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1.
本文对ZnO结构太阳能电池钙钛矿(CaTiO3)薄 膜层中嵌入的Ag粒子的等离子体增强进行了理论分析。由于引入了Ag颗粒,归因于Ag颗粒的 强表面等离子体吸收和Ag与CaTiO3之间的协同作用,太阳能电池的吸收得以增强。在计算 分析中,Ag粒子的最佳半径为80 nm。优化的纳米结构的平均吸收效 率可以达到80%,比纯CaTiO3薄膜层结构的平均吸收效率高24%。因此认为,本文设计研究的 Ag/CaTiO3太阳能电池结构可能以低成本和简单的制造工艺成为未来工业制造领域的焦点 。  相似文献   

2.
ZnO缓冲层改善Rubrene/C70有机太阳能电池的性能   总被引:2,自引:2,他引:0  
通过制备结构为ITO/ZnO/C70 /Rubrene/MoO3/Al 的有机太阳能电池(OSCs),研究了ZnO作为阴极 修饰层对Rubrene/C70有机太阳能电池性能的改善。同时通过 优化ZnO的厚度研究了ZnO的工作机理。 从实验结果可以看出,随着ZnO厚度的变化,器件的短路电流密度(Jsc)、开路电压(Voc)、填充因子 (FF)、光电转换效率(PCE)和串联电阻(Rs)等性能参数呈现出了规律 性变化,当ZnO层厚度比较 薄时,器件PCE随着厚度的增加不断增大,当ZnO层厚度为53nm时,器件PCE达到最高为1.13%, 对应的Jsc、Voc、FF分别为2.82mA·cm-2、0. 84V、45.86%,Rs为66.2Ω·cm2,当ZnO层厚度继续增 加时,器件PCE开始减小。对比没有ZnO阴极修饰层,器件最优时 的Jsc、Voc、FF和PCE 分别提高了49%、17%,Rs降低了56%。  相似文献   

3.
多孔ZnO纳米花电子传输层对有机太阳能电池性能的优化   总被引:1,自引:1,他引:0  
通过水热法制备了多孔、单晶结构的三维ZnO纳米花材料。研究了不同生长时间下(6h、9h和12h)的ZnO材料的形貌及光电性能。结果表明,反应9h的多孔ZnO纳米花材料具有较高透光率、低缺陷密度以及高载流子迁移率等优点,是较为理想的电子传输层材料。将这些材料应用于有机太阳能电池的制备,性能测试结果表明,以生长时间为9h的多孔ZnO纳米花材料作为电子传输层的器件性能最佳,与无ZnO修饰层的参比器件相比,其短路电流密度Jsc和光电转化效率(PCE)明显提高,分别达到了5.68mA/cm2和1.24%。  相似文献   

4.
低温处理的TiO2纳米颗粒薄膜作为缓冲层的有机光伏电池   总被引:1,自引:1,他引:0  
通过溶胶凝胶法(sol-gel)合成了TiO2纳米颗 粒(NPs),制备了结构为 ITO/PEDOT:PSS/P3HT:PCBM/TiO2/Al的有机太阳能电池(OSC)器件。通过优化阴极缓冲 层TiO2NPs的 热处理温度,考察了温度以及溶剂对TiO2NPs薄膜的光学性能、形貌结构和电学 性能的影响,并研究了其对OSC性能的影响及作用机理。实验发现,TiO2NPs处理温度 为80℃时,器件 的效率达到了2.52%。相对于参比器件,器件的光电转换效率(PCE) 、填充因子(FF)分别提高了60%、64.7%。  相似文献   

5.
为了进一步平衡OLED器件内部空穴和电子载流子 的注入,制备了结构为ITO/NPB(40nm)/Alq3(45nm)/Bphen:(X%)BCP:(5%)Cs2CO3(15nm)/Cs2CO3(1.5 nm)/Al(100nm)的OLED器件,通过改变BCP 的掺杂浓度,研究了以Bphen:BCP:Cs2CO3作为电子传输层对OLED器件发光亮度、电流 密度和效率等性能 的影响。结果表明,采用Bphen:BCP:Cs2CO3作为电子传输层能提高器件的电子注入能力 ,改善器件的性能, 相比于未引入BCP的器件,采用BCP掺杂浓度为10%的Bphen:BCP:Cs2CO3作为电子传输层 ,可以使器件 的最大电流效率提高46%,达到3.89cd/A,且 在电压从为5V上升至10V的过程中,器件的色坐标一直为 (0.35,0.55),具有很高的稳定性。原因是由于BCP的高LUMO能级和高 HOMO能级,能够有 效阻挡空穴到达阴极,减小空穴漏电流,同时使电子的注入更容易,电子和空穴的注入更加 平衡,发光也更加稳定。  相似文献   

6.
以实现宽谱减反介质复合纳米结构表面的高 效单结GaInP太阳电池为目标,利用严格耦合波分析理论, 仿真研究了该电池表面的介质复合纳米结构对太阳电池宽谱减反、归一化吸收、最大化理想 效率的影响。该介质复 合纳米结构从上往下依次为SiO2纳米锥、SiO2介质层和SiNx介质层,通过对SiO2纳米锥占空比、深宽比以及对SiO2和SiNx介质层厚度等参数的系列仿真最终优化出适用于单结Ga InP电池的表面结构。结果表明:当SiO2纳米锥底部 直径D=550nm、高度H=650 nm、SiN x介质层厚度为60 nm时电池具有最高的 最大化理想转换效率为28.58%。上述结果为后期实验以及该类电池 实现规模化生产奠定了基础。  相似文献   

7.
利用溶胶-凝胶旋涂镀膜法结合热处理工艺在FTO玻璃上制备了ZnO薄膜,并通过X射线衍射(XRD)、扫描电子镜(SEM)对其晶相及表面形貌进行了表征;以酞菁染料ZnPc和窄禁带半导体PbS量子点(Q-PbS)为敏化剂,分别制备了FTO/ZnO/ZnPc电极、FTO/ZnO/Q-PbS电极和FTOZnO/Q-PbS/ZnPc电极,结果表明,ZnPc和Q-PbS对ZnO纳米颗粒膜产生了良好的敏化作用,且两者的复合敏化效果最好;制备了FTO/ZnO/Q-PbS/ZnPc为光阳极的染料敏化太阳能电池(DSSC),在模拟太阳光下,电池的开路电压为304mV,短路电流为1.42mA,光电转换效率为0.696%,填充因子为0.348。  相似文献   

8.
石墨烯掺杂Cs2CO3作为高效电子注入层的OLEDs性能研究   总被引:2,自引:2,他引:0  
研制了石墨烯掺杂Cs2CO3(Cs2CO3:Graphe ne )作为高效电子注入层、结构为ITO/N,N′-bis-(1-naphthyl) -N,N′-diphenyl-1,1′-biphenyl-4,4′-diamine (NPB)(50 nm)/tris-(8-hydroxy quinoline)-aluminum Alq3(80 nm)/Cs2CO3:Gra phene (mss 20% 1nm)/Al(120 nm)的OLEDs。将其与标准器件ITO/NPB(50 nm)/Alq3(80 n m)/LiF(0.5 nm)/Al(120 nm)作性能比较,研究石墨烯掺杂在Cs2CO3中作为电子注入层 对 OLEDs性能的影响。结果表明,基于Cs2CO3:Graphene结构作为电子注入层的器 件效率要高于LiF作为电子注入层的器件,其最大电流效率达到2.02 cd/A, 是标准器件的2.59倍;亮度也高于LiF作为电子注入层的器件,在10 V时达 到最大值7690cd/m2,是标准器件最大亮度 的2.07倍。性能得到提高的主要机理是由于Cs2CO3:Graphene的引入提高了电子注入效率。  相似文献   

9.
目前染料敏化太阳能电池的天然染料主要以花青 素为主,但花青素敏化太阳能电池的 光电转换效率比较低。本研究从黑枸杞中提取花青素,利用阿魏酸、草酸和咖啡酸对黑枸杞 染料进行酰化改性,并将其作为敏化剂组装染料敏化太阳能电池。利用紫外-可见吸收光谱 , 循环伏安测试对染料的光谱吸收特性及光电性能进行了表征。结果表明:黑枸杞经酰化后光 谱范围有效扩宽,酰化黑枸杞染料均能将电子注入到TiO2导带边缘,并且咖啡酸酰化后的 光吸收效率最大。在100 mW/cm2入射光照下,黑枸杞经酰化后光电 转换效率提高,其中咖 啡酸酰化后光电转换效率最大为1.01%。采用电化学阻抗进一步分析 电子在电池界面的传 输,酰化黑枸杞染料能够有效的抑制TiO2与离子电解液之间的复合率。  相似文献   

10.
为了发展高性能、低成本和结构简单的ZnO紫外 光探测器。在本文中,利用溶液法,制备出ZnO 纳米颗粒,采用透射电子显微镜(TEM)、X射线衍射仪(XRD)、紫外-可见分光光度计和荧光 光谱仪,分别 研究了ZnO纳米颗粒的形貌、晶相结构和光学特性。结果显示:样品呈球形状的颗粒,尺寸 分布在6~8.5nm 之间,平均粒径为7.1nm,为六方纤锌矿结构。发现ZnO纳米颗 粒的陡峭吸收边出现在370nm附近,在390nm 处出现一个很强的近带边发射峰和一宽泛的可见光发光带。此外,利用制备的ZnO纳米颗粒 ,旋涂在刻蚀 有叉指电极的FTO(SnO2:F)上,制备出紫外光探测器,测试了它在暗态和365 nm紫外光照下的电流-电压(I-V) 和电流-时间(I-t)特性。结果表明:紫外光探测器的灵敏度、光响应度、响 应时间、恢复时间分别为62.4(在 -3.5V处),13.6A/W(在+5V处), 15s。另外,它的光响应机理主要由于ZnO纳米 颗粒表面吸附的氧起主导作用。  相似文献   

11.
DUV lithography, using the 248 nm wavelength, is a viable manufacturing option for devices with features at 130 nm and less. Given the low kl value of the lithography, integrated process development is a necessary method for achieving acceptable process latitude. The application of assist features for rule based OPC requires the simultaneous optimization of the mask, illumination optics and the resist.Described in this paper are the details involved in optimizing each of these aspects for line and space imaging.A reference pitch is first chosen to determine how the optics will be set. The ideal sigma setting is determined by a simple geometrically derived expression. The inner and outer machine settings are determined, in turn,with the simulation of a figure of merit. The maximum value of the response surface of this FOM occurs at the optimal sigma settings. Experimental confirmation of this is shown in the paper.Assist features are used to modify the aerial image of the more isolated images on the mask. The effect that the diffraction of the scattering bars (SBs) has on the image intensity distribution is explained. Rules for determining the size and placement of SBs are also given.Resist is optimized for use with off-axis illumination and assist features. A general explanation of the material' s effect is discussed along with the affect on the through-pitch bias. The paper culminates with the showing of the lithographic results from the fully optimized system.  相似文献   

12.
This paper presents a new method to increase the waveguide coupling efficiency in hybrid silicon lasers. We find that the propagation constant of the InGaAsP emitting layer can be equal to that of the Si resonant layer through improving the design size of the InP waveguide. The coupling power achieves 42% of the total power in the hybrid lasers when the thickness of the bonding layer is 100 nm. Our result is very close to 50% of the total power reported by Intel when the thickness of the thin bonding layer is less than 5 nm. Therefore, our invariable coupling power technique is simpler than Intel's.  相似文献   

13.
The relation between the power of the Brillouin signal and the strain is one of the bases of the distributed fiber sensors of temperature and strain. The coefficient of the Bfillouin gain can be changed by the temperature and the strain that will affect the power of the Brillouin scattering. The relation between the change of the Brillouin gain coefficient and the strain is thought to be linear by many researchers. However, it is not always linear based on the theoretical analysis and numerical simulation. Therefore, errors will be caused if the relation between the change of the Brillouin gain coefficient and the strain is regarded as to be linear approximately for measuring the temperature and the strain. For this reason, the influence of the parameters on the Brillouin gain coefficient is proposed through theoretical analysis and numerical simulation.  相似文献   

14.
Today, micro-system technology and the development of new MEMS (Micro-Electro-Mechanical Systems) are emerging rapidly. In order for this development to become a success in the long run, measurement systems have to ensure product quality. Most often, MEMS have to be tested by means of functionality or destructive tests. One reason for this is that there are no suitable systems or sensing probes available which can be used for the measurement of quasi inaccessible features like small holes or cavities. We present a measurement system that could be used for these kinds of measurements. The system combines a fiber optical, miniaturized sensing probe with low-coherence interferometry, so that absolute distance measurements with nanometer accuracy are possible.  相似文献   

15.
The parallel thinning algorithm with two subiterations is improved in this paper. By analyzing the notions of connected components and passes, a conclusion is drawn that the number of passes and the number of eight-connected components are equal. Then the expression of the number of eight-connected components is obtained which replaces the old one in the algorithm. And a reserving condition is proposed by experiments, which alleviates the excess deletion where a diagonal line and a beeline intersect. The experimental results demonstrate that the thinned curve is almost located in the middle of the original curve connectivelv with single pixel width and the processing speed is high.  相似文献   

16.
From its emergence in the late 1980s as a lower cost alternative to early EEPROM technologies, flash memory has evolved to higher densities and speedsand rapidly growing acceptance in mobile applications.In the process, flash memory devices have placed increased test requirements on manufacturers. Today, as flash device test grows in importance in China, manufacturers face growing pressure for reduced cost-oftest, increased throughput and greater return on investment for test equipment. At the same time, the move to integrated flash packages for contactless smart card applications adds a significant further challenge to manufacturers seeking rapid, low-cost test.  相似文献   

17.
Waveguide multilayer optical card (WMOC) is a novel storage device of three-dimensional optical information. An advanced readout system fitting for the WMOC is introduced in this paper. The hardware mainly consists of the light source for reading, WMOC, motorized stages addressing unit, microscope imaging unit, CCD detecting unit and PC controlling & processing unit. The movement of the precision motorized stage is controlled by the computer through Visual Basic (VB) language in software. A control panel is also designed to get the layer address and the page address through which the position of the motorized stages can be changed. The WMOC readout system is easy to manage and the readout result is directly displayed on computer monitor.  相似文献   

18.
It is well known that adding more antennas at the transmitter or at the receiver may offer larger channel capacity in the multiple-input multiple-output(MIMO) communication systems. In this letter, a simple proof is presented for the fact that the channel capacity increases with an increase in the number of receiving antennas. The proof is based on the famous capacity formula of Foschini and Gans with matrix theory.  相似文献   

19.
Due to variable symbol length of digital pulse interval modulation(DPIM), it is difficult to analyze the error performances of Turbo coded DPIM. To solve this problem, a fixed-length digital pulse interval modulation(FDPIM) method is provided. The FDPIM modulation structure is introduced. The packet error rates of uncoded FDPIM are analyzed and compared with that of DPIM. Bit error rates of Turbo coded FDPIM are simulated based on three kinds of analytical models under weak turbulence channel. The results show that packet error rate of uncoded FDPIM is inferior to that of uncoded DPIM. However, FDPIM is easy to be implemented and easy to be combined, with Turbo code for soft-decision because of its fixed length. Besides, the introduction of Turbo code in this modulation can decrease the average power about 10 dBm, which means that it can improve the error performance of the system effectively.  相似文献   

20.
The collinearly phase-matching condition of terahertz-wave generation via difference frequency mixed in GaAs and InP is theoretically studied. In collinear phase-matching, the optimum phase-matching wave hands of these two crystals are calculated. The optimum phase-matching wave bands in GaAs and lnP are 0.95-1.38μm and 0.7-0.96μm respectively. The influence of the wavelength choice of the pump wave on the coherent length in THz-wave tuning is also discussed. The influence of the temperature alteration on the phase-matching and the temperature tuning properties in GaAs crystal are calculated and analyzed. It can serve for the following experiments as a theoretical evidence and a reference as well.  相似文献   

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