共查询到20条相似文献,搜索用时 15 毫秒
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M. V. Nazarov A. I. Laskin I. R. Ilyasov A. A. Lamberov A. Sh. Bikmurzin V. M. Shatilov 《Catalysis in Industry》2013,5(2):143-147
Pilot tests of SGA-2M promoted Pd/Al2O3 catalyst in the selective hydrogenation of acetylene are performed on an industrial ethane-ethylene fraction in a system of two serially arranged adiabatic flow reactors. The optimum process conditions under which the conversion of acetylene reaches 100% at a selectivity of 68.2% with respect to ethylene are determined: system pressure, 21 atm; hydrocarbon feedstock hourly space velocity (HSV), 1500 h?1, carbon monoxide concentration, 7 ppm; H2: C2H2 molar ratio at the first and second hydrogenation stages, 1.0: 1.0 and 1.4: 1.0; inlet temperature of the first and second reactors, 40 and 55°C, respectively. The interregeneration service life of the SGA-2M catalyst under optimum conditions is estimated at 12 months. SGA-2M catalysts can be recommended for purifying ethane-ethylene fractions containing up to 2 vol % of acetylene. 相似文献
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新型仲醇脱氢制酮催化剂的研究 总被引:2,自引:1,他引:1
本文介绍一种新型醇脱氢催化剂。该催化剂以氧化铜为主要活性组分,用氧化铝为粘接剂成型,加入氧化钾改性,用于异丙醇、仲丁醇或环己醇的脱氢,具有催化剂强度高、脱氢活性及产物选择性好、抗积碳失活、性能稳定等优点。 相似文献
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A. I. Laskin I. R. Ilyasov M. V. Nazarov A. A. Lamberov I. F. Nazmieva V. M. Shatilov A. Sh. Bikmurzin 《Catalysis in Industry》2013,5(3):232-237
KGS-3 catalyst is tested in the selective hydrogenation of methylacetylene and propadiene contained in industrial pyrolysis propane-propylene fractions at a pilot installation in two successive adiabatic flow reactors equipped with immobile catalyst beds. The optimum technological conditions for hydrogenation are determined, ensuring a residual content of acetylene and diene admixtures of no more than 5 ppm: pressure in the system, 18 atm; hydrocarbon feedstock hourly space velocity (HSV), 2100 h?1; molar ratio of hydrogen to the sum of methylacetylene and propadiene in the first and second reactors, respectively, 1.1 : 1.0 and 1.6 : 1.0; temperatures, 50 and 55 °C. Under these conditions, KGS-3 catalyst ensures 100% conversion of methylacetylene and propadiene with a propylene selectivity of 76.7%. The expected service life of this catalyst is about 14 months. The catalyst can be used for the purification of hydrocarbon fractions containing up to 5 wt % of acetylene and diene admixtures. 相似文献
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研究了以Na Al O2-Al2(SO4)3为原料制备直链烷烃脱氢催化剂载体的工艺,考察p H交替变化对直链烷烃脱氢催化剂载体孔结构的影响,采用XRD、TEM、DTG、DTA、氮吸附-脱附仪和压汞仪等对载体的晶相、粒子形态、结晶水含量、比表面积及孔分布进行表征。结果表明,p H交替变化使拟薄水铝石晶粒尺寸增加,结晶水含量降低,制备出孔容≥1.2 m L·g-1、比表面积≤150 m2·g-1和堆积密度≤0.32 g·m L-1的具有双孔分布的直链烷烃脱氢催化剂载体γ型氧化铝。酸性条件下,大量细小无定形氧化铝迅速溶解,有利于更多细小拟薄水铝石颗粒形成;碱性条件下,这些迅速溶解的无定型氧化铝附着在拟薄水铝石颗粒上,使拟薄水铝石一次粒子逐步长大,结晶度增加。 相似文献
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A. A. Lamberov S. R. Egorova Kh. Kh. Gilmanov A. N. Kataev G. E. Bekmukhamedov 《Catalysis in Industry》2017,9(1):17-22
Results from pilot tests of microspherical aluminochromium KDI-M catalyst mixed with IM-2201 in a large-scale unit (Nizhnekamskneftekhim) for iso-butane dehydrogenation are discussed. Compared to KDI catalyst, its modified analogue KDI-M is more active and selective; the optimized grain-size composition and mechanical strength ensures higher yields of iso-butylene and longer nonstop operation (up to 400 days) of the reactor unit. 相似文献
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E. Kh. Karimov L. Z. Kas’yanova E. M. Movsumzade R. R. Daminev O. Kh. Karimov M. R. Yalalov 《Theoretical Foundations of Chemical Engineering》2016,50(1):92-96
A theoretical model of the industrial method of the compensation of thermal energy consumed on the endothermic dehydrogenation on a fixed catalyst layer has been described. The combination of endothermic dehydrogenation with interlayer (intermediate) oxidation of produced hydrogen has been considered based on the example of the dehydrogenation of isoamylenes to isoprene. The calculated results are compared with laboratory tests. 相似文献
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研究了以亚磷酸二异辛酯为配体的氯化稀土配合物(简称Nd)与三异丁基铝(简称Al)组成的二元稀土催化体系催化苯乙烯与异戊二烯的共聚行为,考察了Al与Nd的摩尔比、聚合温度、单体配比等对共聚行为及共聚物组成和链结构的影响。结果表明,该催化体系能够实现异戊二烯的均聚,但不能催化苯乙烯均聚,而催化二者共聚的活性取决于单体配比且低于异戊二烯的均聚。所得产物为无规共聚物,其中异戊二烯链节以顺式-1,4-结构为主(95%~96%),含少量3,4-结构,几乎不含反式-1,4-结构;共聚物中的结合苯乙烯量随Al与Nd的摩尔比、聚合温度及单体配比中苯乙烯量的增加而增大。苯乙烯以孤立单元形式嵌入在异戊二烯链节之间,因此所得共聚物为"准"无规共聚物;共聚物的重均分子量最高可达19.3×105,分子量分布随着共聚物中结合苯乙烯量的增加而变宽,甚至出现双峰分布。 相似文献
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采用XRD、TPR、BET和N2O滴定法对仲丁醇脱氢催化剂YTDH-1G与对比剂A进行表征,并采用常压固定床反应器考察两种催化剂的仲丁醇脱氢活性和甲乙酮选择性。结果表明,催化剂中添加Zr O2后可以提高催化剂活性组分的分散度,改善催化剂的还原性能。催化剂YTDH-1G表明的Cu比表面积和分散度明显大于对比剂A。在考察的实验范围,催化剂YTDH-1G的催化活性和产物选择性优于对比剂A,对工艺条件的适应性较强,可在较宽的温度和空速范围使用,具有较好的工业应用前景。 相似文献
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采用自主技术制备的三元高效Cr系丁烷脱氢L-1催化剂,以炼油厂碳四为原料,在固定床微反评价装置对其丁烷催化脱氢反应的催化性能进行评价。结果显示,反应温度590℃,空速750 h^(-1)条件下,反应在1 h内,丁烷转化率60%~69%、选择性90%~95%、丁烯收率为59%~66%。催化剂再生后试验结果表明,再生催化剂,反应在1 h内,丁烷转化率约65%,丁烯选择性约95%,丁烯收率保持高于60%,连续再生性能表明催化剂具有良好的稳定性,催化剂的性能较优。 相似文献
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《Applied Catalysis A: General》2001,205(1-2):109-115
Test data for the catalytic oxidation of ethylene glycol (EG) into glyoxal obtained with a laboratory continuous flow tubular reactor are reported. A ferric molybdate catalyst modified with triammonium phosphate was used. Reaction parameters (temperature, contact time) affect the product distribution. The yield of glyoxal for the Fe-Mo-P catalyst was 43.3% at 88.9% conversion, whereas the corresponding values for the Fe-Mo (unmodified catalyst) were 20.5 and 97.2%. The addition of phosphorus formed a new Fe2M0P12 phase which restrains the reaction pathway towards carbon oxides. 相似文献
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开发成功了具有高活性、高选择性、低水同比、高侧压强及抗水性能好等特点的三叶型355催化剂。工业试生产和工业生产结果表明,在反应温度为620℃,流体空速为1.0h,水油比为2.0的条件下,可使乙苯转化率大于80%,苯乙烯收率大于76%,苯乙烯选择性大于95%。 相似文献
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改性五氯化钼催化剂合成3,4-聚异戊二烯 总被引:2,自引:0,他引:2
利用正辛醇改性五氯化钼催化体系催化异戊二烯聚合得到了3,4-聚异戊二烯。研究了n(Mo)/n(Ip)、n(Al)/n(Mo)、间甲酚用量等聚合条件对聚合活性和聚合产物相对分子质量的影响。利用红外对聚合物进行了表征,并且通过红外谱图研究了聚合温度对聚合物3,4-结构含量的影响。结果表明,改性五氯化钼催化得到的聚合产物与铁系低分子聚合物具有相近的3,4-结构含量(质量分数为55%~61%),并且3,4-结构含量随着聚合温度升高先升高后降低。对聚合物进行特性粘数和GPC的表征表明,合成的3,4-聚异戊二烯特性粘数为1.2~2,多分散系数小于3。 相似文献
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乙烯是重要的有机化工原料,随着乙烯需求量的不断增加以及石油资源的日益匮乏,乙烷脱氢已成为乙烯增产的重要途径。乙烷脱氢制乙烯受到越来越多的关注,乙烷脱氢催化剂逐步改善。本文首先介绍了近年来国内外乙烷脱氢制乙烯的研究现状,然后从催化剂制备方法、性能以及应用等方面对乙烷催化脱氢催化剂和乙烷氧化脱氢催化剂的研究进行了总结,并对其进行了系统分类。催化脱氢是低碳烷烃转化为烯烃的有效途径,烯烃选择性高,受到热力学平衡限制,能耗较高。氧化脱氢由于氧化剂的引入打破了热力学平衡限制,能够有效抑制焦炭的生成,减少能量消耗。然而,深度氧化反应难于控制,乙烯的选择性低。因此,选取合适的催化脱氢催化剂,尽可能提高乙烷单程转化率、降低能耗是乙烷脱氢的关键。 相似文献