InAsSbP double-heterostructure lasers for the spectral range 2.7–3.0 µm (T=77 K)

We have produced, by using liquid-phase epitaxy, 2.7 to 3.0-μm lasers based on InAsSbP double-heterostructures with different phosphorus contents in the active and wide-gap regions. The lasers possess threshold current density ∼0.8 kA/cm² at 77 K and operate in the pulsed mode up to ∼124 K with maximum threshold current density 10–12 kA/cm². The lasers have a low series resistance ∼0.45 Ω. Fiz. Tekh. Poluprovodn. 32, 241–244 (February 1998)     

Photoelectric phenomena in ZnO:Al-<Emphasis Type="Italic">p</Emphasis>-Si heterostructures

Al-doped zinc-oxide (ZnO:Al) films are obtained by magnetron sputtering. Based on an investigation of electrical properties of the films, it is shown that the electron density in these films is as high as 5×10²⁰ cm⁻³ and is practically constant in the temperature range 77–300 K, which indicates high efficiency of doping ZnO with an Al impurity. It is found that the deposition of thin films (d≈1 μm) on the p-Si(111) surface leads to the formation of heterostructures with the highest photosensitivity of ∼400 V/W at T=300 K, which oscillates in the spectral range 1.3–3.5 eV. With the oblique incidence of linearly polarized radiation, induced pleochroism emerges in such heterostructures. The magnitude of pleochroism oscillates in the range 5–40% (θ≈75°), which is associated with the interference phenomena in the ZnO films. The prospects of using the heterostructures obtained as highly selective photosensors of natural and linearly polarized radiation are considered. __________ Translated from Fizika i Tekhnika Poluprovodnikov, Vol. 37, No. 11, 2003, pp. 1329–1333. Original Russian Text Copyright ? 2003 by Nikitin, Nikolaev, Polushina, V. Rud’, Yu. Rud’, Terukov.     

Current-voltage characteristics of Si:B blocked impurity-band structures under conditions of hopping-transport-limited photoresponse

The photoconductivity of Si:B blocked-impurity-band (BIB) structures with boron concentration in the active layer ∼10¹⁸ cm⁻³ has been studied. Measurements were performed in the temperature range 4.2–10 K at different intensities of the exciting radiation 10¹⁰–10¹⁵ photons/cm²·s. Photoexcitation at 5.5 μm was realized using a semiconductor laser. At temperatures below 6 K and low bias voltages (<0.5 V) the current-voltage characteristics were found to have a threshold-like character. The threshold voltage rises as the temperature is lowered and the radiation intensity is increased. A model based on the Frenkel’-Poole effect in the impurity band has been developed. This model can be used to numerically describe the current-voltage characteristics with accuracy better than 5%. As a result, it is found that the photoconductivity rises and then reaches a plateau as the radiation intensity increases. Under these conditions, as under equilibrium conditions (in darkness), the hopping conductivity also depends exponentially on the electric field. This fact is explained in terms of the destruction by the electric field of (A ⁺-A ⁻) impurity complexes which appear under nonequilibrium conditions. Fiz. Tekh. Poluprovodn. 32, 192–199 (February 1998)     

Self-organized nanoscale InP islands in an InGaP/GaAs host and InAs islands in an InGaAs/InP host

Arrays of strained nanoscale InP islands in an In_0.49Ga_0.51P host on a GaAs(100) substrate and InAs islands in a In_0.53Ga_0.47As host on an InP(100) substrate are obtained by metalorganic vapor-phase epitaxy (MOVPE). Their structural and photoluminescence properties are investigated. It is shown that the nanoscale islands that are formed measure 80 nm (InP/InGaP) and 25–60 nm (InAs/InGaAs). The photoluminescence spectra of the nanoscale islands display bands in the wavelength ranges 0.66–0.72 and 1.66–1.91 μm at 77 K with maxima whose position does not vary as the effective thickness of InP and InAs increases. The radiation efficiency of the nanoscale InP islands is two orders of magnitude greater than the luminescence intensity of the InAs islands. Fiz. Tekh. Poluprovodn. 33, 858–862 (July 1999)     

Infrared spectroscopy of chromium-doped cadmium selenide

The maximum optical-absorption cross section of Cr²⁺ ions was evaluated from near-infrared (NIR) absorption spectroscopy and direct measurements of the chromium concentration in Cr²⁺:CdSe crystals. The emission lifetime of the excited state, ⁵E, of Cr²⁺ was measured as a function of Cr²⁺ concentration in the 2×10¹⁷ −2×10¹⁸ ions/cm³ range and as a function of temperature from 77–300 K. Lifetime values were as high as ∼6 μs in the 77–250 K range and decreased to ∼4 μs at 300 K because of nonradiative decays. Assuming that most of the Cr dopant is in the Cr²⁺ state, an optical-absorption cross section σ_a of (1.94±0.56) × 10⁻¹⁸ cm² was calculated. Implications for laser performance are discussed.     

Recombination mechanisms in doped n-type Hg1−x CdxTe crystals and properties of diffusion p +-n junctions based on them

We made p ⁺-n-type photodiodes for the 3–5 and 8–12 μm wavelength regions by diffusing As into single-crystal n-Hg_1−x Cd_xTe substrates, and investigated their electrical and photoelectric properties. Analysis of the temperature dependences of the differential resistance and current-voltage characteristics led us to conclude that charge-carrier transport is predominately due to the generation-recombination mechanism at a temperature of 77 K. As the temperature increases, a contribution from the diffusion component also appears. We obtained values of the product R ₀ A≅0.3–1.0, 1–10, and (1–10)×10⁴ Ω · cm² for diodes with long-wavelength photosensitivity cutoffs λ_c≅11.5, 10.5, and 6.0 μm, respectively, indicating that they could operate in the regime where performance is limited by background radiation fluctuations. Fiz. Tekh. Poluprovodn. 31, 350–354 (March 1997)     

Transformation of luminescence centers in CVD ZnS films subjected to a high hydrostatic pressure

The cathodoluminescence and optical-transmission spectra of ZnS were analyzed to study the effect of a high hydrostatic gas pressure (1500 atm at 1000°C) on the equilibrium between intrinsic point defects in zinc sulfide grown by chemical vapor deposition (CVD) with an excess of zinc. The cathodoluminescence spectra were measured at 80–300 K and excitation levels of 10²² and 10²⁶ cm⁻³ s⁻¹; the optical-transmission spectra were measured at 300 K in the wavelength range 4–12 μm. It is found that exposure to a high hydrostatic gas pressure transforms the self-activated emission in the cathodoluminescence spectrum: (i) a new short-wave-length band appears at 415 nm with its intensity increasing by one to three orders of magnitude; and (ii) the long-wavelength band that peaks at 445 nm and is observed in as-grown crystals becomes quenched. Simultaneously, the cathodoluminescence band peaked at 850 nm and related to vacancies V _S is no longer observed after high-pressure treatment. These effects are attributed to a partial escape of excess zinc (Zn_i) from crystals and additional incorporation of oxygen into lattice sites (O_S). A doublet band I ₁, which peaked at ∼331–332 nm at 80 K and at ∼342–343 nm at 300 K and is related to excitons bound to acceptor levels of oxygen centers, was observed. This band is found to be dominant in the cathodoluminescence spectrum at an excitation level of 10²⁶ cm⁻³ s⁻¹. Traces of the ZnO phase are apparent after the high-pressure treatment in both the cathodolumi-nescence spectra (the bands at 730 and 370 nm) and the transmission spectra (narrow bands in the region of 6–7 μm). __________ Translated from Fizika i Tekhnika Poluprovodnikov, Vol. 38, No. 1, 2004, pp. 39–43. Original Russian Text Copyright ? 2004 by Morozova, Karetnikov, Plotnichenko, Gavrishchuk, Yashina, Ikonnikov.     

Optically active layers of silicon doped with erbium during sublimation molecular-beam epitaxy

A study is made of the electrical, optical, and structural properties of Si:Er layers produced by sublimation molecular-beam epitaxy. The Er and O contents in the layers, grown at 400–600°C, were as high as 5×10¹⁸ and 4×10¹⁹ cm⁻³, respectively. The electron concentration at 300 K was ∼10% of the total erbium concentration and the electron mobility was as high as 550 cm²/(V·s). Intense photoluminescence at 1.537 μm was observed from all the structures up to 100–140 K. The structure of the optically active centers associated with Er depended on the conditions under which the layers were grown. Fiz. Tekh. Poluprovodn. 33, 156–160 (February 1999)     

Manifestation of percolation conductivity of short-channel field-effect transistors in the spectrum of shallow interface states

The effective density of shallow interface states N _ss is investigated in the temperature range T=77–300 K using the field-effect method in short-channel (0.5–5 μm) Si-MNOS and GaAs-based FET’s with high (greater than 10¹² cm⁻²) concentrations of built-in charge in the subgate insulator. A peculiarity of the density of electronic states N _ss was found having the form of a peak, which manifests itself more distinctly at lower temperatures, higher concentrations of built-in charge, and shorter gates. The peak was observed at the same values of the channel conductance G∼q ²/h, regardless of variations in the above-enumerated parameters, the thickness of the sub-gate insulator, and the channel-length-to-width ratio. This means that the energy depth of the peak (∼40–120 meV) varies in proportion to T, which contradicts the current understanding of the interface states caused by both the fluctuation potential (FP) and surface defects or traps. The results are interpreted within the framework of percolation theory applied to the conductivity of strongly disordered systems. The N _ss peculiarity is associated with a transition from the conductivity of a two-dimensional effective solid, which occurs when the fluctuation potential is strongly screened by surface electrons, to conductivity via a quasi-one-dimensional potential trough organized by local regions with reduced surface potential under conditions of a strong fluctuation potential. Fiz. Tekh. Poluprovodn. 31, 1460–1467 (December 1997)     

Photovoltaic effect in the impurity absorption region of Si-structures with blocked impurity conductivity

A study is made of the field dependence of the photoconductivity in two-layer Si:Sb-and Si:Bstructures with blocked impurity-band conductivity and different thicknesses of the undoped (blocking) layer. The impurity concentration in the doped (active) layer was ≈10¹⁸ cm⁻³. Measurements were made at temperatures T=4–15 K for high (Φ∼10¹⁶ photons/cm² · s) and low (Φ<10¹⁴ photons/cm² · s) incident photon fluxes. A photovoltaic effect is observed in the Si:B structures with a thin (3 μm) blocking layer. It is found that a photovoltage develops for photons with energies exceeding the ionization energy of boron and its magnitude is independent of the photoexcitation intensity (for Φ>10¹³ photons/cm² · s) and, in the limit of low temperatures, it is close to the activation energy ɛ ₃ for jump conductivity in the active layer. The photovoltaic effect is explained by ballistic transit of the blocking layer by holes emitted from the contact which are then cooled in the active layer, as well as by the presence of a potential barrier ≈ɛ ₃ between the active and blocking layers. These factors are taken into account in a model for describing the major features of the dependence of the photovoltage on temperature and on the photon intensity and energy. Fiz. Tekh. Poluprovodn. 33, 456–463 (April 1999)     

Effect of successive implantation of Ag+(Cu+) and Xe+ ions on the recombination properties of CdxHg1−x Te crystals

The effect of successive double implantation of Ag⁺(Cu⁺) and Xe⁺ ions on the recombination properties of Cd_xHg_1−x Te (0.2<x<0.3) crystals has been investigated. It is shown that after implantation of ions of one chemical element, followed by diffusion thermal annealing at temperatures below 150–200 K, recombination through local levels lying 30±5 meV below the conduction band bottom dominates. Successive double implantation of Ag⁺(Cu⁺) and Xe⁺ ions followed by diffusion thermal annealing changes the course of the temperature dependence of the lifetime of the nonequilibrium charge carriers. It was determined that for Cd_xHg_1−x Te crystals with x⋍0.20–0.25 in the temperature interval 700–200 K the lifetime of the nonequilibrium charge carriers is low (τ<0.15 μs) and does not depend on the temperature. For Cd_xHg_1−x Te crystals with x⋍0.3 recombination of nonequilibrium charge carriers occurs through two types of levels: in the temperature range 140–200 K — deep levels E _t1⋍E _c −51 meV and at lower temperatures (77–140 K) — through shallower levels E _t2⋍E _c −(16±2) meV. Fiz. Tekh. Poluprovodn. 31, 786–789 (July 1997)     

Photoelectrical memory in GaAs/AlGaAs multilayer quantum-well structures

An increase in the dark current (by 2–3 orders of magnitude) in GaAs/Al_xGa_1−x As multilayer quantum-well structures with x⋍0.4 is observed after illumination of the structures with optical light (λ<1.3 μm). This increase is sustained for an extended time (more than 10³ s) at low temperatures. It then decreases to its initial value upon heating of the sample. A model of the barrier with local sag of the conduction band facilitating tunneling is proposed. The conduction band sag and the magnitude of the current grow due to optical ionization of uncontrolled deep level clusters present in the barrier and decrease due to subsequent capture of electrons from the conduction band by the deep levels upon heating. Fiz. Tekh. Poluprovodn. 32, 209–214 (February 1998)     

InAsSb/InAsSbP double-heterostructure lasers emitting in the 3–4 µm spectral range

Our earlier reports concerning the fabrication by liquid-phase epitaxy and investigation of InAsSbP/InAsSb/InAsSbP double heterostructure lasers emitting at 3–4 μm are reviewed. The dependences of spectral characteristics and the spatial distribution of the laser emission on temperature and current are discussed. Lasing modes are shifted by 0.5–1.0 cm⁻¹ to longer wavelengths with increasing temperature. The tuning of the lasing modes by means of current is very fast (10⁻⁸–10⁻¹² s). With increasing current, the modes are shifted to shorter wavelengths by 50–60 ? at 77 K. The maximum mode shift of 104 ? (10 cm⁻¹) is observed at 62 K. The spectral line width of the laser is as narrow as 10 MHz. Abnormally narrow directional patterns in the p-n junction plane are observed in some cases in the spatial distribution of laser emission. The current tuning of lasers, due to nonlinear optical effects, has been modeled mathematically in good agreement with the experiment. Transmittance spectra of OCS, NH₃, H₂O, CH₃Cl, and N₂O gases were recorded using current-tuned lasers. __________ Translated from Fizika i Tekhnika Poluprovodnikov, Vol. 35, No. 12, 2001, pp. 1466–1480. Original Russian Text Copyright ? 2001 by Danilova, Imenkov, Kolchanova, Yakovlev. See [1].     

Energy spectrum of acceptors in the semimagnetic semiconductors p-Hg1−x MnxTe in the spin-glass region

The far-IR transmission and photoconductivity in the semimagnetic alloys p-Hg_1−x Mn_xTe (x=0.20–0.22) at temperatures 2–7 K were investigated at fixed frequencies of optically pumped molecular lasers in the region 49–311 μm. We report the observation of photoexcitation of acceptors from the ground into excited states under conditions when the direct interaction of the magnetic moments of the manganese ions becomes substantial and results in the formation of a spin-glass phase. It was found that the internal field produced by the spontaneous and external polarizations of the magnetic moments of the Mn²⁺ ions in the spin-glass temperature range influences the energy spectrum of acceptors in a magnetic field. Fiz. Tekh. Poluprovodn. 32, 450–452 (April 1998)     

InGaAs/InP heterostructures with strained quantum wells and quantum dots (λ=1.5–1.9 µm)

Strongly strained In_xGa_1−x As/In_0.53Ga_0.47As/InP heterostructures with indium content x=0.69−1.0 in the active region were investigated experimentally and theoretically. Two types of structures were obtained by vapor-phase epitaxy from metalorganic compounds: 1) with isolated compression-strained quantum wells and 2) with self-organized nanosize InAs clusters (quantum dots). The temperature dependence of the quantum radiation efficiency of samples with quantum wells in the temperature range 77–265 K is characterized by T ₀=43 K. One reason for the low value of T ₀ is electron delocalization in the active region. The maximum radiation wavelength obtained in structures with quantum dots is 1.9 μm at 77 K. Fiz. Tekh. Poluprovodn. 33, 1105–1107 (September 1999)     

Two-mode diode-laser spectroscopy with a InAsSb/InAsSbP laser near 3.6 µm

The current dependence of the output frequency of InAsSb/InAsSbP diode lasers at wavelengths near 3.6 μm is studied. It is found that in these lasers the number of lasing modes can be reduced without introducing crystallographic defects. It is shown that the photon momentum aids in suppressing the spectral modes closest to the dominant mode. Two-mode laser spectroscopy is done over an interval of 2 cm⁻¹ for two gases, N₂O and CH₃Cl. Fiz. Tekh. Poluprovodn. 33, 1469–1474 (December 1999)     

Luminescence and electrical properties of InGaN/AlGaN/GaN light emitting diodes with multiple quantum wells

Luminescence spectra of light-emitting diodes based on InGaN/AlGaN/GaN heterostructures with multiple quantum wells are studied for currents in the range J=0.15 μA-150 mA. The comparatively high quantum efficiency for low J(J _max=0.5–1 mA) is a consequence of a low probability for the nonradiative tunnel current. The current-voltage characteristics J(V) are studied for J=10⁻¹²–10⁻¹ A; they are approximated by the function V=ϕk+mkT· [1n(J/J ₀)+(J/J ₁)^0.5] + J · R _s. The portion of V∞(J/J ₁)^0.5 and measurements of the dynamic capacitance indicate that i-layers adjacent to the active layer play an important role. The spectra are described by a model with a two-dimensional density of states with exponential tails in multiple quantum wells. The rise in T with increasing J is determined from the short-wavelength decay of the spectrum of the blue diodes: T=360–370 K for J=80–100 mA. An emission band is observed at 2.7–2.8 eV from green diodes at high J; this band may be explained by phase separation with different amounts of In in the InGaN. Fiz. Tekh. Poluprovodn. 33, 445–450 (April 1999)     

MOVPE growth of HgCdTe for high performance 3–5 µm photodiodes operating at 100–180K

New results are reported on the growth of high performance medium wavelength infrared (3–5 μm) (MWIR) HgCdTe photodiodes in the three-layer P-n-N configuration. The detector structures were grown in situ by metalorganic vapor phase epitaxy (MOVPE) on (211)B oriented CdZnTe substrates. The mobilities of the single n-type layers with x-values of ∼0.30 are in the range of (3–4.5)×10⁴ cm²/V-s at 80K. The lifetimes on unpassivated films range from 1–5 and 4–10 μs at 80 and 180K, respectively, which are within a factor of two or less of the lifetimes calculated for Auger-1 and radiative recombination. The P-n-N films were processed into variable-area backside-illuminated diagnostic arrays and tested for quantum efficiency, spectral response, R_DA, I–V curves and 1/f noise in the 120–180K range. The internal one-dimensional quantum efficiencies are in the range of 85–100%. The optical collection lengths are typically ∼25 μm. I–V curves showed that diffusion current is the dominant junction current mechanism for temperatures ≥100K. R₀A values are at the one-dimensional limit for n-side diffusion currents over the 100–180K range. 1/f noise was measured to be very low at 120K and is the same as that measured in similarly processed arrays from recent LPE grown P-on-N heterojunctions. The results demonstrate that MOVPE growth can be used for large area, high performance MWIR HgCdTe detector arrays operating in the 120–180K temperature range.     

Properties of p +-n structures with a buried layer of radiation-induced defects

The p ⁺-n structures based on n-type Si with dopant density 1.7×10¹³–1.2×10¹⁴ cm⁻³ were irradiated with ²³⁸Pu α particles. A layer containing radiation-induced defects with a density of the order of 3×10¹³ cm⁻³ was produced at a depth of 20 μm. This defect density gave rise to intense draining of nonequilibrium carriers in the injection-extraction regime with stationary injection as well as with pulsed generation by single particles. This makes it possible to treat the damaged layer as a plane, introduced into the bulk, with an infinite surface recombination rate. The radiation-induced defects also participated in decreasing the conductivity. A characteristic space charge distribution and, correspondingly, a bias dependence of the capacitance are observed in the structure under reverse bias. Despite the presence of formally three charge regions, four sections appear on the capacitance curve. This latter effect is due to the “additional” charge step arising in the contact potential difference field and is characteristic of compensated deep levels in semiconductors. Fiz. Tekh. Poluprovodn. 32, 359–365 (March 1998)     

Gain and internal losses in InGaAsSb/InAsSbP double-heterostructure lasers

We report on a study characterizing internal losses and the gain in InGaAsSb/InAsSbP diode-heterostructure lasers emitting in the mid-infrared (3–4 μm). Numerical simulations of the current dependence of the intensity of spontaneous emission above the laser threshold and of the differential quantum efficiency allowed us to determine the intraband absorption k ₀ ≈5.6×10⁻¹⁶ cm². The cavity-length dependence of the threshold current is used to estimate the internal losses at zero injection current α ₀≈5 cm⁻¹. Calculations of the internal losses at laser threshold showed that they increase more than fourfold when the cavity length is decreased from 500 μm to 100 μm. The temperature dependence of the differential quantum efficiency is explained on the assumption that intraband absorption with hole transitions into a split-off band occurs. It is shown that the maximum operating temperature of “short-cavity” lasers is determined by the intraband absorption rather than by Auger recombination. The internal losses are shown to have a linear current dependence. The separation of the quasi-Fermi levels as a function of current demonstrates an absence of voltage saturation of the p-n junction above threshold. Fiz. Tekh. Poluprovodn. 33, 759–763 (June 1999)