共查询到19条相似文献,搜索用时 140 毫秒
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采用乳化液膜法去除焦化废水中的苯酚,建立了以磷酸三丁酯(TBP)为载体、Span-80为表面活性剂、煤油作膜溶剂及NaOH溶液为内相的乳化液膜体系.首先采用红外光谱分析得出TBP与酚类物质属氢键缔合.其次通过液膜稳定性实验表明,当表面活性剂体积分数为5%、油内比为1∶1、制乳时间为30 min、制乳转速为2 000 r/min时,可以得到较为稳定的乳化液膜.最后根据分离实验结果得出,当表面活性剂体积分数为5%、NaOH溶液浓度为0.5 mol/L、载体体积分数为0.2%、乳水比为1/3时,苯酚的迁移率可达到95%以上. 相似文献
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乳状液膜法处理H酸废水的实验研究 总被引:1,自引:1,他引:1
以Span-80、FSN-100为复合表面活性剂,TOA为流动载体,研究了乳状液膜处理H酸废水时TOA浓度、内相NaOH浓度、油内比Roi、外相pH、乳水比Rew及搅拌强度等因素对废水COD去除率指标的影响,分析了其内在影响因素的规律性.同时,实验结果表明乳状液膜法处理H酸废水具有较好的应用前景. 相似文献
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采用以磷酸三丁酯(TBP)为流动载体,液体石蜡为膜相添加剂,煤油为膜溶剂与表面活性剂组成的W/O型乳状液膜体系提取模拟发酵液中的青霉素,考察了单一表面活性剂、混合表面活性剂对青霉素传质和液膜溶胀的影响.实验结果表明:聚胺类表面活性剂(兰113B、N205、ECA4360)对青霉素的提取率优于酯类表面活性剂(span80),且用量少、液膜溶胀率低;酯类表面活性剂与聚胺类表面活性剂不能配伍使用,聚胺类表面活性剂混合性能优于单一表面活性剂,有利于提高青霉素的传质,降低液膜溶胀.表面活性剂在液膜分离中起着极为重要的作用,直接影响着液膜的稳定性、溶胀性能及液膜的破乳.选择性能优良的表面活性剂,适宜的液膜配方和操作条件,有利于控制液膜溶胀,提高青霉素的提取率. 相似文献
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乳状液膜法提取赖氨酸 总被引:4,自引:0,他引:4
研究了用乳状液膜法提取赖氨酸的液膜配方及一些重要操作参数 ,初步得出了既能相对减少溶胀 ,又能保持较高分离效率的膜组成及最佳工艺条件 .赖氨酸提取的液膜组成为 :载体二 - (2 -乙基己基 )磷酸脂 7% (质量分数 ) ,表面活性剂 (Span - 80 ) 5 % (质量分数 ) ,膜溶剂 5 0 % (体积分数 )液体石蜡和 5 0 %煤油 .内相选用 0 .5mol/L的HCl溶液 ,处理比为 3.75 ,提取率可达 72 .6 % 相似文献
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研究了用中空纤维膜组件脱除CO2的吸收过程,制备了一系列不同装填率的中空纤维膜组件.用这些膜组件进行实验,以不同浓度的单乙醇胺(MEA)溶液为吸收剂,研究了气液两相的流量和浓度、组件的装填率、吸收剂的循环使用等因素对CO2膜吸收过程的影响.实验结果表明:气、液相流量的增大和液相MEA浓度的增加都可使CO2的传质通量增大;气相CO2浓度的增加会使总传质系数减小;在组件进口气液流量和浓度相同的条件下,组件装填率(0.5%~21%)的变大有利于CO2的脱除;随着吸收液循环次数的增加,CO2的传质通量和其脱除率都会降低. 相似文献
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液膜法处理高氟废水研究 总被引:10,自引:0,他引:10
利用N205-N1923-煤油液膜体系,CaCl2溶液作内相,对高氟废水的处理进行了研究。利用正交实验确定了影响最大的因素,并研究了各种因素对处理的影响。经30min处理,外相F^-浓度可由0.500g/L降至0.010g/L以下,可达到工业排放标准。 相似文献
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The emulsion liquid membrane technique was used for the extraction of hexavalent chromium ions from aqueous solution of waste sodium dichromate recovered from the pharmaceutical industry wastewater. The liquid membrane used was composed of kerosene oil as the solvent, Span-80 as the surfactant and potassium hydroxide as internal reagent. Trioctyl amine and Aliquat-336 were used as carriers. The emulsion stability was carried out at different surfactant concentration, agitation speed and emulsification time. Statistical experimental design was applied for the optimization of process parameters for the extraction of chromium by emulsion liquid membrane. The effects of process parameters namely, agitation speed, membrane to emulsion (M/E) ratio and carrier concentration on the extraction of chromium were optimized using a response surface method. The optimum conditions for the extraction of chromium (VI) using response surface methodology for Trioctyl amine were: agitation speed – 201.369 rpm, M/E ratio – 0.5887% (v/v) and carrier concentration – 4.0932% (v/v) and for Aliquat-336: agitation speed – 202.097 rpm, M/E ratio – 0.5873% (v/v) and carrier concentration – 3.9211% (v/v). At the optimized condition the maximum chromium extraction was found to be 89.2% and 96.15% using Trioctyl amine and Aliquat-336, respectively. 相似文献
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The extraction equilibrium of Co(II) from thiocyanate medium by CYANEX 923 (mixture of straight chain alkylated phosphine oxides) in cyclohexane was studied. The stoichiometry of the extraction reaction was postulated based on slope analysis method and the extraction constant Kex was calculated. The stripping percentage of Co(II) with sulphuric acid from the loaded CYANEX 923 was found to increase with the increase in acid concentration. The extraction of Co(II) from aqueous thiocyanate medium into emulsion liquid membrane using CYANEX 923 extractant was also studied. The influence of different parameters such as stirring speed, surfactant concentration, pH of the extractant phase, carrier concentration, internal phase stripping acid concentration, initial Co(II) concentration as well as temperature on the emulsion stability were investigated. The applicability of the emulsion liquid membrane (ELM) process using CYANEX 923 as extractant and SPAN 80 as surfactant for the removal and the concentration of Co(II) from thiocyanate solution was investigated. The results show that it is possible to recover 95% of cobalt in the inner phase after 10 min of contacting time with a concentration factor of 5. 相似文献
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用含两亲高分子的液膜迁移痕量Cr3+ 总被引:1,自引:0,他引:1
将两亲高分子聚(甲基丙烯酸十二酯一丙烯酸)作为膜稳定剂加到由Span-80、P507、煤油、液体石蜡和水等组成的W/O型乳液膜中,研究了此体系对痕量Cr^3 的迁移作用。结果表明,由于两亲高分子的空间稳定作用而导致乳液膜对Cr^3 具有较高的迁移效率。 相似文献
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Study on a new surfactant for removal of phenol from wastewater by emulsion liquid membrane 总被引:1,自引:0,他引:1
Mortaheb HR Amini MH Sadeghian F Mokhtarani B Daneshyar H 《Journal of hazardous materials》2008,160(2-3):582-588
Removal of phenol from wastewater using emulsion liquid membrane (ELM) is studied in present study. A new polyamine-type surfactant was synthesized and used for stabilizing of the emulsion phase. The results for the emulsion made by the synthesized surfactant showed much better stability and performance in the separation process compared to that by conventionally used Span 80. To determine the optimum operation conditions, the effect of several parameters such as emulsifier concentration, concentration of NaOH in the internal phase, oil to internal phase volume ratio, mixing intensity, temperature, solvent type, and stabilizer concentration have been investigated. It was found that under the optimum conditions, more than 98% of phenol can be removed in a single-stage process. The removal efficiency can be increased to 99.8% in a two-stage process. 相似文献
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乳状液膜法提取青霉素G的研究 总被引:4,自引:2,他引:2
使用青霉素G钠盐纯品溶液,模拟考察了乳状液膜法分离青霉素的条件.着重研究了提取率与膜中载体类型、Span-80用量的关系,优化出最佳提取条件,在最佳条件下青霉素的提取率可达92%,浓缩比可达9. 相似文献
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油内比和表面活性剂浓度对(稀型)乳状液膜工业过程的影响 总被引:3,自引:1,他引:2
在当前破乳技术的基础上,用稀型乳状液膜法治理粘胶纤维工业酸性含锌废水、选择稀型乳状液的油内比Roi大于3,表面活性剂T154的体积分数降至0.6%的条件,在工业上实现了含锌废水的处理,这过程既无二次污染,又 收锌资源,具有一定的经济效益。 相似文献
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表面活性剂对液膜法提取柠檬酸影响的研究 总被引:5,自引:0,他引:5
表面活性剂种类和浓度对液膜法提取柠檬酸的提取率和乳液溶胀都有一定影响 .在给定条件下 ,提取率随表面活性剂浓度的增大而提高 ,由LMA -1所制成的液膜对柠檬酸的提取率比Span -80高 ,且产生的乳液溶胀也比较小 相似文献