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微电解-铁碳内电解耦合预处理高浓度染料废水 总被引:1,自引:0,他引:1
以实际废水为研究对象,采用微电解-铁碳内电解联合工艺法处理高浓度、高色度和高含盐量高的染料废水,考察了固/液比、铁/碳比、电流密度等因素对色度和化学需氧量(COD)的去除率的影响。结果表明,当反应时间为30 h、固液比(体积比)为1∶20、铁碳比(体积比)为1∶1、电流密度为9.26 mA/cm2时,该组合工艺处理印染废水效果稳定,平均出水色度值为1000 倍,COD去除率达到56.5%。综合处理效果与经济两方面因素,电解-内电解耦合工艺是预处理高浓度燃料废水的有效方法之一。 相似文献
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采用钌铱镀层钛电极为阳极,不锈钢为阴极,电Fenton法处理实际染料废水,采用单因子分析方法考察电极材料、电解时间、电流密度、极板间距、p H值、硫酸亚铁投加量、曝气量和搅拌速度等参数对染料废水COD去除率的影响。当电解时间为2 h,电流密度为1.2 A/mm2,极板间距为2.5 cm,p H值为2.5,硫酸亚铁投加量为0.5 g/L,曝气量为2 L/min,搅拌速度为1000 r/min,COD去除率达到47.84%。对电流密度、极板间距、p H值、硫酸亚铁投加量设计正交实验,极板间距、p H和硫酸亚铁投加量对电Fenton体系去除率的影响显著,电流密度对去除率影响不显著。 相似文献
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电絮凝(EC)具有成本低、操作简单、无需添加药剂、污泥少以及无二次污染等优点。采用电絮凝技术处理模拟铬黑T(EBT)染料废水,研究了不同电解质及其浓度、电流密度、初始pH以及溶液初始浓度对染料废水的脱色率和化学需氧量(COD)去除率的影响。结果表明,该技术对染料废水的色度和COD的去除均有良好的去除效果,在纯Al板为电极,染料废水浓度为100 mg/L,极板间距为15 mm,NaCl浓度为0.75 g/L,电流密度为10 mA/cm2,溶液初始pH为6的实验条件下,电解20 min,脱色率可达97.5%,COD去除率为61.3%。电絮凝过程中不仅可以产生有较强吸附作用的絮体,还可以产生能够破坏染料分子中发色基团的强氧化性物质,从而降低废水的色度和COD含量。因此,电絮凝技术在染料废水的处理方面有一定的应用前景。 相似文献
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采用电絮凝气浮法处理分散艳蓝E-4R染料废水,考察了电解时间、废水初始浓度、pH值及外加电解质氯化钠和絮凝剂等不同反应条件对废水处理效果的影响。结果表明,染料废水脱色率随着电解时间的加大而逐渐增大并随初始浓度的增大而慢慢降低;pH值在2.5~10范围内电解均可获得较高的脱色率。初始浓度为400 mg/L的染料废水,电解20 min后脱色率即达87.39%,但TOC去除率只有10.49%。投加50 mg/L氯化钠后,脱色率和TOC去除率分别达到93.61%和73.49%,TOC去除率提高60%以上。在电解的条件下投加不同絮凝剂能提高染料废水的处理效果,其处理效果从大到小依次为:硫酸铝>三氯化铝>硫酸亚铁,它们的适宜用量分别为50,100,100 mg/L。 相似文献
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超重力-电催化耦合法降解含酚废水 总被引:1,自引:0,他引:1
将自制的超重力多级同心圆筒电解装置应用于电催化降解含酚废水的过程中, 解决电化学法处理废水存在"气泡效应"和"传质受限"导致的废水处理效率降低的难题。考察了超重力因子、电流密度、电解时间、电解质浓度、液体循环流量、苯酚初始浓度对废水降解效果的影响, 确定了超重力-电催化耦合法处理含酚废水的最佳工艺条件。结果表明:超重力因子为30、电流密度为200A/m2、电解质浓度为3g/L、液体循环流量为80L/h、电解时间为7h时, 处理初始浓度100mg/L的含酚废水, 苯酚去除率可达99.1%, COD去除率可达24.7%。超重力电催化法强化了离子传质过程, 实现了废水中苯酚的高效去除, 为含酚废水的处理研究探索了一种新途径。 相似文献
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Chien-Hsin Yang 《加拿大化工杂志》1999,77(6):1161-1168
Ruthenium-tin binary oxides [(Ru+Sn)O2] were coated on titanium substrates by thermal decomposition. The surface morphologies and elemental analyses of these electrodes were examined by means of scanning electron microscopy. The electrochemical behaviours were characterized by cyclic voltammetry and linear-scan voltammetry (LSV) methods. The effects of electrolysis condition for the current efficiency (CE) of hypochlorite production on binary (Ru+Sn)O2 electrodes and the treatment of a high salt-containing dye wastewater using this hypochlorite were also investigated. The highest CE for hypochlorite production exists on an RS3 (40 to 80 mol% Sn in coating solution) electrode. The major factors influencing CE for hypochlorite production are the electrolyte flow rate, current density, and chloride (Cl-) concentration. Major factors affecting energy yield are current density, Cl- concentration, and electrode distance. For low current density (300 mA.cm?2), high Cl- concentration (1 mol.L?1), and 0.45 cm electrode separation, a high specific energy is obtained. The RS3 electrode exhibits the best removal of organics and chromophor groups in the dye wastewater. On this electrode, better removal of organics and chromophor groups is obtained at 300 mA.cm?2. The colour of black-red dye wastewater becomes light yellow when a charge of 792 A·min was passed, while the chemical oxygen demand (COD) of this wastewater is decreased from 10500 mg.L?1 to 1250 mg.L?1. 相似文献
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The purpose of this paper was to investigate the possibility of treating C. I. Reactive Blue 19 wastewater by electrochemical oxidation via electrogenerated active chlorine, using metallic oxide coatings (dimensional stable anode, DSA) as anode. The electrolysis for the simulated wastewater was conducted at a constant current. Absorbances at 592 nm and 255 nm were measured to follow the decolorization of the dye and the degradatin of its aromatic ring. After 4 h of electrolysis under the experimental conditions: current density of 15 A·m^-2, 0.2 mol·L^-1 NaCl, 0.1 mol·L^-1 Na2SO4, 0.1 mmol·L^-1 dye, initial pH=6.4 and T=30℃, 100% decolorization of the dye and about 45% degradation of its aromatic ring were achieved, while no obvious change of total organic carbon was observed. The experimental results suggest that the decolorization of the dye and degradation of its aromatic ring were directly affected by current density, temperature, concentrations of the dye and sodium chloride, while slightly affected by initial pH and sodium sulfate concentration; the decolorization of the dye and degradation of its aromatic ring followed pseudo-first-order kinetics; and indirect electrooxidation, using electrogenerated active chlorine, predominated in the electrochemical oxidation. 相似文献
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An electrolytic process based on chlorine generation was adopted to treat wastewater containing textile dyes. In situ production of hypochlorous acid was achieved in an undivided electrolytic cell. The cell contained a graphite rod as the anode and a stainless steel sheet as the cathode. The generated chlorine reacts with water leading to the formation of hypochlorous acid and hydrochloric acid. The resultant hypochlorous acid, being an oxidising agent, oxidises the organic components present in the textile wastewater. In this study, the colour in wastewater containing Procion Navy and Procion Red dyes, respectively, was completely removed after 40 min of electrolysis at a constant current density of 39 mA/cm2 (where the initial dye concentrations were 3700 and 3200 mg/l, respectively). In the case of the Procion Yellow and composite dyes, complete colour removal occurred after 50 min of electrolysis (with initial dye concentrations of 3500 mg/l). Even though colour removal occurred during the electrolysis process, it required up to 180 min of electrolysis to reduce the COD values for the four dyes (Procion Navy, Red, Yellow and the composite) from the initial levels of 4520, 4200, 4170 and 4283 mg/l to 70, 45, 39 and 52 mg/l, respectively. This clearly indicates that the process removes both colour and organic components present in textile wastewater. 相似文献
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Karuppan Muthukumar P Shunmuga Sundaram N Anantharaman C Ahmed Basha 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2004,79(10):1135-1141
Textile dye house wastewater from a reactive dye processing unit was treated by using an electrochemical oxidation technique. The experiments were carried out in an electrochemical bipolar disc reactor using RuO2 coated on titanium as anode and titanium as cathode. The sodium chloride present in the effluent was used as supporting electrolyte. Operating parameters such as current density, reservoir hold‐up and electrolysis time were studied for maximum Chemical Oxygen Demand (COD) reduction and other relevant parameters such as current efficiency and power consumption per kg of COD removal were calculated. The higher flow rate and lower reservoir hold‐up resulted in improved COD removal. The applied current density was also found to significantly influence the reduction of COD. A suitable mathematical model is also proposed to illustrate the relationship between the basic parameters. Pseudo mass transfer coefficients were also evaluated for different experimental conditions. Copyright © 2004 Society of Chemical Industry 相似文献
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