共查询到20条相似文献,搜索用时 31 毫秒
1.
Ya-Lun Su Lai Kwok Leung Yu-Rong Bi Yu Huang Zhen-Yu Chen 《Journal of the American Oil Chemists' Society》2000,77(8):807-813
The present study examined the antioxidant activity in heated canola oil of hexane, acetone, and methanol extracts of dry
roots of gansu huangqin (Scutellaria rehderiana) as well as six flavonoids isolated from the acetone and methanol extracts. The oxidation was conducted at 95°C by monitoring
oxygen consumption and decreases in both linoleic and α-linolenic acids. The acetone extract was most effective in inhibiting
oxidation of canola oil, followed by the methanol extract. The antioxidant activity of gansu huangqin acetone extract was
dose-dependent. Among the six flavonoids, baicalein and ganhuangenin were more effective than butylated hydroxytoluene (BHT)
in protecting canola oil from oxidation. The present results suggest that the acetone extract of this root may be a potential
source of natural antioxidants for use in processed foods. 相似文献
2.
Reiko Nakayama Yoshiyuki Tamura Hiroe Kikuzaki Nobuji Nakatani 《Journal of the American Oil Chemists' Society》1999,76(5):649-653
The antioxidant activities of several extracts from Susabinori (Porphyra yezoensis) were measured by the ferric thiocyanate method and the thiobarbituric acid method. The methanol, acetone, ethyl acetate,
and hexane extracts, and the chloroform-soluble and water-soluble fractions from the chloroform-methanol extract exhibited
higher activities than α-tocopherol. The hot water extract showed little activity. Thin-layer chromatography analysis of the
active extracts suggested the existence of several antioxidants. The activity of the chloroform soluble fraction was due to
chlorophyll analogs. A strong antioxidant was isolated from the methanol extract, accompanied by several amino acids such
as leucine and phenylalanine. This compound was identified as usujilene, a kind of mycosporine-glycine like amino acid. 相似文献
3.
F. J. Eller J. K. Moser J. A. Kenar S. L. Taylor 《Journal of the American Oil Chemists' Society》2010,87(7):755-762
Tomato seeds represent a very large waste by-product from the processing of tomatoes into products such as tomato juice, sauce
and paste. One potential use for these seeds is as a source of vegetable oil. This research investigated the oil content of
tomato seeds using several extraction techniques as well as an examination of the oil extracts to determine the composition
of the minor constituents such as phytosterol and antioxidant composition. The oxygen radical absorbance capacity (ORAC) of
the tomato seed oils were also measured and correlated with antioxidant contents. This research demonstrated that tomato seed
oil yield was highest using hot ethanol and followed by hot hexane and finally SC-CO2. The SC-CO2 treatment, however, had the highest total phytosterol content as well as highest individual phytosterol content. Sitosterol,
cycloartanol, and stigmasterol were the most abundant phytosterols present in the extracts. The highest concentrations of
antioxidants were found in the hexane extract. The most abundant antioxidants found in the tomato seed oils were all-trans-lycopene, cis-3-lycopene and β-carotene. ORAC was highest for the hexane extract. Oil yield was inversely proportional to both α-tocopherol
and γ-tocopherol content and positively correlated with cis-3-lycopene content. ORAC values were positively correlated with only all-trans-lycopene and cis-3-lycopene demonstrating their role as antioxidants in the tomato seed oil. 相似文献
4.
The lipid fraction of annatto (Bixa orellana L.) seeds was extracted with a Soxhlet apparatus with n-hexane and isolated by thin-layer chromatography. The fatty-soluble antioxidant fraction contained only tocotrienols, mainly
δ-tocotrienol, but no tocopherols. The presence of tocotrienols was confirmed by gas chromatography-mass spectrometry. The
quantities of δ-tocotrienol were 140–147 mg/100 g dry seeds and 5.2–5.5% wt/wt of lipid extract, determined by gas chromatography
and high-performance liquid chromatography, respectively. Currently no vegetable species seems to contain comparable concentrations
of δ-tocotrienol. 相似文献
5.
Niger (Guizotia abyssinica) seed was ground and then defatted with hexane. The meal remaining after oil extraction was tested as a source of antioxidants.
Three solvent systems, A [80∶20 (vol/vol) ethanol/water], B [80∶20 (vol/vol) acetone/water], and C (water) were evaluated
as extraction media. Crude extracts were examined for their antioxidant activity in a β-carotene-linoleate and a meat model
system. Extract A exhibited superior antioxidant activity, compared to extracts B and C, and its composition was studied further
by using column chromatography and HPLC. Four fractions (I–IV) were obtained, of which fractions III and IV showed activity
in the β-carotene-linoleate model system. Fraction IV was also highly effective in scavenging the 2,2-diphenyl-1-picrylhydrazyl
radical but was less active when used in a bulk oil model system. Preparative TLC showed fraction IV as consisting of two
components. UV spectroscopy suggested that the major active component pressent was a chlorogenic acid-related compound. Furthermore,
HPLC analysis established that chlorogenic acid was dominant in the free phenolics fraction (2.6 mg/g). Upon hydrolysis, however,
a substantial amount of caffeic acid (42.8 mg/g) was released, presumably from esterified and glycosylated chlorogenic acid.
Thus, niger extracts derive their antioxidant activity, at least in part, from the chlorogenic acid-related compounds. 相似文献
6.
Antioxidant activity of burdock (Arctium lappa Linné): Its scavenging effect on free-radical and active oxygen 总被引:1,自引:0,他引:1
Pin-Der Duh 《Journal of the American Oil Chemists' Society》1998,75(4):455-461
The antioxidant activity and free-radical and active oxygen-scavenging activity of burdock extracts were investigated. Of
the solvents used for extraction, water yielded the greatest amount of extract that exhibited the strongest antioxidant activity.
Water extracts of burdock (WEB) and hot water extracts of burdock (HWEB) exhibited comparable and marked activity on inhibition
of linoleic acid peroxidation, indicating that heat treatment did not alter the antioxidant activity of WEB. WEB and HWEB
produced significantly lower (P<0.05) malondialdehyde (MDA) in both linoleic acid and liposome model systems than did the control. Moreover, mixtures of
tocopherol (Toc), WEB, and HWEB exhibited a remarkable synergistic antioxidant effect in a liposome system; WEB and HWEB thus
potentiated the action of Toc. Furthermore, WEB and HWEB displayed a marked inhibitory effect on lipid peroxidation of rat
liver homogenate in vitro. WEB and HWEB exhibited an 80% scavenging effect on α,α-diphenyl-β-picrylhydrazyl radical and marked reducing power, indicating
that WEB and HWEB act as primary antioxidants. Both extracts at a dose of 1.0 mg exhibited a 60.4–65.0% scavenging effect
on superoxide and an 80.5% scavenging effect on hydrogen peroxide. They also showed a marked scavenging effect on the hydroxyl
radical. These results revealed that WEB and HWEB are also active as oxygen scavengers and as secondary antioxidants. Based
on these results, termination of free-radical reactions and quenching of reactive oxygen species in burdock extracts are suggested
to be, in part, responsible for the antioxidant activity of burdock extracts. 相似文献
7.
Shinya Ashida Satoshi F. Noguchi Tateo Suzuki 《Journal of the American Oil Chemists' Society》1994,71(10):1095-1099
Substances with antioxidative properties were obtained from an ether extract ofSwertia japonica Makino. Six active components of the extract were isolated and identified as methylbellidifolin, methylswertianin, swertianin,
bellidifolin, norswertianin and desmethylbellidifolin. These six xanthone derivatives were shown to possess different antioxidant
activities by chemiluminescent assay. The antioxidative activities of bellidifolin, norswertianin and desmethylbellidifolin
were higher than those of butylated hydroxytoluene (BHT) and α-tocopherol. On autoxidation of methyl linoleate, bellidifolin
had activity similar to that of BHT. On the basis of the data present on antioxidative properties and data reported on the
mutagenicities of the xanthones, both activities were shown to give a good correlation. 相似文献
8.
Paul R. Pike El-Sayed M. Abdel-Aal Arthur R. McElroy 《Journal of the American Oil Chemists' Society》2007,84(7):663-667
Oat cultivar AC Vermont was malted to concentrate antioxidants, milled to fractionate only the endosperm portion and extracted
with methanol to isolate the crude antioxidants. The oat malt antioxidant fraction was assessed as a natural antioxidant based
upon enhancing the stability of corn oil against oxidation and compared to the synthetic antioxidant butylated hydroxytoluene
(BHT). The induction time (time required for the formation of 10 meq hydroperoxide per kilogram corn oil thermally oxidized)
was used to measure antioxidant activity of oat antioxidant or BHT. The protection factor achieved by crude oat malt antioxidant
extract concentrate at 0.26% (2,600 μg/g) was comparable to BHT (75 μg/g). The antioxidant activity of the oat and barley
malt extract concentrates was not significantly different. However, the extract concentrate of oat malt had 44% less color
compared to that of barley malt at equal concentrations showing its potential as a natural food antioxidant. 相似文献
9.
Zhen-Yu Chen Ya-Lun Su Yu-Rong Bi Suk Ying Tsang Yu Huang 《Journal of the American Oil Chemists' Society》2000,77(1):73-78
There is an increasing interest in natural antioxidants present in traditional Chinese herbal medicines. The present study
examined the antioxidant activity of heane, acetone, and methanol extracts, as well as baicalein purified from the dry roots
of Scutellaria baicalensis Georgi (common name: Huangqin), in heated canola oil. Oxygen consumption and decreases in linoleic acid linolenic acid content
were monitored in canola oil held at 90–93°C. Among the three extracts, the acetone extract was most effective against oxidation
of canola oil, followed by the methanol extract of the dry roots. The antioxidant activity of these three extracts correlated
well with their content of baicalein, which provided strong protection to canola oil from oxidation. The antioxidant activity
of Huangqin acetone extract was dose-dependent. The acetone extract at 100 ppm or above was even more effective than butylated
hydroxytoluene at 200 ppm in protecting canola oil from oxidation. The present results suggest that the acetone extract of
these roots should be further explored as a potential source of natural antioxidants for use in the processed foods. 相似文献
10.
Synergistic effects of rosemary, sage, and citric acid on fatty acid retention of palm olein during deep-fat frying 总被引:1,自引:0,他引:1
Irwandi Jaswir Yaakob B. Che Man David D. Kitts 《Journal of the American Oil Chemists' Society》2000,77(5):527-533
A study to optimize the use of oleoresin rosemary extract, sage extract, and citric acid in refined, bleached, and deodorized
(RBD) palm olein during deep-fat frying of potato chips was performed using response surface methodology. Results showed that
the natural antioxidants used in this study retarded oil deterioration, as evidenced by retention of fatty acid profiles.
The linoleic to palmitic (C18∶2/C16∶0) ratio was chosen as the parameter for optimizing the use of natural antioxidants in
RBD palm olein during deep-fat frying. Linoleic (R
2=0.946) and palmitic (R
2=0.825) acids were found to be the most important dependent variables, giving highest R
2 values to various antioxidant treatments after 25 h of frying. All three antioxidants had independent significant (P<0.05) effects on the C18∶2/C16∶0 ratio. In fact, significant effects on the C18∶2/C16∶0 ratio of RBD palm olein were also
given by a second-order form. A combination of 0.076% oleoresin rosemary extract, 0.066% sage extract, and 0.037% citric acid
produced the optimal retention of the essential fatty acid C18∶2. In addition, a synergistic effect among these antioxidants
on the fatty acid ratio of RBD palm olein was found. 相似文献
11.
Susana Nieto Argelia Garrido Julio Sanhueza Luis A. Loyola Glauco Morales Federico Leighton Alfonso Valenzuela 《Journal of the American Oil Chemists' Society》1993,70(8):773-778
The antioxidant activities against fish oil oxidation of six commercially available flavonoids and of five flavonoids purified
from two Chilean native plants were compared to those ofdl-α-tocopherol and of two synthetic antioxidants, butylated hydroxytoluene and butylated hydroxyanisole. Among the commercial
flavonoids, catechin, morin and quercetin showed a higher activity when fish oil oxidation (either spontaneous or Fe2+-induced) was assessed from the formation of peroxides or thiobarbituric acid-reactive substances. Among the native flavonoids,
the 5,3′,4′-trihydroxy-7-methoxy flavanone (designated as Pt-2) showed the highest antioxidant activity. Mixtures of quercetin
or of Pt-2 withdl-α-tocopherol produced better inhibitory effects when compared to that of each substance assayed by itself. Also, when Pt-2
and quercetin were assayed in combination (0.3 g/kg oil and 0.7 g/kg oil, respectively), a synergistic antioxidant effect
was observed. Results indicate that several flavonoids could be used as natural antioxidants as a means to replace those synthetic
antioxidants, the use of which has been questioned. 相似文献
12.
N. K. Andrikopoulos H. Brueschweiler H. Felber Ch. Taeschler 《Journal of the American Oil Chemists' Society》1991,68(6):359-364
Triglycerides, together with nine synthetic phenolic antioxidants most commonly used to prevent oxidation of edible oils and
fats, as well as the natural antioxidants tocopherols andα-tocopherol acetate, were separated by high performance liquid chromatography by means of a reversed phase C18-column and gradient elution with water/acetonitrile/methanol/isopropanol. Besides dilution of the oil with isopropanol/hexane,
no further example preparation was required. UV detection was applied. The synthetic antioxidants propyldodecylgallate, octyldodecylgallate,
dodecylgallate, 3-tert-butyl-4-hydroxyanisol,tert-butylhydroquinone, 3,5-di-terf-butyl-4-hydroxytoluene, 2,6-di-tert-butyl-4-hydroxymethyl-phenol, 2,4,5-trihydroxybutyrophenone and nordihydro-quaiaretic acid, as well asα- andδ-tocopherol andα-tocopherol acetate were base-line separated;β- andγ-tocopherol, however, eluted together. The triglycerides, detected at λ = 215 nm, were separated according to then-partition
number. The absorption at λ = 215 nm revealed saturated and unsaturated triglycerides. The absorption at λ = 280 nm indicated
triglycerides with conjugated unsaturation, relating information about refining and heat treatment of the oil. Oxidized unsaturated
triglycerides showed absorption at γ = 230 nm. Triglycerides of ricinoleic acid, a hydroxymonoun-saturated acid, gave identical
UV spectra. The simultaneous detection of antioxidants and triglycerides may be used to study inhibition effects by antioxidants
in oils.
To whom correspondence should be addressed. 相似文献
13.
The Antioxidant Functions of Tocopherol and Tocotrienol Homologues in Oils,Fats, and Food Systems 总被引:2,自引:0,他引:2
Christine M. Seppanen Qinghua Song A. Saari Csallany 《Journal of the American Oil Chemists' Society》2010,87(5):469-481
This review paper is focused on the relative antioxidant activities of tocopherols and tocotrienols in oils and fats and certain
food systems. α-Tocopherol generally showed better antioxidant activity than γ-tocopherol in fats and oils, but at higher
concentrations γ-tocopherol was found to be a more active antioxidant. The results of studies on the optimum antioxidant concentrations
of tocopherols in oils and fats indicated that the optimal level for α-tocopherol is usually lower than other tocopherols,
meaning less α-tocopherol is needed for maximum antioxidant protection. There are comparatively very few studies related to
the antioxidant activities of tocotrienols in oils and fats. It has been stated that generally γ-tocotrienol has higher antioxidant
effect than α-tocotrienol, and tocotrienols may be better antioxidants than their corresponding tocopherols in certain oils
and fats systems. Studies on the antioxidant activity of various tocopherols in food systems are varied and cannot be uniformly
evaluated because experiments have generally focused on different foods and used various methods for the detection of antioxidant
activities. Depending on the food system, in certain cases tocopherols were better antioxidants than synthetic antioxidants
such as butylhydroxy toluene (BHT) or butylhydroxy anisole (BHA). However, in certain other food systems the synthetic antioxidants
were more effective to increase the shelf life and the stability of foods than those containing tocopherols. 相似文献
14.
The existence of a female-produced sex pheromone in the yellowheaded spruce sawfly,Pikonema alaskensis (Rohwer) (Hymenoptera: Tenthredinidae) was demonstrated by field and greenhouse bioassays. Virgin females, their empty cocoons (with which they were confined during handling procedures), and the hexane extract of these cocoons were attractive in the field. The only Florisil fraction of this extract consistently attractive by itself was that eluted with hexane, but three, more polar fractions (eluted with 5%, 25%, and 50% ether in hexane) each synergized the hexane fraction, increasing bioassay responses 10–30 times. Fractions derived directly from virgin females yielded comparable results. The greenhouse data corroborated the field data, except that the 5% ether-hexane fraction, while very synergistic in the field, was consistently inactive in the greenhouse. 相似文献
15.
Tocopherols can exhibit opposite effects in aqueous media on linoleic acid autoxidation rate. The effect which was observed
depended on tocopherol concentration and on the tocopherol itself. At 0.05 mole of tocopherol per mole of linoleic acid, α-tocopherol
was prooxidant while in similar conditions, δ-tocopherol was anti-oxidant as well as γ-tocopherol. However, this latter one
exhibited a slight antioxidant activity. When tocopherol concentration decreased (twice as weak), α-tocopherol still exhibited
the same pro-oxidant activity, while the antioxidant effect of γ and δ tocopherols was increased. The study of tocopherol
stability by HPLC has shown that tocopherol oxidation increased in order δ < γ < α. There was a relationship between the ability
for a tocopherol to be easily oxidized by air and its prooxidant activity. Tocopherol oxidation would enhance the formation
of a perhydroxyl radical ([·OOH] or one of this type [O20=, ·OH]) which was responsible for the prooxidant effect. 相似文献
16.
J. C. Evans D. R. Kodali P. B. Addis 《Journal of the American Oil Chemists' Society》2002,79(1):47-51
The optimal concentration for tocopherols to inhibit soybean oil oxidation was determined for individual tocopherols (α-,
γ-, and δ-tocopherol) and for the natural soybean oil tocopherol mixture (tocopherol ratio of 1∶13∶5 for α-, γ-, and δ-tocopherol,
respectively). The concentration of the individual tocopherols influenced oil oxidation rates, and the optimal concentrations
were unique for each tocopherol. For example, the optimal concentrations for α-tocopherol and γ-tocopherol were ∼100 and ∼300
ppm, respectively, whereas δ-tocopherol did not exhibit a distinct concentration optimum at the levels studied (P<0.05). The optimal concentration for the natural tocopherol mixture ranged between 340 and 660 ppm tocopherols (P<0.05). The antioxidant activity of the tocopherols diminished when the tocopherol levels exceeded their optimal concentrations.
Above their optimal concentrations, the individual tocopherols and the tocopherol mixture exhibited prooxidation behavior
that was more pronounced with increasing temperature from 40 to 60°C (P<0.05). A comparison of the antioxidant activity of the individual tocopherols at their optimal concentrations revealed that
α-tocopherol (∼100 ppm) was 3–5 times more potent than γ-tocopherol (∼300 ppm) and 16–32 times more potent than δ-tocopherol
(∼1900 ppm). 相似文献
17.
Electrophile tocopheryl quinones from the phenolic antioxidants γ-tocopherol and δ-tocopherol form Michael adducts with the
thiol nucleophile glutathione. These tocopheryl quinones are involved in cytotoxicity, apoptosis, and mutagenesis, and their
biologic properties are associated with the depletion of intracellular thiols. We now show that both proteins and tissues
treated with the electrophile γ-tecopheryl quinone (γ-TQ) form thiol adducts. The monoglutathion-S-yl derivative of γ-TQ was subjected to thermochemolysis with the strong methylating base tetramethylammonium hydroxide. GC/MS
showed four signature peaks and a fragmentation pattern characteristic of the thiol adduct. Similarly, pure monoglutathion-S-yl and diglutathion-S-yl derivatives of δ-TQ were subjected to thermochemolysis, and GC/MS showed characteristic fragmentation patterns for thiol
adducts. The four signature peaks were identified when pure proteins with accessible thiol groups (hemoglobin and histone),
FBS, and tissue culture medium and cell preparations were treated with γ-TQ. Signature peaks in both complete medium and washed
cells showed the presence of both soluble and insoluble thiol adducts. The effective or free arylating electrophile concentration
in complete medium should always be evaluated in tissue culture studies. γ-TQ is a mutagen but not a genotoxin; therefore,
the histone adduct may be a previously unrecognized histone modification involved in chromatin dynamics leading to mutagenesis. 相似文献
18.
Chia seeds as a source of natural lipid antioxidants 总被引:8,自引:0,他引:8
M. Silvia Taga E. E. Miller D. E. Pratt 《Journal of the American Oil Chemists' Society》1984,61(5):928-931
Chia (Salvia sp) seeds were investigated as a source of natural lipid antioxidants. Methanolic and aqueous extracts of defatted chia seeds
possessed potent antioxidant activity. Analysis of 2 batches of chia-seed oils demonstrated marked difference in the fatty
acid composition of the oils. In both batches, the oils had high concentrations of polyunsaturated fatty acids. The major
antioxidant activity in the nonhydrolyzed extract was caused by flavonol glycosides, chlorogenic acid (7.1 × 10−4 mol/kg of seed) and caffeic acid (6.6 × 10−3 m/kg). Major antioxidants of the hydrolyzed extracts were flavonol aglycones/kaempferol (1.1 × 10−3 m/kg), quercetin (2.0 × 10−4 m/kg) and myricetin (3.1 × 10−3 m/kg); and caffeic acid (1.35 × 10−2 m/kg). Two methods were used to measure antioxidant activities. Both were based on measuring bleaching ofβ-carotene in the coupled oxidation ofβ-carotene and linoleic acid in the presence of added antioxidants. 相似文献
19.
Rudolf H. Scheffrahn Ruei-Ching Hsu Nan-Yao Su Jacob B. Huffman Sharon L. Midland James J. Sims 《Journal of chemical ecology》1988,14(3):765-776
The heartwood of bald cypress,Taxodium distichum (L.) Rich., resisted feeding attack by the Formosan subterranean termite,Coptotermes formosanus Shiraki. Hexane-extracted heartwood, however, was consumed at > 12 times the amount of sound heartwood eaten. A bioassay usingT. distichum sapwood as a feeding substrate was employed to assess the antitermitic activity of successive hexane, acetone, and methanol extracts of heartwood shavings and isolates derived from the active hexane extract. Two fractions, eluted from the crude hexane extract by liquid chromatography, significantly reduced termite feeding compared to the parent extract, while a third fraction was less active than the original hexane extract. Each fraction contained one major component. All three components were structurally related diterpenes. The two most active heartwood constituents were identified by GC-MS and NMR as ferruginol and manool, while the third and least active, but most prevalent, compound in heartwood was identified as nezukol. Results of bioassays suggest that these allelochemicals act principally as feeding deterrents with accompanying termite mortality due to starvation. 相似文献
20.
Fatihanim Mohd Nor Suhaila Mohamed Nor Aini Idris Razali Ismail 《Journal of the American Oil Chemists' Society》2009,86(2):141-147
The antioxidative properties of Curcuma longa (turmeric) leaf extract were evaluated in refined, bleached and deodorized (RBD) palm olein using accelerated oxidation and
deep frying studies at 180 °C for up to 40 h. The extract was capable of retarding oil oxidation and deterioration significantly
(P < 0.05) at 0.2% concentration, better than 0.02% BHT for the Oxidative Stability Index (OSI) in an accelerated oxidation
study and also the peroxide value in deep frying studies. In sensory evaluation, the French fries were acceptable and were
not significantly different (P < 0.05) from one another for color, oiliness and crispiness throughout the 40-h frying study. Curcuma longa leaf extract, which had a polyphenol content of 116.3 ± 0.2 mg/g, possessed heat-stable antioxidant properties and may be
a good natural alternative to existing synthetic antioxidants in the food industry. 相似文献