共查询到20条相似文献,搜索用时 828 毫秒
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《广州化工》1976,(1)
由广州制漆厂、广州东风化工厂、广州造船厂协作试制的H_(210)聚酚氧保养底漆经过两年多的不断研究和改进,各项技术性能和实船施工效果基本符合造船工业钢材自动抛丸除锈防腐流水线工艺的要求,广东省军工局受六机部委托汇同广州市化工局于一九七五年十二月在广州进行了技术鉴定。鉴定认为,H_(210)保养底漆用于钢材自动抛丸除锈防腐流水线工艺真有较好的性能,具体表现为: 1.能够使用喷涂施工,干燥速度比环氧富锌底漆快,喷漆后5—10分钟即可吊运; 2.喷漆后的钢材进行气割和焊接时产生的主要有害气体为国家规定最高容许浓度的1/11,为环氧富锌底漆的1/7,工人施工以后未发现象环氧富锌底漆那种发热头昏等 相似文献
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《涂料工业》2016,(4)
用电化学交流阻抗技术(EIS)分析了环氧富锌底漆、环氧云铁中间漆和氟碳面漆配套而成的3种不同涂层体系(单涂层、双涂层及三涂层体系)在3.5%NaCl水溶液中的失效过程。通过|Z|0.01 Hz、涂层孔隙率和吸水率的变化分析了底漆、中间漆和面漆对涂层整体防腐性能的影响。结果表明,环氧云铁中间漆的抗腐蚀介质渗透能力优于环氧富锌底漆和氟碳面漆,对复合涂层体系的防护性能起到了重要作用。浸泡初期,中间漆对涂层屏蔽性能影响很大;浸泡中后期,环氧富锌底漆发挥阴极保护和腐蚀产物的屏蔽作用,使得涂层的防护性能得到有效提高。氟碳/环氧云铁/环氧富锌复合的三涂层体系的吸水率和孔隙率总体最低,吸水率能在较长时间保持在较低水平,对水和离子渗透起到了很有效的屏蔽作用。 相似文献
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采用聚氨酯改性环氧树脂为基料,环己酮、甲基异丁基酮和2-庚酮(MAK)为混合溶剂,三聚磷酸铝和磷酸锌、云母氧化铁红作为防锈颜填料,制备聚氨酯改性环氧树脂基防腐底漆,研究了基料、混合溶剂和防锈颜填料等因素对底漆防腐性能的影响。利用红外光谱、接触角测试、机械性能测试、电化学交流阻抗谱、耐腐蚀介质测试、单因素和正交试验等方法检测底漆的防腐性能。结果表明:混合溶剂质量比为5∶4∶1的清漆涂层阻抗为1.32×1010Ω·cm2;颜基比(P/B)为0.8~0.9、三聚磷酸铝与磷酸锌质量比为6∶4、厚度为75~90μm的色漆涂层阻抗高达2.1×1010Ω·cm2,涂层电容低至7.2×10-11F/cm2;底漆具有优异的机械性能和防腐性能,能够满足石油储罐的防腐技术要求。 相似文献
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Relationships between the spherulite morphology and changes in hydrogen‐bonding interactions between the linear poly(ethylene oxide) (PEO) polymer and a crosslinking epoxy system (diglycidylether of bisphenol‐A resin with 4,4′‐diaminodiphenylsulfone) (DGEBA/DDS) before and after cure have been explored The hydrogen‐bonding interaction is more significant before cure because of the interactions between the ether group of PEO and the amine group of DDS. The interaction between PEO and epoxy/DDS becomes less in the cured network. The morphology of the PEO crystals is, in turn, affected by the contents and chemical structures (functional groups, molecular weights, crosslinks, etc) of crosslinking epoxy/DDS. PEO/poly(4‐vinyl phenol) (PVPh), a thermoplastic non‐curing miscible system with the hydrogen bonding between the ether group of PEO and the ? OH group of PVPh, is also compared. In comparison with the PEO/epoxy/DDS system, the spherulite morphology of PEO/PVPh becomes more extensively spread out, with the extents increasing with the PVPh contents in the PEO/PVPh blend. © 2001 Society of Chemical Industry 相似文献
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《Journal of Adhesion Science and Technology》2013,27(6):407-425
Three-layer films were prepared with polyethylene (PE) and poly(ethylene terephthalate) (PET) films as the outer layers and a film of high-density polyethylene (HDPE)/ethylene-methyl acrylate-glycidyl methacrylate (E-MA-GMA) terpolymer blend as the inner layer using compression molding. E-MA-GMA, an elastomer containing an epoxy functional group, was used as the adhesion promoting agent in the multilayer films. The effects of processing temperature, pressure application time and elastomer concentration on adhesion were investigated. The adhesion strength between PE and PET films increased with increasing bonding temperature, bonding time and elastomer concentration. From contact angle measurements, it was observed that the work of adhesion between the polymers increased with increasing amount of elastomer. Improved adhesion between PET and HDPE with 30% elastomer films was confirmed by SEM analyses of the film layers. Using FT-IR analysis of PE/HDPE-30% elastomer/PET delaminated film, the decrease in peak intensity of the epoxy groups tends to indicate reaction of epoxy functionality with functional groups in PET. 相似文献
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《应用聚合物科学杂志》2018,135(22)
In this study, we synthesized poly(methyl methacrylate) (PMMA) epoxy vitrimer composites by doping methyl methacrylate (MMA) and benzoyl peroxide into a curing system of epoxy resin and citric acid. The vitrimer composites were characterized with dynamic mechanical thermal analysis, scanning electron microscopy, and stress‐relaxation and lap‐shear testing. The test results show that with increasing amount of MMA, the existence of PMMA in the epoxy vitrimer matrix in the form of intermiscible, slightly soluble, and phase separation became more evident. When the doping amount of PMMA reached 10–25 wt %, the bonding strength of the PMMA–epoxy vitrimer composites was about two times that of the epoxy vitrimer (from 2.3 to 4.3 MPa). This showed that the self‐healing strength of the vitrimer composites was better than that of the pure vitrimer. When the PMMA in the epoxy matrix was in a slightly soluble form, the linear PMMA improved the mechanical properties of the epoxy vitrimer by physical winding. At the same time, the doping of PMMA promoted the transesterification rate of the epoxy vitrimer and enhanced the bonding strength of the composites without lowering the epoxy vitrimer glass‐transition temperature. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018 , 135, 46307. 相似文献
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Poly(?-caprolactone) (PCL) of ca. 20,000 molecular weight is shown to be partially miscible with three aromatic-amine-cured epoxy resins. This conclusion is based on the depression of the epoxy Tg, the effect on physical and mechanical properties, and the observation that a large proportion (40-55%) of the PCL ester groups are involved in hydrogen bonding. This miscibility behavior is compared to PCL blends with anhydride-cured epoxy resins, which appear to have a two-phase morphology. The different miscibilities are rationalized on the basis of the existence of functional groups (e. g., hydroxyl) in amine-cured epoxies which are capable of hydrogen bonding to the PCL ester groups. Anhydride-cured epoxy resins contain fewer potential hydrogen bonding sites. 相似文献
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Influence of intramolecular specific interactions on phase behavior of epoxy resin and poly(ε-caprolactone) blends cured with aromatic amines 总被引:1,自引:0,他引:1
Two aromatic amines were used as the curing agents to prepare the thermosetting blends of epoxy and poly(ε-caprolactone) (PCL). When cured with 4,4′-methylenebis(2-chloroaniline) (MOCA), the thermosetting blends are miscible in the amorphous state in the entire composition, which was evidenced by the behavior of single, and composition-dependent glass transition temperatures (Tg's) in terms of thermal analysis. Fourier transform infrared spectroscopy (FTIR) showed that there are the intermolecular specific interactions (viz. hydrogen bonding) between the component polymers. However, the 4,4′-diaminodiphenylsulfone (DDS)-cured epoxy forms the immiscible blends with PCL. The blends displayed a typical reaction-induced phase separation morphology. The phase behavior seems to be more than the expected since it was ever proposed that there would be the intermolecular specific interactions between amine-cured epoxy and PCL, which would fulfill the miscibility of the systems. To interpret the phase behavior, we investigated that the miscibility and intermolecular specific interactions in the blends of model compounds and linear homologues of epoxy with PCL. It was observed that in MOCA-cured blends there were much stronger intermolecular specific interactions than in DDS-cured counterparts. The weaker intermolecular specific interactions between DDS-cured epoxy and PCL resulted from the formation of the intramolecular hydrogen bonding interactions within DDS-crosslinked epoxy, which were involved with the sulfonyl groups and the secondary hydroxyls. The intramolecular association could suppress the formation of the strong intermolecular hydrogen bonding interactions between carbonyls and hydroxyls of amine-cured epoxy, which are sufficient to fulfill the homogenization of the system during the in situ polymerization. Therefore, the presence of the intramolecular specific interactions between sulfonyl and hydroxyl groups was taken as the origin of phase-separated morphology for DDS-cured blends of epoxy with PCL. 相似文献