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微电子组装中Sn-Zn系无铅钎料的研究与开发 总被引:6,自引:3,他引:3
无铅钎料的研究开发是我国电子材料行业目前面临的紧迫课题.其中Sn-Zn系无铅钎料具有低的熔点,优良的力学性能,能获得可靠的钎焊接头,且其原材料丰富、价格便宜,有望替代Sn-Pb钎料.但该系钎料易氧化,抗腐蚀性较差,目前还未得到广泛的采用.介绍了开发新型无铅钎料应满足的要求,及几种有潜力的Sn-Zn系无铅钎料. 相似文献
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Sn-Zn系无铅钎料最新进展 总被引:1,自引:0,他引:1
Sn-Zn系钎料熔点与传统Sn-37Pb钎料十分接近,成本低廉,被研究者所推崇。由于Zn的存在导致Sn-Zn钎料润湿性差及抗氧化性不足,阻碍了该钎料的发展。添加合金元素和纳米颗粒是改善Sn-Zn钎料组织和性能行之有效的方法之一,为国内外研究者所推崇。结合国内外Sn-Zn系无铅钎料最新研究成果,探讨添加微量的合金元素In、Ni、Cr、Ga、Bi、Cu、Al、Ag、稀土元素及纳米颗粒对钎料润湿性、抗氧化性、力学性能、显微组织和界面组织的影响,同时简述有关钎剂对Sn-Zn的影响,并对Sn-Zn系钎料的发展趋势进行分析与展望。 相似文献
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无铅电子钎料合金蠕变性能研究 总被引:7,自引:0,他引:7
设计制作了一种简单可靠的弯折蠕变测量装置,比较了两种无铅电子钎料合金Sn-9Zn和Sn-3.5Cu-0.7Ag与传统电子钎料合金Sn-40Pb的常温蠕变性能,以及冷却条件对其蠕变强度的影响。结果表明:两种无铅钎料的抗蠕变性能大大优于传统锡铅钎料;Sn-3.5Ag-0.7Cu合金的抗蠕变性能优于Sn-9Zn合金;冷却速率对Sn-9Zn合金和Sn-3.5Ag-0.7Cu合金组织的影响类似,然而对蠕变强度的影响却相反:水冷使两种合金的组织相对于空冷都明显细化,Sn-9Zn合金的蠕变强度因之降低,而Sn-3.5Ag-0.7Cu合金的蠕变强度却因之提高。对可能产生的原因进行了讨论。 相似文献
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稀土改性的Sn-58Bi低温无铅钎料 总被引:1,自引:0,他引:1
研究了微量稀土对Sn-58Bi低温钎料的改性作用.试验添加质量分数为0.1 ?组混合稀土的无铅材料,并对比Sn-58Bi和Sn-58Bi0.5Ag合金.观察了钎料显微组织的变化并做了定量分析,采用DSC测试了钎料的熔化温度,同时测量了钎料的润湿性能、接头强度与硬度.结果表明,微量稀土添加细化了Sn-58Bi钎料合金的显微组织,对钎料的熔化温度几乎没有影响,能显著改善Sn-58Bi钎料的润湿性能和接头剪切强度,而且改善的程度优于添加微量Ag对Sn-58Bi钎料的作用. 相似文献
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无铅钎料对不锈钢的腐蚀性研究 总被引:2,自引:2,他引:0
相对于传统的Sn-Pb合金,无铅钎料在高温下对不锈钢的腐蚀性明显加强,从而造成波峰焊接设备的损坏。通过试验的方式,在450℃条件下将不锈钢材料、表面特殊氮化处理不锈钢、钛合金和铸铁浸入液态无铅钎料Sn-0.7Cu中720h,通过腐蚀界面的微观组织分析,研究了无铅钎料侵蚀不锈钢界面的机理以及几种材料的耐腐蚀性分析,从而为防止无铅钎料的腐蚀提供可靠的依据。 相似文献
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本文涵盖了自1995年至2005年所有涉及到无铅钎料的中国专利。报告的钎料范围是用于表面组装技术,有明确限定成分和成分质量比的Sn基无铅钎料(无铅焊料)。报告的主要内容包括无铅钎料专利的申请者情况及申请和授权情况;在申请专利钎料中Sn-Zn系、Sn-Ag系、Sn-Bi系和Sn-Cu系的数量分布情况以及钎料所含元素情况;国外申请者申请和授权情况;制备方法的情况。最后指出了我国的无铅钎料专利领域存在的问题和发展方向。 相似文献
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合金元素对Sn-Zn基无铅钎料高温抗氧化性的影响 总被引:27,自引:12,他引:15
研究了不同微量合金元素对Sn-Zn基无铅钎料高温抗氧化性的影响。钎料在液态下的表面颜色变化以及热重分析表明,Al、Cr能明显改善Sn-Zn基钎料的抗氧化性能。通过俄歇能谱深度剖析和X射线衍射分析探讨了合金元素的抗氧化机理:Al和Cr在钎料表面或亚表面富集,形成阻挡层,抑制了钎料的氧化。比较了合金元素对Sn-Zn基钎料润湿性能的影响,结果表明Al的加入不利于钎料的铺展。通过实验得出结论:Cr是一种比Al更具有吸引力的Sn-Zn基钎料的高温抗氧化合金元素。 相似文献
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Tao-Chih Chang Min-Hsiung Hon Moo-Chin Wang Dong-Yih Lin 《Advanced Packaging, IEEE Transactions on》2004,27(1):158-164
The effect of thermal cycling on the adhesion strength of the Sn-9Zn-xAg-Cu interface has been investigated by using pull-off tester, X-ray diffractometer, scanning electron microscope and energy dispersive spectrometer. The Sn-9Zn-xAg lead-free solders offer a better thermal cyclic resistance than the 63Sn-37Pb and Sn-9Zn solder alloys. The adhesion strength of the Sn-9Zn-Cu interface increases from 4.4 /spl plusmn/ 0.4 MPa to 13.8 /spl plusmn/ 0.9 MPa with increasing the thermal cycles from zero to three times but it decreases to 8.5 /spl plusmn/ 0.8 MPa for five cycles. The Sn-9Zn-xAg solder alloys (x=0.5, 2.5, and 3.5 wt%) have a similar tendency and the maximum adhesion strength of 21.41 /spl plusmn/ 1.5 MPa for the Sn-9Zn-2.5Ag solder alloy has been obtained after three thermal cycles. The adhesion strength of the Sn-9Zn-1.5Ag-Cu interface increases from 7.8 /spl plusmn/ 0.6 to 16.6 /spl plusmn/ 0.9 MPa with increasing the thermal cycles from 0 to 5 times. 相似文献
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The microstructures and mechanical properties of Sn-8.55Zn-xAg-0.45 Al-0.5Ga (wt.%) lead-free solders were investigated. The
x content of the solders investigated were 0.5–3.0 wt.%. The results indicate that Ag plays an important role not only in
the structure but also in the mechanically properties. The mechanical properties and differential scanning calorimetry (DSC)
behavior has been compared with that of 63Sn-37Pb solder. Small additions of Ag decreased the melting point of the Sn-8.55Zn-xAg-0.45Al-0.5Ga
solders while maintaining the same strength and ductility as the 63Sn-37Pb solder. 相似文献
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Dissolution behavior of Cu and Ag substrates in molten solders 总被引:1,自引:0,他引:1
This study investigated the dissolution behavior of Cu and Ag substrates in molten Sn, Sn-3.5Ag, Sn-4.0Ag-0.5Cu, Sn-8.6Zn
and Sn-8.55Zn-0.5Ag-0.1Al-0.5Ga lead-free solders as well as in Sn-37Pb solder for comparison at 300, 350, and 400°C. Results
show that Sn-Zn alloys have a substantially lower dissolution rate of both Cu and Ag substrates than the other solders. Differences
in interfacial intermetallic compounds formed during reaction and the morphology of these compounds strongly affected the
substrate dissolution behavior. Soldering temperature and the corresponding solubility limit of the substrate elements in
the liquid solder also played important roles in the interfacial morphology and dissolution rate of substrate. 相似文献
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Processing and creep properties of Sn-Cu composite solders with small amounts of nanosized Ag reinforcement additions 总被引:3,自引:0,他引:3
F. Tai F. Guo Z. D. Xia Y. P. Lei Y. F. Yan J. P. Liu Y. W. Shi 《Journal of Electronic Materials》2005,34(11):1357-1362
In this research, nanosized Ag reinforcement particles were incorporated by mechanical means into a promising lead-free solder,
Sn-0.7Cu, in an effort to improve the comprehensive property of the Sn-0.7Cu solder. Wettability, mechanical performance,
and creep-rupture life tests were conducted to study the difference between Sn-0.7Cu solder and its composite solder with
different Ag reinforcement volume fractions. Experimental results indicated that the composite solders and their joints showed
better wettability and mechanical properties, as well as longer creep-rupture lives, than Sn-0.7Cu solder. The composite solder
with 1vol.%Ag reinforcement addition exhibited the best comprehensive property as compared to the composite solders with other
reinforcement volume fractions. Systematic creep-rupture life tests were conducted on the 1vol.%Ag-reinforced Sn-0.7Cu-based
composite solder joints. Significant enhancement of the creep-rupture lives were found in the composite solder joints under
different stress and temperature combinations as compared to the Sn-0.7Cu solder joint. Ductile rupture surfaces were exhibited
in most of the broken solder joints. 相似文献
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采用悬滴法测量了3种无铅钎料合金(Sn-3.0Ag-0.5Cu、Sn-0.7Cu与Sn-9.0Zn)在260℃时的表面张力,分别为525.5,534.8和595.4 mN/m;同时采用座滴法测量了其在260℃熔融状态下与Cu基板的接触角,分别为24.5°、28.0°和102.5°,并且与传统Sn-37.0Pb钎料进行了比较研究。结果表明,无铅钎料合金的表面张力与接触角均大于Sn-37.0Pb钎料。结合Young-Dupre公式讨论了钎料合金表面张力与其润湿性能的相关性,认为Sn基钎料合金在Cu基板上的润湿性能主要取决于其表面张力。 相似文献
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The specific heat capacities (C
p) of Sn-Zn-based solders and Sn-Ag-Cu solders have been studied using differential scanning calorimetry. The procedure of
measuring the specific heat capacity followed the standard test method designed by the American Society for Testing and Materials
(ASTM) E1269-05. The results of this work are lists of specific heat capacities of Sn-9Zn, Sn-9Zn-xAg (x = 0.1, 0.5, 1, 2, and 3), Sn-9Zn-0.5Ag-yAl (y = 0.1, 0.2, and 0.5), Sn-9Zn-0.5Ag-yGa (y = 0.1, 0.2, and 0.5), Sn-8.5Zn-0.5Ag-0.01Al-0.1Ga, and Sn-zAg-0.5Cu (z = 1.0, 2.0, 3.0, and 3.5). The study also found that C
p increased with increasing heating temperature. Furthermore, the lead-free solders investigated have a higher specific heat
capacity than the traditional Sn-37Pb solder. Among the studied lead-free solders, Sn-3.5Ag-0.5Cu has the lowest C
p and Sn-9Zn-0.1Ag has the highest C
p. Increased silver content in the Sn-9Zn-xAg and Sn-xAg-0.5Cu solder alloys was also found to effectively lower their C
p. 相似文献
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无铅焊料在清华大学的研究与发展 总被引:2,自引:0,他引:2
清华大学材料科学与工程系电子材料与封装技术研究室研制了6个系列的无铅焊料:Sn-3.5Ag添加Cu或Bi; Sn-3.5Ag-1.0Cu添加In或Bi; Sn-Ag-Cu-In添加Bi; Sn-Ag-Cu添加Ga; Sn-Zn添加Ga; Sn-Zn添加多种元素。重点介绍了Sn-Zn添加多种元素。对6个系列无铅焊料的研究取得了较好的实验结果,得到比较理想的低温焊料体系,有的合金熔点已非常接近铅锡共晶焊料熔点183℃。 相似文献
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The microstructures and mechanical properties of Sn-8.55Zn-0.5Ag-0.45Al-yGa (wt.%) lead-free solders were investigated. The
y content of the solders investigated was 0.5–3.0 wt.%. The results indicate that Ga exhibits prominent influence in the microstructure
as well as mechanical properties of the solders. By increasing Ga, the fraction of the Sn/Zn eutectic region decreases and
the Sn-matrix region increases. An increase in the Ga content from 0.5 wt.% to 2.0 wt.% enhances the tensile strength while
degrading the ductility. The mechanical properties and differential scanning calorimetry (DSC) behavior have been compared
with that of the 63Sn-37Pb solder. Gallium lowers the melting point of the Sn-8.55Zn-0.5Ag-0.45Al-yGa solders. The Sn-8.55Zn-0.5Ag-0.45Al-0.5Ga
solders exhibit greater tensile strength and better ductility than the 63Sn-37Pb solder. 相似文献