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在真空下,在CVD法合成碳纳米管过程中,对有效利用金属催化剂薄膜合成分离单壁碳纳米管的方法进行了探讨。 相似文献
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碳纳米管/聚合物复合材料研究和应用进展 总被引:8,自引:0,他引:8
碳纳米管的发现引起科学界及产业界的极大重视,大量的研究集中在碳纳米管的合成、生长机理、物理性能的表征等方面。随着碳纳米管合成、提纯、化学修饰等领域的研究不断取得进展,碳纳米管/聚合物复合材料的研究已成为世界科学研究的热点。综述了碳纳米管/聚合物复合材料研究在机械、电学、光学性能等方面所取得的进展与应用。 相似文献
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采用快速冷冻化学共沉淀法制备非晶态Ni(OH)2粉体,将其作为电化学活性物质复合碳纳米管合成镍电极材料,研究了其电化学性能. 结果表明,加入碳纳米管有效减少了镍电极的电荷转移电阻,增大了电极反应过程的质子扩散系数. 复合0.5%(w)碳纳米管合成的非晶态氢氧化镍电极材料在1 C充放电制度下,放电终止电压为1.0 V时,其放电比容量高达336.5 mA×h/g,放电中值电压为1.251 V,充放电循环30次,放电比容量保持率为96.74%,表现出较好的高倍率充放电性能. 相似文献
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本文综述了单壁碳纳米管的制备方法,重点阐述了化学气相沉积法的合成运用,并对目前碳纳米管在聚合物基纳米复合材料方面的研究做了综合阐述。 相似文献
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碳纳米管由于其独特的结构和优异的电学、光学、力学、热学等物理化学性能,在材料、电子器件、传感器、催化剂和能源等领域具有广泛的应用前景,但是如何低成本批量制备高品质的碳纳米管是实现碳纳米管大规模应用的关键。本文综述了近年来化学气相沉积法合成碳纳米管的研究进展,表明化学气相沉积法是大规模可控制备碳纳米管最有效的方法,并对其未来的发展方向进行了分析和展望。 相似文献
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In this study “core‐shell” structure of carbon nanotube (CNT) nanocapsules, which aimed at toughening poly(lactic acid) (PLA) were designed by a synthetic strategy consisting of two reaction steps. The first step was to produce reactive chemical bond to bridge CNTs and PLA. So coupling agent KH570 was used to modify CNTs (CNTs‐KH570). The second step involved ring open polymerization of lactide (LA). Lactide polymerized into PLA under catalysis and meanwhile grafted onto CNTs via KH570 (CNTs‐KH570‐PLA). Thus, the CNTs nanocapsules were constructed. Fourier transform infrared spectroscopy (FTIR) showed coupling agent KH570 succeeded in linking CNTs and PLA during LA polymerization. In addition, scanning electron microscopy (SEM) and transmission electron microscope (TEM) indicated CNTs dispersed homogeneous in PLA matrix and the compatibility between them was excellent. The mechanical test also suggested the designed nanocapsules had good effect on toughening PLA composites. This research found one economical and simple way to improve PLA mechanical properties and further broaden its application in many fields. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134, 44919. 相似文献
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Wenwei Wang Cuijuan Jiang Ledong Zhu Nana Liang Xuejiao Liu Jianbo Jia Chengke Zhang Shumei Zhai Bin Zhang 《International journal of molecular sciences》2014,15(9):15981-15993
Soluble carbon nanotubes (CNTs) have shown promise as materials for adsorption of environmental contaminants such as Bisphenol A (BPA), due to the high adsorption capacity and strong desorption hysteresis of BPA on CNTs. The adsorption of BPA to CNTs may change the properties of both BPA and CNTs, and induce different toxicity to human and living systems from that of BPA and CNTs alone. Herein, we report that oral exposure of BPA/MWCNT–COOH (carboxylated multi-walled carbon nantubes) adduct to mice during gestation and lactation period decreased the male offspring reproductive toxicity compared with those induced by BPA alone. The adduct decreased malondialdehyde (MDA) level in testis and follicle-stimulating hormone (FSH) in serum, but increased the level of serum testosterone in male offspring in comparison to BPA alone. Our investigations broadened the knowledge of nanotoxicity and provided important information on the safe application of CNTs. 相似文献
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聚氨酯/碳纳米管复合材料的研究进展 总被引:3,自引:2,他引:1
近年来,利用碳纳米管制备聚氨酯复合材料引起人们的高度重视。本文对聚氨酯/碳纳米管复合材料的研究进展状况进行综述。概述了聚氨酯和碳纳米管的性质以及碳纳米管的改性处理方法;介绍了聚氨酯/碳纳米管复合材料的制备方法,包括物理共混法和原位聚合法;讨论了碳纳米管对复合材料力学性能、电学性能、光学性能以及其他性能的影响。结果表明,碳纳米管的加入使得复合材料在上述性能方面都有不同程度的改善。最后探讨了该研究领域存在的问题及今后可能的发展方向。 相似文献
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《Ceramics International》2021,47(23):32837-32846
Performance degradation always occurs in carbon fibers/carbon nanotubes (CFs/CNTs) multi-scale reinforced composites prepared by chemical vapor deposition (CVD) method. In this study, pyrolytic carbon (PyC) interlayers are introduced to overcome this problem, and the mechanism is studied in detail. The multi-scale reinforcements are combined with lithium aluminosilicate (LAS) glass-ceramic into ceramic matrix composites by slurry impregnation and hot pressing sintering. The results show that the PyC interlayers can protect the CFs from corrosion of the catalyst at high temperature, improve stress transfers and promote the synergy between various components. The CNTs and LAS matrix form a transition area, which causes deflection and shunting when cracks propagate. These factors have greatly increased the crack extension energy, so the mechanical properties have been greatly improved. The flexural strength, fracture toughness and work of fracture reach 602 ± 55 MPa, 10.7 ± 2 MPa m1/2, 4.6 ± 0.7 kJ m−2, respectively, which are 42.3%, 42.6% and 76.9% higher than CF/LAS. This work expands the study of the CFs/CNTs multi-scale reinforcements and the LAS composites, and provides a useful reference for the related research. 相似文献
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Danial Danaei Amir Abbas Nourbakhsh Parvaneh Asgarian Amirhossein Nourbakhsh Kenneth J.D. MacKenzie 《Ceramics International》2019,45(5):5525-5530
Silicon carbide synthesis by a magnesiothermal method was investigated using MCM-48 as the silica source mechanically mixed with carbon nanotubes (CNTs) as the carbon source, and nanocomposites of MCM-48/functionalized CNTs (CNTF). SiC syntheses were carried out with different molar ratios of MCM-48, carbon and magnesium at 700?°C in argon. The MCM-48 and carbon nanotube starting materials and the SiC products were characterized by BET, XRD, FESEM, EDX and TEM. The effect of the carbon content and the type of CNTs (either functionalized or unfunctionalized) on the SiC synthesis was studied. The results show that an improved yield of SiC is obtained when the carbon nanotubes are functionalized, producing a better contact with the MCM-48. This improved contact between the reactants ensures a good degree of reaction in a stoichiometric mixture of silicon and carbon, with no improvement in product formation being achieved by the use of additional carbon. These findings suggest that the degree of contact between reactants is an important factor in the magnesiothermal synthesis of SiC. The SiC products from magnesiothermal synthesis of the functionalized nanocomposite precursors were shown by TEM and FESEM to have unusual nanofiber morphologies mimicking the morphology of the CNTF nanotubes. 相似文献
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《国际智能与纳米材料杂志》2013,4(2):136-171
Embedding carbon nanotubes (CNTs) in load-bearing composite laminate hosts to turn them into nano-laminates is a rapidly emerging field and has tremendous potential in enhancing the mechanical performance of the host laminates. This state-of-the-art review intends to provide a physical insight into the understanding of the enhancing mechanisms of the processed and controlled CNTs in the nano-laminates. It focuses on four aspects: (1) physical characteristics of CNTs, including CNT length, diameter, weight percentage and surface functionalization; (2) processing and control techniques of CNTs in the fabrication of nano-laminates, including distribution, dispersion and orientation controls of CNTs; (3) mechanical properties along with their testing methods, including tension, in-plane compression, in-plane and interlaminar shear (ILS), flexure, mode I and mode II fracture toughness as well as compression-after-impact (CAI), ballistic protection and fatigue; and (4) CNT–matrix load transfer and enhancing mechanisms along with a few major governing factors. The selective and uniform production of CNTs with specific dimensions and physical properties has yet to be achieved on a consistent basis. Moreover, the processing details of CNTs vary very significantly among different researchers so that the processed CNTs share little common characteristics. There is little control over the CNT orientations in most fabrication processes of the nano-laminates except for some cases associated with chemical vapor deposition (CVD). There are only two reports on in-plane compression and there is only one on in-plane shear. For reinforcement-dominated mechanical properties such as longitudinal tension and flexure, there was little enhancement reported. However, the substantial enhancement in in-plane compression strength was also reported. For matrix-dominated mechanical properties, such as transverse tension, in-plane shear, ILS strength and mode I and mode II fracture toughness, a significant enhancement, albeit with substantially varying degrees, was reported for ILS strength and mode I and mode II fracture toughness values. Meanwhile, the lack of consistent characterization of those properties was also noticeable. There is little established understanding of the enhancing mechanisms in nano-laminates. 相似文献