AZ31镁合金变形与强韧化研究

研究了AZ31镁合金组织的演变过程和力学性能,结果表明:通过挤压变形及动态再结晶,可以显著细化合金晶粒,其尺寸可由约100μm减少到5μm;二次变形可以提高镁合金的抗拉强度。可见塑性变形是同时实现镁合金构件成形和强韧化的有效途径。     

油气润滑对AZ80镁合金铸坯表面质量和组织的影响

本文以自主设计的镁合金油气润滑铸造装置制备了直径154mm的AZ80镁合金铸坯,系统研究油气润滑对AZ80镁合金铸坯表面质量和凝固组织的影响,并对其机理进行了探讨。采用结果表明:采用油气润滑铸造时,氩气和润滑油在石墨环内表面形成了一层油气混合膜,改变了熔体和结晶器的接触方式和热交换状态,从而制备出高品质的AZ80镁合金铸坯。随着气体压力的增加,铸坯表面粗大的偏析瘤和皮下偏析层得到抑制,凝固组织得到了明显细化。当气体压力增加到0.4 MPa时,铸坯皮下偏析层厚度从1252μm降至628μm,铸坯R/2、心部晶粒尺寸和二次枝晶间距显著减小。随着凝固组织的细化,Al、Zn和Mn元素的宏观偏析得到了改善。     

AZ61镁合金挤锻复合成形组织与力学性能

采用铸坯挤压制备具有最终试样二维几何特征的AZ61镁合金预成形坯材,经过一次纵向模压制备了近终成形的拉伸试样,对试样进行了组织和拉伸性能检测。实验结果表明:在挤锻复合成形工艺过程中,材料组织经过变形与再结晶,晶粒尺寸从铸态的121μm细化为挤压态的8~15μm,锻压后进一步细化到2~5μm。经历了挤锻复合成形后,材料的室温抗拉强度、屈服强度、伸长率和硬度分别达到315.2MPa2、27.4MPa和20.5%,比铸态分别提高了42.4%、76%和71%;拉伸失效断口也从铸态的准解理断裂过渡为模压后以韧性断裂为主的特征。     

AZ31镁合金变形与强韧化研究

研究了AZ31镁合金组织的演变过程和力学性能,结果表明：通过挤压变形及动态再结晶,可以显著细化合金晶粒,其尺寸可由约100μm减少到5 μm;二次变形可以提高镁合金的抗拉强度.可见塑性变形是同时实现镁合金构件成形和强韧化的有效途径.     

变形参数对AZ31镁合金组织性能的影响

对AZ31镁合金铸棒在不同变形温度和变形程度下的再结晶行为进行了观察，并测量了各变形条件下的拉伸性能。结果表明，挤压变形及动态再结晶，可以显著的细化铸造AZ31合金的晶粒(由铸态的约100μm减少到约5μm)。随变形温度的升高，AZ31合金的抗拉强度下降，到一定温度后，趋于稳定。     

温变形对AZ31镁合金组织的影响

为了有效细化镁合金的晶粒 ,以提高其力学性能 ,通过对铸态AZ31进行等温压缩实验 ,并采用现代微观分析手段 ,研究变形参数对AZ31镁合金组织的影响。结果表明 :2 10℃变形可以显著地细化铸造AZ31合金的晶粒 ,其尺寸可由铸态的约 10 0 μm减少到 5 μm左右 ;同时证明温变形能明显提高镁合金的抗拉强度。     

预变形对锥台剪切变形镁合金组织与性能的影响

利用WDW3100电子万能试验机对铸态AZ31镁合金试样进行预压缩量0%和3%处理,并采用新型的锥台强剪切挤压变形方法将AZ31镁合金铸棒挤压成板材。通过金相显微镜、拉伸性能测试及断口扫描分析研究预压缩变形对锥台剪切变形镁合金的微观组织与力学性能的影响。结果表明:3%预变形处理对铸态镁合金植入大量的孪晶组织,为后续动态再结晶提供充足的形核点,且镁合金在变形过程中受到剧烈强剪切变形,使得挤压成形板发生了充分的动态再结晶,晶粒细化至4.5μm。预压缩3%镁合金经锥台剪切变形后,伸长率高达23.6%,屈服强度和抗拉强度高达280.4 MPa和225.3 MPa。与预压缩0%的挤压镁合金相比,断裂伸长率提高幅度高达91%,屈服强度和抗拉强度略有降低。挤压温度对镁合金组织性能有重要的影响,预压缩3%的镁合金经290℃锥台剪切变形后,获得均匀细小的晶粒组织,具有优良的综合力学性能。     

变质处理对MB2镁合金挤压变形前后组织与性能的影响

通过加入稀土及其他合金元素对MB2镁合金铸锭进行复合变质处理,随后在330℃下进行挤压成形,得到强度高、塑性变形性能优良的镁合金型材,并采用金相显微镜、图像分析系统及MTS-810材料测试系统等分析了变质元素对镁合金组织性能的影响.结果表明,变质处理可以使β-Mg17Al12相由原来的连续网状分布变为分散的粒状分布,并使铸态MB2镁合金的晶粒由原来的100～200μm细化到约15～35μm;挤压变形后变质的MB2镁合金晶粒进一步细化到5～10μm左右,合金的抗拉强度和伸长率分别由原来的247MPa和13%提高到312MPa和22%.     

等通道转角挤压Mg-6Zn-2Si合金组织及性能研究

采用等通道转角挤压变形工艺,在573 K下以Bc路径对Mg-6Zn-2Si镁合金进行4道次和8道次挤压细化合金晶粒来提高其力学性能,同时对合金室温拉伸断口进行分析,并阐述了等通道挤压改善实验合金微观组织和力学性能的机理。结果表明:经4道次挤压后晶粒由310μm细化到13μm,Mg_2Si相最大约60μm,细化为细小颗粒状约7μm,α-Mg基体与Mg Zn相均得到显著细化,屈服强度提高180%,伸长率提高140%,抗拉强度提高75%。与4道次相比,经8道次挤压后微观组织无明显变化,屈服强度有所提高,抗拉强度和伸长率变化不大。合金的室温拉伸断口由铸态合金的脆性断口过渡为韧性断口,并且韧窝加深,分布更均匀。     

连续变断面循环挤压对AZ31镁合金组织与力学性能的影响

采用连续变断面循环挤压技术及新型复合模具对AZ31镁合金进行挤压变形,分析织构演变和循环次数对AZ31镁合金的组织和力学性能的影响。结果表明:AZ31镁合金经过3次循环的变形,上下端平均晶粒尺寸由母材的29.4μm细化到6.1μm,显微硬度提高了18.4 HV,水平方向和轴向的抗拉强度均得到显著提高,轴向的伸长率得提高15.1%,并且宏观织构显示晶粒取向发生了定向转变。     

Effects of grain refinement on mechanical properties and microstructures of AZ31 alloy

Cerium was added in AZ31 alloy with the contents of 0.4%,0.8%and 1.2%respectively to produce experimental alloys. The grain refinement of Ce in the as-cast and rolled AZ31 alloy were studied by using Polyvar-MET optical microscope with a VSM2000 quantitative analysis system,KYKY2000 SEM and Tecnai G~2 20 TEM.And the mechanical properties of AZ31+Ce alloy were tested on a CSS-44100 testing system with computerized data acquisition.The results show that the cerium has a good grain refinement effect on the ...     

异步轧制AZ31镁合金板材室温冲压性能研究

文章主要对异步轧制AZ31镁合金板材室温冲压性能进行了研究,以探讨提高镁合金板材冲压性能的途径。结果表明,异步轧制有利于板材的晶粒细化,其晶粒尺寸约为7.6μm,明显小于普通轧制板材的12.5μm;而由于异步轧制过程中剪切变形的作用,异步轧制使板材的(0002)基面晶粒取向减弱;与普通轧制相比,异步轧制板材的应变硬化能力增加,屈服强度降低,制耳参数减小,但塑性应变比也降低,这可归因于异步轧制所导致的晶粒细化和晶粒取向的改变。     

热拉伸变形对AZ31B镁合金薄板显微组织的影响

利用单向热拉伸实验和金相显微镜研究了AZ31B镁合金薄板热变形过程及其动态再结晶组织变化规律。结果表明,在变形温度为160℃、应变速率为1×10-3s-1时,拉伸变形后得到的显微组织是混合组织。260℃~280℃时形成均匀分布的细小等轴晶粒,其晶粒平均尺寸为5μm左右。在变形温度为320℃~400℃、变形速率为1×10-3s-1~3.3×10-4s-1时,晶粒平均尺寸为10μm~20μm,沿晶界出现氧化现象,且氧化"黑色"斑点发生聚集。     

连续变断面循环挤压AZ31镁合金的组织与性能

采用连续变断面循环挤压法分别对变形镁合金AZ31铸锭和商业AZ31进行不同循环道次的变形,考察其组织、性能变化.结果表明:AZ31镁合金铸锭经过一个循环的挤压,晶粒明显细化.商业AZ31铝合金材料分别进行2、4、6、8次循环变形,随着变形量增大,平均晶粒尺寸不断减小,组织趋于均匀;真应变为16时,平均晶粒尺寸为5.5 μm;随着循环次数增加,伸长率不断增加,与原始态的相比可提高2倍左右,但强度没有明显变化.     

Microstructure and temperature monitoring during the hot rolling of AZ31

This study details the microstructural evolution during hot rolling of AZ31 alloy sheet using a pilot-scale rolling mill. The aim is to understand the deformation mechanisms leading to grain refinement under industrial processing conditions and to design and optimize the hot rolling schedule for AZ31 in order to produce sheet with a fine and homogeneous microstructure. The study examined three different hot rolling temperatures, 350, 400, and 450°C, and two rolling speeds, 20 and 50 rpm. A total thickness reduction of 67% was obtained using multiple passes, with reductions of either 15% or 30% per pass. It was found that the microstructure of the AZ31 alloy was sensitive to the rolling temperature, the reduction (i.e., strain) per pass and the rolling speed (i.e., strain rate). The results show that the large cast grain structure is broken down by segmentation of the cast grain through localized deformation in twin bands, where dynamic recrystallization occurs in these bands as well as at the grain boundaries (necklacing).     

Structure and mechanical properties of AZ31 magnesium alloy billets by different hot-top semi-continuous casting technology

AZ31 alloy billets of 200 mm in diameter were produced by three different processes of conventional direct chill(DC) casting,low-frequency electromagnetic casting(LFEC) and low-frequency electromagnetic vibration casting(LFEVC),respectively.The effect of LFEC and LFEVC on the microstructures,macrosegregation and mechanical properties of AZ31 alloy billets was investigated.In conventional DC casting,the AZ31 alloy billets exhibited coarse grains(about 370 μm) and severe segregation of Al and Zn.In the presence of a solo low-frequency alternating magnetic field or a low-frequency electromagnetic vibration field applied during DC casting of φ200 mm AZ31 billets,grains in the AZ31 alloy billets were effectively refined(about 210 μm) and the macrosegregation of Al and Zn in the billets was greatly decreased.Furthermore,the tensile strength,fracture elongation and hardness of the as-cast AZ31 alloy billets were improved by the processes of LFEC and LFEVC relative to that cast by the process of conventional DC casting.     

铸造Mg-4Al-2Sn-Y-Nd镁合金的热压缩行为与加工图

利用热压缩实验研究一种新型的具有优异室温塑性的Mg-4Al-2Sn-Y-Nd镁合金的高温流变行为,变形温度为200～400℃,应变速率为1.5×10-3～7.5 s^-1。结果表明：合金的应变速率敏感因子（m）在不同变形温度下均明显小于AZ31镁合金的m值,因此该合金适合在高应变速率下进行热加工。在真应力-应变曲线基础上,建立Mg-4Al-2Sn-Y-Nd 镁合金高温变形的本构方程,并计算得到合金的应力指数为10.33,表明合金在高温下主要的变形机制为位错攀移机制。同时,利用加工图技术确定合金的最佳高温变形加工窗口,即变形温度在350～400℃之间,应变速率在0.01～0.03 s^-1。     

AZ31镁合金差温热轧过程的晶粒细化

实验研究了经不同道次差温热轧AZ31镁合金的金相组织,结合对轧制过程,尤其是轧件温度场的数值模拟结果,分析了AZ31镁合金差温热轧过程晶粒细化机制与主要影响因素,获得了通过轧制过程动态再结晶,使轧材晶粒尺寸随轧制道次增加,而持续细化的工艺参数,并制备出平均晶粒尺寸为5μm左右的细晶AZ31镁合金板材。     

Anticorrosive magnesium phosphate coating on AZ31 magnesium alloy

A novel anticorrosive film with a thickness of approximately 50 μm was successfully coated on an AZ31 magnesium alloy by chemical and low-heat treatments (50 °C). The film was a single-phase system of newberyite (MgHPO₄•3H₂O) having an orthorhombic crystal structure. The corrosion current density of the newberyite film coated on the AZ31 magnesium alloy decreased by more than two orders of magnitude as compared to that of the AZ31 magnesium alloy. The static water contact angle of the newberyite film was less than 10°. The average value of the scratch critical load for the newberyite coating was estimated to be approximately 15 mN.