、制氢装置的开关磁阻风电制氢动力传动系统机电耦合动力学模型,仿真分析变风况下系统的能量流、机电耦合动力学特性以及并联电解槽数量对系统动态特性的影响.结果表明:...     

On the economics of a hydrogen bus fleet powered by a wind park – A case study for Austria

This paper investigates the economics of a fuel cell bus fleet powered by hydrogen produced from electricity generated by a wind park in Austria. The main research question is to simultaneously identify the most economical hydrogen generation business model for the electric utility owning wind power plants and to evaluate the economics of operating a fuel cell bus fleet, with the core objective to minimize the total costs of the overall fuel supply (hydrogen production) and use (bus and operation) system. For that, three possible operation modes of the electrolyzer have been identified and the resulting hydrogen production costs calculated. Furthermore, an in-depth economic analysis of the fuel cell buses as well as the electrolyzer technology has been conducted. Results show that investment costs are the largest cost factor for both technologies. Thus, continuous hydrogen production with the smallest possible electrolyzer is the economically most favorable option. In such an operation mode (power grid), the costs of production per kg/H₂ were the lowest. However, this means that the electrolyzer cannot be solely operated with electricity from the wind park, but is also dependent on the electricity mix from the grid. For fuel cell buses, the future cost development will depend very much on the respective policies and funding programs for the market uptake, as to date, the total cost of use for the fuel cell bus is more than two times higher than the diesel bus. The major final conclusion of this paper is that to make fuel cell electric busses competitive in the next years today severe policy interferences, such as subsidies for these busses as well as electrolyzers and bans for fossil energy, along with investments in the setup of a hydrogen infrastructure, are necessary.     

Predicting efficiency of solar powered hydrogen generation using photovoltaic-electrolysis devices

Hydrogen fuel for fuel cell vehicles can be produced by using solar electric energy from photovoltaic (PV) modules for the electrolysis of water without emitting carbon dioxide or requiring fossil fuels. In the past, this renewable means of hydrogen production has suffered from low efficiency (2–6%), which increased the area of the PV array required and therefore, the cost of generating hydrogen. A comprehensive mathematical model was developed that can predict the efficiency of a PV-electrolyzer combination based on operating parameters including voltage, current, temperature, and gas output pressure. This model has been used to design optimized PV-electrolyzer systems with maximum solar energy to hydrogen efficiency. In this research, the electrical efficiency of the PV-electrolysis system was increased by matching the maximum power output and voltage of the photovoltaics to the operating voltage of a proton exchange membrane (PEM) electrolyzer, and optimizing the effects of electrolyzer operating current, and temperature. The operating temperature of the PV modules was also an important factor studied in this research to increase efficiency. The optimized PV-electrolysis system increased the hydrogen generation efficiency to 12.4% for a solar powered PV-PEM electrolyzer that could supply enough hydrogen to operate a fuel cell vehicle.     

Mathematical modelling of coupled and decoupled water electrolysis systems based on existing theoretical and experimental studies

Since it has the potential to significantly reduce gaseous emissions in the near future, electrolytic hydrogen production using electricity generated from renewable energy sources, such as solar radiation, is key. Water splitting processes occurring in electrolyzer cells are complex phenomena. Therefore, to fully realize such processes, different technologies have been accounted for. The focus of this work is on the mathematical modeling of three different electrolyzer cells related technologies, (i) alkaline, (ii) proton exchange membrane (PEM), and (iii) decoupled water splitting. Accordingly, several existing mathematical models for alkaline and PEM electrolyzers are initially revised. Next, a comprehensive mathematical model capable of properly predicting the performance of the three electrolyzer technologies accounted for here is proposed. The developed mathematical models are then used to predict the behavior of electrolyzer cells under different operation conditions. The obtained results are finally compared in terms of cell voltages, cell efficiencies, and hydrogen production rates. When compared to other results available in the literature, the cell voltage ones obtained using the new proposed model are in relatively good agreement. Specifically, for a current density range of 0–200 mA/cm², cell pressures between 10 and 40 bar, and a cell temperature of 60 °C, cell voltage requirements are between 1.25 and 1.75 V, with the E-TAC technology performing better than the other two ones accounted for. In addition, for current densities of more than 100 mA/cm² and cell pressures below 5 bar, Faraday's efficiencies are almost the same for all three technologies, i.e., about 95%. However, for higher cell pressures, significant differences in Faraday's efficiency appear. Based on the work carried out, it is concluded that developing a sound mathematical model is crucial both for the comprehension of coupled and decoupled water electrolysis-related processes and for their use in the simplest and most reliable way.     

Design of a solar hydrogen refuelling station following the development of the first Croatian fuel cell powered bicycle to boost hydrogen urban mobility

Hydrogen refuelling stations are important for achieving sustainable hydrogen economy in low carbon transport and fuel cell electric vehicles. The solution presented in this paper provides us with a technology for producing carbon dioxide free hydrogen, which is an approach that goes beyond the existing large-scale hydrogen production technologies that use fossil fuel reforming. Hence, the main goal of this work was to design a hydrogen refuelling station to secure the autonomy of a hydrogen powered bicycle. The bicycle hydrogen system is equipped with a proton exchange membrane fuel cell stack of 300 W, a DC/DC converter, and a metal hydride storage tank of 350 NL of hydrogen. The hydrogen power system was made of readily available commercial components. The hydrogen station was designed as an off-grid system in which the installed proton exchange membrane electrolyzer is supplied with electric energy by direct conversion using photovoltaic cells. With the hydrogen flow rate of 2000 cc min⁻¹ the hydrogen station is expected to supply at least 5 bicycles to be used in 20 km long city tourist routes.     

基于新能源发电的电解水制氢直流电源研究

利用新能源发电进行电解水制氢是实现新能源就地消纳和氢能利用的重要途径,以匹配电解水制氢工作特性的制氢电源为研究对象,通过分析质子交换膜电解槽电解电流、温度与电解槽端口电压、能量效率、制氢速度之间的关系,得出制氢电源需具备输出低电流纹波、输出大电流、宽范围电压输出的特性。为满足新能源电解制氢系统需求,提出一种基于Y型三相交错并联LLC拓扑结构的制氢电源方案,该方案谐振腔三相交错并联输出,满足电解槽大电流低纹波工作特性,并采用脉冲频率控制实现谐振软开关,提高变换效率。最后,搭建仿真模型和6 kW模块化实验样机,验证所提出方案的合理性与可行性。     

Hybrid energy system for hydrogen production in the Adrar region (Algeria): Production rate and purity level

The following work treat the prediction of the production rate and purity level of hydrogen produced by an alkaline electrolyzer fed by a renewable source in a hybrid energy system HES in the locality of Adrar in the south of Algeria. This work is made for different renewable energy penetration rate from 0% to 60% of conventional power (Genset generator). The cell electrolyzer model permits to predict the production rate of hydrogen with accuracy, according to operating parameters, climatic conditions and the load of the site of Adrar. The study permits to introduce a model of hydrogen purity level based on the operating parameters and the power supplying the alkaline electrolyzer. It also shows that the great influence of the intermittent energy supplying the electrolyzer on the production rate and purity level of hydrogen. The prediction of production rate and purity level by the models allow to obtain a distribution and storage of hydrogen produced according to predetermined selection criteria imposed by the operator.In the process of electrolysis, the oxygen is considered as by-product of the hydrogen production. The amount and purity level were estimated jointly.An HES-H₂ production program under MATLAB^®/SIMULINK^® has been developed to simulate the hourly evolution of the production rate and purity level of hydrogen and oxygen produced by an electrolyzer for different penetration rate of renewable energies in an HES.     

考虑多变量因素影响的光伏PEM制氢系统建模与分析

针对复杂工况对光伏制氢系统性能产生不确定性的影响,提出考虑多变量因素影响的光伏制氢系统模型,探索辐照度、温度、膜厚、压力等因素对光伏质子交换膜（PEM）制氢系统的影响。系统首先建立考虑辐照度、温度、膜厚、压力等因素影响的光伏-质子交换膜电解槽-氢储罐的光伏制氢模型,之后对系统进行定量计算和定性分析,并依据实际光伏数据进行实验验证。结果表明,在额定功率范围内,太阳电池输出电流和功率随辐照度的增加而增大,随温度的升高而降低。质子交换膜电解槽电压随辐照度、膜厚、压力的增加而增大,随温度的升高而减小。太阳电池输出功率、质子交换膜电解槽电压的变化趋势与辐照度变化趋势具有一致性。最终计算得到太阳电池系统、质子交换膜电解槽系统和总系统效率分别为16.8%、72.2%和12.1%。     

Technico-economic analysis of off grid solar PV/Fuel cell energy system for residential community in desert region

A technico-economic analysis based on integrated modeling, simulation, and optimization approach is used in this study to design an off grid hybrid solar PV/Fuel Cell power system. The main objective is to optimize the design and develop dispatch control strategies of the standalone hybrid renewable power system to meet the desired electric load of a residential community located in a desert region. The effects of temperature and dust accumulation on the solar PV panels on the design and performance of the hybrid power system in a desert region is investigated. The goal of the proposed off-grid hybrid renewable energy system is to increase the penetration of renewable energy in the energy mix, reduce the greenhouse gas emissions from fossil fuel combustion, and lower the cost of energy from the power systems. Simulation, modeling, optimization and dispatch control strategies were used in this study to determine the performance and the cost of the proposed hybrid renewable power system. The simulation results show that the distributed power generation using solar PV and Fuel Cell energy systems integrated with an electrolyzer for hydrogen production and using cycle charging dispatch control strategy (the fuel cell will operate to meet the AC primary load and the surplus of electrical power is used to run the electrolyzer) offers the best performance. The hybrid power system was designed to meet the energy demand of 4500 kWh/day of the residential community (150 houses). The total power production from the distributed hybrid energy system was 52% from the solar PV, and 48% from the fuel cell. From the total electricity generated from the photovoltaic hydrogen fuel cell hybrid system, 80.70% is used to meet all the AC load of the residential community with negligible unmet AC primary load (0.08%), 14.08% is the input DC power for the electrolyzer for hydrogen production, 3.30% are the losses in the DC/AC inverter, and 1.84% is the excess power (dumped energy). The proposed off-grid hybrid renewable power system has 40.2% renewable fraction, is economically viable with a levelized cost of energy of 145 $/MWh and is environmentally friendly (zero carbon dioxide emissions during the electricity generation from the solar PV and Fuel Cell hybrid power system).     

Optimized photovoltiac system for hydrogen production

Hydrogen, which can be produced by water electrolysis, can play an important role as an alternative to conventional fuels. It is regarded as a potential future energy carrier. Photovoltaic arrays can be used in supplying the water electrolysis systems by their energy requirements. The use of photovoltaic energy in such systems is very suitable where the solar hydrogen energy systems are considered one of the cleanest hydrogen production technologies, where the hydrogen is obtained from sunlight by directly connecting the photovoltaic arrays and the hydrogen generator. This paper presents a small PV power system for hydrogen production using the photovoltaic module connected to the hydrogen electrolyzer with and without maximum power point tracker. The experimental results developed good results for hydrogen production flow rates, in the case of using maximum power point tracker with respect to the directly connected electrolyzer to the photovoltaic modules.     

The economic analysis for hydrogen production cost towards electrolyzer technologies: Current and future competitiveness

Hydrogen production by electrolysis technology spurs as extensive investigation toward new clear energy acquisition. The mainstream hydrogen production electrolyzers, including alkaline electrolyzer (ALK), anion exchange membrane electrolyzer (AEM), and proton exchange membrane electrolyzer (PEM), are traced to compare their current and future hydrogen production cost regarding technology development. Technologies' characteristics are originally described as the polarization curve parameters such as current density, overpotential, and polarization curve slope. The feature of crucial materials such as catalysts and membranes are also taken into consideration. Then, a bottom-up hydrogen production cost prediction model stemming from technical factors is established with a combination of manufacturing and operating considerations. According to model predictions, the cost of hydrogen production of ALK will be 23.85% and 51.59% lower than AEM and PEM technologies in the short term. However, under technological advancement or breakthrough, the hydrogen production cost of AEM and PEM is expected to be 24% and 56.5% lower in the medium-term and long-term, respectively. The lifetime of the electrolyzers is significantly vital to affect the cost of hydrogen production. The cost reduction space brought about by various technical factors is also explored for the blueprint planning of the hydrogen economy.     

基于链式分配策略的风氢耦合系统设计与控制

针对风力发电“弃风”电量耦合制氢问题,提出一种基于链式分配策略的风氢耦合系统。首先建立能表征弃风电量与质子交换膜电解槽主要特性的风氢耦合拓扑电路结构,围绕高降压比交错Buck变换器及其控制方法构建风氢耦合系统,并提出多堆质子交换膜电解槽风氢耦合系统链式功率分配策略。最后通过算例仿真验证该系统可提升弃风利用率和系统可靠性,可有效解决弃风电量水电解制氢耦合控制与功率分配问题。     

Algorithm for calculation and selection of micro hydropower plant taking into account hydrological parameters of small watercourses mountain rivers of Central Asia

Tajikistan and Kyrgyzstan are the two countries in Central Asia that have a huge reserve of hydro resources of the region. It is important to recognize the significance of the part played by the micro-hydropower plants (HPP) in the electric power generation in Tajikistan and Kyrgyzstan from the point of view of sustainable economic development. After all, the construction of micro-HPPs in mountainous areas will reliably ensure the development of small and medium-sized enterprises in the field of agriculture and livestock, industry, tourism, improve the social conditions of the population, as well as ensure the production of “green” hydrogen, which will contribute to the development of an environmentally friendly transport system in the regions. Micro HPPs gained recognition as a good alternative to traditional power generation for many developing countries around the world.This study presents a structural model and methodology of choice of a feasible type of micro HPP using the developed algorithm for calculation of hydro turbines’ characteristics based on the hydrological characteristics of small and shallow watercourses located in Central Asian countries, such as Kyrgyzstan and Tajikistan. Based on this model, the software “Calculation and choosing the type of hydro turbines for micro HPPs” has been developed. Depending on the load, a consumer can choose one of the suggested types of micro-hydroelectric power plants to meet his requirements. When choosing the type of micro-hydroelectric power station, a consumer should also take into account the factor of the seasonality of the water level, the constancy and speed of the water, and the volume of river water, since in some places the water freezes in winter.