Programmable Electrofabrication of Porous Janus Films with Tunable Janus Balance for Anisotropic Cell Guidance and Tissue Regeneration

Janus films with controlled pore structures can be particularly important in diverse applications. There remains a challenge for simple, rapid, and scalable fabrication methods to control Janus balance (JB) including the thickness of the individual face as well as porosity and pore size. Here the electrofabrication of a porous Janus film with controlled Janus balance from aminopolysaccharide chitosan under the salt effect is reported. Sequential deposition of chitosan under programmable salt environment and electrochemical conditions enables construction of Janus films with precisely controlled Janus balance. Bioactive partially soluble calcium phosphate (CaP) salts can also generate porous structure in Janus film. It is specifically reported that a chitosan/hydroxyl apatite (HAp) composite Janus film can serve as an effective scaffold for guided bone regeneration. The dense layer functions to provide mechanical support and serves as a barrier for fibrous connective tissue penetration. The porous composite layer functions to provide the microenvironment for osteogenesis. In vivo studies using a rat calvarial defect model confirm the beneficial features of this Janus composite for guided bone regeneration. These results suggest the potential of electrofabrication as a simple and scalable platform technology to tune the self‐organization of soft matter for a range of emerging applications.     

Small Molecules in Light‐Emitting Electrochemical Cells: Promising Light‐Emitting Materials

Light‐emitting electrochemical cells (LECs) are solid‐state lighting devices that convert electric current to light within electroluminescent organic semiconductors, and these devices have recently attracted significant attention. Introduced in 1995, LECs are considered a great breakthrough in the field of light‐emitting devices for their applications in scalable and adaptable fabrication processes aimed at producing cost‐efficient devices. Since then, LECs have evolved through the discovery of new suitable emitters, understanding the working mechanism of devices, and the development of various fabrication methods. LECs are best known for their simple architecture and easy, low‐cost fabrication techniques. The key feature of their fabrication is the use of air stable electrodes and a single active layer consisting of mobile ions that enable efficient charge injection and transport processes within LEC devices. More importantly, LEC devices can be operated at low voltages with high efficiencies, contributing to their widespread interest. This review provides a general overview of the development of LECs and discusses how small molecules can be utilized in LEC applications by overcoming the use of traditional lighting materials like polymers and ionic transition metal complexes. The achievements of each study concerning small molecule LECs are discussed.     

Photoinduced Directional Proton Transport through Printed Asymmetric Graphene Oxide Superstructures: A New Driving Mechanism under Full‐Area Light Illumination

2D‐material‐based membranes with densely packed sub‐nanometer‐height fluidic channels show exceptional transport properties, and have attracted broad research interest for energy‐, environment‐, and healthcare‐related applications. Recently, light‐controlled active transport of ionic species in abiotic materials have received renewed attention. However, its dependence on inhomogeneous or site‐specific illumination is a challenge for scalable application. Here, directional proton transport through printed asymmetric graphene oxide superstructures (GOSs) is demonstrated under full‐area illumination. The GOSs are composed of partially stacked graphene oxide multilayers formed by a two‐step direct ink writing process. The direction of the photoinduced proton current is determined by the position of top graphene oxide multilayers, which functions as a photogate to modulate the horizontal ion transport through the beneath lamellar nanochannels. This transport phenomenon unveils a new driving mechanism that, in asymmetric nanofluidic structures, the decay of local light intensity in depth direction breaks the balance of electric potential distribution in horizontal direction, and thus generates a photoelectric driving force for ion transport. Following this mechanism, the GOSs are developed into photonic ion transistors with three different gating modes. The asymmetrically printed photonic‐ionic devices provide fundamental elements for light‐harvesting nanofluidic circuits, and may find applications for artificial photosynthesis and artificial electric organs.     

A Low-Noise Broadband Light Source for a WDM-PON Based on Mutually Injected Fabry–PÉrot Laser Diodes With RF Modulation

We demonstrated improved performance of a low-noise broadband light source (BLS) based on mutually injected Fabry–PÉrot laser diodes for a large capacity and high bit-rate wavelength-division-multiplexed passive optical network (WDM-PON). The 3-dB linewidth and relative intensity noise of each mode of the low-noise BLS are improved by radio-frequency modulation, where the frequency was detuned from the fundamental noise peak of the low-noise BLS. Then, a 622-Mb/s WDM-PON was demonstrated. Furthermore, a 1-Gb/s WDM-PON can be realized with Manchester coding at a channel spacing of 100 GHz. Thus, the proposed low-noise BLS can be employed to realize a highly scalable WDM-PON.      

Electron Field Emission of Geometrically Modulated Monolayer Semiconductors

Electron field emission, electrons emitted from solid surfaces under high electric field, offers significant scientific interests in materials sciences and potential optoelectronics applications. 2D atomic layers, such as MoS₂, exhibit fascinating properties for diverse applications in next‐generation nanodevices and rich physical phenomena for fundamental research. However, the study on field emission of semiconducting monolayers is lacking owing to its low efficiency and stability of electron emission. Here, electron field emission of the geometrically modulated monolayer semiconductors suspended with 1D nanoarrays is demonstrated. Chemical vapor deposition synthesis of two prototype monolayers of transition metal dichalcogenides (TMD), MoS₂ and MoSe₂, is presented and their diverse band structures offer an ideal platform to explore the fundamental process of the electron emission in the TMD. Geometrical modulation and charge transfer of the semiconducting monolayers can be significantly tuned with the structural suspension with the 1D ZnO nanoarrays. Possible mechanisms on the enhanced electron emission of the 2D monolayers are discussed. With geometrical control of the monolayers, a highly efficient and stable electron emission of TMD monolayers is achieved in low turn‐on electric fields, enabling applications on electrons sources and opening a new avenue toward geometrically tuned atomic layers.     

Photoelectric Effects in Single Domain BiFeO3 Crystals

Energy harvesting from sunlight is essential in order to save fossil fuels, which are found in limited amount in the earth's crust. Photovoltaic devices converting light into electrical energy are presently made of semiconducting materials, but ferroelectrics are also natural candidates because of their internal built‐in electric field. Although they are clearly uncompetitive for mainstream applications, the possibility to output high photovoltages is making these materials reconsidered for targeted applications. However, their intrinsic properties regarding electronic transport and the origin of their internal field are poorly known. Here, it is demonstrated that under intense illumination and electric field, oxygen vacancies can be controllably generated in BiFeO₃ to dramatically increase the conductance of BiFeO₃ single crystals to a controllable value spanning 6 orders of magnitude while at the same time triggering light sensitivity in the form of photoconductivity, diode, and photovoltaic effects. Properties of the bulk and the Schottky interfaces with gold contacts are disentangled and it is shown that bulk effects are time dependent. The photocurrent has a direction that can be set by an applied field without changing the ferroelectric polarization direction. The self‐doping procedure is found to be essential in both the generation of electron hole pairs and the establishment of the internal field that separates them.     

半导体中的谷间电子转移和体振荡

从GaAs/AlAs量子阱的量子限制、能带混合和隧穿共振中发现了新的异质谷间转移电子效应。用它制成了定位精度高的高效谷间电子布居控制极。把这种控制极设置于耿氏有源层的阴极端,消除了器件中的死区,抑制了强场畴,产生高效的电场弛豫振荡模。通过长有源层样品的模拟设计,发现了新的触发多电子束弛豫振荡模,实现了体振荡。模拟设计得出在20～25GHz频段能获得50W以上的脉冲振荡输出,效率大于40%。     

Heterointegration of Pt/Si/Ag Nanowire Photodiodes and Their Photocatalytic Properties

Photocatalyst mediated photoelectrochemical processes can make use of the photogenerated electrons and holes onsite for photocatalytic redox reactions, and enable the harness and conversion of solar energy into chemical energy, in analogy to natural photosynthesis. However, the photocatalysts available to date are limited by either poor efficiency in the visible light range or insufficient photoelectrochemical stability. We show that a Pt/Si/Ag nanowire heterostructure can be rationally synthesized to integrate a nanoscale metal-semiconductor Schottky diode encased in a protective insulating shell with two exposed metal catalysts. The synthesis of Pt/Si/Ag nanowire diodes involves a scalable process including the formation of silicon nanowire array through wet chemical etching, electrodeposition of platinum and photoreduction of silver. We further demonstrated that the Pt/Si/Ag diodes exhibited highly efficient photocatalytic activity for a wide range of applications including environmental remediation and solar fuel production in the visible range. In this article, photodegradation of indigo carmine and 4-nitrophenol were used to evaluate the photoactivity of Pt/Si/Ag diodes. The Pt/Si/Ag diodes also show high activity for photoconversion of formic acid into carbon dioxide and hydrogen.     

Catalytic and Light‐Driven ZnO/Pt Janus Nano/Micromotors: Switching of Motion Mechanism via Interface Roughness and Defect Tailoring at the Nanoscale

The first models of mesoporous ZnO/Pt Janus micromotors that show fuel‐free and light‐powered propulsion depending on the interface roughness are shown. Two models of ZnO semiconducting particles with distinct surface morphologies and pore structures are synthesized by self‐aggregation of primary nanoparticles and nanosheets into nanoscale rough and smooth microparticles, respectively. The self‐assembled nanosheet model (smooth) provides a large surface for the formation of a continuous Pt layer with strong adherence, whereas the discontinuous Pt species take place inside the inter‐nanoparticles pores in the self‐assembled nanoparticle model (rough). The effects of the interface, surface porosity, defect, and charge transfer on the light‐powered motion for both well‐designed mesoporous ZnO/Pt Janus micromotors are investigated and compared to find the underlying propulsion mechanisms. The degradation of two model pollutants is demonstrated as a proof‐of‐concept application of these carefully engineered Janus micromotors. In this work, it is shown that by discreet material fabrication together with semiconductor/metal interface charge transport interpretation, it would be possible to develop new light‐driven Janus micromotors based on other photocatalysts containing active surfaces such as TiO₂.     

Self‐Propelled 3D‐Printed “Aircraft Carrier” of Light‐Powered Smart Micromachines for Large‐Volume Nitroaromatic Explosives Removal

Self‐propelled micro‐/nanomotors are in the forefront of materials research, for applications ranging from environmental remediation to biomedicine. However, due to their limited sizes, they can only navigate within small distances, typically in the order of millimeters, which inevitably hinder their use for large‐volume real applications. Here it is shown that a 3D‐printed millimeter‐scale motor (3DP‐motor) can act as “aircraft carrier” of TiO₂/Pt Janus micromotors and be used for enhanced large‐volume environmental remediation applications. The 3DP‐motor can move fast for tens of meters through the Marangoni effect by asymmetrically releasing ethanol. During its navigation, this 3DP‐motor can carry and slowly release in solution TiO₂/Pt Janus micromotors which can be propelled by light illumination while acting as photodegradation agents. Highly efficient degradation of nitroaromatic explosives over a large solution area is achieved. A wall‐following motion of the 3DP‐motor without external guidance is also demonstrated which is generated by the chemiosmotic flow at the wall vicinity. This can be easily tuned by changing the wettability of the wall surface and also modifying the shape of 3DP‐motor, leading to different motion behaviors. This work introduces a new concept of micromotors carried by large millimeter sized motors to traverse long distances and it should find a broad range of applications.     

A 2-bit highly scalable nonvolatile memory cell with two electrically isolated charge trapping sites

A highly scalable 2-bit nonvolatile memory (NVM) cell using two electrically isolated charge trapping sites is proposed and demonstrated by numerical device simulation. The operational mechanisms including read, program, erase and inhibit in an array structure are studied in detail. This double storage capability per single cell and highly scalable structure is very suitable for high density nanometric NVM applications.     

An Error Bound for Near-Field Array Synthesis

An expression for the upper bound of any component of the electric or magnetic field at any point in a region is derived in terms of a product of two surface field integrals. The result is most useful for bounding errors in near-field array synthesis, but might have other applications where upper bounds on field magnitudes are desired.     

Black Gold: Broadband,High Absorption of Visible Light for Photochemical Systems

Here, a black Au surface is presented: a material solely composed of Au that is capable of absorbing more than 92% of the incident light over a spectral region ranging from 300 to 600 nm and that can maintain a high absorbance (above 70%) for wavelengths up to 800 nm. The black Au surface is fabricated by a simple and scalable template‐assisted physical vapor deposition technique and possesses the flexibility of adhering to any arbitrary substrate. The high absorbance of Au originates from the close packing of high aspect ratio Au nanotubes possessing a random tapered wall thickness. Fabry–Perot resonances of gap‐plasmon modes between the Au nanotubes are also responsible for the strong suppression of reflectance of black Au as demonstrated by finite element method simulations. Furthermore, the ability of this surface to drive photochemical transformations under visible light illumination is demonstrated. Hence, black Au could provide a new paradigm for the use of highly absorbing metal nanostructures to effectively harvest the entire visible spectrum for photorelated applications such as solar fuel production, photodetection, and photovoltaics.     

Electric Field-Driven Dielectrophoretic Elastomer Actuators

Dielectrophoresis is the electro-mechanical phenomenon where a force is generated on a dielectric material when exposed to a non-uniform electric field. It has potential to be exploited in smart materials for robotic manipulation and locomotion, but to date it has been sparsely studied in this area. Herein, a new type of dielectrophoretic actuator exploiting a novel electroactive polymer is described, termed as dielectrophoretic elastomer (DPE), which undergoes electric field-driven actuation through dielectrophoresis. Unique deflection and morphing behavior of the elastomer induced by controlling the dielectrophoretic phenomenon, such as out-of-plane deformation and independence of electric field polarity, are illustrated. The dielectric and mechanical properties of the DPE are studied to gain insight into the influence of materials composition on deformation. Actuation performance using different electrode parameters is experimentally investigated with supplementary analysis through finite element simulation, revealing the relationship between electric field inhomogeneity and deflection. The applications of DPE actuators in a range of robotic devices is demonstrated, including a pump, an adjustable optical lens, and a walking robot. This diverse range of applications illustrates the wide potential of these new soft-and-smart electric field-driven materials for use in soft robotics and soft compliant devices.     

Fouling-Proof Cooling (FP-Cool) Fabric Hybrid with Enhanced Sweat-Elimination and Heat-Dissipation for Personal Thermal Regulation

Passive cooling fabric that facilitates sweat-wicking and evaporation is highly desirable for promoting human body's thermal comfort and reducing energy consumption. However, highly hydrophilic sweat-wicking fabric fails to repel external fouling due to the contradiction between hydrophilicity and lyophobicity. Moreover, conventional passive cooling fabrics show limited evaporation capacity when they reach the adsorption limit in intense perspiration scenarios. Herein, a fouling-proof cooling (FP-Cool) fabric with an interactive functional structure design for highly-efficient personal thermal regulation is proposed by constructing spatially distributed superoleophobic Janus channels on an optimized heat conductive superomniphobic fabric. The dominant superomniphobicity and superoleophobic Janus feature endow the outer FP-Cool fabric with durable performance (up to 3000 cycles’ abrasion) to repel oil/water-based contaminations. The Janus channels rapidly pull sweat out of the inner fabric for efficient evaporation, ensuring a dry sense of skin. The FP-Cool fabric preserves 40% higher thermal conductivity, and over 50% higher evaporation rate than conventional fabrics. In the sweat evaporation test, the FP-Cool fabric shows up to 100% reduction in sweat gain ratio to cotton fabric. The concept would have implications for intelligent textiles design, and the synthesis strategy can be applied in various applications such as oil-water separation and microfluidics control.     

用光电导天线产生太赫兹电磁波的饱和效应研究

根据半导体光电子学理论,分析了光注入非平衡载流子(电子-空穴对)的瞬态输运机理,研究了不同条件下的SI-GaAs光电导偶极天线太赫兹波辐射功率和辐射强度的饱和效应.结果表明其主要原因是在外加偏置电场作用下,光注入载流子出现了空间电荷电场屏蔽和辐射电场屏蔽现象,对提高太赫兹波辐射功率和辐射强度起到了遏制作用.对于电极间隙大小不同的天线,两种屏蔽效应的作用不同;在触发光能一定的情况下,照射光斑较大时屏蔽效应较小.     

Radiation pattern synthesis for arrays of conformal antennas mounted on arbitrarily-shaped three-dimensional platforms using genetic algorithms

A domain-decomposition/reciprocity procedure is presented which allows the radiation patterns of microstrip patch antennas mounted on arbitrarily-shaped three-dimensional perfectly electric conducting (PEC) platforms to be computed accurately as well as efficiently. The utility of this technique is demonstrated by considering an example consisting of a nine-element conformal array of microstrip patch antennas mounted axially along a finite-length PEC circular cylinder. It is shown that the elements close to the ends of the cylinder have significantly different patterns than those close to the center of the cylinder. The results from this example suggest that the common practice where all the individual element patterns are assumed identical is not always valid and, in fact, can lead to significant performance degradation in the design of conformal phased arrays. This observation is supported by the fact that an attempt to steer the main beam of the nine-element conformal array to an angle /spl theta//sub 0/=60/spl deg/ using a standard uniform progressive phase shifting technique proves unsuccessful. Next a genetic algorithm (GA) synthesis procedure is introduced that is capable of determining the optimal set of element excitation phases required to yield a desired or specified far-field radiation pattern. The results of this GA phase-only optimization are shown to yield the desired main beam steered to the correct angle for this nine-element linear array mounted on a circularly cylindrical platform. The GA radiation pattern synthesis procedure introduced appears to be a highly effective means of correcting for platform effects on the individual element patterns of a conformal phased array.     

Tunable Dielectric Function in Electric‐Responsive Glass with Tree‐Like Percolating Pathways of Chargeable Conductive Nanoparticles

The design of nanostructured materials with specific physical properties is generally pursued by tuning nanoparticle size, concentration, or surface passivation. An important step forward is to realize “active” systems where nanoparticles are vehicles for controlling, in situ, some specific, tuneable features of a responsive functional material. In this perspective, this work focuses on the rational design of a nanostructured glass with electrically tuneable dielectric function obtained by injection and accumulation of charge on embedded conductive nanocrystals. This enables electrically controlled switching of semiconducting nanophases to charged polarisable states to be achieved, which could lead to smart, field‐enhancement applications in nanophotonics and plasmonics. Here, it is shown that such response switching can be obtained if a percolating charge‐transport mechanism is activated through a disordered tree‐like network, as is demonstrated to be possible in SiO₂ films where suitable dispersions of SnO₂ nanocrystals, with conductive interfaces, are obtained as a result of a new synthesis strategy.     

3D Aluminum Hybrid Plasmonic Nanostructures with Large Areas of Dense Hot Spots and Long‐Term Stability

Plasmonic materials possessing dense hot spots with high field enhancement over a large area are highly desirable for ultrasensitive biochemical sensing and efficient solar energy conversion; particularly those based on low‐cost noncoinage metals with high natural abundance are of considerable practical significance. Here, 3D aluminum hybrid nanostructures (3D‐Al‐HNSs) with high density of plasmonic hot spots across a large scale are fabricated via a highly efficient and scalable nonlithographic method, i.e., millisecond‐laser‐direct‐writing in liquid nitrogen. The nanosized alumina interlayer induces intense and dual plasmonic resonance couplings between adjacent Al nanoparticles with bimodal size distribution within each of the hybrid assemblies, leading to remarkably elevated localized electric fields (or hot spots) accessible to the analytes or reactants. The 3D‐stacked nanostructure substantially raises the hot spot density, giving rise to plasmon‐enhanced light harvesting from deep UV to the visible, strong enhancement of Raman signals, and a very low limit of detection outperforming reported Al nanostructures, and even comparable to the noble metals. Combined with the long‐term stability and good reproducibility, the 3D‐Al‐HNSs hold promise as a robust low‐cost plasmonic material for applications in plasmon‐enhanced spectroscopic sensing and light harvesting.     

Dynamics of an ensemble of cyclotron oscillators in the field of a charged filament

The effect of an external static radial electric field on the characteristics of a superradiation pulse of an ensemble of cyclotron oscillators is investigated in a numerical experiment. It is demonstrated that this external field alters the amplitude, the width, and the peak time of the radiation generated by this active medium.