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石墨/二硫化钼/丁腈橡胶复合材料的性能 总被引:1,自引:0,他引:1
采用机械共混法制备了石墨/二硫化钼(MoS2)/丁腈橡胶(NBR)复合材料,考察了石墨和MoS2用量对复合材料物理机械性能及摩擦性能的影响,并用扫描电子显微镜表征了填料在橡胶基体中的分散情况。结果表明,石墨/MoS2/NBR复合材料的拉伸强度、撕裂强度和邵尔A硬度均高于石墨/NBR复合材料和MoS2/NBR复合材料,当添加10份石墨和7份MoS2时,复合材料的物理机械性能最佳,且填料在橡胶基体中的分散性最好,摩擦因数达到最小值0.7。 相似文献
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本文选用双-(γ-三乙氧基硅基丙基)四硫化物(Si-69)为改性剂,利用球磨法制备了接枝改性白炭黑。利用热失重法(TG)分析了改性剂用量和改性时间等因素对接枝率的影响。将改性白炭黑用于天然橡胶(NR)/ 反式聚异戊二烯(TPI)的补强中,比较了未改性白炭黑和改性白炭黑对胶料的硫化性能、物理机械性能和动态性能等的影响。结果表明,在0~12份范围内,改性剂用量越大,白炭黑接枝率越高,但综合物理机械性能最佳值则出现在改性剂用量为10份时。在15~45 min范围内,改性时间对白炭黑接枝率影响不明显,但当改性时间为45 min时,综合物理机械性能最佳。白炭黑经接枝改性后改善了其在橡胶基体中的分散性和与橡胶基体的相容性,添加改性白炭黑胶料的抗湿滑性能、滚动阻力和动态生热性能均有改善。 相似文献
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石墨/铜粉改善双马来酰亚胺复合材料摩擦性能 总被引:1,自引:0,他引:1
采用层压成型制备了2类改性双马来酰亚胺纤维复合材料,分别考察了石墨、铜粉的用量对纤维复合材料摩擦性能(摩擦系数,磨损率)和力学性能的影响,并用扫描电镜对复合材料的磨损表面形貌进行了分析。结果表明:石墨对改善双马来酰亚胺的摩擦磨损性能较铜粉更有效。石墨的质量分数为3%时,复合材料的摩擦磨损性能和力学性能达到最佳。 相似文献
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采用大分子表面处理剂LMPB-g-KH570对纳米Si_3N_4表面进行修饰。利用共混技术制备了纳米Si_3N_4/ACM复合材料。利用RPA-8000、SEM、TEM等测试技术,对纳米复合材料的微观结构和性能进行了分析和评价。结果表明,大分子表面改性剂能有效改善复合材料的微观界面结构,促进纳米Si_3N_4在橡胶基体中的有效分散,橡胶硫化性能得到改善,力学性能得到提高。添加2.0份改性纳米Si_3N_4/ACM复合材料,胶料正硫化时间减少38 s,拉伸强度提高24.8%,撕裂强度提高3.39%。 相似文献
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磷石膏晶须表面改性及其在PP中初步应用 总被引:1,自引:0,他引:1
采用硅烷偶联剂KH570对磷石膏晶须进行超声波表面改性。考察了改性时间、改性温度、改性剂用量等条件对磷石膏晶须的表面改性影响。并分析了KH570对磷石膏晶须改性作用机理。结果表明:当KH570的用量为磷石膏晶须质量的5%,改性时间为80 min,改性温度在50℃时,获得最佳的改性效果。由红外光谱分析可知磷石膏晶须表面羟基与KH570发生了化学键的作用。改性的磷石膏晶须/PP复合材料的相容性较好,复合材料力学性能较纯PP材料有所提高。 相似文献
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《Ceramics International》2020,46(9):13695-13703
Manganese–copper ferrite (MCFO) and dysprosium (Dy)-doped manganese–copper ferrite nanocomposites (Mn0.5Cu0.5DyxFe2−xO4) (x = 0, 0.05, 0.10, and 0.15) were synthesized by sonochemical method. Crystal structure and the structural parameters of the MCFO were analyzed based on the doping concentration of Dy ion. It was observed that the average crystalline size of the synthesized nanocomposite decreases when the concentration of Dy increases. The existing spherical surface morphology of the MCFO and Dy-doped MCFO nanocomposites were obtained through scanning electron microscopy. In the UV spectrum, the pristine MCFO sample showed an absorbance peak at 743 nm whereas the absorbance values of Dy-doped ferrite nanocomposite considerably shifted (blue) toward a lower wavelength (231–222 nm). The dielectric parameters of all ferrite nanocomposites were studied in the frequency range of 100 Hz to 5 MHz. The dielectric spectrum revealed that dielectric constant and loss tangent decreased with increased doping concentration of Dy ion. The saturation magnetization also changed with Dy doping in MCFO. The impact of Dy on manganese–copper ferrite changed the optical, dielectric and magnetic properties of the prepared binary ferrite nanocomposite, which can be used for microwave-absorbing material applications. 相似文献
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E. S. Zainudin S. M. Sapuan K. Abdan M. T. M. Mohamad 《Polymer-Plastics Technology and Engineering》2013,52(1):97-101
Mechanical strengths of a banana pseudo-stem (BPS) fiber and unplasticized polyvinyl chloride (UPVC) composite were evaluated to assess the possibility of using it as a new material in engineering applications. Samples were fabricated by the compression molding process with reference to the effect of filler loading. The samples were submitted to mechanical tests to measure tensile, flexural, and impact properties of the composites. The nature of adhesion between the matrix and the reinforcement and information relating the structure of mechanical properties can be obtained by scanning electron microscopy (SEM) assessment of the composite fracture surface. The mechanical properties show that the composites did not have good adhesion between filler and matrix; on the other hand, the filler insertion improved the flexural modulus and the material rigidity. 相似文献
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核壳纳米粒子作为复合纳米粒子一个重要的分支,由于其光、磁和催化等方面的优异性能,近年来引起了人们广泛的关注.本文主要介绍了核壳纳米粒子的制备方法及诸多性能,并对核壳纳米粒子的发展进行了展望. 相似文献
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王丽 《合成材料老化与应用》2014,(4):15-17
分别以聚四氢呋喃醚二醇(PTMEG)、聚氧化丙烯二醇(PPG-1000)为软段,以二苯基甲烷二异氰酸酯(MDI-50、MDI-100LL),以及扩链剂1,4-丁二醇(BDO)、三羟甲基丙烷(TMP)为硬段,采用预聚体法制备了聚氨酯弹性体。并系统研究了聚氨酯体系中各组分的种类对材料机械性能和阻尼性能的影响。 相似文献
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《Ceramics International》2020,46(2):1974-1981
Nowadays, complicated preparation processes and harsh sintering conditions wave transparent ceramics limit its further development. To solve this problem, we explore a promising precursor by adopting a polymerization-pyrolysis method to prepare porous Si–Al–O–B ceramics at a mild sintering condition (1000 °C). The porous Si–Al–O–B ceramics exhibits enhanced wave transparency at 10–16 GHz with a low dielectric constant (<3), a low loss angle tangent value (<0.01), and simultaneously, a relative high flexible strength of 82 MPa. According to the results of the XRD and FTIR analysis, porous Al4B2O9 crystallization dispersed in the amorphous SiO2 matrix constructs the main phases of the products. The changes of Al and B elements are confirmed to have an effect on the phase compositions and micro structure of the composite ceramics, which obviously affect the mechanical and dielectric properties of the derived ceramics. The as-prepared porous Si–Al–O–B ceramics could be a potential candidate for next generation electronic window materials due to its low dielectric constant and loss angle tangent value, as well as high flexible strength. 相似文献
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Effects of support and additive on oxidation state and activity of Pt catalyst in propane combustion 总被引:1,自引:0,他引:1
The effects of support and additive on the oxidation state and catalytic activity of Pt catalyst in the low temperature propane combustion were systematically investigated on Pt/MgO, Pt/Al2O3 and Pt/SiO2–Al2O3. The catalytic activity varied much with both support materials and additives. The catalyst on the more acidic support showed higher activity, and the catalytic activity on every support materials increased as the electronegativity of additives increased, while some additives decreased the activity. The oxidation state of platinum, estimated by white line intensity of Pt LIII-edge XANES spectrum, also varied with the support and additives, and additives with higher electronegativity greatly prevented the platinum from its oxidation under oxidising atmosphere. Among almost all the catalysts with various supports and various additives, a clear relationship was observed between the oxidation state of platinum and the catalytic activity; the more metallic platinum showed higher activity. Thus, it was concluded that the total electrophilic/electrophobic property derived from those of the support and additive controls the oxidation state of platinum, which intensively affects the catalytic activity; i.e. higher electrophilic property provides less oxidised platinum, resulting in high catalytic activity. The mechanism of this effect was also discussed on the basis of thermochemical data, and it was proposed that the electrophobic materials promote the noble metal oxidation since the noble metal oxo-anion such as PtOδ− is more stabilised with electrophobic cation. 相似文献