Magnetic shielding using high-temperature superconductors

Magnetic shields of various high-temperature superconductors, YBa₂Cu₃O_7−x (YBCO), YBa₂Cu₃O_7−x -Ag composites (random inclusions as well as non-random coatings) and Bi₂Sr₂Ca₂Cu₃O _x (BSCCO) were prepared by uniaxial as well as isostatic compression with various dimensions. The shielding properties were measured at 77 K for dc and ac magnetic fields in the range of frequencies from 100 Hz to 10 kHz. The critical penetration field (CPF), defined as the value of the applied magnetic field at which a detectable field was observed inside the cylinder, varied from cylinder to cylinder and also with the ageing of the cylinders in the case of YBCO shields. The highest value of CPF was 16 G at 77 K for YBCO shield prepared by isostatic compression. Even though the stability of BSCCO shields with respect to ageing is good, the CPF values are very low compared to those for YBCO. Detailed studies were performed in the case of YBCO shields. The CPF decreased as a function of time over a period of 90 days. The CPF decreased as the frequency of the applied field was increased. The wave form of the field inside the pot for a sinusoidal applied field was highly distorted and showed the presence of higher harmonics with appreciable amplitude. The wave form was Fourier-analysed to yield the field inside the shield along with the harmonics. The shields with Ag addition seem to give better performance at high fields.     

High-capacity superconducting current leads of Y1Ba2Cu3O7?x

We have fabricated and measured a high-capacity superconducting current lead composed of a Y₁Ba₂Cu₃O_7–x cylinder, 20 cm long and 0.9 cm² cross section. A steady-state, d.c., critical current of 225 A at a temperature of 77 K was measured in this sample, using a voltage criterion of 2×10^–7 V/cm (p = 8×10^–10 ohm-cm). This current was limited by the currentinduced, self magnetic field. To our knowledge this is the largest d.c. critical current so far reported in a Y₁Ba₂Cu₃O_7–x sample and demonstrates the possibility of using hightemperature superconducting HTS materials for current leads to low-temperature superconducting LTS magnets or in power distribution systems.     

Magnetic field enhancement of high-Tc superconducting pancake coils by Mu metal sheets

High permeability ring-shaped mu metal sheets have been used to enhance magnetic fields in the bore of Bi-based high-T _c superconducting coils. The central magnetic fieldB ₀, generated by pancake coils placed between mu metal sheets, was measured at liquid nitrogen temperature 77 K. The increasing rate (IR) of the central magnetic fieldB ₀ for single pancake coils was from 15 to 63% by using a 0.1 mm thick mu metal sheet. IR was decreased when the originalB ₀ value increased. The thickness of mu metal sheets also affected IR. It was found that IR increased as the number of mu metal sheets was increased. In a test double-pancake coil IR reached 101%,B ₀ was enhanced from 902 to 1815 G, when the total thickness of mu metal sheets on the top and bottom surface of the coil was 2.0 mm. These results indicate that the well-designed high-permeability materials can significantly enhance the magnetic fields generated by high-T _c superconducting coils and magnets.     

Superconductivity and Ferromagnetism of the Ru-1232 Compounds in the (Ru1?xNbx)Sr2(GdCe1.8Sr0.2)Cu2Oz System

The Ru-1232 compounds have been synthesized in the (Ru_1–xNb _x )Sr₂(GdCe_1.8Sr_0.2)Cu₂O _z system, and effects of Nb substitution for Ru on superconductivity and ferromagnetism of the Ru-1232 compounds have been investigated. First, X-ray powder diffraction study shows that nearly the single 1232 phase samples can be obtained in the x composition range from 0.0 to 0.3. Then, from the electrical resistivity study, it is found that each of the samples shows resistivity dropping phenomenon at two temperatures of T _c ^l and T _c ^h, which originates from superconductivity of the Ru-1232 phase and the Ru-1222 one, respectively. Both of the starting temperatures are lowering with increasing Nb content x. Lastly, from the magnetic susceptibility study, it is found that superconducting transition temperature T _c is 20 K for the Ru-1232 sample with x = 0.0 and the ferromagnetic transition temperature T _m is about 90 K. This study also shows that both of the values of T _c and T _m become low with increasing x from 0.0 to 0.3.     

Superconductivity in Na-doped Bi2Sr2CaCu2O y system

Samples with the nominal composition Bi₂Sr₂Ca_1−x Na _x Cu₂O _y (x=0, 0·1, 0·2 and 0·3) were prepared by solid-state reaction of the individual compounds. X-ray diffraction patterns indicate that the samples have a majority 2212 phase with 2223 also being present. From the DC four-probe resistance data, we have observed that the furnace-cooled samples show metallic behaviour while the quenched samples show superconductivity up to 97 K.     

Superconductivity at 103 K in CdBa2(Ca0.7Y0.3)Cu2Oy

A cadmium analogue of the mercury system with nominal composition CdBa₂(Ca_1–xY_x)Cu₂O_y has been synthesized. Thex=0 samples contain about 12 vol.% of the 1212 phase but are not superconducting. Thex=0.3 samples are superconducting atT _on = 103 K. The EDX analysis of 18 microcrystals shows a broad cationic distribution of the different components. The observed broad superconducting transition is attributed to the variousT _c of the different microcrystals.     

Investigation of Magneto-Resistance Behavior in High Pulsed Magnetic Fields up to 35 T of YBa2Cu3O x and YBa2Cu3O x (5% Ag-doped) Thick Films Near 77 K

We investigated the influence of pulsed magnetic fields of up to 35 T on thick film samples of YBa₂Cu₃O _x (x<6.8) and YBa₂Cu₃O _x (5% Ag-doped), produced from powders on which electromagnetic separation had been performed. It was discovered, that subjecting the thick film samples of YBa₂Cu₃O _x to 10 pulses of a cyclic pulsed magnetic field of 32 T had the effect of significantly increasing T _c . The films had an oxygen deficit of 6.6–6.8%. Initially, T _c was 74 K. After the treatments by the strong pulses of magnetic fields, T _c had increased to 80 K. On the other hand, in YBa₂Cu₃O _x (5% Ag), the processing by strong pulsed magnetic fields will lead to dynamic mechanic stresses, which will increase the amount of tetragonal phases and lead to a lower temperature of the superconductivity transition.     

Nano Fe<Subscript>3</Subscript>O<Subscript>4</Subscript> Induced Fluxoid Jumps and Low Field Enhanced Critical Current Density in MgB<Subscript>2</Subscript> Superconductor

Nano particle of Fe₃O₄ (nFe₃O₄) up to 6 at% were doped in the superconducting MgB₂ samples. Despite the strong ferromagnetic nature of Fe₃O₄, both the ac susceptibility and the resistivity measurements show that up to 4 at% of Fe₃O₄, T _c =38 K is not changed, whereas for 6% T _c decreases by 6 K. This indicates that a low concentration of Fe does not substitute either the Mg or B sites and probably occupies the intergrain spaces. For 0.5% doped Fe₃O₄, an increase in J _c with respect to the pure MgB₂ samples is observed in the lower field and temperature regions (H<2 T and 20 K) indicating an enhanced flux pinning and the magnetic activation, i.e., the interaction between the magnetic dipole of Fe ion and the vortices is weak in comparison to the effective pinning potential. Whereas, at H>2 T, J _c of the doped samples is always less than that of MgB₂, and the activation is dominant in comparison with the effective pinning potential provided by the doping. Flux jumps are observed in lower T and H regions for the samples doped up to 1% nFe₃O₄ only. Magnetization plots of higher Fe content samples exhibited clear paramagnetic background. Mossbauer measurements for the higher (4, 6 at%) nFe₃O₄ doped MgB₂ samples show that at RT, the hyperfine field for both samples is ∼100 kOe and ∼120 kOe at 90 K. This means that the nFe₃O₄ particles decompose and form possibly an intermetallic Fe-B phase in the matrix.     

Superconductivity of Ba1 ? xKxBiO3 (0.35 < x < 1) Synthesized by the High Pressure and High Temperature Technique

Ba_{1 – x} K _x BiO₃ (BKBO) samples with 0.35 < x < 1 were synthesized by the high pressure and high temperature technique. XRD analysis showed that the BKBO samples were single phase for the whole range of the potassium doping concentration. The change of superconducting transition temperature, T _c, as well as lattice parameters have been investigated upon doping concentration. As the K doping concentration (x) increases from x = 0.37, T _c decreases from 30.4 K to almost zero at x = 0.74. However, in some BKBO samples without including any barium in the starting composition (x = 1), which is denoted as KBO samples, superconductivity is observed with T _c as high as 9 K with partial substitutions of Bi at the K site. Depending on the synthesis condition of the KBO samples, T _c and lattice parameters were different from sample to sample. Compared with other superconducting bismuthates, the evolution of T _c by potassium doping in the cubic BKBO system is discussed in terms of its electronic band structure.     

Film thickness dependence of critical current density for YBa2Cu3O7 films post-annealed at a low oxygen partial pressure

The variation of critical current density at 77 K as a function of film thickness was studied for YBa₂Cu₃O₇ films on (100) LaAlO₃ substrates. Film thicknesses were in the range 0.2–1.6m. The films were deposited by co-evaporation and post-annealed under conditions which have previously resulted in high-quality films (750°C and an oxygen partial pressure of 29 Pa). The critical current density at 77 K exceeds 1 MA cm^–2 for the thinner films, and decreases with increasing film thickness in excess of about 0.4m. The decrease is in rough agreement with a switch fromc-axis toa-axis growth at about this critical thickness. A good anticorrelation was found between room temperature resistivity and critical current density at 77 K. The results are compared to those obtained before by post-annealing at 850°C in 1 atm of oxygen.     

Finite Ferromagnetic Clusters La1?xZnxMnO3 (x = 0.05 and 0.10)

Detailed magnetic and nonlinear susceptibility measurements of the La_1–x Zn _x MnO₃ system are reported. For x = 0.05 and 0.1, a typical ferromagnetic (FM) signal in the field-cooled curve is observed at 38 K. However, for the insulating antiferromagnetic (AFM) parent compound LaMnO₃ and for the x = 0.2 and 0.33 samples, the magnetization curves in the low temperature range, are smooth and flat. This observation confirms the coexistence of finite FM clusters in the insulating AFM region below the critical concentration (x _c = 0.16) for percolation, predicted by the percolation model.     

Anomalous Reentrant Resistance Phenomena in Superconducting Sr1 ? xKxBiO3: Recovery of Superconductivity with Electric or Magnetic Field

The temperature-dependent resistivity of Sr_{1 – x}K_xBiO₃, with x = 0.4–0.6, has been measured as a function of the magnetic field (or electrical current). Although X-ray diffraction results are more or less identical to single phase for the measured 10 samples, the EDS results indicate that the potassium content, x, varies from 0.4 to 0.6 and the electrical resistance varies quite sensitively from sample to sample. For the samples of resistivity less than 4 m cm at room temperature with (15 K)/(273 K) < 0.9, superconductivity is observed with T_c 12 K. Other samples exhibit a reentrant resistance below the superconducting transition temperature. The reentrant resistance, however, decreases as the external magnetic field (or electrical current) is applied, and some samples show the recovery of superconductivity upon the application of a magnetic field (or electrical current). Disorderness in the junction area between superconducting grains seems to be vital for the observed anomalous reentrant resistance. Further investigations are on to understand this intriguing phenomena.     

Thermoelectric properties of niobium doped hexagonal barium titanate

The ceramic samples of Nb doped hexagonal barium titanate (h-Ba₁Nb_xTi_1−xO₃) were prepared by the usual solid state reaction using stoichiometric amounts of BaCO₃, TiO₂, and Nb₂O₅ powders for different concentrations of Nb. These samples were characterized by X-ray diffraction (XRD), electric and magnetic measurements. The XRD patterns of all these samples showed an average hexagonal structure refined in space group P6₃/mmc. The electrical resistivity showed a semiconducting like behavior from 400 K down to the lowest possible measured temperature. The magnetic susceptibility measured up to 400 K in an applied field of 1 T changes from diamagnetic to paramagnetic one, reaches a certain maximum at x=0.02 and then decreases with increased dopant concentration. The density of states (DOS) deduced from the paramagnetic susceptibility showed a peak at x=0.02 nominal concentration of Nb. We attribute this phenomenon as an increase in the effective mass of carriers with dopant concentration. The thermoelectric power measured from 77–300 K for all these samples is negative showing that conduction carriers are electrons in this system and its magnitude is directly proportional to the temperature. We suggest that conduction in this system occurs through variable range hopping between localized states within an impurity band at low temperature.     

Magnetic properties of the mixed spinel Co1+x Si x Fe2−2x O4

The structural and magnetic properties of the mixed spinel Co_1+x Si _x Fe_2?2x O₄ system for 0·1≤x≤0·6 have been studied by means of X-ray diffraction, magnetization, and Mössbauer spectroscopy measurements. X-ray intensity calculations indicate that Si⁴⁺ ions occupy only tetrahedral (A) sites replacing Fe³⁺ ions, and the added Co²⁺ ions substitute for (B) site Fe³⁺ ions. The Mössbauer spectra at 300 K have been fitted with two sextets in the ferrimagnetic state corresponding to Fe³⁺ at the A and B sites, forx≤0·3. The Mössbauer intensity data shows that Si possesses a preference for the A site of the spinel. The variation of the saturation magnetic moment per formula unit measured at 300 K with the Si content, is explained on the basis of Neel’s collinear spin ordering model forx≤0·3 which is supported by Mössbauer, and X-ray data. The Curie temperature decreases nearly linearly with increase of the Si content, forx=0·1–0·6.     

Study of the Influence of MgO Nano-Oxide Addition on the Electrical and Mechanical Properties of (Cu<Subscript>0.25</Subscript>Tl<Subscript>0.75</Subscript>)-1234 Superconducting Phase

The effect of nano-size MgO (40–60 nm) addition on the physical properties of polycrystalline (Cu_0.25Tl_0.75)-1234 was studied. The MgO-concentration (x) varied from 0.0 to 1.0 wt.% of the sample’s total mass. X-ray analysis, granular structure examination, energy dispersive X-ray spectroscopy, electrical resistivity, critical current density at different applied magnetic fields and Vickers microhardness measurements were carried out to study the performance of these samples. Phase examination by X-ray diffraction indicated that MgO-addition enhanced the (Cu_0.25Tl_0.75)-1234 phase formation till x=0.6 wt.%. Granular investigation by scanning electron microscope reveled that both number and size of voids decreased as x increased from 0.0 to 0.6 wt.%. These results were supported by the sample’s porosity calculation. The superconducting transition temperature and critical current density were found to have optimum values at x=0.6 wt.%. Furthermore, the Vickers microhardness increased till x=0.6 after that it decreased with further increase in x.     

New magnetic implant material for interstitial hyperthermia

Magnetic properties and heat generation characteristics of a bio-compatible ceramic Mg_1+xFe_2–2xTi_xO₄ system have been investigated as an implant material for the magnetic induction hyperthermia. Curie temperature (T_c) of the ceramic decreases with increasing x; and become T_c, 350 K at x ç0:35 and, 315 K at x ç 0:38; which is suitable Curie temperature for implant material. The temperature of ceramic as a function of time under the high frequency alternating magnetic field is self-controlled at T_c.

The surface temperature of a powder injection sphere cancer model, which was a mixture of the agar phantom and the ceramic powder implant, and the temperature distribution around the sphere set in the pure agar phantom matrix have been measured. The result is in good agreement with calculation using a finite element method (FEM). It was found that the temperature distribution inside of the sphere and the minimum quantity of Mg_1+xFe_2–2xTi_xO₄ necessary for hyperthermia could be estimated by the FEM calculation.