Commercial Application of the XYA-5 Catalyst in Acrylonitrile Unit

The XYA-5 catalyst was first applied in commercial scale on an 80-kt/a acrylonitrile unit at the Daqing Refining and Chemical Company. Test results had shown that the once-through yield of acrylonitrile exceeded 80% with the unit consumption ofpropylene reaching 1032 kg on each ton of acrylonitrile. The product quality could be easily put under control and the distribution of reaction products was reasonable with good cleaning performance and stability of the catalyst that was suitable for use on this commercial unit.     

Study on the Performance and Commercial Application of New Generation DMMC-1 Type Catalyst for Deep Catalytic Cracking

Over the past decades SINOPEC has been uninterruptedly engaging in the development and upgrading of deep catalytic cracking （DCC） technology for manufacturing propylene from heavy oil. Recently SINOPEC after having made a lot of progress in the area of oil refining at the molecular level has developed a new generation DMMC-1 type catalyst designed for the DCC process. The laboratory evaluation tests have shown that compared to the existing MMC-2 type catalyst that features the best comprehensive performance, the DMMC-1 type catalyst has increased the propylene yield by 2.2% with the propylene selectivity increased by 10%. The said catalyst has improved its ability for heavy oil cracking and coke selectivity along with reduction of olefin content in gasoline to achieve a better product distribution and improve the product quality. The results of application of the said catalyst in a 650-kt/a commercial DCC unit at SINOPEC Anqing Branch Company have revealed that the DMMC- 1 catalyst demonstrated an enhanced capability for heavy oil cracking and could increase the total liquid yield to 84.56 m% from 83.92 m%, the LPG yield to 38.90 m % from 34.60 m %, the propylene yield to 17.80 m% from 15.37 m% and the propylene concentration to 45.91 m% from 44.91 m%, and reduce the coke yield from 7.61 m% to 7.05 m% and the olefin content in gasoline from 42.3 v% to 37.5 v%, resulting in an incremental profit amounting to 52.19 million RMB a year. This technology has further upgraded and developed the DCC technology which has been commanding a leading position among the industry peers.     

Commercial Test Project for Manufacture of Hexane-1 with Independent Intellectual Property Right Possessed by Petro China was Implemented at Daqing Petrochemical Company

The commercial test project rated at 5 kt/a hexane- 1, on which PetroChina has the independent intellectual property right, is under construction intensively at the No.2 Chemical Plant of Daqing Petrochemical Company. This project adopts the ethylene oligomerization process for manufacture of hexane-1 in the presence of chromium catalyst. The investment in this project totals 74 million RMB and the project is scheduled for completion by the end of September 2008.     

Study on the Performance of Regenerated Catalyst for Ammonoximation of Cyclohexanone

The study on the deactivated catalyst and the regenerated catalyst for the 70 kt/a cyclohexanone ammonoximation commercial test unit had revealed that addition of a proper amount of silicon additive could suppress the solubilization-induced loss of silicon in catalyst while providing protection to the catalyst. Compared to the direct calcination method for catalyst regeneration, adoption of the regeneration method through pretreatment-calcination of catalyst could be more beneficial to the restoration of catalyst channels and enhancement of the performance of the regenerated catalyst, which could be repeatedly regenerated and utilized. The outcome of commercial scale testing of the catalyst had indicated the good performance of the regenerated catalyst, which could be used for four times, resulting in a reduction of the production cost of cyclohexanone-oxime in big chunks.     

＂Development of the Enegy Saving Tvpe GS-11 Catalyst for Dehvdrogenation of EthvIbenzene and Its Commercial Testing＂ Passed Appraisal

The project ＂Development of the energy saving type GS-11 catalyst for dehydrogenation of ethylbenzene and its commercial testing＂ jointly undertaken by the SINOPEC Shanghai Petrochemical Research Institute and the Qilu Petrochemical Company had passed in November 2008 the appraisal organized by the SINOPEC Science and Teehnology Development Division.     

英文摘要

Progress of overseas hydrotreating catalyst processes for clean diesel oil/2009,20 （ 2 ） ： 1-4
Yuan Lijian, Yuan Dahu, Zhang Fingyuan （1.Daqing Petrochemical Company No.1 Chemical Plant, Daqing 163714, China; 2.Daqing Chemical Research Center, Daqing 163714, China）
Abstract： The increasingly higher requirement for environmental protection has accelerated the ever upgrading of diesel oil standard. The oil refining industry over the world has continually made improvements and innovations to the existing processes and developed some advanced technologies to meet the requirement for the production of clean diesel oil. This paper summarized the technical progress of diesel oil hydrotreating catalyst in overseas oil refineries. Keywords： clean diesel oil; hydrotreating catalyst; technical progress     

Commercial Application of CPP for Producing Ethylene and Propylene from Heavy Oil Feed

A new process named CPP (Catalytic Pyrolysis Process) for producing ethylene and propylene from heavy oil feedstock has been developed. The catalyst CEP was specially designed for this process, which has bi-functional catalytic activities for both carbonium ion reaction and free radical reaction, so as to maximize the yields of ethylene and propylene. The commercial trial showed that the yield of ethylene and propylene was 20.37% and 18.23% respectively in maximum ethylene operation with Daqing AR as feedstock, and the yield of ethylene and propylene was 9.77% and 24.60% respectively in maximum propylene operation by using the same feedstock.Compared with steam cracker, the feed cost of CPP is much lower for producing ethylene and propylene.     

Development of Novel Resid Hydrometallization Catalyst RDM-3

Based on the reaction mechanism of resid hydrodemetallization, a new catalyst carrier was designed and prepared. As compared with the similar type of catalyst carrier, the said new carrier featured a higher pore volume, a larger pore diameter and a weaker surface acidity, which could improve the diffusion performance and stable reaction performance of the catalyst. The active metal components were loaded on the said carrier by a new technique for better metal dispersion, thus the impurity removal rate of the new catalyst, RDM-3, was improved significantly. The commercial test of the RDM-3 catalyst showed that the process of catalyst preparation was stable, the catalyst performance was slightly better than the catalyst prepared in the lab, therefore, the catalyst could be manufactured in commercial scale.     

Development and Application of the CGP-2 Catalyst in the MIP-CGP Process

The research and development of the CGP-2 catalyst, which was used in the MIP-CGP process for reducing the olefin and sulfur contents of FCC naphtha and enhancing the propylene yield, were introduced. A specific type of metal compound was added into the matrix to provide active centers for reactions including catalytic conversion and selective adsorption of sulfur containing compounds. The CGP-2 catalyst possessed excellent hydrothermal stability to meet the requirements of the 2rid reaction zone of the MIP-CGP process. The commercial test of the said catalyst at the SINOPEC Cangzhou refinery showed that in comparison with the base case （using the CGP-1Z catalyst） the CGP-2 catalyst could reduce the sulfur content of FCC naphtha by 30.32% and increase the propylene yield along with good coke selectivity. Thus, the naphtha produced by the MIP-CGP process at the Cangzhou refinery can meet the new gasoline standard enforced in July 2005.     

Study and Pilot Scale Development of Catalyst for Ethylebenzene Synthesis THrough Transalkylation of Benzene and Polyethylbenzene

This paper refers to the results of study and development of benzene and polyethylbenzene transalkylation catalyst (type AEB-1) for syntthesis of ethylbenzene,The effect of reaction conditions on the reaction performance of the catalyst was investigated in the pressurized microreactor CDS-900,A transalyltaion catalst with high activity,good selectivity and stability was developed following a 2000-hour test on the activity and stabiity of the catalyst .The preparation of this catatlyst was implemented in pilot scale and this catalyst was tested for activity and stability in a 150 t/a pilot unit for production of etheylbenzene ,The test results have shown that this transalkyliation catalyst has excellent activity ,seletivity and stability,The operation of pilot test unit ran smoothly and the process schemis is viable.     

全减压渣油催化剂在VRFCC上的应用

介绍了两种新型减压渣油催化剂DVR－1及进口Ramcat催化剂在燕化公司炼油事业部二套催化裂化装置上的工业应用情况。通过比较，得出如下结论：两种催化剂的焦碳选择性好，能满足大掺渣比的技术要求，并且提高了催化汽油辛烷值，增加了经济效益。     

渣油裂化催化剂DVR-1的研制及其工业应用

开发了DVR -1渣油裂化催化剂 ,采用超稳Y型分子筛的改性技术及活性担体的开发技术 ,对催化剂配方进行了优化 ,使该剂具有渣油裂化能力强、活性高、抗重金属污染能力强、稳定性好的特点。燕山石化公司二套催化装置工业应用结果表明 ,加工大庆渣油在掺渣比高达 85 %时 ,轻质油收率仍能接近 70 %     

国产钛系BCH催化剂在淤浆法HDPE装置上的应用

淤浆法生产高密度聚乙烯所使用的主催化剂为钛系高效催化剂，大庆石油化工总厂ＨＤＰＥ装置通过对国产ＢＣＨ催化剂的小聚合评价及工业优大批量使用，结果表明：ＢＣＨ催化剂综合性能指标好，催化剂活性高，氢调敏感性好，对产品的质量指标有优化和改善的显著效果，催化剂耗量进口催化剂低。     

改进DVR-1裂化催化剂配方以降低生焦率

中国石化股份有限公司金陵分公司1号催化裂化装置于2001年初进行了掺渣扩容改造，在生产中发现装置的生焦率较高。在对装置的技术状况进行充分的分析研究后，认为在改进催化剂配方方面存在一定的空间，故对使用的DVR—1催化剂的配方进行了改进，降低了担体的酸强度并采用了复合型分子筛。结果表明，使用改进型DVR—1催化剂后，生焦率有一定程度的下降，产品分布得到了改善。     

PHF-101柴油加氢精制催化剂的工业应用

介绍了PHF-101柴油加氢精制催化剂在中国石油大庆石化分公司1.2 Mt/a柴油加氢精制装置首次工业应用情况,加工原料为大庆催化裂化柴油、焦化柴油和焦化汽油的混合油,在不同工况下可生产满足国Ⅲ、国Ⅳ及国Ⅴ排放标准要求的柴油。经过37个月的运转,催化剂活性、稳定性良好。     

MB-86型丙烯腈催化剂的工业应用

MB-86丙烯腈催化剂通过大庆石化总厂化纤厂7000吨/年丙烯腈装置工业应用,丙烯腈单程收率80％以上,丙烯单耗为1.05—1.08吨/吨丙烯腈。工业运转结果表明,MB-86催化剂稳定性及耐磨性良好,反应产物分布合理。可用于原使用C_(41)、C_(49)及类似系列催化剂的万吨级丙烯腈工厂,反应器不必进行改造。     

SD-1石蜡加氢精制催化剂工业生产及应用

在试验室研制、工业制备放大和工业应用试验的基础上，进行SD—l石蜡加氢精制催化剂的批量生产，并在大庆石化公司炼油厂100kt/a中压石蜡加氢生产装置上首次工业应用。应用效果良好，产品蜡除含油量由计划控制外，其它指标到达全炼优级品要求，生产操作指标明显优于国产同类催化剂，处于国内二十世纪90年代先进水平。     

渣油催化裂化集部动力学模型的研究与应用

提出了一个用于渣油催化裂化过程的十四集总动力学模型,该模型的建立以大庆渣油为原料,采用DVR－1渣油催化裂化催化剂,使用此模型分虽在中型提升管反应器和工业提升管装置的多种反应条件下,对渣油催化裂化过程的产率进行了计算,用该模型计算的产率与相同反应条件下中型试验数据进行比较,各产品产率的平均误差最大值为0．63％,与工业标定数据比较,各产品产率的平均误差最大值为0．81％,该模型可用预测设定反应条件下的产品产率。     

新型重油催化裂化催化剂HSC-1的研究开发

以高活性高稳定性的高稀土含量超稳改性分子筛为活性组元开发了新型重油催化裂化催化剂HSC-1,并利用XRF、BET、孔体积、磨损指数、粒度测定等对其化学组成及物化性能进行了分析,利用轻油微反及ACE对催化裂化性能进行了考察。结果表明,制备的催化剂HSC-1具有物化性能好、重油裂化能力及抗金属污染能力强、产物分布好、焦炭选择性及汽油选择性好,以及优异的降低汽油烯烃含量的特性。