共查询到20条相似文献,搜索用时 139 毫秒
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孔雪松 《现代塑料加工应用》2013,25(4):9-13
分别研究了弹性体和无机纳米粒子对回收丙烯腈-丁二烯-苯乙烯共聚物(ABS)的增韧。结果表明:弹性体能使回收ABS树脂的韧性得到恢复,但导致刚性下降;无机纳米粒子对ABS树脂的增韧能力有限,但能增加ABS的刚性。最后采用弹性体/无机纳米粒子复合体系改性回收ABS树脂,添加质量分数5%~8%的高胶粉和质量分数2%~3%无机纳米粒子时,实现了对回收ABS树脂的增强增韧。 相似文献
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《化学推进剂与高分子材料》2015,(6):32-38
介绍了用无机纳米粒子改性聚氨酯弹性体的制备方法,综述了纳米Si O2、纳米Zn O、纳米蒙脱土、纳米Ca CO3、纳米Ti O2、碳纳米管以及其他无机纳米粒子改性聚氨酯弹性体的研究进展,指出了无机纳米粒子改性聚氨酯弹性体目前存在的问题。 相似文献
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有机/无机纳米复合粒子是一种性能优异的纳米复合材料,基于分裂/融合过程的细乳液聚合是制备此类复合粒子的新型方法。从热力学角度出发,基于界面Gibbs自由能最低原理推导了核壳型、半球型、夹心型和分离型有机/无机纳米复合粒子平衡型态的界面Gibbs自由能方程,考虑了聚合过程中单体转化率对纳米复合粒子热力学平衡型态的影响,扩展了上述方程应用范围。将这些热力学方程用于炭黑/(聚)苯乙烯/水体系中,发现当无机颗粒体积分数小于0.2时,核壳型纳米复合粒子的界面Gibbs自由能最低;随着单体转化率的增加,核壳型、半球型和夹心型复合粒子的界面Gibbs自由能略有下降,这可能是由于聚苯乙烯/水相的界面张力略低于苯乙烯/水相的数值造成的。 相似文献
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综述了弹性体与无机纳米粒子协同增韧改性环氧树脂以及纳米弹性体粒子增韧环氧树脂的应用进展,并且对纳米技术在弹性体增韧环氧树脂中的应用进行了展望。 相似文献
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采用纳米无机粒子对茂金属聚乙烯(POE)弹性体增韧聚丙烯(PP)二元共混体系进行改性。从而制得PP/POE/无机纳米粒子三元复合材料。分别探讨了纳米高岭土和纳米碳酸钙对复合材料拉伸性能和冲击性能的影响,并考察了不同纳米粉体的增强效果。 相似文献
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Silvia Schicker Daniel E. García Igor Gorlov Rolf Janssen Nils Claussen 《Journal of the American Ceramic Society》1999,82(10):2607-2612
Wet milling of Al2 O3 -aluminide alloy (3A) precursor powders in acetone has been investigated by milling Fe/Al/Al2 O3 and Fe2 O3 /Al/Al2 O3 powder mixtures. The influence of the milling process on the physical and chemical properties of the milled powders has been studied. Particle refinement and homogenization were found not to play a dominant role, whereas plastic deformation of the metal particles leads to the formation of dislocations and a highly disarranged polycrystalline structure. Although no chemical reactions among the powder components in Fe2 O3 /Al/Al2 O3 powder mixtures were observed, the formation of a nanocrystalline, ordered intermetallic FeAl phase in Fe/Al/Al2 O3 powder mixtures caused by mechanical alloying was detected. Chemical reactions of Fe and Al particle surfaces with the atmosphere and the milling media lead to the formation of highly porous hydroxides on the particle surfaces. Hence the specific surface area of the powders increases, while the powder density decreases during milling. The fraction of Fe oxidized during milling was determined to be 0.13. The fraction of Al oxidized during milling strongly depends on the metal content of the powder mixture. It ranges between 0.4 and 0.8. 相似文献
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Lorraine Falter Francis David A. Payne 《Journal of the American Ceramic Society》1991,74(12):3000-3010
Thin layers of Pb[(Mg1/3 Nb2/3 )1– x Ti x ]O3 (PMNT) were prepared by spin casting alkoxide-based solutions on platinized Si. The effects of additives, heat treatment, and composition ( x = 0 to 0.9) on perovskite phase development, ceramic microstructure, and dielectric properties are reported. Depending upon the processing conditions, ceramic thin layers could be formed in a nonferroelectric pyrochlore phase (A2 B2 O6 ) or in a ferroelectric perovskite phase (ABO3 ). The dimensions of the pyrochlore and perovskite units cells were related and increased with Mg and Nb contents. To minmize pyrochlore formation, the most effective processing method involved rapid heat treatment between successive solution depositions. Phase development and microstructure were also affected by solution additives. Additions of benzoic acid were found to affect the structure in solution and the later organic pyrolysis behavior from thin layers. The effect of composition on the dielectric and ferroelectric properties is also reported. 相似文献
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ALEXANDRA NAVROTSKY BARRY A. WECHSLER KAREN GEISINGER FRIEDRICH SEIFERT 《Journal of the American Ceramic Society》1986,69(5):418-422
Solution calorimetry of MgAl2 O4 -Al8/3 O4 solid solutions was performed in a molten 2PbO · B2 O3 solvent at 975 K. The results indicate small negative heats of mixing, relative to spinel standard states for both end-members. These data were combined with information on the energetics of the α-γ transition in Al2 O3 and on the MgAl2 O4 -Al8/3 O4 (MgO-Al2 O3 ) subsolidus phase relations to estimate the partial molar entropy of mixing of γ-Al8/3 O4 in the solid solution. This entropy is much less positive than that calculated from several models for the configurational entropy of mixing of magnesium, aluminum, and vacancies on octahedral and/or tetrahedral sites. The data suggest a good deal of local order to be present in the solid solutions, consistent with negative enthalpies of mixing and entropies of mixing far less than ideal configurational values. 相似文献
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A mean field model, for storage and desorption of NOx in a Pt/BaO/Al2O3 catalyst is developed using data from flow reactor experiments. This relatively complex system is divided into five smaller sub-systems and the model is divided into the following steps: (i) NO oxidation on Pt/Al2O3; (ii) NO oxidation on Pt/BaO/Al2O3; (iii) NOx storage on BaO/Al2O3; (iv) NOx storage on Pt/BaO/Al2O3 with thermal regeneration and (v) NOx storage on Pt/BaO/Al2O3 with regeneration using C3H6. In this paper, we focus on the last sub-system. The kinetic model for NOx storage on Pt/BaO/Al2O3 was constructed with kinetic parameters obtained from the NO oxidation model together with a NOx storage model on BaO/Al2O3. This model was not sufficient to describe the NOx storage experiments for the Pt/BaO/Al2O3, because the NOx desorption in TPD experiments was larger for Pt/BaO/Al2O3, compared to BaO/Al2O3. The model was therefore modified by adding a reversible spill-over step. Further, the model was validated with additional experiments, which showed that NO significantly promoted desorption of NOx from Pt/BaO/Al2O3. To this NOx storage model, additional steps were added to describe the reduction by hydrocarbon in experiments with NO2 and C3H6. The main reactions for continuous reduction of NOx occurs on Pt by reactions between hydrocarbon species and NO in the model. The model is also able to describe the reduction phase, the storage and NO breakthrough peaks, observed in experiments. 相似文献
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Jian Liu Zhen Zhao Chunming Xu Aijun Duan Ling Zhu Xuezhong Wang 《Catalysis Today》2006,118(3-4):315-322
Vanadium oxides supported on γ-Al2O3, SiO2, TiO2, and ZrO2 were studied on their molecular structures and reactive performances for soot combustion. To investigate the effect of different alkali metals on the structures and reactivities of supported-vanadium oxide catalysts, they were doped into the V4/TiO2 catalyst which had the best intrinsic activity for soot combustion in the selected supported vanadium oxide catalysts. The experimental results demonstrated that the catalytic properties of these catalysts depended on the vanadium loading amount, support nature, and the presence or the absence of alkali metals. The spectroscopic analysis (FT-IR and UV–vis) and H2-TPR results revealed that the higher activity of alkali-promoted vanadium oxide catalysts could be related to the ability of alkali metal promoting the redox cycle of the active vanadyl species. TG results showed that adding alkali to Vm/TiO2 catalyst was beneficial to lowering their melting points. Low melting points could ensure the good surface atom migration ability, which would improve the contact between the catalyst and soot. Due to the alkali metal components promoting the redox ability and the mobility of the catalysts, alkali-modified vanadium oxide catalysts could remarkably improve their catalytic activities for soot combustion. The catalytic activity order for soot combustion followed Li > Na > K > Rb > Cs in the catalyst system of alkali-V4/TiO2, and the reason why it followed this sequence was discussed. 相似文献
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(Na1/2 La1/2 )(Mg1/3 Nb2/3 )O3 undergoes a series of phase transitions that involve cation order on the A- and B-sites of the parent perovskite structure. At high temperatures both sites contain a random distribution of cations; below 1275°C a 〈111〉 layering of Mg and Nb leads to the formation of a 1:2 ordered structure with a monoclinic supercell. A second transition was observed at 925°C, where the Na and La cations order onto alternate A-site positions along the 〈001〉 direction of the parent subcell. By quenching samples from above 1275°C to preserve the disorder on the B-site, a fourth variant of this compound was obtained by inducing A-site order through a subsequent anneal at 900°C. Although the changes in structure do not produce significant alterations in the relative permittivity (ɛr ∼ 35), they do have a significant effect on the value of the temperature coefficient of the capacitance. 相似文献
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Kathleen B. Alexander Fred J. Walker Rodney A. McKee Fred A. List III 《Journal of the American Ceramic Society》1990,73(6):1737-1743
Titanium oxide/aluminum oxide films have been deposited using molecular beam epitaxy methods and characterized by reflection high-energy electron diffraction and transmission electron microscopy techniques. Growth on silicon substrates below 973 K resulted in primarily amorphous multilayers. At 1323 K, the deposition of titanium in an oxygen atmosphere on (0001) Al2 O3 substrates resulted in films of Ti2 O3 . These films consisted of small domains, up to 60 nm, slightly misoriented from a [1120] ∥ [1120] orientation relationship. Two variants of Ti2 O3 were observed due to multiple positioning during growth. Closing the titanium shutter during growth resulted in an oriented TiO2 film. 相似文献
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Elena R. Andrievskaya Lidia M. Lopato Vasily P. Smirnov 《Journal of the American Ceramic Society》1996,79(3):714-720
A mathematical model of the liquidus surface based on a reduced polynomial method was proposed for the system HfO2 -Y2 O3 -Er2 O3 . The results of calculations according to this model agree fairly well with the experimental data. Phase equilibria in the system HfO2 -Y2 O3 -Er2 O3 were studied on melted (as-cast) and annealed samples using X-ray diffraction (at room and high temperatures) and micro-structural and petrographic analyses. The crystallization paths in the system HfO2 -Y2 O3 -Er2 O3 were established. The system HfO2 -Y2 O3 -Er2 O3 is characterized by the formation of extended solid solutions based on the fluorite-type (F) form of HfO2 and cubic (C) and hexagonal (H) forms of Y2 O3 and Er2 O3 . The boundary curves of these solid solutions have the minima at 2370°C (15. 5 mol% HfO2 , 49. 5 mol% Y2 O3 ) and 2360°C (10. 5 mol% HfO2 , 45. 5 mol% Y2 O3 ). No compounds were found to exist in the system investigated. 相似文献
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Jazaer Dawody Magnus Skoglundh Louise Olsson Erik Fridell 《Applied catalysis. B, Environmental》2007,70(1-4):179-188
In this work, a kinetic model is constructed to simulate sulfur deactivation of the NOx storage performance of BaO/Al2O3 and Pt/BaO/Al2O3 catalysts. The model is based on a previous model for NOx storage under sulfur-free conditions. In the present model the storage of NOx is allowed on two storage sites, one for complete NOx uptake and one for a slower NOx sorption. The adsorption of SOx is allowed on both of these NOx storage sites and on one additional site which represent bulk storage. The present model is built-up of six sub-models: (i) NOx storage under sulfur-free conditions; (ii) SO2 storage on NOx storage sites; (iii) SO2 oxidation; (iv) SO3 storage on bulk sites; (v) SO2 interaction with platinum in the presence of H2; (vi) oxidation of accumulated sulfur compounds on platinum by NO2. Data from flow reactor experiments are used in the implementation of the model. The model is tested for simulation of experiments for NOx storage before exposure to sulfur and after pre-treatments either with SO2 + O2 or SO2 + H2. The simulations show that the model is able to describe the main features observed experimentally. 相似文献
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Hong-Wen Wang 《Journal of the American Ceramic Society》1995,78(4):1134-1135
in a recent article of the Journal , Yu et al .1 reported their experimental results on the effect of Al2 O3 and Bi2 O3 on the formation mechanism of Sn-doped Ba2 Ti9 O20 . They claimed that both Al2 O3 and Bi2 O3 can dramatically assist the formation of Sn-doped Ba2 Ti9 O20 but are based on different mechanisms. They concluded that first, Bi2 O3 melts above 830°C and accelerates the migration of the involved reactants to form Ba2 Ti9 O20 ; second, Al2 O3 can reduce the height of the potential energy barrier of the formation of Ba2 Ti9 O20 due to the intergrowth of BaAl2 Ti6 O16 phase. They explained their results from a point of view that the formation of Ba2 Ti9 O20 is controlled by (1) the migration of reactants to the interfaces and (2) the height of the potential-energy barrier of the reaction at the interfaces. However, based on their results, we feel their conclusions are incautious and may be misleading, as will be discussed later. 相似文献