大光斑高均匀度发散式太阳模拟器设计

为了实现大光斑直径高均匀度太阳辐照模拟,设计了大光斑发散式太阳模拟器。根据太阳光谱分布特性选取短弧氙灯作为光源,建立光源功率计算模型;基于成像倍率和氙弧峰值点离焦量之间的关系,优化设计聚光系统和光学积分器,提高太阳模拟器的辐照均匀度;同时,结合短弧氙灯的光谱特性,建立光谱匹配模型,设计光学滤光片在不同波长的透过率。实验结果表明:设计的发散式太阳模拟器辐照面积为2 m,当工作距离为6、8、10 m时,辐照不均匀度分别优于3.33%、3.51%和4.3%,且光谱与AM1.5太阳光谱A级标准相匹配。     

Effect of alkali treatment on the spectral response of silicon-nanowire solar cells

The effect of alkali treatment of Si nanowires (SiNWs) on the spectral response of solar cells was investigated using monochromatic incident photon-to-electron conversion efficiency spectroscopy. SiNWs were prepared on a substrate by metal-assisted etching and were then treated with NaOH/isopropanol. The results show that alkali treatment of SiNWs for 30 s obviously improved the cell conversion efficiency. This was attributed to enhancement of the red light response and a decrease in surface reflectivity from 6% to ~2%. However, SiNW alkali treatment led to poor blue light response, which is a major limiting factor for efficient SiNW solar cells. To improve the photovoltaic properties of SiNW cells, a near-complete response over the whole solar spectrum is essential.     

Study of the high throughput flexographic process for silicon solar cell metallisation

A commercially available silver paste was modified to match the flexographic process requirements. Rotational and oscillatory rheological tests were carried out to assess the printability and spreading behaviour of the resulting inks. Then, a multifactorial approach was used on a laboratory‐scale printing press to adapt the flexographic process for the front side metallisation of Cz‐Si solar cells, especially for the seed layer deposit of two layer contacts. To quickly identify the significant process parameters, a fractional design of experiment based on a screening approach at two levels was performed. Afterwards, two full factorial designs of experiments were implemented. While the first one allows a better understanding of the effect of the main factors and interactions, the second allows a fine tuning and a confirmation of the first results. Additionally, this methodology allows corroborating the influence of the ink rheological properties on the printing results. Following the process study and optimisation, a seed layer with an average width of 25 µm was printed at a high 0.3 m/s throughput. Additional results suggest that the line width and the throughput can be further improved, which underlines the potential of flexography for photovoltaic applications. Finally, the light‐induced process was used to thicken the seed layer after a standard firing‐through step, leading to an encouraging 17.9% efficiency on Cz‐Si solar cells. Copyright © 2015 John Wiley & Sons, Ltd.     

Photovoltaic performance of Organic Photovoltaics for indoor energy harvester

Wireless sensor network becomes widespread into home and offices to keep them comfort and save the energy. The battery-less wireless sensor nodes need the high performance indoor solar cells for stable and sustainable operation. Organic Photovoltaics (OPV) has great indoor photovoltaic performance because ultra-thin organic layer has strong absorption against the UV–visible spectrum that is good spectral matching with indoor lightings. In this study, OPV module has 8 cells in series and same size as the conventional amorphous silicon solar cells (a-Si) for indoor light harvesting. OPV and a-Si are measured their photovoltaic performance under the fluorescent light and demonstrated for energy harvester of wireless sensor network. The output power of OPV and a-Si is 43.4 μW cm⁻² and 28.5 μW cm⁻² at fluorescent light 1000lux respectively. The data transmission rate of the wireless sensor node driven by OPV is 30–40% improved under the dim light condition compared to a-Si.     

Amplitude Stabilization of a Microwave Signal Source

Recent developments in the microwave field have provided new tools for use in regulating the output amplitude of a microwave signal source. An amplitude or power stabilizer has been constructed at the National Bureau of Standards Boulder Laboratories, using the recently developed self-balancing dc bolometer bridge and a commercially available, electrically controlled, ferrite attenuator which achieves power stabilities of a few parts in 10/sup 4/ per hour. Use of a high directivity directional coupler permits stabilization of the forward traveling component of the signal, thus providing the equivalent of a matched, stable generator. In practice, a broad-band source match of vswr less than 1.05 is achieved, and this figure may be further improved, at a given frequency, by suitable tuning. In addition, the device has applications as a precision broad-band attenuator, since known changes in power level may be achieved by switching certain of the associated dc components.     

InGaP//GaAs//c‐Si 3‐junction solar cells employing spectrum‐splitting system

In this work, we practically demonstrated spectrum‐splitting approach for advances in efficiency of photovoltaic cells. Firstly, a‐Si:H//c‐Si 2‐junction configuration was designed, which exhibited 24.4% efficiency with the spectrum splitting at 620 nm. Then, we improved the top cell property by employing InGaP cells instead of the a‐Si:H, resulting in an achievement of efficiency about 28.8%. In addition, we constructed 3‐junction spectrum‐splitting system with two optical splitters, and GaAs solar cells as middle cell. This InGaP//GaAs//c‐Si architecture was found to deliver 30.9% conversion efficiency. Our splitting system includes convex lenses for light concentration about 10 suns, which provided concentrated efficiency exceeding 33.0%. These results suggest that our demonstration of 3‐junction spectrum‐splitting approach can be a promising candidate for highly efficient photovoltaic technologies. Copyright © 2016 John Wiley & Sons, Ltd.     

Improving the fill factor of N2200-based all polymer solar cells by introducing EPPDI as a solid additive

A cheap and commercially available small molecule (namely EPPDI) is introduced to the active layer of N2200-based all polymer solar cells as a solid additive. EPPDI at the optimal ratio can improve the D-A nano-scale morphology and reduce trap density of the active layer by filling morphological spaces. As a result, the photovoltaic performance of the resulting devices based on PF2:N2200 are increased from 6.28% to 7.03% with significantly enhanced fill factor. This work demonstrates a facile approach for improving the performance of all polymer solar cells.     

Reciprocity between electroluminescence and quantum efficiency used for the characterization of silicon solar cells

Spectrally and spatially resolved electroluminescence emission of crystalline silicon solar cells is interpreted in terms of two electro‐optical reciprocity relations. The first relation links the photovoltaic quantum efficiency to the electroluminescence spectrum. Both methods contain information on recombination and the optical pathlength of the incident light, simultaneously. From the electroluminescence spectrum, we derive the pathlength enhancement factor of textured and untextured crystalline silicon solar cells. Further, we use local quantum efficiency measurements to quantitatively explain light induced current as well as panchromatic electroluminescence images. A second reciprocity relation connects open circuit voltage of a solar cell with the light emitting diode quantum efficiency of the same device. For a given quality of light trapping and a given open circuit voltage, we predict the attainable LED quantum efficiency and verify our results experimentally. Copyright © 2009 John Wiley & Sons, Ltd.     

A Low Temperature Route toward Hierarchically Structured Titania Films for Thin Hybrid Solar Cells

The requirement of high‐temperature calcination for titanium dioxide in (solid‐state) dye‐sensitized solar cells (DSSCs) implies challenges with respect to reduced energy consumption and the potential for flexible photovoltaic devices. Moreover, the use of dye molecules increases production costs and leads to problems related with dye bleaching. Therefore, fabrication of dye‐free hybrid solar cells at low temperature is a promising alternative for current DSSC technology. In this work the authors fabricate hierarchically structured titania thin films by combining a polystyrene‐block‐polyethylene oxide template assisted sol–gel synthesis with nano‐imprint lithography at low temperatures. The achieved films are filled with poly(3‐hexylthiophene) to form the active layer of hybrid solar cells. The surface morphology is probed via scanning electron microscopy and atomic force microscopy, and the bulk film morphology is examined with grazing incidence X‐ray scattering. Good light absorption by the active layer is proven by UV–vis spectroscopy. An enhancement in light absorption is observed and ascribed to light scattering in mesoporous titania films with imprinted superstructures. Accordingly a better photovoltaic performance is found for nano‐imprinted solar cells at various angles of light incidence.     

Towards realization of a large‐area light‐emitting diode‐based solar simulator

Solar simulators based on light‐emitting diodes (LEDs) have shown great promise as alternative light sources for indoor testing of photovoltaic cells with certain characteristics that make them superior to the traditional solar simulators. However, large‐area uniform illumination more suitable for larger cells and module measurements still remain a challenge today. In this paper, we discuss the development and fabrication of a scalable large‐area LED‐based solar simulator that consists of multiple tapered light guides. We demonstrate fine intermixing of many LED light rays and power delivery in the form of a synthesized AM 1.5 spectrum over an area of 25 cm × 50 cm with better than 10% spatial nonuniformity. We present the spectral output, the spatial uniformity, and the temporal stability of the simulator in both the constant current mode and the pulsed‐mode LED operation, and compare our data with the International Electrotechnical Commission standards on solar simulators for class rating. Although the light intensity with our current design and settings falls short of the standard solar AM 1.5 intensity, this design and further improvements open up the possibility of achieving large‐area, high‐power indoor solar simulation with various desired spectra. Copyright © 2011 John Wiley & Sons, Ltd.     

Response of photovoltaic cells to pulsed laser illumination

Future space missions may use laser power beaming systems with a free electron laser (FEL) to transmit light to a photovoltaic array receiver. To investigate the efficiency of solar cells with pulsed laser light, several types of GaAs, Si, CuInSe₂, and GaSb cells were tested with the simulated pulse format of the induction and radio frequency (RF) FEL. The induction pulse format was simulated with an 800-watt average power copper vapor laser and the RF format with a frequency-doubled mode-locked Nd:YAG laser. Averaged current versus bias voltage measurements for each cell were taken at various optical power levels and the efficiency measured at the maximum power point. Experimental results show that the conversion efficiency for the cells tested is highly dependent on cell minority carrier lifetime, the width and frequency of the pulses, load impedance, and the average incident power. Three main effects were found to decrease the efficiency of solar cells exposed to simulated FEL illumination: cell series resistance, LC “ringing”, and output inductance. Improvements in efficiency were achieved by modifying the frequency response of the cell to match the spectral energy content of the laser pulse with external passive components     

二氧化钛纳米管染料敏化电池的制备和性能

利用两步阳极氧化法,在钛片上成功制备了高质量的二氧化钛纳米管阵列薄膜。利用场发射扫描电子显微镜,对二氧化钛纳米管阵列薄膜进行了形貌表征。之后,将不同厚度的薄膜组装成背光式染料敏化太阳电池,并测量了它们的光电转化性能。发现,随着薄膜层厚度的增加太阳电池的转化效率也逐渐提高。当薄膜厚度为15μm时,电池的转化效率达到3.04%。     

基于F-P滤波器实现宽谱光源的甲烷差分检测

构建了一种利用F-P滤波器实现甲烷气体差分检测的系统。该系统采用宽谱LED作光源，选用甲烷气体在6060．6cm^-1附近的梳状吸收谱作为探测对象，通过F-P滤波器选择与待测甲烷吸收谱匹配的探测光，对F-P的精细度和腔长进行选择，推导得出了甲烷气体浓度的计算方法，实现了系统的差分吸收检测。该系统进一步提高了气体测量的灵敏度和稳定性。     

An ice machine adapted into an autonomous photovoltaic system without batteries using a variable‐speed drive

The adaptation of a commercially available ice machine for autonomous photovoltaic operation without batteries is presented. In this adaptation a 1040 W_p photovoltaic array directly feeds a variable‐speed drive and a 24 V_dc source. The drive runs an induction motor coupled by belt‐and‐pulley to an open reciprocating compressor, while the dc source supplies a solenoid valve and the control electronics. Motor speed and refrigerant evaporation pressure are set aiming at continuously matching system power demand to photovoltaic power availability. The resulting system is a simple integration of robust, standard, readily available parts. It produces 27 kg of ice in a clear‐sky day and has ice production costs around US$0.30/kg. Although a few machine features might be specific to Brazil, its technical and economical guidelines are applicable elsewhere. Copyright © 2010 John Wiley & Sons, Ltd.     

Large-scale,adhesive-free and omnidirectional 3D nanocone anti-reflection films for high performance photovoltaics

An effective and low-cost front-side anti-reflection(AR) technique has long been sought to enhance the performance of highly efficient photovoltaic devices due to its capability of maximizing the light absorption in photovoltaic devices. In order to achieve high throughput fabrication of nanostructured flexible and anti-reflection films, large-scale, nano-engineered wafer molds were fabricated in this work. Additionally, to gain in-depth understanding of the optical and electrical performance enhancement with AR films on polycrystalline Si solar cells, both theoretical and experimental studies were performed. Intriguingly,the nanocone structures demonstrated an efficient light trapping effect which reduced the surface reflection of a solar cell by17.7% and therefore enhanced the overall electric output power of photovoltaic devices by 6% at normal light incidence. Notably, the output power improvement is even more significant at a larger light incident angle which is practically meaningful for daily operation of solar panels. The application of the developed AR films is not only limited to crystalline Si solar cells explored here, but also compatible with any types of photovoltaic technology for performance enhancement.     

基于菲涅尔透镜与抛物面反射镜光伏系统设计

在菲涅尔透镜具有聚光特性的基础上,提出一种同时利用抛物面反射镜焦点发出的光线可反射成平行光的特性混合式聚光光伏系统。利用Zemax软件,对整个聚光光伏系统进行仿真并得到初步仿真数据,参考仿真结果对聚光系统进行改进优化,提高了光能吸收率和有效几何聚光比,同时降低了系统实现成本提高了实用性。     

Uncertainty of the spectral mismatch correction factor in STC measurements on photovoltaic devices

Valuation of photovoltaic devices depends strongly on the measured power output of the device. This quantity is usually determined under artificial sunlight in production line measurement systems or industrial or research test labs. A practical calibration chain is realized essentially with measurements at solar simulators. The measurement conditions are defined in the IEC 60904 series of standards. An important part of the standard testing conditions is the definition of a specific spectral distribution of the sunlight (AM1.5 global). The inevitable deviations of the spectrum of artificial light sources from the standard spectrum have to be taken into account by a spectral mismatch factor. The uncertainty of this crucial correction is spectrally dependent, in most cases unknown and complex and inconvenient to evaluate. In this article a randomizing method is proposed which allows one to calculate the uncertainty of the mismatch factor from the uncertainties of the input parameters determined with high spectral resolution. Based on a range of different spectral responses of solar cells on the one hand and variations of the solar simulator spectral distribution on the other, we are able to generalize the results to a broad set of measurement configurations. A sensitivity analysis reveals the crucial wavelength regions and thus allows the systematic optimization of simulator spectra and selection of reference cells. Copyright © 2010 John Wiley & Sons, Ltd.     

Design and realization of transparent solar modules based on luminescent solar concentrators integrating nanostructured photonic crystals

Herein, we present a prototype of a photovoltaic module that combines a luminescent solar concentrator integrating one‐dimensional photonic crystals and in‐plane CuInGaSe₂ (CIGS) solar cells. Highly uniform and wide‐area nanostructured multilayers with photonic crystal properties were deposited by a cost‐efficient and scalable liquid processing amenable to large‐scale fabrication. Their role is to both maximize light absorption in the targeted spectral range, determined by the fluorophore employed, and minimize losses caused by emission at angles within the escape cone of the planar concentrator. From a structural perspective, the porous nature of the layers facilitates the integration with the thermoplastic polymers typically used to encapsulate and seal these modules. Judicious design of the module geometry, as well as of the optical properties of the dielectric mirrors employed, allows optimizing light guiding and hence photovoltaic performance while preserving a great deal of transparency. Optimized in‐plane designs like the one herein proposed are of relevance for building integrated photovoltaics, as ease of fabrication, long‐term stability and improved performance are simultaneously achieved. © 2015 The Authors. Progress in Photovoltaics: Research and Applications published by John Wiley & Sons Ltd.     

Pre-Buried ETL with Bottom-Up Strategy Toward Flexible Perovskite Solar Cells with Efficiency Over 23%

With rapid development of photovoltaic technology, flexible perovskite solar cells (f-PSCs) have attracted much attention for their light weight, high flexibility and portability. However, the power conversion efficiency (PCE) achieved so far is not yet comparable to that of rigid devices. This is mainly due to the great challenge of depositing homogeneous and high-quality perovskite films on flexible substrate. In this study, the pre-buried 3-aminopropionic acid hydroiodide (3AAH) additives into the electron transport layer (ETL) and modified the ETL/perovskite (PVK) interface by a bottom-up strategy. 3AAH treatment induced a templated perovskite grain growth and improved the quality of the ETL. By this, the residual stresses generated in PVK during the annealing-cooling process are released and converted into micro-compressive stresses. As a result, the defect density of f-PSCs with pre-buried 3AAH is reduced and the photovoltaic performance is greatly improved, reaching an exceptional PCE of 23.36%. This strategy provides a new idea to bridge the gap between flexible and rigid devices.     

激光加工中光参量的测试技术及设备

由于激光加工机本身所追求的质量要求促使激光参量测试技术要与之相适应。本文着重介绍与激光加工相关的激光功率、能量及光束质量等参量测量与监测技术及一些商品化的检测仪器。