螺环倍半萜岩兰烷属系列天然产物的全合成

利用deMayo光环加成反应构成了螺环倍半萜岩兰烷属系列天然产物的基本构架，再经多步化学修饰，完成了（±）－β-岩兰酮，（±）-鲸螺醇和（±）-异鲸螺醇的全合成．     

一种新型分子自组装模型物的合成及晶体结构研究

在水溶液中,Ｐｄ＾２＋与ＳＣＮ＾－,４,４’－联吡啶通过分子自组装形成台阶式一维长链结构。晶体结构研究表明,该晶体属于三斜晶系,空间群Ｐｉ：ａ＝８．９５５（２）Ａ,ｂ＝１０．７５８（２）Ａ,ｃ＝１０．８５５（２）Ａ,ａ＝７０．５６（３）°,β＝６９．２５（３）°,γ＝８１．０２（３）°,ｖ＝９２１．４（３）Ａ＾３,ｚ＝２,Ｄｃ＝１．７９１ｇ／ｃｍ＾３,μ＝１．４７０ｍｍ＾－１,Ｍｒ＝４９６．９２,     

H与He、Ne、Ar、Kr、Xe碰撞角分布的理论研究

本文用我们计算的氢原子与惰性气体原子间的相互作用势，系统地研究了低能（０．４－５０ｗｅＶ）情况下在０°－１８０°范围，氢原子被惰性气体原子弹性散射，角分布的计算值与查到的实验值基本一致。     

鄂东南晚二叠世大隆组层状硅质岩成因地球化学及沉积环境

鄂东南地区的晚第二叠世大隆组中存在数层与地层融合产生的薄层状硅质岩，其微量元素，微量元素，稀土元素，硅和氧同位素地球化学特征表明其为热水沉积硅基岩，Ａｌ－Ｆｅ－Ｍｎ和Ｆｅ－Ｍｎ－（Ｎｉ＋Ｃｏ＋Ｃｕ）三角图上，硅质岩属较典型的热水沉积硅质岩，硅质岩ＭｎＯ／ＴｉＯ２〈０．５，δＣｅ平均值为０．８０，δ＾３０Ｓｉ值为０．３×１０＾－３～０．７×１０＾－３，表明本区晚二叠世大隆组层状硅质岩主要在浅海环境下     

广西凭祥逆冲推覆构造的发现及意义

凭祥逆冲推覆构造是广西境内首次在上古生办地台盖层中发现的大型叠瓦状逆冲推覆构造。长度〉３０ｋｍ，总体走向２５°－４０°，断面倾向南东，倾角２０°－３０°，逆冲方向３０７°－３１０°，分带特征明显。经平衡剖面复原计算其缩短率ｅ＝０３３．３％，相对长度比εγ＝６６．７％，推覆蹁〉５６００ｍ。     

苏皖交界地区蛋白石硅岩热水沉积地球化学特征

产于凹凸棒石粘土矿层中的硅岩具有特征的沉积构造，ＳｉＯ２含量高（７７．９２￣８９．４４％），Ｕ／Ｔｈ〉１、Ｚｎ、Ａｓ、Ｓｂ等元素含量高，稀土总量低（４．５×１０＾－６￣１６．５５×１０＾－６）。稀土配分型式及氧稳定同位素组成与热水沉积硅岩一致，推算形成温度为７１℃￣８１℃。上述特征表明硅岩为热水沉各位产，亦说明在苏皖凹凸棒石粘土矿床形成过程中存在有热水事件。     

任意倾斜角度下平行平板封闭夹层自然对流换热实验研究

通过实验，在温差从10℃到90℃，夹层间距从0．01m至0．08m，空气层与水平面夹角在0°～90°变化范围内，全面分析了夹层温差、夹角、Re数、间距、纵深比等因素对换热的影响．拟合出了各角度下的准则方程式，并在θ＞60°时，用（1－θ／18O）n来体现角度变化对换热的影响，避免出现90°时准则式与其它角度下形式无法统一的问题．分析了一定温差、角度下对流换热量随间距的变化关系，给出了最佳间距，从而为工程计算提供了理论依据．     

高性能溶液型SBS压敏胶的研制

研究了影响ＳＢＳ 溶剂型压敏胶粘剂性能的因素,结果表明：溶剂和增粘树脂种类软化剂用量影响最大．实验所得制品在某些性能上（１８０°剥离强度 １１５０～１２７０ Ｎ／ｍ持粘力 ２７～５１ｈ）超过文献中同类制品值．     

2,4—二硝基苯酚,四氢呋喃合铬（Ⅲ）四苯基卟啉的合成及表征

采用两种不同的方法合成了一种新的铬（Ⅲ）四苯基卟啉配合物,２,４－（Ｏ２Ｎ）２Ｃ６Ｈ３ＯＣｒ（Ⅲ）ＴＰＰ·ＴＨＦ（Ａ）（ＴＰＰ＝ｔｅｔｒａｐｈｅｎｙｌｐｏｒ　ｐｈｙｒｉｎ）．对其进行了元素分析和红外、紫外可见、核磁表征,并对其晶体进行了Ｘ射线分析．     

4,5-二溴邻硝基苯基萤光酮-非离子表面活性剂分光光度法测定微量钼

研究了在吐温－４０存在下，用４，５－二溴邻硝基苯基萤光酮（ＤＢＯＮ－ＰＦ）在１．１～１．３ｍｏｌ／Ｌ盐酸介质中测定微量钼的方法。在５４０ｎｍ处测得表观摩尔吸光系数为９．５×１０４Ｌ·ｍｏｌ－１·ｃｍ－１．钼的含量在０～１４μｇ／２５ｍＬ的范围内，符合比耳定律。大多数常见阳离子不干扰，用本法测定了合金钢中的微量钼，获得了满意的结果。     

对青少年学生5项身体素质均值的分析研究

通过对苏北地区盐城、连云港市7－18岁中、小学生5项身体素质抽样调查数据均值的比较研究,分析了当前城乡青少年身体素质的基本发展状况,并且有针对性地就学校体育工作的开展提出了相应的科学性建议和对策。     

Preparation and characterization of nanocomposite MgFe<Subscript>2</Subscript>O<Subscript>4</Subscript>/SiO<Subscript>2</Subscript>

Nanocomposites MgFe₂O₄/SiO₂ were successfully synthesized by the sol-gel method in the presence of N, N-dimethylformamide (DMF). The formation of pure MgFe₂O₄ was confirmed by powder X-ray diffraction (XRD) and electron diffraction. The structural evolution of MgFe₂O₄ nanocrystals was followed by powder X-ray diffraction and IR absorption spectroscopy. The formation of spinel structure of MgFe₂O₄ started at 800 °C, and completed at 900 °C. The transmission electron microscopy (TEM) measurements suggest that the particle sizes increase with the increasing annealing temperature, and the mean particle sizes of the spherical samples annealed at 800 °C, 900 °C and 1 050 °C are ca. 3 nm, 8 nm and 11 nm, respectively. Magnetization measurements at room temperature and 78 K indicate superparamagnetic nature of these MgFe₂O₄ nanocrystals. Funded by the National Natural Science Foundation of China(No. 30771676), the Natural Science Foundation of Jiangsu Province (No. BK20081842), and the Foundation of Nanjing Bureau of Personal for the Returned Overseas Chinese Excellent Scholars     

Effect of barium oxide on the formation and coexistence of tricalcium silicate and calcium sulphoaluminate

Formation and coexistence of tricalcium silicate (C₃S) and calcium sulphoaluminate (C₄A₃ ) minerals in Portland cement clinker containing calcium sulphoaluminate were investigated. The f-CaO content, mineral composite and formation of mineral in the clinker were analyzed respectively by chemical analysis, differential scanning calorimetry(DSC) and X-ray diffraction. The results show that, adding a suitable amount of BaO can improve the burnability of raw meal and promote the f-CaO absorption. Tricalcium silicate and calcium sulphoaluminate minerals can form and coexist in clinkers at 1 234–1 317 °C by the addition of BaO to the raw meal. A suitable amount of BaO expanded the coexistence temperature of two minerals by 58 °. Funded by the National Basic Research Program of China (No. 2009CB623100), National Eleven Five-Year Scientific and Technical Support Plans (No. 2006BAF02A24), the Natural Science Fund for Colleges and Universities in Jiangsu Province(No. 08KJB430006), the Open Fund for the Key Laboratory of Inorganical and Composite Materials in Jiangsu Province(No. wjjqfhxc1200801) and the Innovation Fund of Doctoral Dissertation of Nanjing University of Technology (No. BSCX200705)     

高职院校信息化建设的基本思路与途径——以连云港财经高等职业技术学校数字化校园建设为例

信息化建设在改革高职教育人才培养模式、推进高职教育教学改革、提高高职教育办学质量、建立现代高职教育体制等方面发挥明显的推动作用。在调查研究基础上,通过对他校先进经验的借鉴,江苏省连云港财经高等职业技术学校在数字化校园建设实践中,进行了创新发展,对高职院校信息化建设的基本思路与途径进行了探索尝试。     

Structure and pozzolanic activity of calcined coal gangue during the process of mechanical activation

On the basis of analyzing coal gangue’s chemical and mineral compositions, the structure change of coal gangue during the mechanical activation was investigated by XRD, FTIR, NMR, and the mechanical strength of the cement doped coal gangue with various specific surface area was tested. The experimental results indicate that, the lattice structure of metakaolin in coal gangue samples calcined at 700 °C disorganizes gradually and becomes disordered, and the lattice structure of α-quartz is distorted slightly. The pozzolanic activity of the coal gangue increases obviously with its structural disorganization. Funded by the Key Laboratory Foundation of Ecological-Environment Materials (Yancheng Institute of Technology) of Jiangsu Province (XKY2006020), and the Natural Science Foundation of Jiangsu Provincial Education Department(07KJB430123)     

基于主成分综合模型和聚类分析的连云港市城市竞争力评价

首先构建了地级城市竞争力评价指标体系,然后运用统计分析软件(SPSS)对原始数据进行分析处理,得出地级城市竞争力综合评价模型,并通过该模型对江苏省13个地级市竞争力进行了综合评价,结论是南京、苏州、无锡城市竞争力最强,常州、南通较强,镇江、扬州、徐州一般,泰州、连云港、盐城较弱,淮安、宿迁最弱。该计算结果为连云港市制定切实有效的促进经济、社会发展的规划和措施提供了参考。     

连云港海岸带生态环境遥感分析与评价

探讨了基于遥感技术的连云港海岸带生态环境质量及其动态变化的评价。采用TM,SPOT多光谱扫描仪图像波段,通过各类遥感数据图像处理分析,直接从遥感图像信息中提取水质信息、植物绿色素信息和海岸带污染信息动态变化因子,在试验采样值的对比下,测量海岸带生态环境时空分布动态变化。评价了连云港海岸带环境,提出了水体污染主要来源是灌河河流入海排污、植被总面积增加的时空变化信息。     

分布式问题求解中协作方法的研究

分布式问题求解是分布式人工智能研究和应用的一个重要分支,如何使各个只有局部的,不完全知识的知识源协主财工作、合作求解问题是它的一个最基本也是最重要的研究内容之一。     

Effects of Chemical Treatments on Thermal Expansion Properties of Cordierite Ceramics

Cordierite honeycomb ceramics was treated with 1.5 M HNO3 , followed with 1.5 M NaOH at 93 ℃. The combination of acid treatment with alkali treatment significantly diminished the rebounding of coefficient of thermal expansion （CTE） caused by heat treatment, a phenomenon observed in samples treated solely with acid. Inductively coupled plasma （ICP） analysis results reveal that the alkali treatment preferentially dissolved ＂free＂ SiO2 left in the acid-treated samples, which is considered to be a key factor responsible for the CTE rebounding.     

连云港近岸海域沉积物中重金属污染平面分布研究

分3个区域全面分析了连云港近岸海域沉积物中主要重金属含量平面分布特征,共采集了28个表层沉积物样品,研究表明,各区域中重金属主要污染物为Cu,其次分别为As,Cd和Pb,Hg污染水平相对较低;临洪河口、碱厂排污和西大堤工程对连云港近岸海域沉积物中污染物分布影响较大;和1985年西大堤工程建设前相比较,重金属Pb和Cd污染呈减轻趋势,Cu和As污染呈加重趋势;3个区域相比较,碱厂区域沉积物质量最差,污染呈加重趋势。