多壁碳纳米管/氧化亚铜的制备及其对N-甲酰吗啉的光催化性能

采用液相还原法制备多壁碳纳米管/氧化亚铜(MWCNTs/Cu2O)复合微球。利用傅立叶变换红外光谱仪(IR)、扫描电子显微镜(SEM)、X射线衍射仪(XRD)等对样品进行官能团分析、物相分析和形貌观察,结果表明:多壁碳纳米管以纵横穿插方式与氧化亚铜形成复合微球。对比氧化亚铜和多壁碳纳米管/氧化亚铜对目标有机物N-甲酰吗啉的光催化活性,结果表明:多壁碳纳米管/氧化亚铜复合催化剂的催化效果明显优于氧化亚铜。     

Photocatalytic degradation of 2,4-dinitrophenol (DNP) by multi-walled carbon nanotubes (MWCNTs)/TiO2 composite in aqueous solution under solar irradiation

Nanosized multi-walled carbon nanotubes (MWCNTs)/TiO₂ composite and neat TiO₂ photocatalysts were synthesized by sol-gel technique using tetrabutyl titanate as a precursor. The as prepared photocatalysts were characterized using XRD, SEM, FTIR and UV-vis spectra. The samples were evaluated for their photocatalytic activity towards the degradation of 2,4-dinitrophenol (DNP) under solar irradiation. The results indicated that the addition of an appropriate amount of MWCNTs could remarkably improve the photocatalytic activity of TiO₂. An optimal MWCNTs:TiO₂ ratio of 0.05% (w/w) was found to achieve the maximum rate of DNP degradation. The effects of pH, irradiation time, catalyst concentration, DNP concentration, etc. on the photocatalytic activity were studied and the results obtained were fitted to the Langmuir-Hinshelwood model to study the degradation kinetics. The optimal conditions were an initial DNP concentration of 38.8 mg/L at pH 6.0 with catalyst concentration of 8 g/L under solar irradiation for 150 min with good recyclisation of catalyst. The degree of photocatalytic degradation of DNP increased with an increase in temperature. The MWCNTs/TiO₂ composite was found to be very effective in the decolorization and COD reduction of real wastewater from DNP manufacturing. Thus, this study showed the feasible and potential use of MWCNTs/TiO₂ composite in degradation of various toxic organic contaminants and industrial effluents.     

Acid-treated carbon nanotubes and their effects on mortar strength

In the present study, multi-walled carbon nanotubes (MWCNTs) were treated in an acidic mixture solution, made with nitric and sulfuric acids in a ratio of 3:1 by volume. The durations of the treatment were 100 and 180 min. The defects of these treated MWCNTs were examined using Raman spectroscopy. The attachment of hydroxyl functional groups to the walls of the MWCNTs were verified using FTIR spectroscopy. The dispersion of CNTs with acid treatment is assessed using UV-Vis spectroscopy and Scanning Electron Microscopy (SEM). The results indicate that the duration of the acid treatment has significant effect on both the degree of defects and functionality of the MWCNT. The compressive strength of mortar increased with the addition of the acid-treated MWCNTs; however, no appreciable difference was noted for the two treatment durations under this study.     

Adsorption of 2,4,6-trichlorophenol by multi-walled carbon nanotubes as affected by Cu(II)

Adsorption equilibrium of 2,4,6-trichlorophenol (TCP) on multi-walled carbon nanotubes (MWCNTs) was investigated to explore the possibility of using MWCNTs for concentration, detection and removal of TCP from contaminated water. The adsorption of TCP on MWCNTs at pH 4 was nonlinear, reversible and best fit by a Polanyi-Manes model. Oxidation treatment increased surface area and introduced hydrophilic carboxylic groups to the defect sites of MWCNTs, hence increased the sorption of TCP and Cu(II) individually. Cu(II) suppressed the sorption of TCP on oxidized MWCNTs15A, but had little effect on as-grown MWCNTs15. TCP had no influence on Cu(II) sorption to either. The mechanisms of Cu(II) suppression effect on TCP adsorption are ascribed to the formation of surface complexes of Cu(II), which was verified by X-ray absorption spectroscopy. Cu(II) exerts a cross-linking effect of functional groups on adjacent tubes, creating a more tightly knit bundle and suppressing the condensation of TCP in the pore spaces between the tubes. The large hydration sphere around surface complexes of Cu(II) may also intrude or shield hydrophilic sites, leading to the “crowding out” of TCP around the Cu(II)-complexed sites.     

Experimental investigation of the effect of carbon nanotubes and carbon fibres on the behaviour of plain cement composite beams

In this article, the behaviour of reinforced cement composite beams with multi-walled carbon nanotubes (MWCNTs) and carbon fibres (CFs) is investigated. The percentage of CFs was fixed at 0.25 wt% of cement, while the percentage of MWCNTs was varied from 0.25, 0.5, 0.75, 1 wt% of cement. Dispersion of both MWCNTs and CFs was carried out using ultrasonic energy. Composite beams were tested under flexure in order to evaluate their mechanical properties such as flexural strength, toughness and ductility. These results were then compared with the results of plain cement control beams. The present work also investigates the optimum percentage of fibres that gives the best results both in terms of enhanced properties and economy.     

Vibration analysis of multi-walled carbon nanotubes embedded in elastic medium

We propose a method to estimate the natural frequencies of the multi-walled carbon nanotubes (MWCNTs) embedded in an elastic medium. Each of the nested tubes is treated as an individual bar interacting with the adjacent nanotubes through the inter-tube Van der Waals forces. The effect of the elastic medium is introduced through an elastic model. The mathematical model is finally reduced to an eigen value problem and the eigen value problem is solved to arrive at the inter-tube resonances of the MWCNTs. Variation of the natural frequencies with different parameters are studied. The estimated results from the present method are compared with the literature and results are observed to be in close agreement.     

The combined effect of multiwalled carbon nanotubes and exhaust gas recirculation on the performance and emission characteristics of a diesel engine

The present experimental investigation focuses on the combined effects of multiwalled carbon nanotubes (MWCNTs) and exhaust gas recirculation (EGR) of a diesel engine fuelled with Calophyllum inophyllum biodiesel blends. The C. inophyllum biodiesel-diesel blend was prepared in a proportion of 20% biodiesel and 80% diesel (B20) by a volumetric basis with a magnetic stirrer. The MWCNTs (in the mass fraction of 40?ppm) were dispersed into the B20 fuel with the help of an ultrasonicator. The results show that brake thermal efficiency increases by 7.6% with the addition of MWCNTs to the B20 fuel, decreases by 2.42% with the EGR to the B20 fuel, and increases by 2.26% with the addition of MWCNTs and EGR to the B20 fuel compared to the B20 fuel. The maximum cylinder pressure and heat release rate was occurred as 67.35 bar and 74.80?kJ/m³ deg for the B20MWCNT40 fuel at full load condition. The CO and HC emissions for the B20MWCNT40+20%EGR fuel sample were lower compared to the B20 fuel. The Smoke emissions were reduced for B20MWCNT40 fuel compared to the B20 fuel. The NO_x emissions were reduced by 25.6%, 29.7% for B20+20%EGR, B20MWCNT40+20%EGR fuel samples compared to the B20 fuel.     

Transport behavior of functionalized multi-wall carbon nanotubes in water-saturated quartz sand as a function of tube length

A series of one-dimensional column experiments was conducted to examine the effects of tube length on the transport and deposition of 4-ethoxybenzoic acid functionalized multi-wall carbon nanotubes (MWCNTs) in water-saturated porous media. Aqueous MWCNTs suspensions were prepared to yield three distributions of tube lengths; 0.02-1.3 μm (short), 0.2-7.5 μm (medium), and 0.2-21.4 μm (long). Results of the column studies showed that MWCNT retention increased with increasing tube length. Nevertheless, more than 76% of the MWCNT mass delivered to the columns was detected in effluent samples under all experimental conditions, indicating that the functionalized MWCNTs were readily transported through 40-50 mesh Ottawa sand. Examination of MWCNT length distributions in the effluent samples revealed that nanotubes with lengths greater than 8 μm were preferentially deposited. In addition, measured retention profiles exhibited the greatest MWCNT deposition near the column inlet, which was most pronounced for the long MWCNTs, and decreased sharply with travel distance. Scanning electron microscope (SEM) images showed that MWCNTs were deposited on sand surfaces over the entire column length, while larger MWCNT bundles were retained at grain intersections and near the column inlet. A mathematical model based on clean bed filtration theory (CBFT) was unable to accurately simulate the measured retention profile data, even after varying the weighting function and incorporating a nonuniform attachment rate coefficient expression. Modification of the mathematical model to account for physical straining greatly improved predictions of MWCNT retention, yielding straining rate coefficients that were four orders-of-magnitude greater than corresponding attachment rate coefficients. Taken in concert, these experimental and modeling results demonstrate the potential importance of, and need to consider, particle straining and tube length distribution when describing MWCNT transport in water-saturated porous media.     

Carbon nanotube blended polyethersulfone membranes for fouling control in water treatment

Multi-walled carbon nanotube/polyethersulfone (C/P) blend membranes were synthesized via the phase inversion method. The resultant membranes were then characterized by scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), and contact angle. The C/P blend membranes appeared to be more hydrophilic, with a higher pure water flux than the polyethersulfone (PES) membranes. It was also found that the amount of multi-walled carbon nanotubes (MWCNTs) in the blend membranes was an important factor affecting the morphology and permeation properties of the membranes. After 24 h of surface water filtration with 7 mgC/L TOC content, the C/P blend membranes displayed a higher flux and slower fouling rate than the PES membranes. Subsequent analyses of the desorbed foulants showed that the amount of foulant on bare PES membranes was 63% higher than the C/P blend membrane for 2% MWCNTs content. Thus, the carbon nanotube content of the C/P membranes was shown to alleviate the membrane fouling caused by natural water.     

Adsorption of ciprofloxacin on surface-modified carbon materials

The adsorption capacity of ciprofloxacin (CPX) was determined on three types of carbon-based materials: activated carbon (commercial sample), carbon nanotubes (commercial multi-walled carbon nanotubes) and carbon xerogel (prepared by the resorcinol/formaldehyde approach at pH 6.0). These materials were used as received/prepared and functionalised through oxidation with nitric acid. The oxidised materials were then heat treated under inert atmosphere (N₂) at different temperatures (between 350 and 900 °C). The obtained samples were characterised by adsorption of N₂ at −196 °C, determination of the point of zero charge and by temperature programmed desorption. High adsorption capacities ranging from approximately 60 to 300 mg_CPx g_C⁻¹ were obtained (for oxidised carbon xerogel, and oxidised thermally treated activated carbon Norit ROX 8.0, respectively). In general, it was found that the nitric acid treatment of samples has a detrimental effect in adsorption capacity, whereas thermal treatments, especially at 900 °C after oxidation, enhance adsorption performance. This is due to the positive effect of the surface basicity. The kinetic curves obtained were fitted using 1st or 2nd order models, and the Langmuir and Freundlich models were used to describe the equilibrium isotherms obtained. The 2nd order and the Langmuir models, respectively, were shown to present the best fittings.     

Heat transfer enhancement of the AISI stainless steel 304 elliptical annular fin coated with the carbon nanotube

In this work, experimental heat transfer enhancement investigation on the AISI stainless steel 304 (AISI SS 304) elliptical annular fin with nano-coating of multi-walled carbon nanotubes (MWCNTs) and without nano-coating was carried out. The parameters, such as temperature distribution, thermal conductivity, convective heat transfer coefficient, shaped tube efficiency and fin effectiveness, are compared for different heat inputs. The result shows that the thermal conductivity of the stainless steel (AISI SS 304) was increased by 21.1% with MWCNTs coating. The surface temperature of the fin decreases with coating as thermal conductivity increases. Also, the convective heat transfer coefficient of the coated fin increased by 7%. The fin-shaped tube efficiency was increased by 6.2% and the fin effectiveness was increased by 21.8%. The uncertainty of the performance parameters was also determined, the values were±5%.     

Effect of Elevated Temperatures on Mechanical Performance of Normal and Lightweight Concretes Reinforced with Carbon Nanotubes

An experimental program was developed to evaluate the effect of multi-walled carbon nanotubes (MWCNTs) inclusion on elevated temperature properties of normal weight concrete (NWC) and lightweight concrete (LWC). The mechanical performance was assessed by conducting material property tests namely compressive strength (f’_c,_T), tensile strength (f’_t,T), mass loss (M_T), elastic modulus (E_T), compressive toughness (T_c) and stress–strain response under unstressed and residual conditions in the range of 23°C to 800°C. The mechanical properties were measured by heating 100?×?200 mm cylindrical specimens to 200°C, 400°C, 600°C and 800°C at a heating rate of 5°C/min. Results show that the inclusion MWCNTs in cementitious matrices enhanced the fire endurance. The relative retention of mechanical strength and mass of concretes modified with MWCNTs was higher. The stress–strain response of specimens modified with MWCNTs was more ductile. Microstructural study of cyrofractured samples evidenced the homogenous dispersion of nano-reinforcements in host matrix. Furthermore, the data obtained from high temperature material property tests was utilized to develop mathematical relationships for expressing mechanical properties of modified mixes as a function of temperature.     

Effects of humic acid and electrolytes on photocatalytic reactivity and transport of carbon nanoparticle aggregates in water

The effects of naturally occurring macromolecules such as humic acid (HA) and electrolytes on four fullerene nanoparticle suspensions (i.e., C₆₀, C₆₀(OH)₂₄, single- and multiwall carbon nanotubes) were explored with respect to: (1) characteristics of nanoparticle aggregates, (2) transport of the aggregates through a silica porous media, and (3) production of reactive oxygen species (ROS) from the photosensitized fullerene aggregates. The presence of HA and salts increased the size of aggregates and relative hydrophobicity associated with transport through silica beads, while decreasing ROS production. These data illustrate the importance that transformation of engineered nanomaterials (ENMs) through interactions with aquatic solutes may have in altering the environmental behavior of nanomaterials.     

Microstructure characteristics of nonwoven geotextiles using SEM and CT methods

Two digital image methods based on scanning electron microscope (SEM) and computed tomography (CT) were proposed to study the microstructural characteristics of staple fibers and continuous filament geotextiles. Two-dimensional (2D) image analysis was developed for SEM images using a machine-learning-based segmentation algorithm. Three-dimensional (3D) image analysis of the CT images was based on 3D reconstruction and a pore network model. The fiber orientation distribution, porosity, pore size distribution (PSD), and characteristic pore size O₉₅ determined from image analysis were compared with the theoretical equation and bubble point test (BBP) results. It is shown that 2D and 3D image analyses can accurately measure the fiber orientation distribution of the geotextiles. The porosity values obtained using 3D imaging were comparable to theoretical values. The PSD curves obtained in the BBP tests were in good agreement with those obtained using the 3D image method. O₉₅ sizes of continuous filament geotextiles estimated by 2D image analysis compared well with O₉₅ sizes obtained by BBP tests, whereas this was not the case for staple fiber geotextiles. The O₉₅ pore throat sizes of the two nonwoven geotextiles determined by 3D image analysis were comparable to the BBP test-based values and 2D image analysis-based values.     

Evaluation of 1-dimensional nanomaterials release during electrospinning and thermogravimetric analysis

The growing research interests with engineered nanomaterials in academic laboratories and manufacturing facilities pose potential safety risks to students and workers. New nanoparticle substances, compositions, and processing approaches are developed regularly, creating new health risks which may not have been addressed previously. Accordingly, the Institute of Occupational Medicine conducted field studies at Texas A&M University (TAMU) to characterize possible particle emissions during processing and fabrication of carbon nanotubes, copper nanowires, and polymeric fibers. The nature of the monitoring work carried out at TAMU was to investigate the potential release of 1D nanomaterials to air from activities associated with synthesis, handling, thermal gravimetric analysis, and electrospinning processes, and evaluate the effectiveness of the utilized control measures. The potential nanoparticle release to air from each activity was investigated using a combination of particle detection instrumentations, coupled with standard filter-based sampling techniques. The analyses indicated that a measurable quantity of free carbon nanosphere aggregates was detected during these activities; however, no free MWCNTs or nanowires were detected. Scanning electron microscopy identified the presence of carbon nanospheres aggregates on the filters. While the control measures used at TAMU are effective in containing the nanomaterial release during processing, poor handling and occupational hygiene practices can increase the risk of employee exposure to the nanomaterials.     

碳纳米管增强水泥砂浆梁弯曲性能试验研究

以水泥砂浆为基体,多壁碳纳米管(MWCNT)为增强组分,采用不同的分散剂和分散方法制备碳纳米管水泥砂浆(MWCNTRM).通过对碳纳米管水泥砂浆标准试件的三点弯曲试验,研究了分散剂类型及其掺量、水灰比、碳纳米管掺加量对碳纳米管水泥砂浆梁弯曲性能的影响.结果表明:分散剂与碳纳米管的质量比存在一个临界值(分散剂为CTAB时...     

Advanced cement based nanocomposites reinforced with MWCNTs and CNFs

Cementitious materials reinforced with well dispersed multiwall carbon nanotubes (MWCNTs) and carbon nanofibers (CNFs) at the nanoscale were fabricated and tested. The MWCNTs and CNFs were dispersed by the application of ultrasonic energy and the use of a superplasticizer. Mechanical and fracture properties including flexural strength, Young’s modulus, flexural and fracture toughness were measured and compared with similarly processed reference cement based mixes without the nano-reinforcement. The MWCNTs and CNFs reinforced mortars exhibited superior properties demonstrated by a significant improvement in flexural strength (106%), Young’s modulus (95%), flexural toughness (105%), effective crack length (30%) and fracture toughness (120%).     

Relating thermal conductivity of soil skeleton with soil texture by the concept of“local thermal conductivity fluctuation”

The thermal conductivity of the soil skeletonλ;is an essential parameter from the point of view of the correct assessment of soil overall/effective conductivity.This work introduces the concept of“local thermal conductivity fluctuation”which characterizes the microscale variation of conductivity within the solid phase.It is proposed to link the“local fluctuation”of thermal conductivityλwith the soil texture-the information that is available at the scale of engineering applications.It was possible to relate the skeleton thermal conductivity with the grain size distribution of the soil.Finally,based on a large series of numerical simulations,the paper provides four triangle diagrams(at different organic matter contents:0%,2%,4%and 6%)relating the value ofλ;with volume fraction of individual soil separates.This result is extremely important from the practical point of view.One can quickly evaluateλ;value provided that information on the grain size distribution and organic matter content is available.     

An investigation of Al2O3–ZrO2 ceramic composite-coated engine parts using plasma spray method on a diesel engine

ABSTRACT

In this study, the surfaces of the piston, cylinder head and valve parts of the combustion chambers for a single-cylinder diesel engine were coated at 250?µm thick ceramic composite Al₂O₃–ZrO₂ (20–80%) main coating material and 100?µm NiCrAl interlayer material. Also, B6 and B12 biodiesel fuels were produced. Fuel blends were tested on a diesel engine with thermal barrier-coated surfaces for 50?h under the same conditions. When the SEM images and the EDS analysis results of the pistons covered with the ceramic composite main coating material are examined, it has been seen that the coating material permeates the surfaces in a very homogeneous manner and allows to work with high performance without causing any deterioration on the surfaces during working. At high temperatures, the working periods of 50?h and the formation of smoke did not cause any damage to the main material and the coating material.     

Sustainable water-energy nexus in the optimization of the BBC golf-course using renewable energies

ABSTRACT

Water distribution networks and irrigation systems consume high energy quantities that need to be recovered if the water managers want to meet sustainable systems. A sustainability optimization is proposed in this research in order to replace the energy consumption in a golf-course system by renewable solutions joining energy recovery, sustainable urban drainage systems and hybrid solutions (solar panels and wind turbine). Different sustainable approaches were considered in which energy (using PATs), economic and environmental factors were analysed. Both scenarios and analyses showed interesting values related to economic indicators and environmental reductions of CO₂ emissions. The possibility to supply the daily electric consumption in the pumping stations was checked using only renewable systems. Net present value was calculated in different solutions, obtaining positive values as well as the payback period was lower than 6 years. The CO₂ emissions were reduced from 257,000 to 11,500 kgCO₂/year in the most unfavourable scenario.