Future prospects of delignification pretreatments for the lignocellulosic materials to produce second generation bioethanol

Production of bioethanol is winning support from masses because it is a workable choice to solve the problems associated with the fluctuating prices of crude petroleum oil, climatic change, and reducing non‐renewable fuel reserves. First‐generation biofuels are produced directly from food crops. The biofuel (bioethanol, biodiesel) is ultimately derived from the starch, sugar, animal fats, and vegetable oil that these crops provide. It is important to note that the structure of the biofuel itself does not change between generations, but rather the source from which the fuel is derived changes. Corn, wheat, and sugar cane are the most commonly used first‐generation bioethanol feed stocks. Lignocellulosic materials are used as a feed stock for the production of second‐generation bioethanol. The major production steps are (1) delignification, (2) depolymerisation, and (3) fermentation. Agricultural residues are waste materials produced through the processing of agricultural crops. The main reason to use of these agricultural residues to produce bioethanol is to convert waste to value added products. The main challenges are the low yield of the cellulosic hydrolysis process due to the presence of lignin and hemicellulose with cellulose. Pretreatments of lignocellulosic materials to remove lignin and hemicellulose are the techniques used to enhance the hydrolysis. Present review article comprehensively discusses the different pretreatment methods of delignification for ethanol production. Published literature on pretreatments from 1982 to 2018 has been studied. Perspectives, gaps in studies, and recommendations are given to fully describe implementation of eight prominent pretreatments (milling, pyrolysis, organic solvents, steam explosion, hot water treatments, ozonolysis, enzymatic delignification, and genetic modification) for future research. The energy and environmental features of lignocellulosic materials are elaborated to show a sustainable aspect of second‐generation biofuel. It was felt necessary to discuss the concept of bio refinery to make biofuel production financially more attractive as well because the future prospects of second‐generation biofuel are promising.     

2,5-二甲基呋喃的燃烧性能及排放特性的研究

目前由于一种新的合成方法的发明,国际上对于2,5-二甲基呋喃(DMF)作为代用燃料更为关注.在分析比较DMF与乙醇、商用汽油理化性能的基础上,全面地对比研究了各燃料在DISI汽油机( Direct - Injection Spark - Ignition Engine)上的工作特性.初步研究结果表明DMF是很有发展前景的生物燃料,它的一些理化性能与汽油相似且优于乙醇(体积能量密度、研究法辛烷值均高于乙醇等等),并且DMF的层流燃烧速度与汽油接近.在发动机性能试验中,DMF的指示热效率、最高缸内燃烧温度等特征参数以及排放特性大体与汽油相似,稍差于乙醇.     

Research on ethanol production and use from sugar beet in Turkey

Emissions of greenhouse gases such as CO₂, CO, CH₄ and NO_X from fossil fuel use are implicated in climate change. The use of bioethanol is one means to reduce fossil fuel use and emissions of greenhouse gases. This study investigated research to produce ethanol from sugar beet and use as fuel in Turkey. The calculated demand for bioethanol amounted to some 220,000 m³ where a 5% ethanol mix in petrol was used. Turkey has the potential to produce 30 million ton of sugar beet, which is sufficient to meet the bioethanol demand.     

Key prospects and major development of hydrogen and bioethanol production

Cheap Production of bioethanol from renewable lignocellulosic waste has the imperative potential to economically cut burgeoning world dependency on fossils while reducing net emission of carbon dioxide (CO₂), a principal greenhouse gas (GHGs). This paper highlights key benefits and status of bioethanol production technologies, aiming mainly on recent developments and its key potentials in Pakistan. Most sector of Pakistan economy heavily rely on the energy and power that is being produced using traditional approaches like from oil and hydel. However, the sedimentation in dams cut-down the energy generation and overwhelmed severe energy crisis that are witnessed since last decade. Thus, Pakistan must go to avail alternative sources of energy like hydro, biomass and solar so that energy security can be ensured to recover the tremendous loss of economy. Renewable biomass is abundantly available in Pakistan which can be used to produce bioethanol and electricity. Currently, 22 distilleries are producing the ethanol from sugar cane bagasse and out of these only 8 distillation units are producing motor fuel grade ethanol. The current bioethanol production of country is about 403,500 tons/year along with 2423 tons of biodegradable waste available in major cities. In addition, Pakistan produces 6.57, 0.5, 0.66, and 2.66 million tons of sugarcane, corn, rice, and wheat straw per annum, respectively. This biomass can produce 1.6 million liters of bioethanol which can produce approximately 38% of Pakistan's electricity annually. Despite having large potential, Pakistan is still producing a few volumes of ethanol from sugarcane bagasse. The production of bioethanol can be boosted using (I) pretreatment of agricultural biomass by alkali (II) enzymatic and bacteria-based hydrolysis of the biomass (III) post-hydrolysis using pressurized steam above 100 °C (IV) Fermentation of the biomass@ 7–10 h and (V) and (VI) distillation of bioethanol. This study recommends (1) increase R&D capacities mainly in the west and central regions of Pakistan, (2) initiate mega-projects to promote integrated bio-ethanol production at agriculture farms by providing 1/3 subsides, (3) purchase of bioethanol directly from the major agricultural farms, (4) produce bioethanol related manpower from the key research institutes as specified in this study.     

Second generation bioethanol (SGB) production potential in Turkey

Energy demand is increasing by the years. Population's needs and technological investments bring the new approach about generating energy. It is considered that fossil fuels will not be able to respond to all energy requirements after approximately 150 years. Turkey imports nearly all of its petroleum and so this causes major economic problems. Turkey, as a major cereal producer, has a huge potential to grow energy crops and other cellulosic biomaterials and can obtain plant's residues, which are suitable to produce second generation bioethanol (SGB). With domestic production, bioethanol can reduce the dependence of petroleum for Turkey, and greenhouse gas emissions can be decreased. Taking into account Turkey's situation in fuel–oil consumption, costliness of gasoline and environmentally hazardous specification of fossil fuels, bioethanol gains more importance and increases in value. Especially, SGB production is rising. Foodstuffs are valuable, and producing ethanol from directly those materials can cause a crisis in Turkey because lignocellulosic bioethanol is becoming prominent. In this regard, bioethanol production in Turkey becomes a major alternative to petroleum and may be a key to new and clean energy source. Copyright © 2013 John Wiley & Sons, Ltd.     

Biofuel production: Challenges and opportunities

It is increasing clear that biofuels can be a viable source of renewable energy in contrast to the finite nature, geopolitical instability, and deleterious global effects of fossil fuel energy. Collectively, biofuels include any energy-enriched chemicals generated directly through the biological processes or derived from the chemical conversion from biomass of prior living organisms. Predominantly, biofuels are produced from photosynthetic organisms such as photosynthetic bacteria, micro- and macro-algae and vascular land plants. The primary products of biofuel may be in a gas, liquid, or solid form. These products can be further converted by biochemical, physical, and thermochemical methods. Biofuels can be classified into two categories: primary and secondary biofuels. The primary biofuels are directly produced from burning woody or cellulosic plant material and dry animal waste. The secondary biofuels can be classified into three generations that are each indirectly generated from plant and animal material. The first generation of biofuels is ethanol derived from food crops rich in starch or biodiesel taken from waste animal fats such as cooking grease. The second generation is bioethanol derived from non-food cellulosic biomass and biodiesel taken from oil-rich plant seed such as soybean or jatropha. The third generation is the biofuels generated from cyanobacterial, microalgae and other microbes, which is the most promising approach to meet the global energy demands. In this review, we present the recent progresses including challenges and opportunities in microbial biofuels production as well as the potential applications of microalgae as a platform of biomass production. Future research endeavors in biofuel production should be placed on the search of novel biofuel production species, optimization and improvement of culture conditions, genetic engineering of biofuel-producing species, complete understanding of the biofuel production mechanisms, and effective techniques for mass cultivation of microorganisms.     

Studies on ethanol production from water hyacinth—A review

With industrial development growing rapidly, there is a need for environmentally sustainable energy sources. Ethanol from biomass, bioethanol, is an attractive, sustainable energy fuel source for transportation. Based on the premise that fuel bioethanol can contribute to a cleaner environment and with the implementation of environmental protection laws in many countries, demand for this fuel is increasing. Efficient ethanol production is based on optimized processes where utilization of cheap substrates is highly demanding. Utilization of different types of lignocellulosic materials can be considered for production of ethanol. Among various types of lignocellulosic substances water hyacinth (Eichhornia crassipes) is a potential resource available in many tropical regions of the world. It is a noxious aquatic weed which grows fast. A considerable amount of research work is in progress for its bioconversion into ethanol using two-sequential steps of hydrolysis and fermentation. This paper reviews the bioconversion of water hyacinth to ethanol.     

Review of China’s bioethanol development and a case study of fuel supply, demand and distribution of bioethanol expansion by national application of E10

The increasing dependence on imported oil and tremendous greenhouse gases (GHG) emission is making the diversification of primary fuel such as petroleum a critical vital energy and environmental issue in China. China is promoting bioethanol by mandatory use in nine provinces and the expansion is on agenda. This paper first reviews China’s bioethanol development. Next, suitable feedstock crops for expanded ethanol production are discussed. Particularly, bioethanol expansion by national application of E10 is investigated from perspectives of potential in bioethanol supply, projected ethanol demand, and the possible cost-effective bioethanol distribution system. It is calculated that by making use of un-used land for feedstock planting and introduction of improved feedstock varieties, potential bioethanol production capacity in China will be up to 25.33 million tons per year. Ethanol demand for national application of E10 is projected to be around 7 million tons per year. A linear optimization model is used to consider the economic costs of distributing bioethanol in China. The optimization result suggests that development of bioethanol industry may focus on Henan, Jilin, Anhui, Jiangxi and Sichuan basin. It also estimates 53.79 RMB per ton of bioethanol for downstream rail or truck transportation remain a relatively small fraction of total fuel cost. Thanks to the well developed railway network in China, more bioethanol can be distributed at a relatively modest premium distribution costs and with low environmental influences.     

A comparative life cycle assessment of bio‐ and conventional fuels in a Canadian province

In this paper, a comprehensive study on corn‐based ethanol in a Canadian context is conducted, which uses the most reliable and up to date data, considers realistic assumptions, and applies sound methodology to provide a basis for developing future scenarios for corn‐based ethanol and compared the results with the conventional fuel, such as gasoline. It is estimated that the net energy value (NEV), defined as the energy content of a liter of ethanol minus the total energy use to produce a liter of ethanol, is 9.6 MJ L^?1 (LHV), when co‐products energy credits are not considered. In addition, a comparison of life cycle energy use for corn‐based ethanol and gasoline reveals that the life cycle energy use to produce a liter of ethanol is considerably less than the life cycle energy use to produce a liter of gasoline. Furthermore, a comparison of life cycle greenhouse gas (GHG) emissions for corn‐based ethanol and gasoline reveals that the life cycle GHG emissions released per liter of ethanol produced is an order of magnitude lesser than the life cycle GHG emissions released per liter of gasoline produced, when GHG emissions displaced by ethanol co‐products are considered in the estimation. Finally, a comparison of our results in terms of net fossil fuel input, net fossil fuel ratio and GHG emissions is carried out with the results obtained from the ERG biofuel analysis meta‐model (EBAMM) to reflect both Canadian and US perspectives. Copyright © 2010 John Wiley & Sons, Ltd.     

Progress in bioethanol processing

Production of ethanol (bioethanol) from biomass is one way to reduce both consumption of crude oil and environmental pollution. Bioethanol is appropriate for the mixed fuel in the gasoline engine because of its high octane number, and its low cetane number and high heat of vaporization impede self-ignition in the diesel engine. So, ignition improver, glow-plug, surface ignition, and pilot injection are applied to promote self-ignition by using diesel-bioethanol-blended fuel. Disadvantages of bioethanol include its lower energy density than gasoline, its corrosiveness, low flame luminosity, lower vapor pressure (making cold starts difficult), miscibility with water, and toxicity to ecosystems. Bioethanol can be produced from cellulosic feedstocks. One major problem with bioethanol production is the availability of raw materials for the production. The availability of feedstocks for bioethanol can vary considerably from season to season and depends on geographic locations. Lignocellulosic biomass is the most promising feedstock considering its great availability and low cost, but the large-scale commercial production of fuel bioethanol from lignocellulosic materials has still not been implemented. Conversion technologies for producing bioethanol from cellulosic biomass resources such as forest materials, agricultural residues and urban wastes are under development and have not yet been demonstrated commercially. For designing fuel bioethanol production processes, assessment of utilization of different feedstocks (i.e. sucrose containing, starchy materials, lignocellulosic biomass) is required considering the big share of raw materials in bioethanol costs. In this work a review of the biological and thermochemical methods that could be used to produce bioethanol is made and an analysis of its global production trends is carried out.     

How to improve the economy of bioethanol production in Serbia

Bioethanol accounts for the majority of biofuel use worldwide, either as a fuel or a gasoline enhancer. In Serbia, the industrial production of bioethanol still relies on conventional feedstocks containing starch and sugar such as corn, wheat and molasses. In order to improve the economy of bioethanol production and to avoid the competition of the feedstock utilization for food and energy, several production approaches based on crop selection, process integration and waste utilization were considered in this paper. Particular attention was put on utilization of non conventional crops such as triticale and damaged crops not appropriate for food consumption. Potential of lignocellulosic biomass for the production of second generation ethanol in Serbia was also considered as well as the utilization of stillage as a main by-product. The investigated approaches can significantly improve the economy of bioethanol production and contribute to solve serious environmental problems.     

An argument for using biomethane generated from grass as a biofuel in Ireland

The Biofuels Directive proposes 5.75% of transport fuel (by energy) to be replaced by biofuel in the year 2010. This equates to 11.3 PJ in Ireland, which equates to 538 million litres of ethanol or 323 million litres of biodiesel. However, if using biodiesel produced through bioesterification of rapeseed oil, then 6.3% of Irish agricultural land is required to produce 5.75% of transport fuel. Furthermore this equates to 70% of arable land.Using ethanol produced from wheat, 3.9% of Irish agricultural land is required to produce 5.75% of transport fuel. Ethanol produces less energy from a crop, than the energy in the biogas generated when the crop is digested. The ethanol production process uses up to 60% of the produced energy in the final ethanol product. It is shown for compressed biomethane generated from silage that the total parasitic demand of the process is of the order of 25%.Grass/silage is a crop that Irish farmers are familiar with, over 90% of Irish agricultural land is under grass. Grass does not require rotation, it does not require annual ploughing (releasing NO_x), and it sequesters carbon into the soil. Digesting silage, scrubbing the biogas to biomethane, and compressing and utilizing it as a transport fuel, is suggested to be the optimum biofuel for Ireland. The 2010 biofuels target can be met with 1.6% of agricultural land; this is four times less land than required using rapeseed. A conservative economic analysis would suggest a lower cost than ethanol produced from wheat.     

Antimicrobial strategies for limiting bacterial contaminants in fuel bioethanol fermentations

Bioethanol continues to be offered as a viable solution for complex problems ranging from global warming and national energy security to local economic development. Fuel bioethanol burns cleaner than gasoline, is derived from renewable agricultural products, and creates local jobs and income. In December 2007, President Bush signed into law the Energy Independence and Security Act, which increased the renewable fuel standard that was mandated under energy Policy Act of 2005 to 36 billion gallons by 2022.In order to achieve this goal, ethanol production would need to be generated primarily from corn and cellulosic materials. Bioethanol producers are currently involved in variety of technological innovations to reduce energy consumption and production costs, increased efficiency and reduced emissions using the best available control technologies. However, industrial ethanol fermentation is a non-sterile process and contaminant microorganisms can lead to a decrease in industrial productivity and significant economic loss. Currently, bioethanol industries use different antimicrobials including antibiotics to control the contaminants in the fermentors. The emergence of antibiotic resistance among contaminant bacteria in bioethanol fermentors warrants the need for alternative antimicrobials to retain bioethanol production at a profitable level. In addition more and more ethanol producers are seeking to generate distillers grains that can be labeled antibiotic free to be sold in international markets where some restrictions are already in place for reducing and/or eliminating antibiotics usage in animal feed. This review examines the contamination problems, various intervention methods, emergence of antibiotic resistance in contaminant bacteria, and potential alternative options to elucidate antimicrobial products from various natural sources. In particular, emphasis has been given for natural antibacterial products from plant derived products to suggest a new research avenue for the search of new, non-conventional antimicrobial agents to control the contamination problem in the fuel bioethanol industries.     

我国生物燃料乙醇产业新进展

燃料乙醇产业发展近20年来,为支持国家三农事业、改善大气环境、减少原油进口做出多重贡献。近年来,在国家政策推动下,我国生物燃料乙醇产业引起各界高度关注。产业链相关的生产企业、科研机构、石化和汽车行业等从不同视角做了大量实践和研究。本文从生物燃料乙醇技术进步、炼油产业的关联效应、对汽车行业的影响三方面进行概述,分析当前发展生物燃料乙醇产业呈现的新趋势。技术进步方面,从研究到生产实际,已更多地着眼于开发多种原料灵活加工的方式,构建新的产品结构,并采用技术手段降低过程能耗、发掘净能量提升空间、降低生产成本,开辟纤维素乙醇技术的新途径;此外,在产品转化率的科学评价方式、建立可持续综合效益评估模型以及设计新型对称双阴极结构解决乙醇燃料电池稳定性问题有更深入的研究。炼油产业关联效应方面,大量研究分析了油品升级、乙醇的加入对尾气污染物排放的影响;而燃料乙醇对炼油行业的影响涉及油库的改造、对组分油品质的要求、产品结构优化等诸多层面。汽车行业对新燃料系统的关注度也在不断提高,在乙醇汽油的燃烧效率、喷射策略和非常规污染物排放控制等方面有新的方案和比较。整体产业链的研发活力不断加强,正带动产业向着高质量方向发展。     

Liquid biofuels potential and outlook in Iran

Iran’s diversity of terrain and climate enables cultivation of a variety of energy crops suitable for liquid biofuels production. In Iran, the easily and readily available biofuel feedstock today for production of bioethanol is molasses from sugar cane and sugar beet. There is also about 17.86 million tons of crops waste from which nearly 5 billion liters of bioethanol could be produced annually. This amount of bioethanol is sufficient to carry out E10 for spark ignition engine vehicles in Iran by 2026. There is also enormous potential for cultivation of energy plants such as cellulosic materials and algae. Iran has 7%of its area covered with forest products which are suitable sources for liquid biofuels such bioethanol and biodiesel. Iran also has a long tradition of fishing in Caspian Sea and Persian Gulf with about 3200 km coastline and on inland rivers. The produced fish oil and other plant oils such as palm tree, jatropha, castor plant and algae are suitable biodiesel feedstock. Out of 1.5 million tons of edible cooking oil consumed in Iran annually, about 20% of it can be considered as waste, which is suitable biodiesel feedstock.This quantity along with the other possible potential feedstock are favorable sources to carry out B10 step by step until 2026.     

Biomass availability for lignocellulosic ethanol production

The ethanol industry in North America uses starch derived from corn as its primary feedstock. In order to better understand the geographical distribution of advanced ethanol production, potential sources of lignocellulosic biomass for the process are considered. It is shown that the corn-producing regions of North America already support significant amounts of ethanol production, and that few unexploited sources of corn remain for the industry to utilize. Accessing other sources of sugar, including other types of biomass such as lignocellulosic materials, will become necessary for the industry as it expands, quite apart from the need to meet government mandates. The ability of bioconversion and thermochemical conversion to generate biofuels from lignocellulosic biomass is reviewed. The availability of lignocellulosic residues from agricultural and forestry operations is described, and the potential biofuel production associated with these residues is described. A residue-based process could greatly extend the potential of the ethanol industry to become a substantial contributor to the fuel and energy requirements of North America. It is estimated that ethanol production from residues could provide up to 13.7% of Canada’s 2009 transportation fuel demand, and up to 5.2% of the United States’ 2010 fuel demand. Utilizing lignocellulosic biomass will extend the geographic range of the biofuel industry, and increase the stability and security of this sector by reducing the impact of localized disruptions in supply. Development of a residue-based industry will help create the technologies needed to process energy crops as North America moves towards greater transportation fuel independence.     

Potential of bioethanol production from agricultural wastes in Iran

The production of bioethanol from agricultural residues such as wheat, barley, sugar cane, corn and rice in Iran is investigated in this paper. In Iran, agricultural residues are not commonly used for energy application. This paper aims to cover several perspectives on the size of the bioethanol feedstock resource in Iran. Crop residues and sugar cane bagasse are included in feedstock for production of bioethanol. There are approximately 17.86 MT of wasted crops in Iran that can potentially produce 4.91 GL of bioethanol per year. Wheat, sugar cane bagasse, rice, barely and corn are the most favourable bioethanol production source in Iran. Agricultural waste materials can be used for production of bioethanol fuel. Bioethanol can be considered as the optimum alternative fuel for gasoline. Bioethanol is an environmentally friendly fuel and has the potential to provide comparable engine performance results.     

Acidogenesis of cellulosic hydrolysates for new generation biofuels

This article presents a comprehensive review on hydrolysis and acidogenesis of lignocellulosic waste biomass and makes clear new perspectives in biofuel research. Specifically, the acidogenesis of lignocellulosics and liquid effluent have been discussed extensively with potential goal the production of a new generation biofuel. This new biofuel can be produced through esterification of volatile fatty acids with ethanol (produced simultaneously during the acidogenesis) or/and with another alcohol. That will overcome the major problems faced during bioethanol production and concerns the high energy demand of the bioethanol production plant. Specifically, it was found that the main volatile fatty acids formed are formic, acetic, propionic, butyric, lactic and valeric. Their formation depends on NADH/NAD+ proportion and on conditions such as pH, organic load and chemical composition of the waste is treated. These conditions look to affect microorganisms survival and the formation of predominant acetic, butyric and lactic acid. The use of γ-alumina promotes the formation of volatile fatty acids simultaneously with bio-ethanol.     

Agricultural waste resources and biogas energy potential in rural areas of Lao PDR

Lao PDR lacks of conventional energy resources, such as oil and natural gas, and 100% of fossil fuels are imported from abroad. Fossil fuel consumption in Lao PDR in 2010 was about 561 million liters and rapidly increased to 716 million liters by 2015. However, Lao PDR has a high potential for renewable energy, especially from hydropower, agricultural wastes, and livestock wastes, in which agricultural and livestock annually produced a large amount of agricultural residues as a favorable renewable energy sources. In 2016, productivity crops were estimated for 24,608,840 ton and these products amount can be generated annual agricultural residues for 12,525,000 ton, which can be estimated to total of energy potential was 197,840 GJ or 55,001 GWh. The majority of livestock in country are buffaloes, cattle, swine, and poultry; large amount of livestock manure produced from each region and can be feedstock as substrate for biogas digester, which these amounts were estimated about 1,583,740 kg TS/day, and equivalent to 439,917 m3/day of biogas production or 658,376 kWh/day of energy generation. Therefore, objective of this paper is unique to promote and research development the agroforestry residues and livestock wastes as renewable energy resources, and its energy potential for biofuel production, including, biodiesel, bioethanol and biogas in each region of Laos.