Process windows for low-temperature Au wire bonding

The process windows are presented for low-temperature Au wire bonding on Au/Ni/Cu bond pads of varying Au-layer thicknesses metallized on an organic FR-4 printed circuit board (PCB). Three different plating techniques were used to deposit the Au layers: electrolytic plating, immersion plating, and immersion plating followed by electrolytic plating. Wide ranges of wire bond force, bond power, and bond-pad temperature were used to identify the combination of these processing parameters that can produce good wire bonds, allowing the construction of process windows. The criterion for successful bonds is no peel off for all 20 wires tested. The wire pull strengths and wire deformation ratios are measured to evaluate the bond quality after a successful wire bond. Elemental and surface characterization techniques were used to evaluate the bond-pad surfaces and are correlated to wire bondability and wire pull strength. Based on the process windows along with the pull strength data, the bond-pad metallization and bonding conditions can be further optimized for improved wire bondability and product yields. The wire bondability of the electrolytic bond pad increased with Au-layer thickness. The bond pad with an Au-layer thickness of 0.7 μm displayed the highest bondability for all bonding conditions used. The bondability of immersion bond pads was comparable to electrolytic bond pads with a similar Au thickness. Although a high temperature was beneficial to wire bondability with a wide process window, it did not improve the bond quality as measured by wire pull strength.     

Influence of surface contamination on metal/metal bond contact quality

The influence of surface cleanliness of Au/Ni coated multichip materials (MCMs), Ag plated Cu lead frames, and Al bond pads on semiconductor chips on the strength of Au wire bond contacts has been investigated. A clean surface is important for good adhesion in any kind of attachment process. Investigations by means of x-ray photoelectron spectroscopy have been performed on the bond substrates to determine the chemical composition, the nature as well as the thickness of the contamination layer. The influence of contamination on bond contact quality has been examined by pull force measurements, which is an established test method in semiconductor packaging industry for evaluating the quality of wire bonds. The results clearly show that a strong correlation between the degree of contamination of the substrate and pull strength values exists. Furthermore, a contamination thickness limiting value of 4 nm for Au and Ag substrates was determined, indicating good wire bond contact quality. The effect of plasma cleaning on wire bondability of metallic and organic (MCMs) substrates has been examined by pull force measurements. These results confirm the correlation between surface contamination and the strength of wire bond contacts for Au/Ni coated MCMs and Ag plated Cu lead frames. Atomic force microscopy measurements have been performed to determine the roughness of bond surfaces, demonstrating the importance of nanoscale characterization with regard to the bonding behavior of the substrates. Finally, bonding substrates used in integrated circuit packaging are discussed with regard to their Au wire bonding behavior. The Au wire bonding process first results in a cleaning effect of the substrate to be joined and secondly enables the change of bonding energy into frictional heat giving rise to an enhanced interdiffusion at the interface.     

Effect of plasma treatment of Au-Ni-Cu bond pads on process windows of Au wire bonding

The wire bondability of Au-Ni-Cu bond pads with different Au plating schemes, including electrolytic and immersion plates, are evaluated after plasma treatment. The plasma cleaning conditions, such as cleaning power and time, are optimized based on the process window and wire pull strength measurements for different bond pad temperatures. Difference in the efficiency of plasma treatment in improving the wire bondability for different Au plates is identified. The plasma-cleaned bond pads are exposed to air to evaluate the recontamination process and the corresponding degradation of wire pull strength. The changes in bond pad surface characteristics, such as surface free energy and polar functionality, with exposure time are correlated to the wire pull strength, which in turn provides practical information about the shelf life of wire bonding after plasma cleaning.     

Thermosonic bonding of gold wire onto silver bonding layer on the bond pads of chips with copper interconnects

A copper pad oxidizes easily at elevated temperatures during thermosonic wire bonding for chips with copper interconnects. The bondability and bonding strength of a gold wire onto a bare copper pad are seriously degraded by the formation of a copper oxide film. A new bonding approach is proposed to overcome this intrinsic drawback of the copper pad. A silver layer is deposited as a bonding layer on the surface of copper pads. Both the ball-shear force and the wire-pull force of a gold wire bonded onto copper pads with silver bonding layers far exceed the minimum values stated in the JEDEC standard and MIL specifications. The silver bonding layer improves bonding between the gold ball and copper pads. The reliability of gold ball bonds on a bond pad is verified in a high-temperature storage (HTS) test. The bonding strength increases with the storage time and far exceeds that required by the relevant industrial codes. The superior bondability and high strength after the HTS test were interpreted with reference to the results of electron probe x-ray microanalyzer (EPMA) analysis. This use of a silver bonding layer may make the fabrication of copper chips simpler than by other protective schemes.     

Thermosonic bonding of gold wire onto a copper pad with titanium thin-film deposition

A novel thermosonic (TS) bonding process for gold wire bonded onto chips with copper interconnects was successfully developed by depositing a thin, titanium passivation layer on a copper pad. The copper pad oxidizes easily at elevated temperature during TS wire bonding. The bondability and bonding strength of the Au ball onto copper pads are significantly deteriorated if a copper-oxide film exists. To overcome this intrinsic drawback of the copper pad, a titanium thin film was deposited onto the copper pad to improve the bondability and bonding strength. The thickness of the titanium passivation layer is crucial to bondability and bonding strength. An appropriate, titanium film thickness of 3.7 nm is proposed in this work. One hundred percent bondability and high bonding strength was achieved. A thicker titanium film results in poor bond-ability and lower bonding strength, because the thicker titanium film cannot be removed by an appropriate range of ultrasonic power during TS bonding. The protective mechanism of the titanium passivation layer was interpreted by the results of field-emission Auger electron spectroscopy (FEAES) and electron spectroscopy for chemical analysis (ESCA). Titanium dioxide (TiO₂), formed during the die-saw and die-mount processes, plays an important role in preventing the copper pad from oxidizing. Reliability of the high-temperature storage (HTS) test for a gold ball bonded on the copper pad with a 3.7-nm titanium passivation layer was verified. The bonding strength did not degrade after prolonged storage at elevated temperature. This novel process could be applied to chips with copper interconnect packaging in the TS wire-bonding process.     

Effects of metallization characteristics on gold wire bondability of organic printed circuit boards

Organic printed circuit boards (PCBs) with Au/Ni plates on bond pads are widely used in chip-on-board (COB), ball grid array (BGA), and chip-scale packages. These packages are interconnected using thermosonic gold wire bonding. The wire bond yield relies on the bondability of the Ni/Au pads. Several metallization parameters, including elemental composition, thickness, hardness, roughness, and surface contamination, affect the success of the solid state joining process. In this study, various characterization and mechanical testing techniques are employed to evaluate these parameters for different metallization schemes with varying Ni and Au layer thicknesses. The pull force of Au wires is measured as a function of plasma treatment applied before wire bonding to clean the bond pads. Close correlations are established between metallization characteristics and wire bond quality.     

An investigation on the plasma treatment of integrated circuit bond pads

Integrated circuit (IC) bond pads play an important role in the wire bond reliability of the microelectronic devices. Being the device’s only electrical connection to the package and electronic systems, it is mandatory that the bond pads are free of contaminants and possess excellent bonding characteristics. Contaminants such as oxides and organic residues impair the bondability to a considerable extent and are very resistant to conventional wet cleaning methods. In this paper, we report the effects of an Ar/H₂ plasma treatment on the surface chemistry and morphology of IC bond pads. Surface and sub-surface chemical analyses have been conducted using Auger electron spectroscopy (AES), X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM). Results reveal that the oxygen level of the bond pad surface has decreased significantly after the plasma treatment. Although the treatment has successfully removed the surface crystallites on the bond pads on prolong etching; however, the aggressive process has also damaged the passivation layers that surround the pad areas.     

A concept to relate wire bonding parameters to bondability and ball bond reliability

The effects of wire bonding parameters on bondability and ball bond reliability have been investigated. Bondability is characterized by ball shear stress (ball shear force per unit area) and ball bond reliability by median time to failure during in-situ ball bond degradation measurements. By introducing the concept of a reduced bonding parameter (RBP), a combination of all bonding parameters, we are able to relate the bonding parameters to bondability and ball bond reliability. With the appropriate RBP, ball shear force, ball shear stress, andball bond reliability appear to be well-behaved functions of the RBP fora wide range of settings. This provides us with simple analytical tool for optimizing bonding parameter windows.     

Increasing bondability and bonding strength of gold stud bumps onto copper pads with a deposited titanium barrier layer

A flip-chip assembly is an attractive scheme for use in high performance and miniaturized microelectronics packaging. Wafer bumping is essential before chips can be flip-bonded to a substrate. Wafer bumping can be used for mechanical-single point stud bump bonding (SBB), and is based on conventional thermosonic wire bonding. This work proposes depositing a titanium barrier layer between the copper film and the silver bonding layer to achieve perfect bondability and sufficiently strong thermosonic bonding between a stud bump and the copper pad.A titanium layer was deposited on the copper pads to prevent copper atoms from out-diffusing during thermosonic stud bump bonding. A silver film was then deposited on the surface of the titanium film as a bonding layer to increase the bondability and bonding strength for stud bumps onto copper pads. The integration of the silver bonding layer with a diffusion barrier layer of titanium on the copper pads yielded 100% bondability between the stud bump and pads. The strength of bonding between the gold bumps on the copper pads significantly exceeds the minimum average values in JEDEC specifications. The diffusion barrier layer of titanium effectively prevents copper atoms from out-diffusing to the silver bonding layer surface during thermosonic bonding, which fact can be interpreted with reference to the experimental results of energy dispersive spectrometry (EDS) and analyses of Auger depth profiles. This diffusion barrier layer of titanium efficiently provides perfect bondability and sufficiently strong bonding between a stud bump and copper pads with a silver bonding layer.     

Study of Temperature Parameter in Au–Ag Wire Bonding

The effect of the temperature on bondability and bonding process for wire bonding are investigated. Bondability is characterized by shear bonding strength and bonding process is represented by input and output power of ultrasonic transducer. A laser Doppler vibrometer and Labview software were used to record the velocity, voltage and current of transducer at different temperature settings. A K-type thermocouple sensor was used to measure the bonding temperature. Experimental results show that unsuccessful bonding happens at low temperature, and over bonding appears if the temperature is too high. Only when the temperature is at appropriate settings, can a stable and satisfied bondability be attained. The reason for this experimental observation is analyzed. By using a high resolution transmission electron microscope, the atom diffusion depth of Au-Ag bonding interface was measured and the result is about 200 nm. By using joint time-frequency analysis, the instantaneous characteristics of bonding process were observed completely and clearly. It is found that input and output ultrasonic power vs. time-frequency in a bonding process, including resonance frequency, harmonic components and amplitude of ultrasonic energy, vary along with the change of temperature settings.      

Enhancement of the Bondability and Die-Shear Force of Chip–Flex Substrate Assemblies by Depositing a Nickel Layer on the Flex Substrate

A nickel layer and a silver bonding layer have been deposited on copper electrodes over flex substrates to improve the bondability and die-shear force performance of chip?Cflex substrate assemblies when using the thermosonic flip-chip bonding process. For bonding temperature of 200°C, the maximum die-shear force was achieved by combining parameter values of 20.66?W ultrasonic power, 625?gf bonding force, and 0.5?s bonding time. The improved bondability and die-shear force could be attributed to better transfer of ultrasonic power across the bonding interface during thermosonic flip-chip bonding, owing to the high rigidity of the copper electrodes provided by the nickel layer. Experimental results also indicated that high bonding load is necessary at elevated ultrasonic power range to provide firm contact between the bumps and electrodes to enable smooth ultrasonic power transfer across the bonding interface. Moreover, prolonged bonding time caused cracks between the bumps and flex substrate. Close examination of the fracture morphologies after die-shear testing and after ultrasonic separation provided insight into the die-shear force performance as influenced by the process parameters and by the deposition of the nickel layer on the copper electrodes over the flex substrate.     

The effect of thin film structure and properties on gold ball bonding

The gold ball bonding process is widely used for making interconnections between integrated circuit chips and package lead frames, yet the relationships between the wire/substrate materials properties and the bond formation processes are not yet well understood. While the creation of a metallurgical bond at the interface between the wire and substrate is required, the deformation of the wire and substrate also play an important role in bond formation. Bonding to thin film substrates is of particular interest, since thin films often exhibit mechanical behavior distinctly different from bulk materials. In the present study, a systematic investigation has been conducted to understand the effects of the structure and properties of aluminum thin films on the quality of gold ball bonds. A series of aluminum thin films was fabricated with systematic variations in hardness, roughness, thickness, and composition. Gold wires were ball bonded to these substrates, and the bondability and bond shear strengths were assessed. Metallographic sections of several of these specimens were made and examined in the scanning electron microscope. The results show that the film thickness has the most dominant effect on the bondability and bond strength; films that were 0.5 μm thick often exhibited low strength or poor bondability. Very hard films also gave poor results. Ultimately, these results can be used to predict the wire bond reliability expected from various types of thin film metallization.     

Effects of bonding force on contact pressure and frictional energy in wire bonding

A numerical study is made of the elasto-plastic deformation taking place in ultrasonic wire bonding based on the finite element method. A special focus has been placed on how the important wire bonding parameters, such as bond force and power, affect the contact pressure along the wire–bond pad interface. It is shown that the contact interface had a long elliptical shape, and the maximum contact pressure occurred always at the periphery of the contact interface, which is consistent in the current 2D and 3D finite element analyses. The normalised real contact area as well as the maximum frictional energy intensity varied in a similar manner to the contact pressure, with the maximum values occurring at the periphery of contact interface, where weld is preferentially formed in practical wire bonding. A higher bond force does not result in a higher contact pressure, or higher frictional energy intensity, suggesting that a high bond force is not directly correlated to better wire bondability.     

Effects of Cu/Al intermetallic compound (IMC) on copper wire and aluminum pad bondability

Copper wire bonding is an alternative interconnection technology that serves as a viable, and cost saving alternative to gold wire bonding. Its excellent mechanical and electrical characteristics attract the high-speed, power management devices and fine-pitch applications. Copper wire bonding can be a potentially alternative interconnection technology along with flip chip interconnection. However, the growth of Cu/Al intermetallic compound (IMC) at the copper wire and aluminum interface can induce a mechanical failure and increase a potential contact resistance. In this study, the copper wire bonded chip samples were annealed at the temperature range from 150/spl deg/C to 300/spl deg/C for 2 to 250 h, respectively. The formation of Cu/Al IMC was observed and the activation energy of Cu/Al IMC growth was obtained from an Arrhenius plot (ln (growth rate) versus 1/T). The obtained activation energy was 26Kcal/mol and the behavior of IMC growth was very sensitive to the annealing temperature. To investigate the effects of IMC formation on the copper wire bondability on Al pad, ball shear tests were performed on annealed samples. For as-bonded samples, ball shear strength ranged from 240-260gf, and ball shear strength changed as a function of annealing times. For annealed samples, fracture mode changed from adhesive failure at Cu/Al interface to IMC layer or Cu wire itself. The IMC growth and the diffusion rate of aluminum and copper were closely related to failure mode changes. Micro-XRD was performed on fractured pads and balls to identify the phases of IMC and their effects on the ball bonding strength. From XRD results, it was confirmed that the major IMC was /spl gamma/-Cu/sub 9/Al/sub 4/ and it provided a strong bondability.     

Roughness Enhanced Au Ball Bonding of Cu Substrates

Process development studies of Au ball bumping on metallographically polished Cu substrates at ambient temperature were conducted by investigating the effect of process parameters on the ball bond shear force and the extent of bonding. These studies were performed on substrates polished with 0.06-$mu$m or 1-$mu$m abrasive solutions so as to assess the effect of surface roughness on bondability. Response surfaces were generated to illustrate the effects of ultrasonic power, bonding force, and time on bond shear force, and process windows were defined as those parametric combinations that yielded bond shear forces of 25gf or higher. After dissolving the Cu substrate away, the etched surfaces of the Au bumps were examined for bonded areas. Au–Cu ball bonds of about 65$mu$m diameter with bond shear force values higher than 25gf were obtained on 0.06-$mu$m polished substrates, but at an optimum bonding time of 1000ms. Increase in surface roughness, however, reduced the bonding time considerably, and values as low as 200ms were sufficient to yield bond shear force values higher than 25gf on 1.0-$mu$m polished substrates. Bonding on 1.0-$mu$m polished substrates not only reduced the bonding time, but also increased the maximum bond shear force and reduced the localization of bonded areas. These results suggest that a greater number of surface asperities of sufficient height on rougher substrates provide more bonding sites and hence improve the bondability.     

Effect of die-attach temperature (455° C) on the bondability of bond finger of gold packages

A possible cause of non-sticking on the bond finger of the size-braze 48 lead package (SD-48L) is surface contamination. High temperature enhances interdiffusion in thin solid films and oxidation. If the bonding surface is contaminated by any of these processes, bond failure is likely to occur. A study is carried out to investigate whether the heat treatment at the die-attach temperature (455° C) can affect the bondability of the Au bond surface. Based on the results of this study, it is found that heat-treatment at 455° C does not affect the bond quality over a brief period of time after wire bonding.     

Oxidation of copper pads and its influence on the quality of Au/Cu bonds during thermosonic wire bonding process

To understand the copper oxide effect on the bondability of gold wire onto a copper pad, thermosonic gold wire bonding to a copper pad was conducted at 90–200 °C under an air atmosphere. The bondability and bonding strength of the Au/Cu bonds were investigated. The bondability and bonding strength were far below the minimum requirements stated in industrial codes. At elevated bonding temperature of 200 °C, the bondability and bonding strength deteriorated mainly due to hydroxide and copper oxide formation on the copper pad. Oxide formation occurred if no appropriate oxide preventive schemes were applied. At lower bonding temperature, 90 °C, poor bondability and low bonding strength were mainly attributed to insufficient thermal energy for atomic inter-diffusion between the gold ball and copper pad.Copper pad oxidation was investigated using an electron spectroscopy for chemical analysis (ESCA) and thermogravimetric analysis (TGA). An activation energy of 35 kJ/mol for copper pad oxidation was obtained from TGA. This implies that different mechanisms govern the oxidation of copper pad and bulk copper. Hydroxide and copper oxide were identified based on the shifted binding energy. Cu(OH)₂ forms mainly on the top surface of copper pads and the underlying layer consists mainly of CuO. The hydroxide concentration increased with increasing the heating temperatures. After heating at 200 °C, the hydroxide concentration on the copper pad surface was approximately six times that at 90 °C. Protective measures such as passivation layer deposition or using shielding gas are critical for thermosonic wire bonding on chips with copper interconnects.     

Direct gold and copper wires bonding on copper

The key to bonding to copper die is to ensure bond pad cleanliness and minimum oxidation during wire bonding process. This has been achieved by applying a organic coating layer to protect the copper bond pad from oxidation. During the wire bonding process, the organic coating layer is removed and a metal to metal weld is formed. This organic layer is a self-assembled monolayer. Both gold and copper wires have been wire-bonded successfully to the copper die even without prior plasma cleaning. The ball diameter for both wires are 60 μm on a 100 μm fine pitch bond pad. The effectiveness of the protection of the organic coating layer starts from the wafer dicing process up to the wire bonding process and is able to protect the bond pad for an extended period after the first round of wire bond process. In this study, oxidization of copper bond pad at different packaging processing stages, dicing and die attach curing, have been explored. The ball shear strength for both gold and copper ball bonds achieved are 5 and 6 g/mil² respectively. When subjected to high temperature storage test at 150 °C, the ball bonds formed by both gold and copper wire bond on the organic coated copper bondpad are thermally stable in ball shear strength up to a period of 1440 h. The encapsulated daisy chain test vehicle with both gold and copper wires bonding have passed 1000 cycles of thermal cycling test (−65 to 150 °C). It has been demonstrated that orientation imaging microscopy technique is able to detect early levels of oxidation on the copper bond pad. This is extremely important in characterization of the bondability of the copper bond pad surface.     

Investigation on device characteristics of MOSFET transistor placed under bond pad for high-pin-count SOC applications

In the system-on-a-chip (SOC) era, chip layouts of integrated circuit (IC) products become more and more compact for cost reduction. To save layout area for SOC chips, on-chip electrostatic discharge (ESD) protection devices or input/output (I/O) transistors placed under bond pads is a good choice. To ensure that this choice is practicable, a test chip with large size NMOS devices placed under bond pads had been fabricated in a 0.35-/spl mu/m 1P4M 3.3-V CMOS process for verification. The bond pads of this test chip had been drawn with different layout patterns on the interlayer metals for two purposes. One is to investigate the efficiency against bonding stress applied on the active devices under the bond pads. The other purpose is to reduce the parasitic capacitance of bond pads for high-speed or high-frequency circuit applications. DC characteristics of these devices placed under bond pads had been measured under three conditions: before wire bonding, after wire bonding, and after thermal reliability stresses. After assembly with wire bond package and thermal reliability stresses, the measured results show that there are only little variations between devices under bond pads and devices beside bond pads. This result can be applied to save layout area of IC products by realizing on-chip ESD protection devices or I/O transistors under the bond pads, especially for the high-pin-count SOC.     

Numerical analysis of ultrasonic wire bonding: Part 2. Effects of bonding parameters on temperature rise

The thermo-structural analysis of ultrasonic wire bonding is performed by means of 3D finite element method. A special focus has been placed on monitoring the temperature rise during ultrasonic vibration. An equivalent method is used to simulate the wire and bond pad, where the large volumes of wire and bond pad are effectively reduced to small computational magnitudes. The history of temperature changes in the wire-bond pad-substrate interfaces influenced by varying bond forces and bond pad sizes is specifically studied. It is shown that the maximum bulk temperature obtained upon completion of ultrasonic vibration is far lower than the melting temperatures of the wire and bond pad materials, indicating that the bulk temperature rise due to ultrasonic vibration is not directly responsible for ultrasonic wire bonding. A large bond pad size usually leads to a lower temperature rise, and when the pad size reaches a certain value, the effect of bond pad size on temperature rise becomes insignificant. A higher bond force results in a marginally higher temperature rise than a lower bond force, which does not necessarily affect the wire bondability.