DP980表面氧化物对胶接性能的影响

目的 明确高强钢DP980表面氧化物的组成及含量对胶接性能的影响规律,从而改善双相高强钢的胶接性能。方法 通过采用1%(质量分数)的醋酸溶液对双相高强钢DP980表面进行不同时间的酸蚀处理,结合扫描电子显微镜(SEM)、透射电子显微镜(TEM)对高强钢表面氧化物的微观形貌进行观察,通过电子探针(EPMA)表征酸洗前后高强钢表面元素分布变化,采用辉光放电发射光谱仪(GDS)对不同酸洗时间处理的高强钢表面元素的含量随深度变化进行分析,同时通过对Si、Mn元素的高分辨X射线光电子能谱(XPS)分峰拟合,表征高强钢表面不同氧化物成分。通过接触角测试分析酸洗处理对高强钢表面润湿性的影响。最后对不同酸洗时间处理的高强钢进行了胶接试验,探究高强钢表面氧化物含量、形貌及种类对胶接性能的影响规律。结果 DP980表面存在Si、Mn、O元素的富集,其中氧化物以SiO_x、Mn₂SiO₄、MnSiO₃、MnO等形式存在。随着酸洗时间的延长,DP980表面氧化物尤其是Si Ox含量显著降低,颗粒尺寸明显减小,同时表面纳米尺度...     

基于半球凸模试验的高强钢边部成形性敏感度分析

基于半球凸模试验对4种780 MPa级别的典型高强钢开展了边部成形试验,分析了试验过程中的边部变形情况,并对4种典型高强钢冲裁及铣削2种边部质量状态下的试样顶点的极限开裂角度和开裂位置的减薄率进行对比。结果表明:当边部为冲裁边时,CP780极限开裂角度最高,DH780极限开裂角度略低于CP780,DP780及TRIP780极限开裂角度明显降低,仅为DH780的60%左右;对于开裂位置的边部减薄率,CP780最高,达到28.9%,DH780达到15.3%,DP780及TRIP780仅分别为DH780的8.2%和9.5%。改善边部质量可有效提升材料的边部成形性,但不同钢种对其敏感程度不同,相比冲裁边质量,经过边部铣削的DP780及TRIP780边部极限开裂角度及边部减薄率提升约1倍左右,对边部质量敏感程度最高;CP780仅提升1%左右,对边部质量的敏感程度最低;DH780介于CP780和DP780、TRIP780之间。     

高强度双相钢的成形性能

采用光学显微镜、单向/拉压、万能成形、三点弯曲等试验机检测了780~1180 MPa级双相钢的显微组织、力学性能、FLC(成形极限曲线)和冷弯性能。结果表明,随着双相钢的屈服强度增加,其伸长率、n值和r值降低,晶粒细化,马氏体含量增加,平面应变成形极限值从22.7%下降至12.6%,拉伸极限从15.8%下降至8.6%,三点弯曲最小相对弯厚半径从1.13增加到2.86;980 MPa级双相钢随着屈服强度增加,组织均匀性提高,胀形极限从22.8%增加到34.5%,最小相对弯厚半径从2.50减小到1.82;CR420/780DP、CR700/980DP、CR820/1180DP钢的包申格效应常数分别为0.82、0.78和0.79。CR420/780DP和CR820/1180DP钢在压缩过程中塑性变形初始阶段的加工硬化速率高于反向拉伸和单向拉伸塑性变形初始阶段的加工硬化速率。     

常压空气等离子处理对铝合金胶接接头强度的影响

为改善铝合金表面润湿性与胶接强度,采用常压空气射流等离子体对5052铝合金进行表面处理。通过接触角测试,表面自由能计算和胶接接头剪切强度测试表明处理时间对铝合金表面改性效果影响不大,随着处理距离减短,铝合金表面自由能、胶接接头强度均逐步提升。处理距离为5 mm时等离子处理铝合金获得最佳表面改性效果,铝合金胶接接头剪切强度由10.6 MPa提升至19.3 MPa,失效模式由界面失效转变为内聚失效。利用SEM,XPS,傅立叶变换红外光谱等检测手段分析不同处理距离对应表面理化特性的变化,结果表明:处理距离较远时,等离子体并未改变铝合金表面物理形貌,其主要改性效果体现为表面清洗;处理距离较近时,铝合金表面高温熔融产生复杂微结构的粗糙氧化层,同时氧化层表面吸附羟基等极性官能团,显著提升了其表面自由能与胶接强度。     

冷轧双相钢扩孔性能研究

文章以汽车工业广泛使用的不同强度等级冷轧双相钢为研究对象,采用力学性能、硬度及扩孔率测试,并结合显微组织分析研究剪切边缘可成形性的影响因素,为提高冷轧双相钢扩孔性能及优化产品质量提供指导。结果表明:冷轧双相钢DP590和DP780剪切边缘影响区及硬化程度明显高于DP980和DP1180,影响局部可成形性进而影响扩孔性能;添加微合金元素细化组织使马氏体呈岛状弥散分布有利于应变的均匀分配以降低在局部范围造成较高的应变强化,有利于扩孔性能的提高;对于超高强冷轧双相钢DP980和DP1180增大屈强比可明显提高扩孔性能。     

高强钢DP780局部断裂性能研究

高强钢DP780在车身安全结构件中广泛应用。该材料的剪切边延展性的优劣与钢中马氏体的弥散程度和马氏体形貌以及马氏体包围铁素体晶粒的连续度有关。高强钢DP780因其出色的比强度与比刚度,成为先进车身结构制造的首选材料之一。DP780与其他传统材料相比,在车身零部件成形时更多的表现为由于翻边、扩孔等引起的边缘局部开裂。本文旨在以车身某纵梁结构为例,研究DP780的微观组织对零件成形时局部断裂性能的影响。     

超高强双相钢冲杯盐雾延迟开裂性能的研究

利用拉深冲杯盐雾延迟开裂实验研究了三种超高强双相钢的延迟开裂性能。结果表明,DP780钢的抗延迟开裂性能最好,其次为DP980钢,DP1180钢抗延迟开裂性能最差。DP980和DP1180钢存在一临界成型比(DP980钢介于1.6～1.7,DP1180钢约为1.6),在该临界成型比以下时,冲杯试样不会出现延迟开裂现象。此临界成型比可在一定条件下作为超高强钢是否会出现延迟开裂的评价依据。     

热处理对GA钢和双相钢力学性能的影响

利用热处理将GA钢制备成4种类型的双相(DP)钢,并进行了拉伸和冲击试验。通过扫描电子显微镜研究了拉伸和冲击试验的试样(DH36,GA和DP钢)的断裂表面。结果表明,应用热处理方法可以将GA钢成功地转变为DP钢;最低淬火温度的A730W试样的强度优于DH36钢的强度;GA钢具有最高的冲击韧性值;A800W和A900W试样的冲击韧性值高于DH36钢的冲击韧性值。     

B1500HS热成形钢与DP钢的点焊接头拉剪性能

摘要： 文中以3种强度级别的双相钢(DP780,DP980,DP1180)和B1500HS热成形钢的电阻点焊接头为研究对象,研究了DP钢强度对点焊接头拉剪性能的影响,分别观察和分析了接头宏观形貌和微观组织,测试和分析了接头的硬度分布及接头的断裂模式。结果表明,DP钢强度对接头的拉剪强度影响很小,但会影响其断裂模式。B1500HS/DP780的断裂是焊核从DP钢侧拔出,另2种的则是焊核从B1500HS侧拔出,但它们的初始起裂位置均位于亚临界热影响区。B1500HS侧亚临界热影响区软化严重,较基体硬度下降约29%～36%,而DP780无明显软化现象,DP980和DP1180侧的亚临界热影响区软化率分别为17%和25%。说明在异种材料电阻点焊过程中其热影响区的软化程度会影响点焊接头的断裂模式。 创新点： 对B1500HS分别与DP780,DP980,DP1180组成的RSW接头展开对比研究。     

1180 MPa级超高强度汽车薄板钢的延迟断裂性能

利用U型弯曲试验研究了3种1180 MPa级超高强汽车薄板钢的延迟断裂性能。结果表明,DP1180钢的组织主要为马氏体+铁素体;MS1180钢的组织主要为马氏体+少量铁素体;QP1180钢的组织主要为马氏体、铁素体和少量残留奥氏体。DP1180钢的抗延迟断裂性能最好,其次是MS1180钢,QP1180钢的抗延迟断裂性能最差。此外,组织对试验钢的延迟断裂性能有重要影响,马氏体的含量和形貌、残留奥氏体含量都会影响钢的延迟断裂性能。     

Effects of Post-weld Heat Treatment on Microstructure,Mechanical Properties and the Role of Weld Reinforcement in 2219 Aluminum Alloy TIG-Welded Joints

In as-welded state, each region of 2219 aluminum alloy TIG-welded joint shows diff erent microstructure and microhardness due to the diff erent welding heat cycles and the resulting evolution of second phases. After the post-weld heat treatment, both the amount and the size of the eutectic structure or θ phases decreased. Correspondingly, both the Cu content in α-Al matrix and the microhardness increased to a similar level in each region of the joint, and the tensile strength of the entire joint was greatly improved. Post-weld heat treatment played the role of solid solution strengthening and aging strengthening. After the post-weld heat treatment, the weld performance became similar to other regions, but weld reinforcements lost their reinforcing eff ect on the weld and their existence was more of an adverse eff ect. The joint without weld reinforcements after the post-weld heat treatment had the optimal tensile properties, and the specimens randomly crack in the weld zone.     

The First Phase of the SRIF Industrialized Base in ＂West Area＂ Has Been Put into Operation

After nearly two years＇ tense construction, the first phase of industrialized base of Shenyang Research Institute of Foundry （SRIF）, located at the Tiexi Casting and Forging Industrial Park in the west of Tiexi District, has now been completed and formally put into operation.     

THERMODYNAMICS STUDY ON THE DECOMPOSITION OF CHROMITE WITH KOH

Institute of Process Engineering, Chinese Academy of Sciences, China, has proposed a method for oxidative leaching of chromite with potassium hydroxide. Understanding the mechanism of chromite decomposition, especially in the potassium hydroxide fusion, is important for the optimization of the operating parameters of the oxidative leaching process. A traditional thermodynamic method is proposed and the thermal decomposition and the reaction decomposition during the oxidative leaching of chromite with KOH and oxygen is discussed, which suggests that chromite is mainly destroyed by reactions with KOH and oxygen. Meanwhile, equilibrium of the main reactions of the above process was calculated at different temperatures and oxygen partial pressures. The stable zones of productions, namely, K2CrO4 and Fe2O3, increase with the decrease of temperature, which indicates that higher temperature is not beneficial to thermodynamic reactions. In addition, a comparison of the general alkali methods is carried out, and it is concluded that the KOH leaching process is thermodynamically superior to the conventional chromate production process.     

INFLUENCE OF HEAT TREATMENT ON DAMPING BEHAVIOUR OF THE MAGNESIUM WROUGHT ALLOY AZ61

The effect of isochronal heat treatments for 1h on variation of damping, hardness and microstructural change of the magnesium wrought alloy AZ61 was investigated. Damping and hardness behaviour could be attributed to the evolution of precipitation process. The influence of precipitation on damping behaviour was explained in the framework of the dislocation string model of Granato and Lücke.     

Theoretical Analysis for the Motion and Temperature of Melt Droplets in Spray Degassing Process

The motion of melt droplets in spray degassing process was analyzed theoretically. The height of the treatment tank in spray degassing process could be determined by the results of theoretical calculation of motion of melt droplets. To know whether the melt droplets would solidify during spraying process, the balance temperature of melt droplets was also theoretically analyzed. Then proof experiments for theoretical results about temperature of melt droplets were carried. In comparison, the experimental results were nearly similar to the calculation results.     

Growth Kinetics of Single Inclusion Particle in Molten Melts

On the basis of the single-particle framework, a new theory on inclusion growth in metallurgical melts is developed to study the kinetics of inclusion growth on account of reaction and collision. The studies show that the early growth of inclusion depends on reaction growth and Brawnian motion collision, and where the former is decisive, the late growth depends on turbulence collision and Stokes＇ collision, and where the former is dominant; collision growth is very quick during the smelting process, lessened in the refining process, but nearly negligible in the continuous casting process.     

An Easy Way to Quantify the Adhesion Energy of Nanostructured Cu/X(X=Cr,Ta,Mo,Nb,Zr) Multilayer Films Adherent to Polyimide Substrates

An approach based on film buckling under simple uniaxial tensile testing was utilized in this paper to quantitatively estimate the interfacial energy of the nanostructured multilayer films(NMFs) adherent to flexible substrates. The interfacial energies of polyimide-supported NMFs are determined to be *5.0 J/m2 for Cu/Cr, *4.1 J/m2 for Cu/Ta,*2.8 J/m2 for Cu/Mo, *1.1 J/m2 for Cu/Nb, and *1.2 J/m2 for Cu/Zr NMFs. Furthermore, a linear relationship between the adhesion energy and the interfacial shear strength is clearly demonstrated for the Cu-based NMFs, which is highly indicative of the applicability and reliability of the modified models.     

High-Speed Friction Stir Welding of SiC_p/Al–Mg–Si–Cu Composite

A 17 vol% SiCp/Al–Mg–Si–Cu composite plate with a thickness of 3 mm was successfully friction stir welded(FSWed) at a very high welding speed of 2000 mm/min for the first time. Microstructural observation indicated that the coarsening of the precipitates was greatly inhibited in the heat-affected zone of the FSW joint at high welding speed, due to the significantly reduced peak temperature and duration at high temperature. Therefore, prominent enhancement of the hardness was achieved at the lowest hardness zone of the FSW joint at this high welding speed, which was similar to that of the nugget zone. Furthermore, the ultimate tensile strength of the joint was as high as 369 MPa, which was much higher than that obtained at low welding speed of 100 mm/min(298 MPa). This study provides an effective method to weld aluminum matrix composite with superior quality and high welding efficiency.     

新型的治疗阿尔茨海默氏症药物(1-二甲基磷酰基-2,2,2-三氯)-乙基-1-醇烟酸醋对体外神经细胞的作用

目的: 观察本实验室合成的一种治疗阿尔茨海默氏症(AD)的药物(1-二甲基磷酰基-2, 2, 2 -三氯)-乙基^-1-醇烟酸醋(NMF),对体外培养的皮层神经细胞活性的影响以及对海人藻酸(KA)所致的神经损伤的保护作用。方法: 采用体外培养皮层神经元的方法,解剖分离 15 d胚胎小鼠皮层神经细胞, 接种于 96孔板,48 h 后加药并培养 72 h,以 MIT 法 观察 NMF 对小鼠皮层神经细胞活性的影响;同时将接种于 24 孔板的细胞预先给予 NMF,d 3 时加或不加KA处理后,以台盼蓝染色鉴别并计数死、活细胞,可得出细胞的存活率。结果: NMF 明显促进胎鼠皮层神经元活性,其中 NMF1、0. 1、10nmol·L^-1促进神经元活性增殖率分别高达 34.7%、37.4%、36. 7%, NMF 明显促进正常胎鼠皮层神经元存活卒,与对照组比较,10nmol·L^-1 NMF 对皮层神经元的存活率分别提高 39.3%、73.5%。 NMF能显著 对抗 KA 所致的神经元损伤,与 KA 损伤组相比, NMF0.1、10、10nmol·L^-1对损伤皮层神经元的保护率分别为 77.30%、80.10%、84.15%。结论: NMF 明 显促进胎鼠皮层神经元的洁性、提高正常皮层神经元,的存活卒,并能有效地保护KA所致的神经元损伤,提示 NMF 是一种很有潜力的治疗 AD 的药物。     

A STUDY OF TEMPERATURE-DEPENDENT VALENCE BOND STRUCTURE OF TITANIUM

On the basis of energy and shape method for the determination of the valence bond (VB) structures of crystal, the valence bond structure of titanium is redetermined at room temperature and calculated in the whole temperature range of 0-1943K. The outer shell electronic distribution of Ti is e_c~(2.9907) · (s_c~(0.4980) d_c~(2.4927)) ef1.0093 in crystal. The temperature dependences of the VB structures of hcp and bcc phases are the same. The VB structures of hcp and bcc phases monotonically increase or decrease with the increase in temperature, but show discontinuous changes at the phase-transformation temperature 1155K.