表面自组装反应制备液晶光控取向膜

通过聚乙烯醇薄膜表面致密的羟基基团与肉桂酰氯间的选择性酯化反应,将光敏基团连接到聚乙烯醇薄膜表面,制备出一种新型的光敏自组装单层膜.用线性偏振紫外光辐照该薄膜,与光矢量方向匹配的肉桂酸基团发生光化学反应,反应产物沿辐照光的偏振方向分布,形成表面张力各向异性的薄膜.将该薄膜作为向列相液晶的取向膜制成平行液晶器件,在偏光显微镜下观察,发现获得了均一、稳定的取向效果.这种自组装光控取向膜的制作过程简单,且具有良好的热稳定性.     

反应性液晶修饰的光敏聚芳醚光取向稳定性研究

采用反应性液晶通过光聚合反应与聚芳醚光取向膜复合方法,制备了平面转换(In-plane switching,IPS)液晶显示器件,并在高温状态下对其光电显示和取向稳定性能进行了研究。结果显示,与单一聚芳醚光取向膜相比,利用复合光取向膜制备的IPS器件在高温状态下的光电显示和液晶取向稳定性能都得到了明显提高,在65℃明亮显示20h无液晶取向变化,在120℃维持2h无明显光量渗透。在线偏振紫外光下,光敏聚芳醚薄膜发生各向异性光交联反应,其交联程度最高可达67.4%。SEM分析结果发现,反应性液晶单体在UV光照射下,在聚芳醚光取向膜表面上发生了各向异性光聚合反应,沿先前光取向方向形成长度为0.4μm左右的棒状聚合物,有效限制了光取向膜中未交联的柔性基团的活动能力,进而有效增强了复合取向膜对液晶的取向稳定性。     

一种新型光敏小分子用于光控取向的研究

通过在3,5-二羟基苯甲醇分子中的双酚基基团上引入双肉桂酰酯光敏基团的酯化反应,合成了一类新型的分子顶部为羟基极性基团,整个分子构型类似于树枝状的光敏小分子化合物。将此种光敏材料配成一定浓度的溶液,旋涂在玻璃基板上成膜,经过线性偏振紫外光辐照后发生交联反应,制备成光控取向膜。以此种取向膜制成向列相液晶的平行液晶器件,在偏光显微镜下观察,发现取得了均一、稳定的取向效果,并且该取向膜具有良好的热稳定性能。     

基于光敏自组装多层膜的液晶光控取向膜

采用layer-by-layer(LBL)的方法，将基板依次在具有光敏双键的季铵盐水溶液和聚乙烯基苯磺酸钠水溶液中浸泡，石英基板表面形成了自组装多层沉积膜。经线性偏振紫外光辐照后，LBL多层膜表现出明显的紫外吸收各向异性。将两片带有各向异性薄膜的基板做成平行液晶器件。在正交的偏光显微镜下观察，发现取得均一、稳定的取向效果。该种光控取向膜有望用作LCoS微显示的取向层。     

自组装法制备新型液晶垂直取向膜

用硅烷偶联剂3-氨丙基-三乙氧基硅烷,通过自组装反应在石英基板表面制备了含有二苯乙炔基的自组装单层膜。用该自组装膜作为向列相液晶的取向层制成液晶器件,在偏光显微镜下观察,发现向列相液晶获得了均匀、稳定的垂直取向效果。热稳定性试验表明,用自组装方法制备的液晶垂直取向膜有良好的热稳定性,在250℃条件下取向仍可保持。     

双酚A双肉桂酸酯光控取向膜

利用双酚A双肉桂酸酯光敏单体在线偏振紫外光作用下发生光交联反应,制备了光控取向膜。制备过程更为简单,不需要高温热处理过程。液晶分子的排列方向与入射紫外光偏振方向垂直。通过紫外光谱和红外光谱分析了光化学反应过程,链聚合反应与异构反应相比,链状聚合反应对于液晶的排列起重要作用。利用偏振红外光谱对取向膜的有序度值计算发现,有序值较小。利用Cano盒测试了方位锚定能的大小为1.28×10-6J/m2。取向膜的热稳定性可以达到90℃。     

一种新型液晶垂直取向膜

采用离子沉积法在玻璃基板表面制备了十四烷基磺酸盐自组装膜,用带有该自组装膜的基板制成的液晶器件呈现出垂直取向效果。通过自组装反应过程分析,认为自组装膜表面的纵向沟纹引起了液晶的垂直排列。实验发现,当自组装膜烷烃碳链长度大于11个C原子就可获得垂直取向。这种取向膜制作过程简单、热稳定性好,非常有望应用于多畴垂直取向模式的液晶显示器。     

光敏小分子单体链聚合诱导液晶分子排列的研究

两端带有碳碳双键,尺寸与液晶分子相近的刚性小分子单体在线偏振紫外光照射下聚合,形成的聚合物膜能够诱导液晶分子均匀取向。对不同光照时间的紫外吸收光谱谱图比较发现,该取向材料具有较好的光敏性。利用偏振红外光谱测定了取向膜表面的二向色性,并且测得膜表面有序度为0．088。以晶体旋转法测定该取向膜制成的液晶器件,测得预倾角的大小为0．8。     

光敏侧链型高分子液晶的光控取向

日本姬路工大的川月喜弘等研究人员对光敏侧链型高分子液晶的光控取向进行了研究，通过使光敏性良好的β-（2－呋喃基丙烯）基与甲基丙烯系液晶聚合物支链端相结合，力图使光照能量大幅度降低，同时还研究了将烷基丙烯酸酯共聚制膜后，经偏振紫外光照射时，对液晶预倾角及耐热性方面所产生的影响，实验结果表明，具有β－（2－呋喃基丙烯）基的聚合物[Poly(MHFEB)]膜面只用以往具有苯乙烯基聚合物[Poly(MHCEB)]膜面的1／30光照射能量即可实现液晶取向功能，且聚倾角不依赖光能量的变化而变化，而依赖于侧链基成份含量而变化，此外，还显示出高耐热性。     

用线性偏振光聚合法制备LCD取向膜的研究

介绍用线性偏振光聚合法制备肉桂酸聚乙烯醇酯类液晶取向膜，用偏振红外光谱研究ＬＰＰ膜的各向异性和取向能力，以及其与光照时间的关系。并提出，用两片不同的ＬＰＰ取向膜能制备具有较在预倾角的液晶盒。     

Anisotropic thermal conductivity of nanoporous silica film

In this paper, thermal conductivity of porous silica film with porosity from 21 to 64% was studied comprehensively. The corresponded dielectric constant is from 2.5 to 1.5. It is observed that the porous silica material has strong anisotropic characteristic. A serial-parallel hybrid model is proposed to explain the correlation between porosity and thermal conductivity in both in-plane and cross-plane components. The pores in the higher porosity silica film tend to distribute horizontally. This distribution of the pores in the dielectric film is the main factor that induces the anisotropic characteristic. The nonuniform distribution of pores also makes the conventional two-dimensional model of 3u/spl grave/ method inappropriate for extracting the in-plane thermal conductivity. A new method based on the hybrid model was proposed to extract the in-plane thermal conductivity successfully. The anisotropic characteristic of the thermal conductivity may be accompanied by the anisotropic dielectric constant, which will greatly complicate the thermal management and resistance-capacitance delay simulation of the circuits and should be avoided. The proposed model would be helpful on evaluation of new porous low dielectric constant materials.     

Experimental measurement of the critical population inversion for the dye solution laser

The quenching of stimulated emission from organic dye solutions has previously been attributed to optical absorption by dye molecules in the metastable triplet state. By comparing the critical inversion expected for a dye laser with no triplet losses to that obtained from an analysis of the laser that includes the triplet-state loss, the magnitude of the optical loss due to the triplet state can be determined in terms of the absorption and emission spectra, fluorescence decay time, quantum yield, and laser wavelength for a given dye. Measurements of the critical inversion and triplet-state concentration for a flashlamp-excited laser are presented for the xanthene dyes acridine red, fluorescein disodium salt, rhodamine B, and rhodamine 6G. Experiments with 7-hydroxycoumarin were also performed but, due to lack of triplet-state absorption data, the triplet-state concentration could not be determined. It is possible from the measurements to conclude that triplet-state absorption is important in 7-hydroxycoumarin. The critical inversion is found to be approximately 10¹⁵cm^-3for the xanthenes. This value is, in all cases, many times larger than the critical inversion calculated in the absence of triplet losses.     

各向异性PDLC散射膜的特性研究

采用摩擦表面取向层的方法制备了有光学各向异性结构的ＰＤＬＣ膜。研究了液晶盒的厚度、摩擦强度,以及在紫外光诱导相分离过程中的光照强度对ＰＤＬＣ膜的光学各向异性程度和电光特性的影响。对ＰＤＬＣ的光学各向异性进行了研究,并给出了要获得低阈值电压、高各向异性的聚合物分散液晶各向异性膜的盒厚、摩擦强度以及光照度等条件。被取向后的ＰＤＬＣ各向异性膜可被用来作为具有很好光电特性的电可调散射式偏振片。     

IPS-LCD using a glass substrate and an anisotropic polymer film

A lightweight in-plane-switching liquid crystal display (IPS-LCD) using a single glass substrate and an anisotropic polymeric film is demonstrated. The liquid crystal molecules are aligned by the elongated polymer grain of the film. The alignment capability of the anisotropic film is comparable to a buffed polyimide layer. Compared to the LCD using two glass substrates, our new device exhibits a comparable contrast ratio (/spl sim/514:1), driving voltage, and response time because of good LC alignment. Such an anisotropic film can also function as a phase compensation film for widening the viewing angle. This technology is particularly attractive for making single-substrate displays and also has potential for a double-layered guest-host display and a flexible display using IPS LCDs.     

三维掩膜硅各向异性腐蚀工艺释放微悬空结构

提出了一种新颖的基于三维掩膜的硅各向异性腐蚀工艺,即利用深反应离子刻蚀、湿法腐蚀等常规体硅刻蚀工艺和氧化、化学气相沉积(CVD)等薄膜工艺制作出具有三维结构的氧化硅(SiO2)或氮化硅(Si3N4)薄膜,以该三维薄膜作为掩膜进行各向异性腐蚀,该工艺可以应用于MEMS微悬空结构的制作。利用该工艺成功地在单片n-Si(100)衬底上完成了一种十字梁结构的释放,并对腐蚀的过程和工艺参数进行了研究。     

Manufacturing of solder bumps with Cu/Ta/Cu as under bumpmetallurgy

This study investigated the feasibility of the multilayer Cu/Ta/Cu under bump metallurgy (UBM), deposited on AlN/Si where AlN is a thin film. An interdiffusion study found that Ta is an appropriate diffusion barrier layer for the investigated solder bump structure. The temperature profiles and the flux compositions for solder reflow were also investigated. The flux activators investigated include succinic acid, adipic acid, stearic acid, dimethylamine hydrochloride, and diethylamine hydrochloride. Among these, succinic acid was the most appropriate in terms of wetting and cleaning     

“集成电路工艺原理”课程中湿法腐蚀实验安排

为了形象演示"集成电路工艺原理"课程中的各向异性湿法腐蚀,笔者指导学生设计了一组(100)硅片上以SiO2正方薄膜为掩膜的腐蚀实验。学生自主配置KOH了溶液,改变水浴温度进行各向异性腐蚀实验,并利用金相显微镜对样品实时观察并测量。学生在动手过程中可以理解各向异性相关工艺,加强了教学效果。     

Plasma cleaning of the flex substrate for flip-chip bonding with anisotropic conductive adhesive film

Advanced integrated circuit packaging processes require good bondability and reliability between various mating surfaces. A key factor affecting this requirement is surface cleanliness. Plasma cleaning is the most suitable process for optimum surface cleanliness. An investigation of O₂, Ar, and O₂/SF₆ plasma cleaning was carried out on a flexible substrate to study the adhesion of anisotropic conductive adhesive film for flip chip bonding. Surface roughness was found to increase substantially after the plasma treatment. Adhesion strength was evaluated by 90° peeling tests both for untreated and plasma-treated flex. A higher adhesion strength of anisotropic conductive film (ACF) bond was observed after plasma cleaning. The surface morphology of plasma treated and untreated flex substrate before bonding, as well as the fracture surfaces after the peel test for both cases, was characterized by secondary electron image techniques of scanning electron microscopy (SEM). Based on the detailed SEM findings, extensive comparisons were made between the plasma treated and the untreated samples. Mechanical interlocking is found to be responsible for higher peel strength of the plasma treated flex bonding. It was also proposed to select the right flexible substrate for highly reliable, ACF bonded flip chip on flex substrate.     

单玻璃基板与各向异性聚合物膜的IPS-LCD的应用

介绍了一种使用单片玻璃基板和各向异性聚合物膜的轻型、共面转换液晶显示(IPS-LCD)技术。液晶分子由伸长的聚合物膜内的颗粒排列。各向异性聚合物膜的取向性能与聚酰亚胺(PI)摩擦层相当。良好的液晶取向性能使新器件的对比度(514:1)、驱动电压和响应时间都能够与双玻璃基板LCD相比拟。这种各向异性膜也能作为拓宽视角的相位补偿膜来使用。该技术特别引人注目之处在于制作单基板显示器,同时它也具有实现双层宾主显示和IPS-LCD柔性显示的潜在应用。