聚合铝改性磷石膏基超硫矿渣胶凝材料制备与性能研究

以硫酸盐为主要激发剂,辅以少量硅酸盐水泥激发矿渣,破坏矿渣玻璃体的空间结构,促进矿渣水化,研制出一种低污染环境友好型胶凝材料——磷石膏基超硫水泥。使用新型活性聚合铝为添加剂解决超硫水泥早期强度较低、凝结时间长的问题。对活性聚合铝改性超硫水泥的凝结时间、长期力学性能作了研究;使用水化热、XRD、SEM等测试技术分析其改性提升机理。研究结果表明:掺入活性聚合铝可显著加快超硫水泥早期水化速率,促进胶凝材料水化,提高硬化胶凝材料密实度。     

中性钠盐碱矿渣水泥抗化学侵蚀性能研究

研究了中性钠盐碱矿渣水泥在酸性溶液、硫酸盐溶液和海水中的抗化学侵蚀性能。借助X-射线衍射和压汞测孔法考察了中性钠盐碱矿渣水泥的水化产物及水泥石孔结构特征, 并指出高稳定性的水化产物和优良的孔结构是其具有优异抗化学侵蚀性能的主要原因。     

矿渣高钙灰复合水泥的水化程度研究

根据水化热、化学收缩、CH生成量和强度等实验结果，分析了由30％矿渣＋25％改性高钙灰＋45％52．5PⅡ水泥制备的42．5矿渣高钙灰复合水泥在不同龄期的水化程度。与普通硅酸盐水泥相比，由于高掺量的矿渣及改性高钙灰大幅度减少了熟料量，同时其火山灰反应消耗熟料的水化产物CH，水化产物组成和结构改变，水化热显著降低，早期化学收缩降低而后期化学收缩基本一致，不同龄期的CH生成量均显著降低，7d和28d的龄期强度接近，该复合水泥能够有效控制集中放热期的水化程度和优化水化产物组成，有利于改善耐久性。降低水胶比减少水化热、化学收缩和CH生成量，使水化度降低，但有利于水泥石结构的优化。     

氧化石墨烯对矿渣水泥抗压强度及微观结构的影响

为克服矿渣水泥早期强度偏低问题,以氧化石墨烯作为纳米添加剂掺入矿渣水泥中,通过改变氧化石墨烯的掺量,以抗压强度和水化产物为研究对象,进行抗压强度测试试验,并采用X射线衍射、扫描电子显微镜、热分析和纳米压痕等测试方法对水化产物和微观结构进行表征.结果表明:氧化石墨烯可以促进矿渣水泥的水化进程,提高抗压强度,最佳掺量为0.08％;氧化石墨烯在水化过程中起到填充作用和晶核作用,从而提高抗压强度,生成更多水化产物,水化产物中高密度C—S—H凝胶比例增大.该研究结果为改善矿渣水泥早期抗压强度提供了新思路.     

压应力对水泥硬化浆体显微结构的影响

主要研究外加荷载对水泥水化产物与显微结构的影响.以水泥石1 d龄期极限压应力的30%、50%和70%对水泥石施加压力,采用X射线衍射和偏光显微镜研究不同压应力作用下水泥水化的物相、孔分布以及产物分布,结合宏观力学性能的变化,探讨了外力作用下水泥水化过程中微结构形成机理.结果表明,只有当应力达到一定临界值后水泥石的强度才出现下降;压应力没有改变水化产物的类型,但对水化产物的颗粒形貌以及颗粒分布有明显影响.     

尾矿粉对充填体力学性能和微观结构的影响

研究掺入尾矿粉对井下充填体和矿渣硅酸盐水泥胶凝材料体系力学性能和微结构的影响,并利用XRD、SEM、MIP等测试手段分析两种体系下水化产物和孔隙结构的变化。研究结果表明:在尾矿粉取代尾矿砂量不超过20%时,充填体的流动性能会因体系中细颗粒尾矿粉的增多而提高;同时,充填体的抗压强度也会随着尾矿粉的掺入呈线性上升,这主要是因为尾矿粉的掺入改善了充填体的孔结构,降低了充填体中大孔径孔隙数量,从而提高了其抗压强度。尾矿粉取代胶凝材料则可以同时降低体系总孔隙率和孔径大小,提高试块的前期强度,但后期强度则会有所降低。     

超硫酸盐水泥与波特兰水泥混凝土显微结构与性能的比较研究

对比研究了超硫酸盐水泥(SSC)与矿渣硅酸盐水泥(PSC)以及普通硅酸盐水泥(OPC)混凝土在力学性能、水化热、微观结构性能的差异。采用XRD、SEM、TG-DSC、FTIR表征3种水泥混凝土的水化产物及显微结构,以抗压强度来评价三者力学性能。研究结果表明:在混凝土配合比相同条件下,SSC早期3d强度低于PSC和OPC,然而7d龄期后强度增长迅速且超越PSC,并在28d后达到40.5MPa与OPC持平;SSC的水化产物主要是AFt钙矾石和C-S-H凝胶,AFt和剩余的CaSO4.2H2O被紧紧包裹在凝胶中,形成均匀的致密结构,与波特兰水泥水化产物的显著区别是未含有Ca(OH)2,Ca(OH)2含量大小为OPC>PSC>SSC。3种水泥的水化放热量大小为OPC>PSC>SSC,且SSC是一种水化热相当低的水泥。     

钢渣水泥性能与水化机理的研究

研究了钢渣水泥的抗硫酸盐侵蚀性，耐磨性，抗碳化性能以及抗干缩变形能力，各项性能指标均达到或超过纯硅酸盐水泥。采用ＸＲＤ，ＳＥＭ，ＤＴＡ，ＩＭＰ等测试手段研究了钢渣水泥的水化产物，孔结构，对其水化机理进行了分析讨论。     

水泥强度诱导提高方法研究

利用物理性能检测、水化放热测定和孔结构测定方法研究了通过掺加微细矿渣、高铝组分和水化硬化浆体诱导提高硅酸盐水泥强度的方法，并对其作用机理进行了探讨，试验表明，适量的微细高铝组分、矿渣组分及水化硬化浆体能够明显提高硅酸盐水泥强度。     

无熟料高炉矿渣水泥的水化反应特征

为了研究无熟料高炉矿渣水泥(简称NCSC)的水化反应特征,设计不同配合比的NCSC,并进行了XRD、DTA、SEM试验.结果表明:NCSC的水化反应受高炉矿渣粉的碱度、化学成分及玻璃化率的影响外,很大程度上取决于石膏的使用量,并与高炉矿渣存在着最佳配合比;NCSC在水化过程中龄期7天内生成的钙矾石(3CaO·SiO2·3CaSO4·31H2O)是提供早期强度的主要来源,而7天后生成的C-S-H系列水化物是提供其后期强度的主要因素;NCSC在水化过程中几乎不生成氢氧化钙.     

The Hydration Characteristics and Expansion Machanism of Expansive Cement at Low W/B Ratio

1　IntroductionAnexpansiveagentcannotonlymakethestructurehasself waterproofperformance ,butalsoreducetheshrinkageandthecrackingofconcreteeffectively .Soitisextensivelyusedincommonconcrete .However,theappli cationofexpansiveagentinhigh strengthconcreteisnotattractedmuchattention .Itisnotonlybecauseofthebondageoftraditionalviewpointthatitsshrinkagevalueofhigh strengthconcreteismuchgreaterthanthatofcom monconcrete ,butalsothedeficiencyofadequatestudyonthehydrationcharacteristicsandexpansivemechan…     

电阻率法研究早期水泥净浆孔结构的演变过程

采用无电极电阻率法原位连续监测3种水灰比（0.23、0.35和0.53）水泥净浆早期水化过程中电阻率的变化全过程,同时结合等温量热仪测试的水化程度,建立水泥净浆随时间发展过程中浆体电阻率与孔结构发展的定量关系。结果表明：根据电阻率及其微分曲线的变化规律可以把水泥水化过程分为4个阶段：溶解期、诱导期、加速期和减速期。水灰比越低,毛细孔隙率和收缩因子变小,曲折因子变大,致使浆体电阻率升高,而孔溶液电阻率却下降。     

The Hydration of Blended Cement at Low W/B Ratio

1　IntroductionThehydrationandhardeningprocessesofordinarycementhavebeenstudiedintensively[1-3 ] .Partlyreplac ingcementwithflyash ,slag ,orotheractivemineralad mixturecannotonlymodifythecementstrengthgrade ,re ducethehydrationheatofcement ,butalsomelioratethestructureofhardencementpaste[4] .Applyingexpansiveagentinordinaryconcretecancombinethebearingandwaterprooffunctionsofabuilding ,anditcanalsoreducetheshrinkageandpreventthecrackingofconcrete[5,6] .However ,thehydrationprocessofcementmixedw…     

The hydration characteristics and expansion machanism of expansive cement at low<Emphasis Type="Italic">W/B</Emphasis> ratio

The hydration characteristics and expansion impetus of three kinds of cement paste under free-and confined-curing conditions were investigated, which were respectively mixed with three different kinds of expansive agent at low W/B ratio. The results show that the hydration products of pure cement paste and paste mixed with expansive agent are same, but the amount of hydration products, un-hydrated C₃S and C₂S are obviously different at the same hydration age. At 3 d age, the amount of CH in pure cement paste is less than that of paste mixed with expansive agent, but it is reverse when at 28 d age. The amount of AFt at 3d and 28d age in pure cement paste is less than those of paste mixed with expansive agent. Regardless of under free- or confined-curing condition, the amount of ettringite produced varies little since 3d age. The joint effect of the tumefaction of gel-ettringite due to water absorption and the expansive pressure on the pore caused by the crystalloid ettringite is the cause of the volume expansion of cement paste, and the former effect is much greater than the latter. LU Lin-nu : Born in 1972 Funded by 973 High-tech Project of China (No. 2001CB610704-2) and the Natural Science Foundation of Hubei Province(No. 2002AB075)     

The hydration of blended cement at low<Emphasis Type="Italic">W/B</Emphasis> ratio

The hydration process, hydration product and hydration heat of blended cement paste mixed with mineral admixture and expansive agent at low W/B ratio are studied by XRD, thermo analysis, and calorimetry instrument, and they were compared with those of pure cement paste. The results show that pure cement and blended cement at low W/B ratio have the same types of hydration products, but their respective amounts of hydration products of various blended cements at same ages and the variation law of the amount of same hydration products with ages are different; The joint effect of tumefaction of gel-ettringite due to water absorption and the expansive pressure on the pore and rift caused by the crystalloid ettringite is the impetus of the volume expansion of cement paste, and the former effect is much greater than the latter one. HU Shu-guang: Born in 1957 Funded by 973 High-tech Project of China (No. 2001CB610704-2) and the Natural Science Foundation of Hubei Province(No. 2002AB075)     

Microstructure and Composition of Hydration Products of Ordinary Portland Cement with Ground Steel-making Slag

1　IntroductionSteel makingslagisthewasteofsteel makingindus tryandnearlysixteenmilliontonssteel makingslagisproducedinChinaperyear[1] .Justasflyashandblastfurnaceslag ,itisoneofthreekindsofdominantindustrywastesinourcountry .Eventhoughsteel makingslagce menthasdevelopedformorethantwentyyearsinCh ina[2 ,3 ] ,comparedwithothertwowastes ,thestudyandap plicationonsteel makingslagincementandconcreteareinsufficientyet.Moststeel makingslagcementsarepre paredbyinter grindingprocess ,sotheparticlesiz…     

Comparison of hydration properties between cement-GGBS-fly ash blended binder and cement-GGBS-steel slag blended binder

The hydration properties of cement-GGBS-fly ash blended binder and cement-GGBS-steel slag blended binder were compared. The experimental results show that the hydration rate of cement-GGBS- steel slag blended binder is higher than that of cement-GGBS-fly ash blended binder within 28 days, but lower than the latter after 28 days. The hydration of cement-GGBS-steel slag blended binder tends to produce more Ca（OH）2 than the hydration of cement-GGBS-fly ash blended binder, especially at late ages. Cement-GGBS- steel slag mortar exhibits higher strength than cement-GGBS-fly ash mortar within 28 days, but at late ages, it exhibits similar compressive strength with eement-GGBS-fly ash mortar and even slightly lower bending strength than cement-GGBS-fly ash mortar. Cement-GGBS-steel slag paste has finer early pore structure but coarser late pore structure than cement-GGBS-fly ash paste. Cement-GGBS-steel slag paste can get satisfied late pore structure and cement-GGBS-steel slag mortar can get satisfied late strength as compared with pure cement paste and pure cement mortar, respectively.     

粉煤灰-脱硫石膏水泥基材料水化活性及微结构

采用DTA—TG、XRD、SEM以及宏观水化收缩和强度试验等手段研究了粉煤灰一脱硫石膏一水泥三元复合胶凝体系的水化过程、活性效应及微观结构等,根据试验结果总结了复合胶凝材料的水化动力学过程。结果表明,粉煤灰一脱硫石膏水泥石的钙矾石吸热峰强于基准样;在各组分相互活性激发和外掺激发剂作用下,粉煤灰一脱硫石膏水泥石中2次水化效应明显;SEM、XRD表明水泥石早期有明显的钙矾石生成,同时粉煤灰颗粒的表面侵蚀现象明显,进一步说明复合胶凝体系的早期活性得到有效激发,硬化后综合性能得到有效保证。且宏观收缩及强度试验也从侧面印证了微观试验结果。粉煤灰一脱硫石膏水泥基复合胶凝材料体系的研发可大量消耗燃煤电厂的工业废渣,具有显著的“绿色”效应。     

Influence of cellulose ethers on hydration products of portland cement

Cellulose ethers are widely used to mortar formulations,and it is significant to understand the interaction between cellulose ethers and cement pastes.FT-IR spectra,thermal analysis and SEM are used to investigate hydration products in the cement pastes modified by HEMC and HPMC in this article.The results show that the hydration products in modified cement pastes were finally identical with those in the unmodified cement paste,but the major hydration products,such as CH(calcium hydroxide),ettringite and C-...