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1.
为了解决现有冷拼底、面合一阴极电泳涂料乳液分层,丙烯酸酯树脂水解胶化的问题,采用接枝反应,合成了丙烯酸酯-环氧底、面合一的阴极电泳涂料。按国家标准检测这一合成涂料的多种性能;研究了甲基丙烯酸甘油脂(GMA)含量对树脂水溶性和胶体颗粒粒径分布的影响,不同中和度对水溶性的影响,混合体系助溶剂对底、面合一阴极电泳涂料的影响。结果表明:通过多胺将带环氧基团的丙烯酸树脂和带环氧基团的环氧树脂进行链接,能解决乳液分层和丙烯酸酯树脂水解胶化的问题;本阴极电泳涂料实现了底、面合一,兼具良好的耐蚀性和耐候性。 相似文献
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利用插层聚合合成了环氧丙烯酸酯/蒙脱土复合光固化树脂,并采用紫外光固化制备了环氧丙烯酸酯/蒙脱土纳米复合材料.用XRD、DSC对光固化过程中蒙脱土的插层和剥离行为进行了研究,并用FT-IR研究了蒙脱土对环氧-丙烯酸酯体系光固化速率的影响。力学试验证实,光固化后的环氧丙烯酸酯/蒙脱土纳米复合材料冲击与弯曲强度比原本体树脂分别提高了54%和10%. 相似文献
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用液态含环氧基丙烯酸酯低聚物改性环氧树脂 总被引:3,自引:0,他引:3
采用溶液聚合法合成了以丙烯酸丁酯为主链的液态含环氧基丙烯酸酯低聚物,并用其对环氧树脂进行增韧改性.讨论甲基丙烯酸环氧丙酯以及低聚物用量对改性环氧树脂力学性能的影响,并研究了改性环氧树脂的微观形态和耐热性能.结果表明:当低聚物用量为10%(质量分数),丙烯酸丁酯和甲基丙烯酸环氧丙酯的质量比为80∶20时,改性环氧树脂的拉伸强度和冲击强度比纯环氧树脂提高6.7%和219.1%,同时体系的耐热性能基本不下降;改性环氧树脂呈两相结构,随低聚物用量增加橡胶粒子粒径尺寸增大;且Tg先升高后降低. 相似文献
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利用原子转移自由基聚合(ATRP)法合成了丙烯酸丁酯-甲基丙烯酸六氟丁酯嵌段共聚物(PBA-b-PHFBMA),并以核磁共振谱和凝胶渗透色谱对共聚物进行了表征。将制备的含氟嵌段共聚物应用于丙烯酸酯涂料树脂,对其性能进行了研究。结果表明,在丙烯酸酯树脂中加入含氟嵌段共聚物后,树脂的表面性能及耐老化性能有了明显的提高。含氟嵌段共聚物的加入量在10%以上时,丙烯酸酯树脂的表面接触角可从73°提高到90°以上;经紫外光加速老化1700h后,树脂的保光率达90%以上。且含氟嵌段共聚物的加入并不影响丙烯酸酯树脂的其它漆膜性能。 相似文献
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缩聚物/加聚物复合胶乳的制备科学Ⅱ.核壳结构聚氨酯-丙烯酸酯复合乳液的合成与表征 总被引:7,自引:0,他引:7
用合成的含羧基端羟基聚氨酯树脂,通过强外力乳化可形成稳定的水性聚氨酯乳液,与苯乙烯和丙烯酸丁酯等单体共聚,合成具有核壳结构的聚氨酯-丙烯酸酯接枝乳液,通过接枝乳液和共混乳液的性能差别对比,及DSC,FT-IR,粒径分析及力学性能测试分析表明,在聚氨酯-丙烯酸酯接枝乳液中,聚氨酯与丙烯酸酯发生部分交联形成稳定的核-壳结构,文中还对聚氨酯-丙烯酸酯接枝乳液的交联机理进行了研究。 相似文献
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以苯乙烯、丙烯酸丁酯、N-羟甲基丙烯酰胺、丙烯酰胺为原料,用聚乙烯醇(PVA)作为胶体保护剂,采用无皂乳液聚合方式,制备苯乙烯-丙烯酸酯树脂乳液;以HDI三聚体和聚乙二醇单甲醚(MPEG500)为主要原料制备水可分散聚异氰酸酯.苯乙烯-丙烯酸酯树脂乳液与亲水改性聚异氰酸酯复合,得到水分散多异氰酸酯交联改性的苯乙烯-丙烯... 相似文献
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A deposition process on a conducting surface, in which water acted as the dispersed phase and a mixture of poly(methyl methacrylate) and chloroform as the continuous phase, was applied to prepare poly(methyl methacrylate) films. The influence of relative humidity during the film preparation on the surface morphology was investigated by field emission scanning microscopy. High-humidity preparation conditions lead to porous poly(methyl methacrylate) films. These films were then used as templates to perform the selective deposition into the pores of single-walled carbon nanotubes by an electrophoretic method. The attractive properties of carbon nanotubes combined with the versatile properties of poly(methyl methacrylate) open up new opportunities for these nanocomposites to achieve novel architectures in nanodevices and?microdevices. 相似文献
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Jinpeng Mo Naiku Xu Changfa Xiao Xutong Han Yong Liu 《Journal of Materials Science》2014,49(14):4816-4824
Poly(butyl methacrylate) was synthesized via suspension polymerization. Poly(butyl methacrylate) solution was prepared by dissolving it in N, N-dimethylformamide. With benzoyl peroxide as an initiator, hydroxyethyl methacrylate as a physical crosslinker and divinylbenzene as a chemical crosslinker, the spinning solution containing a semi-interpenetrating polymer network structure was produced by initiating the polymerization of physical and chemical crosslinkers in the poly(butyl methacrylate) solution. Then, the spinning solution was electrospun into fibrous mat. Finally, contact angle of the surface of the fibrous mat for water or light petroleum was analyzed by a contact angle tester. Thermal property, crystallization behavior, and morphology of the fibrous mat were also characterized through thermogravimetric analyzer, X-ray diffractometer, and field emission scanning electron microscopy. In addition, its oil-absorptive property and capacity to separate oil from water were investigated. 相似文献
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氟代聚丙烯酸酯的合成与膜形貌及疏水性能 总被引:1,自引:0,他引:1
在过氧化苯甲酰作用下,利用甲基丙烯酸十二氟庚酯与丙烯酸丁酯、甲基丙烯酸二甲氨乙酯、丙烯酸羟丙酯的溶液聚合反应合成了一种氟代聚丙烯酸酯(FBDH),用场发射扫描电镜(FESEM)、原子力显微镜(AFM)等对其结构、成膜性及膜形貌进行了研究.结果表明,在观察尺寸为50 nm、扫描范围为5 μm×5μm条件下,观察所合成的F... 相似文献
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Homogenous, transparent, greenish blue Cu(II) containing PMMA co-polymer disks were prepared through the radical polymerization
of the Cu(II) methacrylate, MMA and HMA using AIBN as an initiator. The dependence of the absorbance and transmittance spectra
with the Cu(II) methacrylate concentration was investigated in the visible range (420–750 nm). From the transmittance measurements
the refractive index and extinction coefficient spectral dependence were calculated by application of an inversion approach.
To further characterize this co-polymer a thermogram was performed. The overall behavior of this material suggests its possible
use as a standard solution for Spectroscopy Equipment Calibration and as a selective optical filter. 相似文献
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The optical-functional poly(methyl methacrylate)-block-Tb complex diblock copolymer brushes grafted from hollow sphere surface via atom transfer radical polymerization were investigated in this work. A sufficient amount of azo initiator was introduced onto hollow sphere surface firstly. Then the monomer methyl methacrylate was polymerized via surface-initiated reverse atom transfer radical polymerization using azo group modified hollow sphere as initiator. Following, the poly(methyl methacrylate) modified hollow sphere was used as maroinitiator for surface-initiated atom transfer radical polymerization of Tb complex. The samples were characterized by Fourier transform infrared spectroscopy, hydrogen nuclear magnetic resonance, gel permeation chromatographer and transmission electron microscopy, respectively. The results indicated that the poly(methyl methacrylate) had grafted from hollow sphere surface and the average diameter of hollow core was about 1 μm. The optical properties of the poly(methyl methacrylate)-block-Tb copolymer modified hollow sphere were also reported. 相似文献
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M. P. Patel M. Braden S. Downes 《Journal of materials science. Materials in medicine》1994,5(6-7):338-339
A heterocyclic methacrylate polymer system, developed originally as a low shrinkage polymer system, has been investigated as a drug release polymer and as a biomaterial for encouraging bone or cartilage regeneration. The system is based on poly (ethyl methacrylate) polymer powder mixed with tetrahydrofurfuryl methacrylate monomer and polymerized at room temperature (PEM/THFM). Promising results have been obtained with this biomaterial, and hence its water uptake properties were investigated in detall, in order to throw some light on the release processes that are involved in vivo and in vitro. Water soluble large molecule analogues were incorporated into the system; these additives increased the water uptake of the system. Isobornyl methacrylate was used as a diluent for the monomer to further reduce the water uptake of the system. In all cases the uptake kinetics did not obey simple diffusion theory, the process being very prolonged and complex. 相似文献
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Hullathy Subban Ganapathy Ha Soo Hwang Min Young Lee Yeon Tae Jeong Yeong-Soon Gal Kwon Taek Lim 《Journal of Materials Science》2008,43(7):2300-2306
Different types of stabilizers architectures based on copolymers composed of hydrophilic components and CO2-philic fluorinated acrylate groups were investigated for the free radical dispersion polymerization of 2-hydroxyethyl methacrylate
(HEMA) at 65 °C in supercritical carbon dioxide (scCO2). Four categories of random and block copolymeric stabilizers consisting of 1H,1H,2H,2H-perfluorooctyl methacrylate (FOMA), oligo(ethylene glycol) methacrylate (OEGMA), dimethyl amino ethyl methacrylate (DMAEMA),
and ethylene oxide (EO) were selected as stabilizers for HEMA. The effect of the stabilizer architecture on the polymerization
results was investigated in terms of stabilizer concentration, the nature of the hydrophilic anchor groups, and block versus
random copolymers. White free-flowing poly(HEMA) powders in high yield were obtained with all stabilizers. While the monomer
conversion was independent, the morphology of particles was found to be considerably affected by the nature of the stabilizers. 相似文献
19.
Spherical calcium carbonate vaterite crystals were synthesized and the effect of them on stabilization of suspension polymerization of methyl methacrylate was investigated. Suspension polymerization of methyl methacrylate could be stabilized with calcium carbonate vaterite crystals and sodium dodecylbenzene sulfonate of the concentrations from 25 to 100 ppm. Poly(methyl methacrylate) beads coated with spherical calcium carbonate vaterite crystals were prepared. With an increase in the concentration of sodium dodecylbenzene sulfonate from 25 to 100 ppm, the amount of calcium carbonate vaterite crystals adhered on the surface of poly methyl methacrylate bead increased and the mean diameters of the polymer beads decreased. 相似文献
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采用超声协助悬浮聚合法以Ni(Ⅱ)离子为模板制备了氨基功能化纳米Fe_3O_4-离子印迹聚(甲基丙烯酸甲酯(MMA)-3-(2-氨基乙基胺)-2-甲基丙烯酸羟丙酯(HPMA)-二乙烯基苯(DVB))磁性复合材料(Fe_3O_4@ion imprinted poly(MMA-HPMA-DVB),Fe_3O_4@IIP(MMA-HPMA-DVB))。通过EA、XRD、FTIR、TEM、VSM等手段对Fe_3O_4@IIP(MMA-HPMA-DVB)的组成、结构、形貌、磁性等进行了表征,并研究了其吸附水中Ni(Ⅱ)的性能。结果表明:合成的Fe_3O_4@IIP(MMA-HPMA-DVB)平均粒径为100nm,饱和磁化强度为43.8emu/g;共聚单体甲基丙烯酸甲酯(MMA)的羰基通过氢键与Fe_3O_4表面羟基结合,有利于Fe_3O_4@IIP(MMA-HPMA-DVB)的核-壳结构的形成与稳定;Fe_3O_4@IIP(MMA-HPMA-DVB)对Ni(Ⅱ)的吸附受溶液pH值影响较小;等温吸附线符合Langmuir模型,饱和吸附量(q_(m,c)=500 mg/g,q_(m,e)=478 mg/g)高于非离子印迹材料(Fe_3O_4@none-ion imprinted poly(MMA-HPMA-DVB),Fe_3O_4@NIP(MMA-HPMA-DVB)),q_(m,c)=90.9mg/g,q_(m,e)=83.8mg/g)。吸附过程可在5min内达到平衡,符合准二级动力学模型。Fe_3O_4@IIP(MMA-HPMA-DVB)能高选择性地有效吸附水中Ni(Ⅱ),对Ni(Ⅱ)的印迹因子(α)为1.9,对几种常见共存离子的选择性因子(β)7.7,是潜在的高选择性吸附和回收Ni(Ⅱ)的功能材料。 相似文献