共查询到16条相似文献,搜索用时 126 毫秒
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对丙烯聚合Ziegler-Natta催化剂中内给电子体的研究进展情况进行了综述,同时分析了单酯类、双酯类、二醚类、二酮类和二醇酯类化合物作为内给电子体的催化剂特性。 相似文献
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丙烯聚合用齐格勒-纳塔催化剂的作用机理 总被引:1,自引:0,他引:1
讨论了丙烯聚合用齐格勒-纳塔催化剂的作用机理,以及反应体系内的氯化镁、内给电子体、烷基铝、硅烷和氢气等对丙烯聚合的影响。 相似文献
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综述了丙烯聚合用Ziegler-Natta(Z-N)催化剂中内给电子体的研究进展,并对各类内给电子体的应用实例进行了评价。其中,以1,3-二醚、琥珀酸酯和1,3-二醇酯类化合物为内给电子体制备的Z-N催化剂具有活性高、立体定向性高,用该催化剂制备的聚丙烯具有特征相对分子质量分布等特点。分析具有代表性的内给电子体所制催化剂的活性中心模型发现,单酯体系的等规和无规活性中心在Lewis酸作用下存在可逆平衡,二醚体系中醚氧原子电子云的转移和二醚的空间结构影响钛活性中心的性能。 相似文献
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二醚化合物在Ziegler-Natta催化剂中的应用及其合成研究 总被引:13,自引:3,他引:10
综述了二醚化合物作为给电子体在Ziegler-Natta催化剂中的应用,简要介绍了二醚化合物的合成方法。 相似文献
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Gerhard Knothe Robert O. Dunn Michael W. Shockley Marvin O. Bagby 《Journal of the American Oil Chemists' Society》2000,77(8):865-871
Several novel fatty diesters with bulky moieties were synthesized by esterification of mono- or bifunctional fatty acids or
with mono- or bifunctional alcohols using p-toluenesulfonic acid as catalyst. They were characterized by 1H and 13C nuclear magnetic resonance as well as positive chemical ionization (PCl) mass spectrometry. The PCl mass spectra of the
resulting diol diesters and diacid diesters are discussed and compared. The compounds were investigated as potential additives
for improving the cold flow properties of vegetable oil esters used as biodiesel.
Retired. 相似文献
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Type 1 yellow carnauba wax has been separated into its structural constituents. Analyses of these constituents by a variety
of conventional techniques has shown the composition to be: hydrocarbon 0.3–1%, aliphatic esters 38–40%, monohydric alcohols
10–12%, ω-hydroxy aliphatic esters 12–14%,p-methoxycinnamie aliphatic diesters 5–7%,p-hydroxycinnamic aliphatic diesters 20–23%, an uncombined triterpene type diol 0.4% and uncombined acids and other unknown
constituents 5–7%. Type 4 carnauba wax, the common wax of commerce, was found to be essentially the same as Type 1, with the
exception that for Type 4, the cinnamic esters were highly polymerized and none of the uncombined triterpene diol could be
isolated.
Presented at the AOCS Meeting, New Orleans, April 1970. 相似文献
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Skin surface lipids of the dog 总被引:1,自引:0,他引:1
The skin surface lipid of the dog has been reported to contain a high proportion of diol diesters having a lower mobility
on thin layer chromatography than diesters from other species in spite of containing similar fatty acid and diol components.
In the present study, dog skin surface lipid was separated by preparative thin layer chromatography into sterol esters (42%),
wax diesters (32%), free sterols (9%), polar lipids (7%), and unidentified components (10%). The diesters contained 1,2-diols,
each esterified with one long chain fatty acid and one isovaleric acid moiety. The diols were principally branched chain C21 and C22 compounds while the long chain fatty acids esterified with them were mainly C20 and C21 branched compounds. The fatty acids from the sterol esters were mostly saturated, branched chain C19 to C23, together with 7% of straight chain monoenoic acids, principally C21 and C22. There were only trace amounts of free sterols other than cholesterol, while the esterified sterols contained 96% cholesterol
and 4% lathosterol. 相似文献
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Synthesis of Some Hydroxyalkyl Glyceryl Diethers and Their Diesters from Hydrogenated Cardanol A few hydroxyalkyl glyceryl diethers and their diesters could be synthesized by the reaction of sodium salt of hydrogenated cardanol with various hydroxyalkyl chlorohydrinethers, the latter being prepared by reacting epichlorohydrin with the corresponding glycols. 相似文献