Tracking solute atoms during bainite reaction in a nanocrystalline steel

Abstract

The extremely slow transformation kinetics of a nanocrystalline bainitic steel makes this novel structure the perfect candidate to determine the carbon content of the bainitic ferrite away from any carbon enriched regions, such as dislocations and boundaries, as the bainite transformation progresses at extremely low temperatures. The purpose of this atom probe tomography study was to systematically track atom distributions during the bainite reaction in a nanocrystalline steel. The results will provide new experimental evidence on the explanation for the incomplete reaction phenomenon and the carbon supersaturation of the bainitic ferrite during transformation, subjects critically relevant to understanding the atomic mechanism controlling bainitic ferrite growth.     

Bainitic transformation kinetics and stress assisted transformation

Abstract

With reference to experimental data, the effects of stress, chemical composition, and transformation temperature on bainitic transformation kinetics are analysed. A decrease of transformation temperature or an increase of carbon equivalent results in a slow rate of bainitic transformation and reduces the promotive effect of stress induced transformation. Moreover, the relative effect of unit stress on kinetic parameter b in the Avrami equation for bainitic transformation is found to be in the 10^-3 order of magnitude, and n (Avrami index) tends to increase with decrease of transformation temperature. A comprehensive model to depict bainitic transformation kinetics dependent on stress and chemical composition as well as transformation temperature is established.     

Model for transition from upper to lower bainite

Abstract

An attempt is made to model the transition from upper to lower bainite in steels, based on the hypothesis that bainitic ferrite grows with a supersaturation of carbon in solid solution. The theory involves a comparison between the time required to reject the excess carbon into the residual austenite by diffusion and the time required to obtain a detectable degree of cementite precipitation in the bainitic ferrite. If the precipitation process is relatively rapid, then it is assumed that lower bainite is obtained. The results are found to be in broad agreement with published experimental data.

MST/1095     

Transformation kinetics of unalloyed and high Mn austempered ductile iron

Abstract

The kinetics of bainitic transformation was studied in unalloyed and 1%Mn alloyed ductile irons. The samples were subjected to different austempering heat treatment cycles in dilatometry equipment. The results showed the effect of Mn on delaying the start and end of bainitic transformation, supposedly because of Mn segregation to the primary austenite grain boundaries. Decreasing austempering temperature led to precipitation of carbides inside the lower bainitic ferrite plates and therefore, more dilatation during the bainitic reaction. The dilatometric results were also used to calculate n and k in the Johnson-Mehl-Avrami equation and to derive the time-temperature-transformation diagrams. X-ray results were used to calculate the quantitative amount of precipitated carbides within lower bainitic ferrite and the dilatation during austempering.     

Low carbon high manganese bainitic steel

Abstract

The present study concerns the mechanical properties of low carbon (0·05 wt-%) high Mn bainitic steel. The continuous cooling transformation diagram exhibited bainitic transformation without any prior diffusive transformation of austenite even for a cooling rate as low as 0·5°C/s. The bainitic steels have shown continuous elongation behaviour with attractive combination of strength (>1200 MPa) and elongation (>14%). The bainitic microstructure obtained after annealing treatment has yielded excellent combination of strength, uniform elongation, yield ratio and static toughness value.     

Sliding wear and low cycle fatigue properties of new carbide free bainitic rail steel

Abstract

A new carbide free bainitic rail steel was prepared, whose comprehensive mechanical properties are equal or superior to current premium pearlitic and bainitic rail steels. The new bainitic rail steel possesses better low cycle fatigue properties and approximate resistance to wear compared with current pearlitic rail steel. The carbon enriched film-like austenite between the ferrite of the new bainitic rail steel can delay crack initiation and propagation in fatigue processes, resulting in a relatively high low cycle fatigue life (about two times) compared to the pearlitic rail steel. Finally, a wear model during sliding wear and deformation model during the low cycle fatigue of pearlitic and bainitic rail steels were established. As a result, the bainitic rail steel with a relatively reasonable combination of wear and fatigue properties compared to pearlitic rail steel is obtained, in which the initiation and propagation of cracks may be partially or entirely removed during the wear process.     

Models for transformation plasticity in loaded steels subjected to bainitic and martensitic transformation

Abstract

The parameter k in the transformation plasticity model for bainitic and martensitic transformations is determined by experiments on four types of steel. The relationships between k and stress and chemical composition of the steels subjected to bainitic and martensitic transformations are obtained. In addition, based on experiments using 26Cr2Ni4MoV steel, the value of k is found first to increase with the increment of stress and then to remain unchanged when predeformation before transformation occurs.     

Stress induced transformation to bainite in Fe–Cr–Mo–C pressure vessel steel

Abstract

The kinetics of the bainitic transformation in a polycrystalline Fe–Cr–Mo–C alloy designed for applications in energy generation systems has been studied, with particular attention to the influence of mild tensile stresses on transformation behaviour. The steel was found to exhibit the incomplete reaction phenomenon, in which transformation to bainite stops well before the residual austenite acquires its paraequilibrium carbon concentration. It was found that even in the absence of an applied stress, the growth of bainitic ferrite caused anisotropic changes in specimen dimensions, consistent with the existence of crystallographic texture in its austenitic condition and, significantly, with the nature of the invariant-plane strain shape change that accompanies the growth of bainitic ferrite. Thus, transformation induced plasticity could be detected in fine grained polycrystalline samples, even in the absence of applied stress. The application of an external stress was found to alter radically the transformation behaviour, with clear evidence that the stress tends to favour the development of certain crystallographic variants of bainite, even though the stress may be well below the single phase yield strength. It is concluded that the transformation is influenced significantly by stresses as low as 45 MN m^?2, even though the effect may not be obvious in metallographic studies. The results are analysed and discussed in terms of the mechanism of the bainite transformation.

MST/1394     

Quantitative research on effects of stresses and strains on bainitic transformation kinetics and transformation plasticity

Abstract

In this paper, the effect of stress and strain on bainitic transformation kinetics and transformation plasticity have been studied quantitatively by means of experiments on a Gleeble-1500 testing machine. It is concluded that applied stresses will promote the evolution of bainitic transformation and increase the maximum volume fraction of the new phase and increase the value of the transformation plasticity parameter. Moreover, predeformation due to applied stress affects both the maximum volume fraction of the new phase and the value of the transformation plasticity parameter with increasing applied stress; but it has little effect on the variation of transformation kinetics parameter with the applied stresses.     

Metallography of bainitic transformation in austempered ductile iron

Abstract

An unalloyed nodular cast iron has been used to investigate the development of microstructure on heat treating in the bainite temperature region. Specimens were austenitised at 900°C for 1·5 h, then austempered for 1, 2, or 3 h at 250,300, and 350°C, respectively, and examined by light, transmission electron, and scanning electron microscopy. Experimental results indicate a microstructure consisting of a stable, highly enriched, retained austenite with one of two lower bainitic ferrite morphologies. One of these morphologies is carbide free acicular ferrite for specimens austempered at 350°C for 1 h and the other is bainitic ferrite in which carbide is distributed within the ferrite produced by different heat treatment conditions. Austempering at 350°C for 2 h and at 300°C for 1 and 2 h resulted in the formation of transition carbides in bainitic ferrite platelets. The η carbide was formed at 350°C for 2 h by precipitation from a bainitic ferrite supersaturated with carbon. By contrast, ? carbide was associated with austempering at 300°C for 1 and 2 h and precipitates either on the austenite twin/bainitic ferrite boundaries or within the bainitic ferrite. The fracture mode of tensile and impact specimens in the austempered condition was fully ductile compared with as cast specimens, which had mixed fracture characteristics.

MST/1646     

Microstructural examination of two experimental high-strength bainitic low-alloy steels containing silicon

Abstract

A detailed microstructural characterization of two silicon-containing low-alloy steels, Fe–0·2C–2Si–3Mn and Fe–0·4C–2Si–4Ni (nominal wt-%), isothermally transformed in the bainitic temperature range (~ 400–250°C), has been carried out using principally electron microscopy, X-ray diffraction, and dilatometry. Upper bainite in these silicon-containing steels consists of bainitic ferrite laths and interwoven thin films of retained austenite instead of cementite. Coarser granular regions of retained austenite may also be obtained. The bainitic ferrite laths (or plates) in lower bainitic structures contain intralath carbides, but the interlath morphology of retained austenite still occurs. The variations in these microstructures with isothermal transformation temperature, and the thermal stability of the retained austenite phase is described and discussed.

MST/526     

Effect of microsegregation on carbide-free bainitic transformation in a high-silicon cast steel

ABSTRACT

A high silicon cast steel was studied in the as-cast condition in order to characterise its solidification macrostructure and microsegregation. The steel, poured into 32?mm-keel-block-shaped moulds, has a coarse solidification structure and marked microsegregation, containing low-alloyed areas with a total alloy content (Cr?+?Mn?+?Si) of 2.3 wt-% and high-alloyed zones of 5.3 wt-%. The bainitic transformation behaviour at 300°C was studied at different austempering times. The bainitic reaction occurs at different rates within the specimen volume, because of its chemical heterogeneity. An austempering heat treatment leads to an inhomogeneous carbide-free bainitic microstructure with different phase amounts, morphologies and sizes. The heterogeneous distribution of sizes and chemical compositions of retained austenite is speculated to benefit mechanical properties.     

Fracture toughness of two experimental high-strength bainitic low-alloy steels containing silicon

Abstract

The fracture toughness of two experimental silicon-containing steels in the bainitic condition has been measured and related to the microstructural state of the steels. The optimum bainitic microstructure for high strength and high toughness combinations consists of bainitic ferrite and thin interwoven laths of retained austenite instead of cementite, this condition being achieved through the silicon addition to the steels. The thin films of retained austenite are thermally and mechanically stable and act to reduce the effective fracture grain size and also possibly help to blunt propagating microcracks; blockier volumes of retained austenite are unstable and hence not beneficial to toughness. The two experimental steels achieved strength and toughness values equal to, or better than, some commercial steels in the martensitic condition.

MST/528     

Transition from bainite to acicular ferrite in reheated Fe–Cr–C weld deposits

Abstract

Factors controlling the transition from acicular ferrite to bainite in Fe–Cr–C weld metals have been investigated. It appears that the presence of allotriomorphs of ferrite at austenite grain boundaries has the effect of suppressing the formation of bainitic sheaves. This in turn allows the acicular ferrite plates to develop on intragranular nucleation sites. A theoretical analysis indicates that bainitic transformation is prevented from developing at the allotriomorphic ferrite/austenite boundaries by the carbon concentration field present in the austenite at the allotriomorphic ferrite/austenite interface. This field does not homogenise within the residual austenite during the time scale of the experiments.

MST/1217     

Microstructure and dynamic strain aging phenomena in two structural steels

Abstract

Two steels with bainitic and martensitic microstructures have been investigated with respect to the changes occurring in their uniaxial tensile properties in the temperature regime where they display dynamic strain aging (DSA) behaviour. The variations in yield strength, ultimate tensile strength, ductility and strain rate sensitivity in the case of martensitic steel have been found to vary in an embrittling manner as compared with those observed in the case of the bainitic steel within the DSA temperature regime. An attempt has been made to provide an insight into the difference in manifestations of DSA on the uniaxial behaviour of the two steels.     

Anomalies in carbon concentration determinations from nanostructured bainite

Abstract

There are large discrepancies in the measured concentrations of carbon in the ferrite and austenite within nanostructured bainite and carbide-free bainitic steels in general. The concentrations are usually measured on the basis of lattice parameters determined using X-ray diffraction, lattice imaging in transmission microscopy, or using the atom probe technique, i.e. time-of-flight mass spectroscopy. We examine here a number of difficulties with these methods and assess the role of defects, crystal symmetry and the heterogeneous distribution of carbon in interpreting the experimental data. Issues where experimental and theoretical work is needed are identified.     

Influence of sulphur additions on impact properties of bainitic or martensitic steels

Abstract

Effects of sulphur addition on the Charpy impact properties of various continuously cooled bainitic steels with different prior austenite grain size, hardness, and content of retained austenite were investigated and compared with martensitic steels. The impact properties of 1473 K austenitised bainitic steels were improved with increasing sulphur content up to 0·1 wt-%, while the impact properties of martensitic steels were deteriorated with increasing sulphur content. The crack initiation energy of bainitic steels increased with the increase of sulphur content because the structure units surrounded by the high angle boundaries were refined with the increase of manganese sulphide inclusions which caused the expansion of ductile fracture area. On the other hand, the impact energy, particularly the crack propagation energy, of martensitic steels decreased with increasing sulphur content because the nucleation sites of voids increased with the increase of manganese sulphide inclusions in the ductile fracture region.     

Fracture behaviour of 8%Ni 980 MPa high strength steel at various temperatures Part 3 – Four-point notched bend tests

Abstract

Based on the results of four-point notched bend tests together with detailed microscopic observations of fracture surfaces and crack configurations below the unbroken notch roots of double notch specimens, the fracture mechanisms in notched specimens of 8%Ni high strength (980 MPa) steel have been observed to be as follows. A fibrous crack initiates in the bainitic matrix at the notch root and then develops into a cleavage crack at a critical length. The cleavage crack propagates in an unstable manner and causes the final fracture of specimen. The critical event controlling the cleavage fracture is the propagation of the bainitic packet-sized crack, and the local fracture stress is measured as around 1845–2200 MPa.     

Transition from upper to lower bainite in Fe–C–Cr steel

Abstract

An analytical evaluation of transition temperature from upper to lower bainite in Fe – 0·38C – 0·93Cr (wt-%) steel was carried out. Calculations were based on the model constructed by Takahashi and Bhadeshia, which involves a comparison between the time t_θ needed to precipitate cementite within the bainitic ferrite plates with the time t_θ required to decarburise supersaturated ferrite plates. It was found that the distribution of lath widths, shown by histograms, of the bainitic ferrite varies with isothermal transformation temperatures and holding times. The transition between upper and lower bainite is found to occur over a narrow range of temperatures (350 – 410°C) and depends on the thickness of bainitic ferrite laths and the volume fraction of precipitated cementite. On comparing t _d and t_θ it was found that a transition temperature from upper to lower bainite reaction L _S of about 350°C could be predicted if the thickness of bainitic ferrite laths is set as w _o = 0·1 μm and the volume fraction of cementite set as ξ = 0·01. Calculated differences in the relative behaviour of t _d and t_θ revealed the occurrence of upper and lower bainite in steel Fe – 0·38C – 0·93Cr consistent with the results of transmission electron microscopy investigation.     

Design of novel high strength bainitic steels: Part 1

Abstract

Mixed microstructures consisting of fine plates of upper bainitic ferrite separated by thin films of stable retained austenite have seen many applications in recent years. There may also be some martensite present, although carbides are avoided by the judicious use of silicon as an alloying element. The essential principles governing the optimisation of such microstructures are well established, particularly that large regions of unstable high carbon retained austenite must be avoided. With careful design, impressive combinations of strength and toughness have been reported for high silicon bainitic steels. The aim of the present work was to ascertain how far these concepts could be extended to achieve unprecedented combinations of strength and toughness in bulk samples subjected to continuous cooling transformation, consistent with certain hardenability and processing requirements. Thus, this paper (part 1 of a two part study) deals with the design, using phase transformation theory, of a series of bainitic alloys, given a set of industrial constraints. Part 2 of the study concerns the experimental verification of the design process.