Single stage and double absorption heat transformers in an industrial application

An industrial application of the single stage and double absorption heat transformer (AHT) systems using water–lithium bromide solutions with water as the refrigerant was analyzed. First, a basic single stage AHT system was described, the operating sequence was explained and thermodynamic system analysis was presented. Next, an application of the single stage AHT system to an industrial company was analyzed. A computer code was prepared to determine the effect of different parameters on the AHT system performance and the results were presented in graphical form. Additionally, the series and parallel double absorption AHT systems were introduced, the operating sequences were explained and thermodynamic system analysis was included. All results were presented in tabular form for comparison. It is concluded that about 50% of the waste heat can be utilized and the hot process water and vapor could be produced by applying single stage and double AHT systems, respectively. The parallel double AHT system could generate more vapor than the series double AHT system. Copyright © 2009 John Wiley & Sons, Ltd.     

Application of absorption heat transformer to recover waste heat from a synthetic rubber plant

This paper reports the test results of the first industrial-scale absorption heat transformer (AHT) equipment in China, to recover the waste heat released from mixture of steam and organic vapor at 98 °C in coacervation section, synthetic rubber plant of Yanshan Petrochemical Corporation, Beijing, China. The recovered heat is used to heat hot water from 95 to 110 °C, feeding back to the coagulator as the supplementary heating source. The AHT system is operating with H₂O/LiBr solution with heat flow of 5000 kW. The coefficient of performance (COP), the thermal efficiency and the temperature lift of the AHT system are presented. The heat transfer characteristics of the AHT components, i.e. absorber, generator, evaporator, condenser and the liquid–liquid solution heat exchanger, are also illustrated by comparison of experimental data and the model calculated results. The results show that the mean COP is 0.47, the gross temperature lift of 25 °C can be realized and the payback period is ≈2 years.     

Performance improvement of absorption heat transformer

In this study, a mathematical model of absorption heat transformer (AHT) operating with the aqua/ammonia was developed to simulate the performance of these systems coupled to a solar pond in order to increase the temperature of the useful heat produced by solar ponds and used a special ejector located at the absorber inlet. By the use of the ejector, the obtained absorber pressure becomes higher than the evaporator pressure and thus the system works with triple-pressure-level. The ejector has two functions: (i) aids pressure recovery from the evaporator and (ii) upgrades the mixing process and the pre-absorption by the weak solution of the ammonia coming from the evaporator. The other advantage of the system with ejector is increased absorber temperature. Therefore, pressure recovery and pre-absorption in the ejector improves the efficiency of the AHT. Under the same circumstances, when compared to an AHT with and without an ejector, the system's COP and exergetic coefficient of performance (ECOP) were improved by 14% and 30%, respectively and the circulation ratio (f) was reduced by 57% at the maximum efficiency condition. Due to the reduced circulation ratio, the system dimensions can be reduced; consequently, this decreases overall cost. The maximum upgrading of the solar pond's temperature by the AHT was obtained at 57.5 °C and gross temperature lift at 97.5 °C with coefficients of performance of about 0.5. The maximum temperature of the useful heat produced by the AHT was 150 °C. In addition, exergy losses for each component in the system were calculated at different working temperatures and the results of both systems with and without an ejector were compared. Exergy analysis emphasised that both the losses and irreversibilities have an impact on the system performance and exergy analysis can be used to identify the less efficient components of the system. Exergy analyses also showed that the exergy loss of the absorber of AHT with ejector was higher than those of other components.     

Heat Transfer and Thermodynamic Performance of LiBr/H2O Absorption Heat Transformer with Vapor Absorption Inside Vertical Spiral Tubes

In this paper, an absorption heat transformer (AHT) with falling film of aqueous LiBr solution inside vertical spiral tubes is installed and tested. The variations of coefficient of performance (COP), thermal efficiency (E_th ), and the heat transfer coefficient of the absorber at different falling film flow rates, hot water flow rates, and operating temperatures are investigated experimentally. The results demonstrated that the coefficient of performance and thermal efficiency of the system decrease with the increase in the flow rate of LiBr solution, and the influence of flow rate of hot water on COP and E_th is insignificant. The available COP in the experiments is higher than 0.4. The heat and mass transfer coefficients of the absorber increase with the increase of the flow rate of LiBr solution, up to 400W/m²/K and 0.013 kg/m²/s (temperature of waste heat is 90°C). The heat transfer coefficient of the absorber increases with the increase of the temperature of waste heat, and decreases with the increase of the cooling water temperature. Meanwhile, the computer code ABSIM (Absorption Simulation) is used to simulate the AHT systems, and the simulated results are compared with the experimental data.     

Numerical investigation of a two-stage air-cooled absorption refrigeration system for solar cooling: Cycle analysis and absorption cooling performances

Two-stage air-cooled ammonia–water absorption refrigeration system could make good use of low-grade solar thermal energy to produce cooling effect. The system simulation results show that thermal COP is 0.34 and electrical COP is 26 under a typical summer condition with 85 °C hot water supplied from solar collector. System performances under variable working conditions are also analyzed. Circular finned tube bundles are selected to build the air-cooled equipment. The condenser should be arranged in the front to get an optimum system performance. The mathematical model of the two-stage air-cooled absorber considering simultaneous heat and mass transfer processes is developed. Low pressure absorber should be arranged in front of middle pressure absorber to minimize the absorption length. Configuration of the air-cooled equipment is suggested for a 5 kW cooling capacity system. Temperature and concentration profiles along the finned tube length show that mass transfer resistance mainly exists in liquid phase while heat transfer resistance mainly exists in cooling air side. The impacts on system refrigeration capacities related to absorption behaviors under variable working conditions are also investigated. Both cycle analysis and absorption performances show that two-stage air-cooled ammonia–water absorption chiller is technically feasible in practical solar cooling applications.     

Effect of irreversibilities on performance of an absorption heat transformer used to increase solar pond’s temperature

Absorption thermal systems are attractive for using waste heat energy from industrial processes and renewable energy such as geothermal energy, solar energy, etc. The Absorption Heat Transformer (AHT) is a promising system for recovering low-level waste heat. The thermal processes in the absorption system release a large amount of heat to the environment. This heat is evolved considerably at temperature, the ambient temperature results in a major irreversible loss in the absorption system components. Exergy analysis emphasises that both losses and irreversibility have an impact on system performance. Therefore, evaluating of the AHT in exergy basis is a much more suitable approach. In this study, a mathematical model of AHTs operating with the aqua/ammonia was developed to simulate the performance of these systems coupled to a solar pond in order to increase the temperature of the useful heat produced by solar ponds. A heat source at temperatures not higher than 100 °C was used to simulate the heat input to an AHT from a solar pond. In this paper, exergy analysis of the AHT were performed and effects of exergy losses of the system components on performance of the AHT used to increase solar pond’s temperature were investigated. The maximum upgrading of solar pond’s temperature by the AHT, is obtained at 51.5 °C and gross temperature lift at 93.5 °C with coefficients of performance of about 0.4. The maximum temperature of the useful heat produced by the AHT was ˜150 °C. As a result, determining of exergy losses for the system components show that the absorber and the generator need to be improved thermally. If the exergy losses are reduced, use of the AHT to increase the temperature of the heat used from solar ponds will be more feasable.     

Experiments of a solar flat plate hybrid system with heating and cooling

Based upon the prior research of the solar hybrid water heater and refrigerator, a new flat plate solar hybrid system with heating and cooling was proposed and experimental prototype device was constructed. With this new hybrid system, the heat and mass transfer can be improved effectively both in desorption process and adsorption process. The conventional flat plate solar water heater collector absorber is immersed inside adsorbent bed in the new hybrid system. The experimental results show that not only the cooling effect can be obtained, but also both the sensible heat of the adsorbent bed and the adsorption heat can be recovered effectively to produce hot water for domestic use. The COP of this new flat plate hybrid system can reach 0.11 and the heat efficiency is about 0.45, this achievement has demonstrated an efficient way of the application of solar energy.     

Thermodynamic performance analysis of gas-fired air-cooled adiabatic absorption refrigeration systems

In China, the application of small size gas-fired air-cooled absorption refrigeration systems as an alternative for electric compression air conditioning systems has shown broad prospects due to occurrence of electricity peak demand in Chinese big cities and lack of water resources. However, for conventional air-cooled absorption refrigeration systems, it is difficult to enhance the heat and mass transfer process in the falling film absorber, and may cause problems, for example, remarkable increase of pressure, temperature and concentration in the generators, risk of crystallization, acceleration of corrosion, degradation of performance, and so on. This paper presents a gas-fired air-cooled adiabatic absorption refrigeration system using lithium bromide–water solutions as its working fluid, which is designed with a cooling capacity of 16 kW under standard conditions. The system has two new features of waste heat recovery of condensed water from generator and an adiabatic absorber with an air cooler. Performance simulation and characteristic analysis are crucial for the optimal control and reliability of operation in extremely hot climates. A methodology is presented to simulate thermodynamic performance of the system. The influences of outdoor air temperature on operation performances of the system are investigated.     

Increase of COP for heat transformer in water purification systems. Part I – Increasing heat source temperature

The integration of a water purification system in a heat transformer allows a fraction of heat obtained by the heat transformer to be recycled, increasing the heat source temperature. Consequently, the evaporator and generator temperatures are also increased. For any operating conditions, keeping the condenser and absorber temperatures and also the heat load to the evaporator and generator, a higher value of COP is obtained when only the evaporator and generator temperatures are increased. Simulation with proven software compares the performance of the modeling of an absorption heat transformer for water purification (AHTWP) operating with water/lithium bromide, as the working fluid–absorbent pair. Plots of enthalpy-based coefficients of performance (COP_ET) and the increase in the coefficient of performance (COP) are shown against absorber temperature for several thermodynamic operating conditions. The results showed that proposed (AHTWP) system is capable of increasing the original value of COP_ET more than 120%, by recycling part of the energy from a water purification system. The proposed system allows to increase COP values from any experimental data for water purification or any other distillation system integrated to a heat transformer, regardless of the actual COP value and any working fluid–absorbent pair.     

A comparative study of an absorber heat recovery cycle for solar refrigeration using NH3-refrigerant with liquid/solid absorbents

This paper presents an investigation on using an ammonia refrigerant with liquid/solid absorbents in an absorber heat recovery cycle where heat released during the absorption process is used to heat up the strong solution coming out of the absorber, thereby reducing the generator heat input and hence improving the coefficient of performance. A comparative thermodynamic study is made with NH₃-H₂O and NH₃-LiNO₃ pairs as working fluids for both conventional absorption and absorber heat recovery systems. It is found that an improvement of about 10 per cent in COP for the absorber heat recovery cycle is achieved over the conventional absorption cycle and the NH₃-LiNO₃ system yields a higher COP than for NH₃-H₂O over a wide range of generator temperatures and condenser/absorber temperatures. A detailed parametric study is also presented in this paper.     

Heat transfer studies on a GAXAC (generator-absorber-exchange absorption compression) cooler

A detailed heat transfer model of GAXAC (generator-absorber-exchange absorption compression) cycle using ammonia–water as working fluid is reported. The effect of UA (heat transfer conductance, kW/K) of each component on COP and cycle capacity is investigated. The results show that UA of the absorber and high temperature generator (HTG) have significant impact on COP and cycle capacity. For a capacity of 11.56 kW, the maximized COP with minimum UA value for all heat exchanging components is found to be 1.185. Further the effect of mass flow rate and inlet temperatures of hot fluid, chilled water and cooling water are also investigated.     

Development and comparison of two-bed silica gel–water adsorption chillers driven by low-grade heat source

A novel silica gel–water adsorption chiller (driven by hot water of 60–90 °C) with three vacuum chambers has been built in Shanghai Jiao Tong University (SJTU). This chiller was an improvement of an earlier deigned chiller and it integrated two single-bed systems (basic system) with only one vacuum valve. The performance of the chiller was tested and compared with the former adsorption chiller. The results show that the cooling power and COP of the chiller are 8.70 kW and 0.39 for the heat source temperature of 82.5 °C, cooling water temperature of 30.4 °C and chilled water outlet temperature of 12 °C. For a higher chilled water outlet temperature of about 16 °C, the COP increases to 0.43 while the cooling power is about 11.0 kW. Compared with that of the former chiller, the COP of this chiller increases by 20%.     

Comparison of parallel and counter flow coil absorber performance

This study concentrates on the absorber used in the vapor absorption systems using water–lithium bromide solution with water as the refrigerant and investigates the simultaneously occurred heat and mass transfer during the absorption process. The heat and mass transfer equations were applied to simulate this process and solved using a computer program written in Delphi 7 for the parallel and counter flow absorbers. The simulation results were compared with the results of the past studies. The solution and cooling water temperatures, the overall heat transfer coefficient, the heat transferred and the mass absorbed were calculated for the parallel and counter flow absorbers. It is concluded that the counter flow absorber presents better performance for all conditions. For smaller number of coils, the difference is smaller, however if the number of coils is bigger, the counter flow absorber presents much better performance than the parallel flow absorber. When the number of coils is 20 and 120, the counter flow absorber provides 1.7% and 26% higher heat and mass transfer than the parallel flow absorber respectively.     

一种新型第二类吸收式热泵的原理及性能分析

提出一种包含吸收溶液冷却结晶过程的新型第二类吸收式热泵循环,并对其工作过程及性能特性进行理论分析与实验研究。结果表明,该循环可在吸收器吸收溶液质量分数显著高于发生器吸收溶液质量分数的条件下工作,其热泵温升能力明显优于现有AHT循环。当冷却结晶终温和冷凝器温度为35℃、发生器温度和蒸发器温度为92℃时,其热泵温升理论上可达97℃。     

Performance of commercially available solar and heat pump water heaters

Many countries are using policy incentives to encourage the adoption of energy-efficient hot water heating as a means of reducing greenhouse gas emissions. Such policies rely heavily on assumed performance factors for such systems. In-situ performance data for solar and heat pump hot water systems, however, are not copious in the literature. Otago University has been testing some systems available in New Zealand for a number of years. The results obtained are compared to international studies of in-situ performance of solar hot water systems and heat pump hot water systems, by converting the results from the international studies into a single index suitable for both solar and heat pump systems (COP). Variability in the international data is investigated as well as comparisons to model results. The conclusions suggest that there is not too much difference in performance between solar systems that have a permanently connected electric boost backup and heat pump systems over a wide range of environmental temperatures. The energy payback time was also calculated for electric boost solar flat plate systems as a function of both COP and hot water usage for a given value of embodied energy. The calculations generally bode well for solar systems but ensuring adequate system performance is paramount. In addition, such systems generally favour high usage rates to obtain good energy payback times.     

Theoretical study on the performance of an integrated ground-source heat pump system in a whole year

Being environmental friendly and with the potential of energy-efficiency, ground-source heat pump (GSHP) systems are widely used. However, in southern China, there exists large difference between cooling load in summer and heating load in winter. Thus the increase of soil temperature gradually year-by-year will decrease the COP of the GSHP system. In this paper, the configuration of a vertical dual-function geothermal heat exchanger (GHE) used in an integrated soil cold storage and ground-source heat pump (ISCS&GSHP) system, which charged cold energy to the soil at night and produced chilled water at daytime in summer, and supplied hot water for heating in winter, is presented. This is then followed by reporting the development of the mathematical model for the GHE considering the impact of the coupled heat conduction and groundwater advection on the heat transfer between the GHE and its surrounding soil. The GHE model developed was then integrated with a water-source heat pump and a building energy simulation program together for a whole ISCS&GSHP system. Then the operation performance of the ISCS&GSHP system used for a demonstration building is studied. These simulation results indicated the system transferred 71.505% of the original power consumption at daytime to that at nighttime for the demonstration building. And the net energy exchange in the soil after one-year operation was only 2.28% of the total cold energy charged. Thus we can see the feasibility of the ISCS&GSHP system technically.     

在第二类吸收式热泵中对螺旋槽管的换热性能研究

为了提高在以溴化锂为工质的第二类吸收式热泵吸收器的性能,在第二类吸收式热泵吸收器内对不锈钢螺旋槽管,即不锈钢光滑管的传热传质性能进行了实验研究.发现螺旋槽管的传热传质性能约为光滑管3倍,螺旋槽管内热媒工质-水的流体阻力系数是光滑管的17～20倍;应用于第二类吸收式热泵中间大大降低换热面积,促进热泵的高效紧凑化.     

Research on performance of mixed absorption refrigeration for solar air-conditioning

A novel lithium bromide/water mixed absorption refrigeration cycle that is suitable for the utilization of solar air-conditioning and can overcome the drawbacks of low system overall efficiency of traditional solar absorption refrigeration air-condition systems is presented. The accessorial high pressure generator was added in the cycle. The lithium bromide solution flowing out from the high pressure generator was mixed with the solution from the low pressure absorber to increase lithium bromide solution concentration and decrease pressure in the high pressure absorber. The performance of a mixed absorption refrigeration cycle was analyzed. The theoretical analysis shows that the highest COP is 0.61, while the highest available temperature difference of heat resource is 33.2°C. The whole coefficient of performance of the solar air-conditioning using mixed absorption cycle is 94.5% higher than that of two-stage absorption. The advantages of solar air-conditioning can be markedly made use of by the cycle.     

Generator absorber heat exchange based absorption cycle—A review

GAX based absorption cooling systems have been investigated in recent years by various groups across the world due to their advantage of offering a higher performance compared to that of the conventional ammonia–water absorption systems. In this paper, a comprehensive review of several different GAX cycle configurations has been explained in detail. The choice of working fluids and the performance of the GAX cycle in terms of coefficient of performance and temperature lift are also presented. The study reveals an improvement in the COP of about 10–20%, 20–30% and 30–40% in absorber heat recovery cycle, simple GAX and branched GAX cycle respectively, than that of a conventional single effect system for the same set of operating conditions. The importance of the GAX cycle with respect to the current energy scenario is also highlighted.     

Simulation studies on R134a—DMAC based half effect absorption cold storage systems

This paper presents simulation studies conducted on a half effect vapour absorption cycle using R134a-DMAC as the refrigerant-absorbent pair with low temperature heat sources for cold storage applications. The intermediate pressure of the cycle has been optimized for maximum COP. The effects of the temperatures of the evaporator, condenser, absorber and generator on the COP of the cycle have also been studied. It is found that the effect of the temperature of the low absorber on the performance is more pronounced than that of the high absorber. The COP for the baseline system is found to vary from 0.35 for low evaporating and high condensing temperatures to 0.46 for high evaporating and low condensing temperatures. The use of a condensate pre-cooler has resulted in an improvement of 5–15% in COP. The performance of this working fluid pair is better than that of ammonia–water for low heat source temperatures in the half effect configuration.