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聚酰胺酸酰亚胺化条件及其对聚酰亚胺力学性能的影响 总被引:1,自引:0,他引:1
采用均苯四酸二酐(PMDA)和4,4'-二氨基二苯醚(ODA)为单体,N-甲基吡咯烷酮(NMP)为溶剂,合成了黏度为1.87 dL/g的聚酰胺酸(PAA)。对聚酰胺酸分别进行了热酰亚胺化和化学酰亚胺化处理,研究了完全酰亚胺化所需的条件以及不同酰亚胺化方式对聚酰亚胺(PI)纤维条断裂强度的影响;对PAA初生纤维条进行拉伸和酰亚胺化处理的顺序不同,所得到的聚酰亚胺(PI)纤维条的力学性能不同,采用先酰亚胺化再拉伸的方法能得到力学性能更优异的聚酰亚胺(PI)纤维条。 相似文献
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《合成纤维工业》2017,(1):50-53
以4,4'-(六氟异丙烯)二酞酸酐(6FDA)与4,4'-双(4-氨基苯氧基)二苯砜(BAPS)为反应单体,以N-甲基-2-吡咯烷酮(NMP)为溶剂,合成了聚酰胺酸(PAA),将PAA溶液采用流延成膜的方法制备成薄膜;另外,将PAA溶液采用干-湿法纺丝工艺制得PAA中空纤维膜,再将PAA薄膜及其中空纤维膜在300℃左右的高温热环化制得6FDA-BAPS型聚酰亚胺(PI)膜。研究了6FDABAPS型PI及其中空纤维膜的结构与性能。结果表明:所合成的6FDA-BAPS型PI为目标产物,其在NNP、N,N-二甲基乙酰胺、四氢呋喃中具有良好的溶解性能。6FDABAPS型PI中空纤维膜外皮层致密、支撑层疏松多孔,该中空纤维膜具有较高的热学性能和力学性能,在氮气氛围中热失重5%的温度为511℃,断裂强度为26.5 MPa。 相似文献
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聚酰亚胺薄膜的酰亚胺化方法 总被引:2,自引:1,他引:1
本文介绍了聚酰亚胺薄膜的两种酰亚胺化方法,即热酰亚胺化(HIM)和化学酰亚胺化(CIM)方法。指出了目前我国生产厂家所采用的热酰亚胺化法的不足之处。阐述了化学酰亚胺化法的优点及其研发途径。指出我们只有走自主研发和技术创新之路,进行具有产业化前途的,高效的聚酰亚胺薄膜化学酰亚胺化技术的开发,才能适应日益增长的高新技术的发展需要。 相似文献
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采用4,4’-二氨基二苯醚和1,6-己二胺(HDA)为二胺单体,与均苯四甲酸酐(PMDA)在二甲基乙酰胺(DMAc)中共聚得到聚酰胺酸(PAA)纺丝原液,通过干法纺丝工艺路线纺制PAA初生纤维,利用热酰亚胺化制备了共聚型聚酰亚胺(PI)纤维;通过红外光谱分析、动态力学分析、热重分析、X射线衍射等手段分析了PI纤维的力学性能及热性能。结果表明:红外光谱分析发现HDA的长亚甲基链引入到PI的链中;当HDA质量分数为20%时,PI纤维的断裂强度和模量分别为5.1 cN/dtex和76 cN/dtex;动态力学和热重分析发现,纤维的玻璃化转变温度为315~380℃,热稳定性在400℃以上;纤维经热处理后聚集态结构存在一定的有序性。 相似文献
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Changwoon Nah Sang Hyub Han Myong‐Hoon Lee Jong Sang Kim Dai Soo Lee 《Polymer International》2003,52(3):429-432
A novel route for making polyimide sub‐micron fibers is described. The ultrafine fibers are prepared by electrospinning a poly(amic acid) solution, a precursor of polyimide, followed by thermal imidization. The fiber diameters, which are much smaller than conventionally spun fibers, range from a few tens of nanometers to several micrometers. A rectangular cross‐section is observed in the case of sub‐micron fibers with a cross‐sectional dimension below ~500 nm. © 2003 Society of Chemical Industry 相似文献
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As one type of high‐performance fibers, the polyimide fibers can be prepared from the precursor polyamic acid via dry‐spinning technology. Unlike the dry‐spinning process of cellulose acetate fiber or polyurethane fiber, thermal cyclization reaction of the precursor in spinline with high temperature results in the relative complex in the dry‐spinning process. However, the spinning process is considered as a steady state due to a slight degree of the imidization reaction from polyamic acid to polyimide, and therefore a one‐dimensional model based on White‐Metzer viscoelastic constitutive equation is adopted to simulate the formation of the fibers. The changes of solvent mass fraction, temperature, axial velocity, tensile stress, imidization degree, and glass transition temperature of the filament along the spinline were predicted. The effects of spinning parameters on glass transition temperature and imidization degree were thus discussed. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009 相似文献
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BACKGROUND: Ternary nanocomposites containing an organomodified layered silicate polyimide additive within a polyamide matrix have been investigated to gain greater insight into structure–property relationships and potential high‐temperature automotive applications. RESULTS: Polyamide nanocomposite blends, containing 3 wt% of organoclay, were prepared and compared with organoclay‐reinforced polyamide and neat polyamide. Nanoclay addition significantly increased heat distortion temperature, as well as both the tensile and flexural moduli and strength. The addition of polyimide demonstrated further increases in heat distortion temperature, glass transition temperature and the flexural and tensile moduli by about 17, 21 and 40%, respectively. The tensile and flexural strengths were either unaffected or decreased modestly, although the strain‐to‐failure decreased substantially. Morphological studies using transmission electron microscopy (TEM) and X‐ray diffraction showed that the nanoclay was dispersed within the ternary blends forming highly intercalated nanocomposites, regardless of the presence and level of polyimide. However, TEM revealed clay agglomeration at the polyamide–polyimide interface which degraded the mechanical properties. CONCLUSIONS: A range of improvements in mechanical properties have been achieved through the addition of a polyimide additive to a polyamide nanocomposite. The decrease in ductility, arising from the poor polyamide–polyimide interface and nanoclay clustering, clearly requires improving for this deficiency to be overcome. Copyright © 2008 Society of Chemical Industry 相似文献