A liquefied energy chain for transport and utilization of natural gas for power production with CO2 capture and storage – Part 1

A novel transport chain for stranded natural gas utilized for power production with CO₂ capture and storage is developed. It includes an offshore section, a combined gas carrier, and an onshore integrated receiving terminal. Due to utilization of the cold exergy both in the offshore and onshore processes, and combined use of the gas carrier, the transport chain is both energy and cost effective. In this paper, the liquefied energy chain (LEC) is explained, including novel processes for both the offshore field site and onshore market site. In the offshore section, natural gas (NG) is liquefied to LNG by liquid carbon dioxide (LCO₂) and liquid inert nitrogen (LIN), which are used as cold carriers. The LNG is transported in a combined gas carrier to the receiving terminal where it is used as a cooling agent to liquefy CO₂ and nitrogen. The LCO₂ and LIN are transported offshore using the same combined carrier. Pinch and Exergy Analyses are used to determine the optimal offshore and onshore processes and the best transport conditions. The exergy efficiency for a thermodynamically optimized process is 87% and 71% for the offshore and onshore processes, respectively, yielding a total efficiency of 52%. The offshore process is self-supported with power and can operate with few units of rotating equipment and without flammable refrigerants. The loss of natural gas due to power generation for the energy requirements in the LEC processes is roughly one third of the loss in a conventional transport chain for stranded natural gas with CO₂ sequestration. The LEC has several configurations and can be used for small scale (<0.25 MTPA LNG) to large-scale (>5 MTPA LNG) transport. In the example in this paper, the total costs for the simple LEC including transport of natural gas to a 400 MW_net power plant and return of 85% of the corresponding carbon as CO₂ for a total sailing distance of 24 h are 58.1 EUR/tonne LNG excluding or including the cost of power. The total power requirements are 319 kWh/tonne, hence the energy costs are 31.9 EUR/tonne LNG adding up to 90.0 EUR/tonne LNG. The exergy efficiency for this energy chain including power production and CO₂ capture is 46.4% with a total cost of 20.4 EUR/MWh for the produced electricity. The total emissions (in CO₂ equivalents) in the chain are 1–1.5% of the transported CO₂.     

Exergy analysis and optimization of a hydrogen production process by a solar-liquefied natural gas hybrid driven transcritical CO2 power cycle

A solar transcritical CO₂ power cycle for hydrogen production is studied in this paper. Liquefied Natural Gas (LNG) is utilized to condense the CO₂. An exergy analysis of the whole process is performed to evaluate the effects of the key parameters, including the boiler inlet temperature, the turbine inlet temperature, the turbine inlet pressure and the condensation temperature, on the system power outputs and to guide the exergy efficiency improvement. In addition, parameter optimization is conducted via Particle Swarm Optimization to maximize the exergy efficiency of hydrogen production. The exergy analysis indicates that both the solar and LNG equally provide exergy to the CO₂ power system. The largest amount of exergy losses occurs in the solar collector and the condenser due to the great temperature differences during the heat transfer process. The exergy loss in condenser could be greatly reduced by increasing the LNG temperature at the inlet of the condenser. There exists an optimum turbine inlet pressure for achieving the maximum exergy efficiency. With the optimized turbine inlet pressure and other parameters, the system is able to provide 11.52 kW of cold exergy and 2.1 L/s of hydrogen. And the exergy efficiency of hydrogen production could reach 12.38%.     

Performance analysis of a CCHP system based on SOFC/GT/CO2 cycle and ORC with LNG cold energy utilization

An innovative CCHP system based on SOFC/GT/CO₂ cycle and the organic Rankine cycle (ORC) with LNG cold energy utilization is proposed to achieve cascade energy utilization and carbon dioxide capture. The mathematical models are developed and the system performance is analyzed using the energy and exergy methods. The results illustrate that the comprehensive energy utilization, the net power generation and the overall exergy efficiencies of the system can reach about 79.48%, 79.81% and 62.29%, respectively, while the power generation efficiency of the SOFC is 50.96% and the CO₂ capture rate of the proposed CCHP system is 79.2 kg/h under the given conditions. It shows that the proposed CCHP system can reach a high energy utilization efficiency with near zero emissions. The influence of some key parameters, such as the fuel utilization factor, the air-fuel ratio, the oxygen concentration in the cathode feed and the compression ratio of the SCO₂ turbine on the performance of the entire system is studied.     

A liquefied energy chain for transport and utilization of natural gas for power production with CO2 capture and storage – Part 4: Sensitivity analysis of transport pressures and benchmarking with conventional technology for gas transport

A novel energy and cost effective transport chain for stranded natural gas utilized for power production with CO₂ capture and storage is developed. It includes an offshore section, a combined gas carrier and an integrated receiving terminal. In the offshore section, natural gas (NG) is liquefied to LNG by liquid carbon dioxide (LCO₂) and liquid inert nitrogen (LIN), which are used as cold carriers. In the onshore process, the cryogenic exergy in the LNG is utilized to cool and liquefy the cold carriers, LCO₂ and LIN. The transport pressures for LNG, LIN and LCO₂ will influence the thermodynamic efficiency as well as the ship utilization; hence sensitivity analyses are performed, showing that the ship utilization for the payload will vary between 58% and 80%, and the transport chain exergy efficiency between 48% and 52%. A thermodynamically optimized process requires 319 kWh/tonne LNG. The NG lost due to power generation needed to operate the LEC processes is roughly one third of the requirement in a conventional transport chain for stranded NG gas with CO₂ capture and sequestration (CCS).     

Thermodynamic modeling and exergy investigation of a hydrogen-based integrated system consisting of SOFC and CO2 capture option

The current study deals with the thermodynamic modeling of an innovative integrated plant based on solid oxide fuel cell (SOFC) with liquefied natural gas (LNG) cold energy supply. For the suggested innovative plant the energy, and exergy simulations are fully extended and the plant comprehensively analyzed. According to mathematical simulations of the proposed plant, a MATLAB code has been extended. The results indicate that under considered initial conditions, the efficiencies of SOFC and net power generation calculated 58% and 78%, respectively and the CO₂-capture rate is obtained 79 kg/h. This study clearly shows that the integrated system reached high efficiency while having zero emissions. In addition, the efficiencies and net amount of power generation, cooling or heating output and SOFC power generation are discussed in detail as a function of different variables such utilization factor, air/fuel ratio, or SOFC inlet temperature. For enhancing the power production efficiency of SOFC, the net electricity, and CCHP exergy efficiency the plant should run in higher utilization factor and lower air/fuel ration also it's important to approximately set SOFC temperature to its ideal temperature.     

A liquefied energy chain for transport and utilization of natural gas for power production with CO2 capture and storage – Part 2: The offshore and the onshore processes

A novel energy and cost effective transport chain for stranded natural gas utilized for power production with CO₂ capture and storage is developed. It includes an offshore section, a combined gas carrier, and an integrated receiving terminal. In the offshore process, natural gas (NG) is liquefied to LNG by liquid carbon dioxide (LCO₂) and liquid inert nitrogen (LIN), which are used as cold carriers. The offshore process is self-supported with power, hot and cold utilities and can operate with little rotating equipment and without flammable refrigerants. In the onshore process, the cryogenic exergy in LNG is used to cool and liquefy the cold carriers, which reduces the power requirement to 319 kWh/tonne LNG. Pinch and exergy analyses are used to determine thermodynamically optimized offshore and onshore processes with exergy efficiencies of 87% and 71%, respectively. There are very low emissions from the processes. The estimated specific costs for the offshore and onshore process are 8.0 and 14.6 EUR per tonne LNG, respectively, excluding energy costs. With an electricity price of 100 EUR per MWh, the specific cost of energy in the onshore process is 31.9 EUR per tonne LNG.     

Design and Optimization of a Full-Generation System for Marine LNG Cold Energy Cascade Utilization

This paper took a 100,000 DWT LNG fuel powered ship as the research object.Based on the idea of"temperature matching,cascade utilization"and combined with the application conditions of the ship,a horizontal three-level nested Rankine cycle full-generation system which combined the high-temperature waste heat of the main engine flue gas with the low-temperature cold energy of LNG was proposed in this paper.Furthermore,based on the analysis and selection of the parameters which had high sensitivity to the system performance,the parameters of the proposed system were optimized by using the genetic algorithm.After optimization,the exergy efficiency of the marine LNG gasification cold energy cascade utilization power generation system can reach 48.06%,and the thermal efficiency can reach 35.56%.In addition,this paper took LNG net power generation as the performance index,and compared it with the typical LNG cold energy utilization power generation system in this field.The results showed that the unit mass flow LNG power generation of the system proposed in this paper was the largest,reaching 457.41 k W.     

Exergy analysis of liquefied natural gas cold energy recovering cycles

Liquefied natural gas (LNG) is known as ‘green fuel’ used in power plant, automobile and so forth due to its higher energy density and environmentally friendly advantages. LNG, besides its high quality chemical exergy, has plenty of physical exergy such as cold exergy and pressure exergy, which could be utilized further. Analysis of physical exergy and its affected factors has been conducted. Based on the analysis, several cycles used for recovering and applying the physical exergy of LNG, such as combined power cycle, gas turbine power generation cycle and automobile air‐conditioning system have been proposed. The parameters affecting the performance of the cycles are discussed. The recovery and utilization of physical exergy of LNG are the important measures to save energy and protect the environment. Copyright © 2005 John Wiley & Sons, Ltd.     

Power generation potential of liquified natural gas regasification terminals

The share of liquified natural gas (LNG) in the international trade of natural gas (NG) is continually increasing. This presents increasing opportunities to build power plants to generate electricity at LNG regasification terminals rather than wasting the power generation potential of LNG at about −162°C by regasifying it by seawater, ambient air, or by burning NG. Typically, over 5% of the NG received at LNG plants is used to liquify the remaining incoming gaseous NG at environmental conditions. Theoretically, all the energy consumed at LNG liquefaction plants can be recovered at LNG regasification terminals. In this study, the theoretical and practical power generation potential of regasified LNG is investigated by performing energy and exergy analyses. It is shown that up to 0.191 kWh of electric power can be generated during the regasification of LNG per standard m³ of NG regasified. The potential economic gains associated with power generation at LNG regasification facilities are demonstrated by analyzing the 2018 LNG imports of Turkey as a case study and the world. It is shown that the 314 million tons of LNG imported globally in 2018 has the electric power generation potential of 88 billion kWh with a market value of over 10 billion USD. It also has the potential to offset 38 million tons of CO₂ emissions.     

Conceptual design and analysis of a novel system based on ash agglomerating fluidized bed gasification for co-production of hydrogen and electricity

In this paper, a novel system with ash agglomerating fluidized bed gasification and CO₂ capture to produce hydrogen and electricity is firstly designed in Aspen Plus. The newly-proposed system is composed of eight subsystems, namely air separation unit, gasification unit, water gas shift unit, Rectisol unit, CO₂ compression unit, Claus unit, pressure swing adsorption unit, gas and steam turbine unit. The thermodynamic performance and hydrogen to coal ratio of the new proposed system are investigated. The results demonstrate that the hydrogen to coal ratio, energy efficiency, net electricity power and exergy efficiency of the overall system for Yangcheng anthracite are 0.096 kg/kg, 46.52%, 1.71 MW and 43.92%, respectively. Additionally, the exergy destruction ratio and exergy efficiency of each subsystem are researched. More importantly, the influences of the oxygen to coal ratio, steam to coal ratio and coal types on the hydrogen to coal ratio, energy efficiency and exergy efficiency are also studied.     

Multiobjective optimization for exergoeconomic analysis of an integrated cogeneration system

In this paper, a novel cogeneration system integrating Kalina cycle, CO₂ chemical absorption, process, and flash‐binary cycle is proposed to remove acid gases in the exhaust gas of solid oxide fuel cell (SOFC) system, improve the waste heat utilization, and reduce the cold energy consumed during CO₂ capture. In the CO₂ chemical absorption process, the methyldiethanolamine (MDEA) aqueous solution is utilized as a solvent, and feed temperature and absorber pressure are optimized via Aspen Plus software. The single‐objective and multiobjective optimization are carried out for the flash‐binary cycle subsystem. Results show that when the multiobjective optimization is applied to identify the exergoeconomic condition, the cogeneration system can simultaneously satisfy the high thermodynamic cycle efficiency and also the low product unit cost. The optimal results of the exergy efficiency, product unit cost, and normalized CO₂ emissions obtained by Pareto chart were 75.84%, 3.248 $/GJ, and 13.14 kg/MWhr, respectively.     

Thermal–economic–environmental analysis and multi-objective optimization of an internal-reforming solid oxide fuel cell–gas turbine hybrid system

In this article, an internal-reforming solid oxide fuel cell–gas turbine (IRSOFC–GT) hybrid system is modeled and analyzed from thermal (energy and exergy), economic, and environmental points of view. The model is validated using available data in the literature. Utilizing the genetic algorithm optimization technique, multi-objective optimization of modeled system is carried out and the optimal values of system design parameters are obtained. In the multi-objective optimization procedure, the exergy efficiency and the total cost rate of the system (including the capital and maintenance costs, operational cost (fuel cost), and social cost of air pollution for CO, NO_x, and CO₂) are considered as objective functions. A sensitivity analysis is also performed in order to study the effect of variations of the fuel unit cost on the Pareto optimal solutions and their corresponding design parameters. The optimization results indicate that the final optimum design chosen from the Pareto front results in exergy efficiency of 65.60% while it leads to total cost of 3.28 million US$ year⁻¹. It is also demonstrated that the payback time of the chosen design is 6.14 years.     

Thermodynamic modeling of an integrated biomass gasification and solid oxide fuel cell system

An integrated process of biomass gasification and solid oxide fuel cells (SOFC) is investigated using energy and exergy analyses. The performance of the system is assessed by calculating several parameters such as electrical efficiency, combined heat and power efficiency, power to heat ratio, exergy destruction ratio, and exergy efficiency. A performance comparison of power systems for different gasification agents is given by thermodynamic analysis. Exergy analysis is applied to investigate exergy destruction in components in the power systems. When using oxygen-enriched air as gasification agent, the gasifier reactor causes the greatest exergy destruction. About 29% of the chemical energy of the biomass is converted into net electric power, while about 17% of it is used to for producing hot water for district heating purposes. The total exergy efficiency of combined heat and power is 29%. For the case in which steam as the gasification agent, the highest exergy destruction lies in the air preheater due to the great temperature difference between the hot and cold side. The net electrical efficiency is about 40%. The exergy combined heat and power efficiency is above 36%, which is higher than that when air or oxygen-enriched air as gasification agent.     

A novel MCFC hybrid power generation process using solar parabolic dish thermal energy

In this paper, a novel molten carbonate fuel cell hybrid power generation process with using solar parabolic dish thermal energy is proposed. The process contains MCFC, Oxy-fuel and Rankine power generation cycles. The Rankine power generation cycles utilized various types of working fluid to emphasize taking advantage of the cycles in different thermodynamic conditions. The required hot and cold energies are provided from solar dish parabolic thermal hot and liquefied natural gas (LNG) cold energies, respectively. The carbon dioxide (CO₂) from MCFC effluent stream is captured from the process at liquid state. The process total heat integrated and in this regards, no need to any hot and cold external sources with the net electrical power generation. The energy and exergy analysis are conducted to determine the approaches to improve the process performance. This integrated structure consumed 2.30 × 10⁶ kg h⁻¹ of air and 2.67 × 10⁶ kg h⁻¹ of LNG to generate 292597 kW of net power. The products of this integrated structure are 6.25 × 10⁴ kg h⁻¹ of condensates, 183 kg h⁻¹ of water vapor, 2.20 × 10⁶ kg h⁻¹ of MCFC effluent stream, 2.60 × 10⁶ kg h⁻¹ of natural gas and 1.10 × 10⁵ kg h⁻¹ of CO₂ in liquid state. The presented new integrated structure has overall thermal efficiency of 73.14% and total exergy efficiency of 63.19%. Also, sensitivity analysis is performed for determination of the process key parameters which affected the process operating performance.     

Novel cogeneration power system with liquefied natural gas (LNG) cryogenic exergy utilization

We propose a new cogeneration power system with two energy sources of fuel chemical energy and liquefied natural gas (LNG) cryogenic energy, and two outputs of electrical power and cooling power. Due to the advanced integration of system and cascade utilization of LNG cryogenic energy, the system has excellent energy saving: chemical energy of fuel and LNG cryogenic energy are saved by 7.5–12.2% and 13.2–14.3%, respectively. As CO₂ is selected as working fluid and oxygen as fuel oxidizer, CO₂ is easily recovered as a liquid with LNG vaporization. In this paper, the typical recuperative Rankine cycle and the corresponding cogeneration system are described and a detailed thermodynamic analysis is carried out to reveal the principle of the cycle and system. Furthermore, the influence of key parameters on performance is discussed. Considering the engineering application, the technical advantages and concerns are pointed out.     

Performance evaluation of a novel CCHP system integrated with MCFC,ISCC and LiBr refrigeration system

This paper proposes a novel combined cooling, heating, and power (CCHP) system integrated with molten carbonate fuel cell (MCFC), integrated solar gas-steam combined cycle (ISCC), and double-effect absorption lithium bromide refrigeration (DEALBR) system. According to the principle of energy cascade utilization, part of the high-temperature waste gas discharged by MCFC is led to the heat recovery steam generator (HRSG) for further waste heat utilization, and the other part of the high-temperature waste gas is led to the MCFC cathode to produce CO₃^2?, and solar energy is used to replace part of the heating load of a high-pressure economizer in HRSG. Aspen Plus software is used for modeling, and the effects of key factors on the system performances are analyzed and evaluated by using the exergy analysis method. The results show that the new CCHP system can produce 494.1 MW of electric power, 7557.09 kW of cooling load and 57,956.25 kW of heating load. Both the exergy efficiency and the energy efficiency of the new system are 61.69% and 61.64%, respectively. Comparing the research results of new system with similar systems, it is found that the new CCHP system has better ability to do work, lower CO₂ emission, and can meet the cooling load, heating load and electric power requirements of the user side at the same time.     

Energy,exergy, economic and environmental (4E) analysis of using city gate station (CGS) heater waste for power and hydrogen production: A comparative study

This paper deals with energy, exergy, economic, and environmental (4E) analysis of two new combined systems for simultaneous power and hydrogen production. The combined systems are integrated from a city gate station (CGS) system, a Rankine cycle (RC), an absorption power cycle (APC), and a proton exchange membrane (PEM) electrolyzer. Since the pressure of natural gas (NG) in transmission pipeline is high, this pressure is reduced at CGS to a lower pressure. However, this NG has also ample potential to be recovered for multiple productions, too. In the proposed systems, the outlet energy of NG is used for power and hydrogen production by employing RC/APC and PEM electrolyzer. The power sub-cycles are driven by waste heat of CGS, while PEM electrolyzer is driven by this waste heat along with a portion of CGS-Turbine output power. A comprehensive thermodynamic modeling and parametric study of the proposed combined systems are conducted from the 4E analysis viewpoint. The results of two proposed systems are compared with each other, considering a fixed value of 1 MW for RC- and APC-Turbines power. Under the same external conditions and using steam as working fluid of RC, the thermal efficiency of the combined CGS/PEM-RC and -APC systems are obtained 32.9% and 33.6%, respectively. The overall exergy efficiency of the combined CGS/PEM-RC and -APC systems are also calculated by 47.9% and 48.9%, respectively. Moreover, the total sum unit cost of product (SUCP) and CO₂ emission penalty cost rate are obtained 36.9 $/GJ and 0.033 $/yr for the combined CGS/PEM-RC and 36 $/GJ and 0.211 $/yr for the combined CGS/PEM-APC systems, respectively. The results of exergy analysis also revealed that the vapor generator (in both systems) has the main contribution in the overall exergy destruction.     

High efficiency power plant with liquefied natural gas cold energy utilization

This article proposes a novel power plant comprising a closed Brayton cycle (CBC) and a Rankine cycle (RC) coupled in series with respect to the flue gases instead of a conventional combined cycle, where the cold energy of the LNG is used to cool the CBC compressor suction. The research study focuses on finding working fluids best suited to the proposed CBC–RC plant and on achieving high efficiency. The proposed working fluids that fulfil the requirements for the CBC are He, N₂ and for the RC are CO₂, ammonia, ethanol or water. An analysis of the power plant using different working fluids is carried out and it is ascertained that the best efficiency conditions for the CBC are achieved with He and CO₂ for the RC. As a result, a thermal efficiency of 67·60%, an overall efficiency of 55·13% and a specific power of 2·465 MW/(kg s⁻¹ LNG) is achieved.     

Energy and exergy analysis of a new hydrogen-fueled power plant based on calcium looping process

A novel hydrogen-fueled power plant with inherent CO₂ capture based on calcium looping process is proposed in this paper. The analyzed system has been evaluated from the energy and exergy points of view, it enables determination of the contribution of main component to the total exergy loss. The results show that energy and exergy efficiencies of the system are 42.7% and 42.25% respectively, combustion chamber and regenerator are responsible for large exergy destructions, mainly due to irreversibilities associated with the combustion reactions, they have great potential for system efficiencies improvements. The effects of various air pressure ratios and gas turbine inlet temperatures on the system thermodynamic performance are also presented. The thermodynamic efficiencies increase with the increase in air pressure ratios and gas turbine inlet temperatures.     

一种基于低品位热源的LNG冷能回收低温动力系统

在分析LNG物理冷Yong的基础上,提出了一种基于低品位热源的LNG冷能回收低温动力系统,并对影响系统循环效率的相关参数进行了研究。结果表明,在较低的热源温度下,系统的热效率和烟效率可以达到30％以上;对影响循环的主要参数分析表明,二次冷煤的冷凝温度及膨胀机进口压力对循环的效率影响很大。随着冷凝温度的降低及膨胀机进口压力的提高,循环热效率、Yong效率都将有所提高。