气-液-固三相气升式环流反应器中牛顿型及非牛顿型流体局部液相传质模型

A small scale isotropic mass transfer model was developed for the local liquid side mass transfer coefficients in gas-liquid-solid three-phase flow airlift loop reactor for Newtonian and non-Newtonian fluids.It is based on Higbie's penetration theory and Kolmogoroff's theory of isotropic turbulence with k1 = 3√2Dε1/3 1/π(η-1/3 1 -λ-1/3 f),where ε1 is local rate of energy dissipation,λf is the local microscale,η1 is the local Kolmogoroff scale and D is the diffusion coefficient.The capability of the proposed model is discussed in the light of experimental data obtained from 12 L gas-liquid-solid three-phase flow airlift loop reactor using Newtonian and non-Newtonian fluids.Good agreement with the experimental data was obtained over a wide range of conditions suggesting a general applicability of the proposed model.     

气-液-固三相下喷环流反应器局部气相流动特性

The local gas-phase flow characteristics such as local gas holdup (εg), local bubble velocity (Vb) and local bubble mean diameter (db) at a specified point in a gas-liquid-solid three-phase reversed flow jet loop reactor was experimentally investigated by a five-point conductivity probe. The effects of gas jet flow rate, liquid jet flow rate, solid loading, nozzle diameter and axial position on the local εg, Vb and db profiles were discussed. The presence of solids at low solid concentrations not only increased the local εg and Vb, but also decreased the local db. The optimum solid loading for the maximum local εg and Vb together with the minimum local db was 0.16 × 10-3 m3, corresponding to a solid volume fraction, εS = 2.5%.     

三相连续环流反应器中氧的液相传质过程

在空气-水-玻璃珠三相连续操作环流反应器中,利用动态溶氧方法研究了表观气速(Ug=0.01~0.13 m/s)、进料浆速(USL=0.001~0.011 m/s)、浆相质量固含率(es=0~30%, w)和固相颗粒大小(dp=59, 200 mm)对环流反应器内氧的液相传质性能的影响. 结果表明,在考察范围内,环流反应器传质系数随表观气速增大而增大,受进料浆速变化的影响较小,随浆相固含率增大呈现先增大后减小的趋势,但在高固含率下(es≥10%, w)的影响不显著;随固相颗粒粒径增大而减小. 同时得到了液相体积传质系数的经验关联式.     

三相下喷式环流反应器的传质性能

在三相非牛顿型流体体系中，对下喷式环流反应器传质特性进行了实验研究。讨论了表观气速、能量耗散速率、导流筒直径与反应器直径比、喷嘴直径、导流筒下端距反应器底部的距离、固体装填量、羧甲基纤维素钠（ＣＭＣ）溶液浓度及其流变特性对它的影响。实验结果表明，容积传质系数随表观气速和能量耗散速率的增加有所增加，在实验条件下，发现最优的导流筒直径与反应器直径比在０．４～０．４５这一范围、固体装填量大约为３％（体积百分比）、导流筒下端距反应器底部的距离为０．０８ｍ左右。同时提出了容积传质系数的经验关联式。     

气升式三相内环流生物反应器内流体力学和传质性能的实验研究

本文通过实验研究了气升式三相内环流反应器在非牛顿流体中的流体动力学特性和传质性能.考察了表观气速、导流筒与反应器截面积之比、固体粒子加入量及CMC溶液浓度等操作条件对气升式三相内环流生物反应器中导流筒与环隙内液体循环速度、气含率、固含率及气-液体积传质系数等流动与传质特性参数的影响.     

三相牛顿流体缩放型导流筒气升式内环流反应器研究

从气相含率、液体循环速度和体积氧传质系数方面研究三相牛顿流体条件下的缩放型导流筒气升式内环流反应器内的流体力学与传质特性。内导流筒分别采用一种传统圆柱型和三种不同结构参数的缩放型, 实验条件为空气 水 树脂三相系统。实验结果表明, 与传统圆柱型导流筒相比较, 缩放型导流筒气相含率和体积氧传质系数分别提高８ ％ 和１０ ％ 以上。圆柱型导流筒反应器的液体循环量（ Ａｒ·ＵＬｒ） 大于各含缩放型导流筒反应器的液体循环量。在固含率分别为０ ％ ,３ ％ ,６ ％ 及９ ％ 条件下, 气相含率和体积氧传质系数随固含率的增大而提高, 液体循环速度随固含率的增大而减少。此外还在Ｈｉｇｂｉｅ 穿透理论和Ｋｏｌｏｍｏｇｏｒｏｆｆ 各向同性理论的基础上建立了体积氧传质系数与操作条件及管结构参数之间的关联式     

非牛顿流体在气升式反应器中的流动特性

以非牛顿型流体在气升式内环流反应器中流动特性为研究对象，考察了在气－液－固三相体系中气含率和液体循环速度随不同的表观气速、固体颗粒粒径和浓度、设备结构尺寸的变化规律。对实验数据进行了回归处理得到气含率和循环速度的经验关联式，并对非牛顿型流体和牛顿型流体在同一反应器中的流动特性作了比较     

气液固三相环流反应器的研究进展

综述了气液固三相环流反应器的类型及工作原理、气液固三相环流反应器的特性参数(气含率、固含率、循环液速、液相体积传质系数、轴向分散系数)的测量方法和影响因素，介绍了特性参数的数学模型。并对现有模型进行了评述。对今后的研究提出一些建议。     

气升式内环流反应器中的液相轴向返混

在５５Ｌ工作体积的气升式内环流反应器中，用羧甲基纤维素溶液模拟生物发酵液的粘性非牛顿流体行为，研究了表观气速及流体物性等参数对气升式内环流反应器中液相在上升段及下降段区域中轴向返混系数的影响，并与其他作用的实验结果进行了比较和分析。     

矩形截面气升式环流反应器中非牛顿流体的气含率与传质系数的研究

研究了一种矩形截面气升式环流反应器,用幂律τ=η_ογ~n(n<1)来表示流体流变学特性的变化.在这类反应器中,假塑性非牛顿流体的气含率ε_g与传质系数K_La的变化规律可用半经验关联式表示ε_g=0.2535(η_ο5000~(n-1))~(-0.161)(1+A_d/A_r)~(-0.434)u_(gr)~(0.856-0.161n)K_La=0.0192(η_ο5000~(n-1))~(-0.902)(1+A_d/A_r)~(-1.228)u_(gr)~(1.955-0.902n)并讨论了该类反应器结构及运行状况,流体性质变化时,反应器传质动力学特性、流动特性和操作弹性变化的规律.     

气升式环流反应器内传质行为的分析与测量

1 INTRODUCTION Airlift loop reactors have emerged as one of the most promising devices in chemical, biochemical and environmental engineering operations. Its main ad-vantages over conventional reactors include excellent contact among different phases, ease of removal or replenishment of particles, and high heat and mass transfer rates[1]. High gas-liquid contacting area and favorable flow pattern are the attractive features of this type of three-phase contactors. Typical processes that ca…     

并流喷射填料塔板流体力学及传质性质性能的实验研究

The jet co-flow packing tray(JCPT) with three different types of perforation in equal opening fraction was tested in two rectangular columns with 0.12 m in width and 0.27 m in length operated with air-water system.The influences of gas phase orifice F-factor and clear liquid height He on the amount of liquid lifted, Q, were examined. The corresponding correlation between Q with F-factor and equivalent diameter of perforated holes as well as Hc was obtained. Furthermore, the non-steady state mass transfer performance of JCPT was tested by the humidification of air with water. Finally, by the analysis of data and comparison, it was found that the JCPT tray with single cap and two holes exhibited the highest mass transfer efficiency and best performance.     

水平管内气液段塞流液塞长度发展规律的实验和模拟研究

In petroleum industry, the slug flow is a fre-quently encountered flow regime in multiphase flowpipeline. For pipeline designers, the liquid slug lengthdistribution is important for the proper design ofdownstream facilities, such as slug catcher and sepa-ration system. However, for its transient and unsteadynature, it is a great challenge for engineers to correctlypredict the flow parameters of slug flow, especiallythe maximum liquid slug length. The unit cell model for slug flow in horizontal…     

用考虑颗粒尾涡效应的双时间尺度耗散模型模拟流体的湍流变动

Presently developed two-phase turbulence models under-predict the gas turbulent fluctuation, because their turbulence modification models cannot fully reflect the effect of particles. In this paper, a two-time-scale dissipation model of turbulence modification, developed for the two-phase velocity correlation and for the dissipation rate of gas turbulent kinetic energy, is proposed and used to simulate sudden-expansion and swirling gas-particle flows. The proposed two-time scale model gives better results than the single-time scale model. Besides, a gas turbulence augmentation model accounting for the f＇mite-size particle wake effect in the gas Reynolds stress equation is proposed. The proposed turbulence modification models are used to simulate two-phase pipe flows. It can properly predict both turbulence reduction and turbulence enhancement for a certain size of particles observed in experiments.     

混合制冷工质核态沸腾的传热研究

Heat transfer coefficients in nucleate pool boiling were measured on a horizontal copper surface for refrigerants, HFC-134a, HFC-32, and HFC-125, their binary and ternary mixtures under saturated conditions at 0.9MPa. Compared to pure components, both binary and ternary mixtures showed lower heat transfer coefficients.This deterioration was more pronounced as heat flux was increased. Experimental data were compared with some empirical and semi-empirical correlations available in literature. For binary mixture, the accuracy of the correlations varied considerably with mixtures and the heat flux. Experimental data for HFC-32/134a/125 were also compared with available correlated equation obtained by Thome. For ternary mixture, the boiling range of binary mixture composed by the pure fluids with the lowest and the medium boiling points, and their concentration difference had important effects on boiling heat transfer coefficients.     

2，6-萘二甲酸二甲酯在有机溶剂中溶解度的测定与关联

Solubility of dimethyl-2,6-naphthalene dicarboxylate in acetic acid, N,N-dimethylfonnamide, N,N-dimethyl acetamide, dimethyl sulphoxide, and N-methyl-2-ketopyrrolidine were determined using a dynamic method. The measured systems were correlated by UNIFAC group contribution method. A new main group （aromatic ester, ACCOO） was defined to express the activity coefficients of the aromatic ester. New interaction parameters of the ACCOO group were expressed as the first-order function of temperature and were determined from the experimental data. The calculated results for the new interaction parameters were satisfactory. The measured systems were also correlated with the Wilson and 2-h models, and the results were compared with those of the UNIFAC model.     

Energy Efficiency of Two‐Phase Mixing in a Modified Bubble Column

Energy efficiency for gas liquid mixing in a modified downflow bubble column reactor has been analyzed in this paper. Efficiencies of the different parts of the bubble column have been assessed on the basis of energy dissipation. Prediction of the energy dissipation coefficient as well as energy utilization efficiency due to gas‐liquid mixing as a function of different physical, geometric and dynamic variables of the system has been done by correlation method. The distribution of energy utilization in the different zones of the column has also been analyzed. Experiments were carried out with air‐water and air‐aqueous solutions of carboxy methyl cellulose with different concentrations.