Long-Term Tritium Transport through Field-Scale Compacted Soil Liner

A 13-year study of tritium transport through a field-scale earthen liner was conducted by the Illinois State Geological Survey to determine the long-term performance of compacted soil liners in limiting chemical transport. Two field-sampling procedures (pressure-vacuum lysimeter and core sampling) were used to determine the vertical tritium concentration profiles at different times and locations within the liner. Profiles determined by the two methods were similar and consistent. Analyses of the concentration profiles showed that the tritium concentration was relatively uniformly distributed horizontally at each sampling depth within the liner and thus there was no apparent preferential transport. A simple one-dimensional analytical solution to the advective–dispersive solute transport equation was used to model tritium transport through the liner. Modeling results showed that diffusion was the dominant contaminant transport mechanism. The measured tritium concentration profiles were accurately modeled with an effective diffusion coefficient of 6×10?4?mm2/s, which is in the middle of the range of values reported in the literature.     

Investigation of Consolidation-Induced Solute Transport. I: Effect of Consolidation on Transport Parameters

This paper presents an experimental investigation of the effect of clay consolidation on parameters that govern the advective-dispersive transport of an inorganic solute. Batch, diffusion, dispersion, and solute transport tests were conducted using kaolinite clay and dilute solutions of potassium bromide (KBr). Batch tests produced the highest levels of K+ sorption and indicated that equilibrium sorption was achieved in approximately 10–30 min. The increase in sorption observed in the batch tests, as compared to the dispersion or solute transport tests, reflects the significantly lower solids-to-solution ratio and more efficient mixing process. By comparison, kaolinite consolidation had little effect on sorption due to the relatively small change in porosity. Values of hydrodynamic dispersion coefficient (Dh), effective diffusion coefficient (D?), and apparent tortuosity factor decreased with decreasing porosity. Values of D? obtained for Br? were generally larger than for K+, whereas Dh values for Br? were significantly smaller than for K+. Values of longitudinal dispersivity (α) were larger for K+ than Br? and showed no clear trend with decreasing void ratio. In general, the experimental results suggest that changes in D? and Dh should be taken into account during clay consolidation whereas the sorption isotherm and α may be considered as unchanged during the consolidation process.     

Transit-Time Design for Diffusion through Composite Liners

Transit-time design methods are presented in this paper for determining the design thickness for composite liners consisting of a geomembrane and a compacted soil liner or geosynthetic clay liner. The design methods are based on a closed-form analytical solution for transient solute diffusion of volatile organic compounds in a composite liner and results from a numerical model. An analytical solution for diffusion in a two-layer soil profile, which is useful for transit-time design of composite liners, is also presented. The analytical solutions are used to develop graphical solution charts that can be used to design composite liners for which the effluent concentration and contaminant flux are less than a specified value. Design examples are included for a composite liner having a compacted soil liner and a composite liner having a geosynthetic clay liner. The method is relatively simple to apply and can be used for preliminary design of composite liners, evaluating experimental results, and verifying more complex numerical models.     

Optimal Design of a Compacted Soil Liner Containing Sorptive Amendments

The design of a compacted soil liner that includes sorptive amendments is presented and evaluated as a combinatorial optimization problem. An objective function based on the materials costs, opportunity costs, and construction costs of the liner was used to evaluate the effect of incorporating four sorptive materials: benzyltriethylammnonium-bentonite, hexadecyltrimethylammonium-bentonite, shale, and granular activated carbon (GAC) into a compacted clay liner in order to mitigate transport of organic solutes through the liner. The results from this study indicate that the inclusion of sorptive amendments as a component in compacted soil liners can effectively retard the transport of organic contaminants through the liner without violating regulatory hydraulic conductivity requirements. In all cases when aqueous transport was considered as a constraint in the objective function formulation, the resulting liner always contained some amount of sorptive amendment. In general, shale and GAC were selected for use in the sorptive liner design for all organic solutes tested. The modeling framework presented in this study is general and could be used to evaluate other types of sorptive materials or additional constraints, and thus represents a flexible new tool for the design of compacted soil liners.     

Diffusive Transport of Permanganate during In Situ Oxidation

The transport of permanganate in low permeability media (LPM) and its ability to degrade trichloroethylene (TCE) in situ were studied through diffusive transport experiments with intact soil cores. A transport cell was developed to measure the effective diffusion coefficient (Deff) of a Br? tracer through intact cores of silty clay LPM obtained from a field site and enable calculation of the apparent tortuosity (τa) of the medium. Then, 5000 mg?L?1 of KMnO4 was added to the cell and diffusive transport and soil matrix interactions were observed. After three months, the soil cores were dissected for morphologic examination and characterization of matrix ions, total organic carbon, MnO4?, and manganese oxides (MnO2). The experiment was then repeated after 2 μL of pure phase TCE were delivered into the center of each of two intact cores. Permanganate transport was observed for one month and then an extraction of the entire soil core was made to determine the extent of TCE degradation. This research demonstrated that permanganate can migrate by diffusion and yield reactive zones that can be predicted based on the properties of the LPM and the oxidant source. Under the experimental conditions examined, permanganate had little effect on the LPM’s pore structure or continuity, and appreciable soil organic matter remained even after 40–60 days of exposure to the oxidant. MnO2 solids, an oxidation by-product, were observed in the LPM, but not at levels sufficient to cause pore filling or alter the apparent matrix tortuosity, even when TCE was present. During diffusive transport of permanganate, TCE in the silty clay LPM was degraded by 97%.     

Flow of Gasoline through Composite Liners

A composite liner composed of a soil/clay liner and a flexible membrane is widely used for waste containment facilities. In this research, an organically modified clay (organoclay BB-40) liner and a high-density polyethylene (HDPE) membrane were studied for preventing the leakage and migration of gasoline from underground storage tanks into the surrounding environment. The equivalent hydraulic conductivity of intact HDPE to gasoline was determined using a specially built system, and the conventional hydraulic conductivity testing method was employed to determine the hydraulic conductivity of compacted organoclays and the permeation rate of gasoline through composite liners. The equivalent hydraulic conductivity of intact HDPE to gasoline was about 10–13 cm/s, and the hydraulic conductivity of the organoclay liner was approximately 6.0×10?9?cm/s, which is nearly 4 orders of magnitude lower than that obtained for unmodified clay. These results show that both organoclay and HDPE are effective in reducing the release of gasoline by advective flow, especially the intact HDPE. The flow of gasoline through the composite liners under the worst condition, was of the same magnitude as that through a single organoclay liner, independent of the flow shape. It can be anticipated that under good contact conditions, the defective HDPE would still be beneficial in reducing the permeation of gasoline due to the decrease of the wetted area of the underlying layer exposed to gasoline leakage.     

Shallow Subsurface Characterization of Gas Transport in a Playa Wetland

Controls on vadose-zone gas transport beneath and adjacent to a southern High Plains ephemeral lake (playa) were investigated. Under dry conditions, vertical gas permeability and tortuosity were enhanced by cracks and root tubules in the upper 2.5 m. Below this depth, the horizontal components of both permeability and tortuosity tensors were dominant. Both atmospheric pumping and pneumatic tests were used to determine the gas permeability tensor; whereas gas tracer tests were used to estimate the tortuosity tensor. The field data were elevated in a multilayer numerical model. The results suggest that gas movement can be dominated by both advection and diffusion, with vertical movement dominating in the shallow zone under dry conditions. After a large precipitation event, vertical gas permeability was reduced and large pressure differentials (as high as 1.5 kPa) were produced, creating driving forces for advective gas transport.     

Comparison of Solute Transport in Three Composite Liners

Three composite landfill liners were compared in this study based on leakage rate, mass flux, and sorptive capacity. One composite liner consisted of a geomembrane and a geosynthetic clay liner (GCL). The other two had a geomembrane and a thicker soil barrier (61 or 122 cm). The analyses employed one- and three-dimensional numerical models that were developed for analyzing contaminant transport through defects in the geomembrane component of composite liners and diffusion of volatile organic compounds through intact composite liners (i.e., composite liners without holes in the geomembrane). Cadmium was used to represent inorganic leachate constituents and toluene was used to represent organic leachate constituents. The composite liner, having a GCL had the lowest leakage rate of the three composite liners. For cadmium, the mass flow rate and sorptive capacity for the three composite liners varied within an order of magnitude. However, for toluene, the mass flux from the GCL composite liner was two to three orders of magnitude greater than that through composite liners having a thicker soil liner. Additionally, for leachate having similar concentrations of cadmium and toluene, the mass flux of toluene can be as much as seven orders of magnitude greater than that for cadmium. For toluene, the sorptive capacity of thicker liners was an order of magnitude greater than that for the GCL composite liner. Similar behavior is expected for other inorganic and organic solutes.     

Investigation of Consolidation-Induced Solute Transport. II: Experimental and Numerical Results

This paper presents an experimental and numerical investigation of consolidation-induced solute transport. Diffusion and large strain consolidation tests were performed on composite specimens of kaolinite clay consisting of an upper uncontaminated layer and a lower layer contaminated with potassium bromide. Experimental measurements of effluent concentration, solute mass outflow, and final concentration profiles were obtained for a variety of initial, boundary, and loading conditions, including unload/reload. Numerical simulations were conducted using a computational model in which solute transport occurs by advection, dispersion, and sorption and is consistent with temporal and spatial variations of porosity and seepage velocity in the consolidating layer. Large strains were taken into account as well as variation of effective diffusion coefficient with porosity and nonlinear nonequilibrium sorption effects. The numerical simulations are in good to excellent agreement with the experimental measurements. Results indicate that, depending on conditions, diffusion and consolidation-induced advection can make important contributions to solute transport and mass outflow. Thus, both mechanisms should be considered for transport analyses involving soft contaminated clays undergoing large volume change. Results also indicate that nonequilibrium sorption effects were not significant for the materials and test conditions used in this study.     

Analytical Solutions for Contaminant Diffusion in Double-Layered Porous Media

Analytical solutions for conservative solute diffusion in one-dimensional double-layered porous media are presented in this paper. These solutions are applicable to various combinations of fixed solute concentration and zero-flux boundary conditions (BC) applied at each end of a finite one-dimensional domain and can consider arbitrary initial solute concentration distributions throughout the media. Several analytical solutions based on several initial and BCs are presented based on typical contaminant transport problems found in geoenvironmental engineering including (1) leachate diffusion in a compacted clay liner (CCL) and an underlying stratum; (2) contaminant removal from soil layers; and (3) contaminant diffusion in a capping layer and underlying contaminated sediments. The analytical solutions are verified against numerical solutions from a finite-element method based model. Problems related to leachate transport in a CCL and an underlying stratum of a landfill and contaminant transport through a capping layer over contaminated sediments are then investigated, and the suitable definition of the average degree of diffusion is considered.     

Coupled Large Strain Consolidation and Solute Transport. II: Model Verification and Simulation Results

The results of numerical simulations for coupled large strain consolidation and solute transport, obtained using the CST1 model, are presented. CST1 accounts for advection, longitudinal and transverse dispersion, first-order decay reactions, and linear equilibrium sorption. Verification checks of CST1 show excellent agreement with analytical solutions for one-dimensional (1D) transport in rigid porous media, including various Peclet numbers and concentration boundary conditions. Similarly excellent agreement is observed for two-dimensional advection-dispersion transport in rigid media and 1D advection-dispersion transport in compressible media undergoing large strain consolidation. CST1 is then used to investigate consolidation-induced solute transport for a single composite liner system and a confined disposal facility for dredged contaminated sediments. In both cases, solute transport was found to be strongly affected by consolidation-induced advection both during and after the consolidation period. Consolidation has a lasting effect on solute migration because transient advective flows change the distribution of solute mass, which then becomes the initial condition for subsequent transport processes.     

Comparison of SF6 and Fluorescein as Tracers for Measuring Transport Processes in a Large Tidal River

We present the first large-scale comparison of a fluorescent dye [fluorescein (C20H10O5Na2)] and a gas [sulfur hexafluoride (SF6)] as tracers of advection and longitudinal dispersion from a dual tracer release experiment conducted in the tidal Hudson River. At the beginning of the experiment, 36?kg of fluorescein and ～ 4.3?mol of SF6 were injected into the Hudson River at an averaged depth of 9.5?m, ～ 1?m above the bottom, near Hyde Park, N.Y. After injection, fluorescein distributions were surveyed for 4 days (until it became undetectable) and SF6 distributions were surveyed for 10 days. The dye resolves initial vertical mixing on the day of injection, and then net advection and longitudinal dispersion, whereas SF6 provides information on net advection and longitudinal mixing on larger spatial scales and longer time scales. Quantitative estimates of transport processes (net advection and longitudinal dispersion) calculated from the two methods are consistent for the first three days, and start to deviate on the fourth day when the signal-to-noise ratio of the dye deteriorated.     

Metal Transport Parameters of a Gneiss Saprolitic Silty Soil for Liner Design

Diffusion coefficients and retardation factors of two metal cations (Cd2+ and Pb2+) were measured for a compacted Brazilian saprolitic soil derived from gneiss, aiming to assess its geoenvironmental performance as a liner for waste disposal sites. This soil occurs extensively all over the country in very thick layers, but has not been used in liners because of its hydraulic conductivity, higher than 10?9?m/s when compacted at optimum water content of standard Proctor energy, but which can be reduced by means of appropriate compaction techniques or additives. Batch, column, and diffusion tests were carried out with monospecies synthetic solutions at pH 1, 3, and 5.5. Measured diffusion coefficients varied between 0.5 and 4×10?10?m2/s. Retardation factors show that cadmium, a very mobile cation, is not adsorbed at pH 1 but is significantly retained at pH 3 and pH 5.5, whereas lead is retained at all tested pH values though slightly at pH 1. Estimated retardation factors from batch tests were 1.3–2.3 times those resulting from column tests and at its highest when obtained by diffusion tests; whereas batch tests allow a more complete exposure of the soil grains to the solution, time-dependent nonspecific adsorption may take longer to occur. The importance of contact time was observed and should be considered in further investigations. Its significant retention of metals suggests a promising utilization of this soil as a bottom liner for wastes landfills.     

Predicting Leakage through Composite Landfill Liners

Leakage through composite landfill liners having various characteristics was analyzed using existing analytical and numerical models developed for the study. Three-dimensional numerical models were used to analyze leakage through circular defects and two-dimensional numerical models were used to analyze leakage from defective seams. Leakage rates predicted with the numerical models were compared to leakage rates predicted using existing equations and analytical models currently being used. These comparisons show that existing equations and analytical models all have limitations and no universal equation or method is available for predicting leakage rates. To overcome some of the deficiencies in the existing equations and models, new equations were developed based on results from the numerical models. Recommendations are made for using the new equations, existing equations, and analytical models to predict leakage rates in thick composite liners having a geomembrane overlaying a compacted soil liner and thin composite liners having a geomembrane overlaying a geosynthetic clay liner.     

Volatile Organic Compound (VOC) Transport through Compacted Clay

Movement of volatile organic compounds (VOCs) through compacted clay liners was investigated using laboratory-scale column and tank tests. Hydraulic conductivity of the compacted clay was not significantly impacted by the introduction of VOCs in concentrations up to 20 mg∕L. Soil-water partition coefficients of the seven VOCs tested had a strong logarithmic relationship with the octanol-water partition coefficient. Partition coefficients from batch tests were in good agreement with those measured directly on soil samples at the termination of the column∕tank tests. The VOCs were degraded in the clay, with estimated half-lives ranging from 2 to 116 days. Mechanical dispersion was not significant in the range of the hydraulic conductivities of the test specimens (i.e., <10?7 cm∕s). Effective molecular diffusion coefficients were mostly in 10?6 cm2∕s and generally decreased with increasing aqueous solubility. Mass transport parameters of VOCs in clay liners can be estimated from laboratory batch tests and properly prepared small-scale column tests. However, accounting for degradation of VOCs and minimizing the number of transport parameters that are simultaneously estimated from a single response-time record are important considerations for accurate determination of transport parameters.     

Numerical Characterization of Advective Gas Flow through GM/GCL Composite Liners Having a Circular Defect in the Geomembrane

Numerical experiments were conducted to understand the effect of geometric and transport characteristics of a geomembrane-geosynthetic clay liner (GM/GCL) composite liner on gas leakage rate through a circular defect in the geomembrane (GM). The originality of the approach proposed in this paper rests on the use of a new conceptual two-layered system for modeling of GM/GCL composite liners where the interface zone between the GM and geosynthetic clay liner (GCL) has been merged with the GCL cover geotextile and handled as one layer; the GCL bentonite layer was considered the second layer. The role of the carrier geotextile layer was ignored since it can be considered as a no pressure loss layer. Analysis of numerical simulation results shows the existence of a constitutive leakage flow surface which enables evaluation of the leakage flow state for different geometric and transport properties of GM/GCL composite liners. Furthermore, the determined surface was also exploited to evaluate gas leakage rates under the framework of the Forchheimer’s analytical solution. The gas leakage rate predictions were found to be in good agreement with experimental results obtained at different GCL moisture content.     

Finite Difference Method for Computation of 1D Pollutant Migration through Saturated Homogeneous Soil Media

The physical processes such as advection, dispersion, and diffusion and interaction between the solution and the soil solids such as sorption, biodegradation, and retention processes have been considered in the governing equation used in the present study. Finite difference method has been adopted herein to solve the one-dimensional contaminant transport model to predict the pollutant migration through soil in waste landfill. In the finite difference technique, the velocity field is first determined within a hydrologic system, and these velocities are then used to calculate the rate of contaminant migration by solving the governing equation. A total of seven contaminants have been chosen for analysis to represent a wide variety of wastes both organic and inorganic. A computer software CONTAMINATE has been developed for solution of the contaminant transport model. Results of this study have been compared with existing analytical solution for validation of the proposed solution technique. Design charts for liners have also been developed to facilitate the designers. The liner thickness has been optimized by considering the effect of velocity of advection, dispersion coefficient, and geochemical reactions for all the contaminants of this study.     

Gas Transport Parameters for Compacted Reddish-Brown Soil in Sri Lankan Landfill Final Cover

Gas exchange through the compacted final cover soil at landfill sites plays a vital role for emission, fate, and transport of toxic landfill gases. This study involved measuring the soil-gas diffusivity (Dp/Do, the ratio of gas diffusion coefficients in soil and free air) and air permeability (ka) for differently compacted soil samples (reddish-brown soil) from the final cover at the Maharagama landfill in Sri Lanka. The samples were prepared by either standard Proctor compaction or hand compaction to dry bulk densities of 1.60–1.94??g?cm-3. Existing and modified models for predicting Dp/Do and ka were tested against the measured data. The simple, single-parameter Buckingham model predicted measured Dp/Do values across compaction levels equally well or better than a dry bulk density (DBD) dependent model and a soil-water retention (SWR) dependent model. The measured ka values for differently compacted samples were highly affected by the compaction level and the sample moisture preparation method. Also, for air permeability, a single-parameter Buckingham-type ka model was most accurate in predicting ka in the differently compacted soil samples. Equivalent air-filled pore diameters (the effective diameter of the drained pores active in leading air through the sample) for gas flow, deq, were calculated from the measured Dp/D0 and ka values. The deq increased with compaction level, suggesting that a very high compaction level creates well-connected macropores in the reduced total pore space of the cover soil. This is an important consideration when designing cover soils for optimally low water and high oxygen exchange while minimizing climate and toxic gas emissions from the waste layer to the atmosphere.     

Coupled Consolidation and Contaminant Transport in Compressible Porous Media

This paper presents an experimental and numerical investigation of coupled consolidation and contaminant transport in compressible porous media. Numerical simulations were performed using the CST2 computational model, in which a dual-Lagrangian framework is used to separately follow the motions of fluid and solid phases during consolidation. Diffusion and large strain consolidation-induced transport tests were conducted on composite specimens of kaolinite slurry consisting of an upper uncontaminated layer and a lower layer contaminated with potassium bromide. Assessment of the importance of the consolidation process on solute transport is based on measured and simulated solute breakthrough curves and final contaminant concentration profiles. CST2 simulations closely match the experimental data for three different loading conditions. Diffusion and consolidation-induced advection made important contributions to solute transport and mass outflow in this study. Additional simulations indicate that consolidation-induced contaminant transport may also be affected by specimen boundary drainage and initial concentration conditions.     

Animal Waste Containment in Anaerobic Lagoons Lined with Compacted Clays

The practice of animal waste containment has recently drawn much interest from public and regulatory agencies in agriculture-oriented states such as Kansas and North Carolina. In this paper, the debate surrounding the practice is outlined, and results from a research investigation pertinent to the state of Kansas are presented. The research investigation involved two phases. In the first phase, compacted specimens of Kansas soils were tested with animal waste as the influent. The key objective of this phase of research was to assess the range of seepage quantities and the transport characteristics of nitrogen in the ammonium form (NH4-N) through the compacted soils. Results from this phase indicated a steady increase of microbial counts in the liquid effluent. However, biological clogging did not appear to be prominent during the NH4-N breakthrough time period. The results indicate significant differences in microbial uptake of NH4-N among samples of the same soil type. In the second phase, analytical and numerical solutions were used to simulate ammonium transport in the field-scale liners and to estimate upper-bound travel times and final concentrations of NH4-N in the underlying soils. Results from this phase showed drastic differences in travel times and end concentrations of NH4-N among liners prepared from the same soil type. The potential for significant retardation, decay, and saturation levels of NH4-N in clay liners suggests that liner thickness is an important parameter. It is concluded that mass transfer characteristics of liner material, cation exchange capacity and microbial uptake in particular, should be important considerations in the design of animal waste lagoon liners.