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以LaCl_3·6H_2O和H_2C_2O_4·2H_2O为原料,用室温固相化学反应首先合成出前驱物草酸镧,经750℃分解3h,得到产物纳米氧化镧。用X-射线粉末衍射和透射电镜对产物的组成、大小、形貌进行表征。结果表明:纳米氧化镧为粒度分布均匀的长方体形结构,平均粒径12nm。并考察了表面活性剂对粒径大小和分散性的影响。 相似文献
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Li Wei Zhang Lili Yang Xujie Lu Lude Wang Xin 《中国稀土学报(英文版)》2006,24(5):573-573
A series of uhrafine K2Ln2Ti3O10(Ln = La, Ce, Pr, Nd, Sm, Eu, Dy)photocatalyst was prepared by microemulsion method based on tetrabutyl titanate reacting with potassium hydroxide and lanthanumoxide. The obtained products were characterized by XRD, TEM and UV-Vis spectra. These results indieate that highly ultrafine K2Ln2Ti3O10 can be accessible at lower fabricating temperature and shorter reation time by this approach. In addition, the investigation on their eatalytieal behavior based on the degradation of methyl orange under UV-Vis light suggests that the degradation rate can reach up to 60%. 相似文献
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In this paper,various techniques including BET,XRD,SEM and XPS were used to study the sintering ofpure and La_2O_3-doped titania.The experimental results show that sintering of titania proceeds via volume diffu-sion.Adding of lanthanum oxide decreases the rate of sintering and hinders the phase transition from anatase torutile crystal by strong surface interaction between the mixed crystals(La_4Ti_9O_(24),La_(0.66)TiO_(2.99))and TiO_2. 相似文献
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《中国稀土学报(英文版)》2020,38(3):281-291
Greener synthesis of ionic liquid(IL) assisted lanthanum oxide(La_2O_3) nanoparticles(NPs) was followed using Andrographis paniculata leaves extract by hydrothermal method at low temperature,The IL assisted La_2O_3(La_2O_3-IL) NPs were characterized by various properties such as structural,spectral,optical,morphological,and biological studies.Powder X-ray diffraction studies confirm that La_2O_3-IL NPs crystallize in the form of body-centered cubic structure and average crystalline size is shown-43 nm.FTIR and Laser Raman spectroscopy confirm the La-O,O-H and various functional groups.The La-O stretching vibration band attributes at 639 cm~(-1).The optical property of La_2O_3-IL NPs was characterized by UV-Vis and photo luminesce nce spectroscopy.The sharp and intense absorbance peak observed in the UV region at 288 nm can be assigned.In the PL spectrum,we observe two different emission bands like blue and green emission.The morphological and particle size determination were investigated by SEM with EDX spectra and TEM analyses.The agglomerated particles of hexagonal,spherical,and parallelogram shape are observed in the TEM images.The chemical elements,binding energies as well as La metal states on the surface of these synthesized NPs were determined using XPS.La_2O_3 NPs for good biological activities regarding antibacterial and anti-inflammatory potentials could be utilized in different biological applications to the food and biomedical industries.La_2O_3-IL has a high percentage of inhibitions than La_2O_3 and standard diclofenac. 相似文献
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In the attempt to reduce surface free energy of silica to improve interaction of silica with silver, silica was doped by different amounts of low surface energy lanthanum, La_2O_3, through impregnation. The doped and undoped silica were used as supports for preparation of Na/Ag/Mo/La_2O_3-SiO_2 catalysts. Catalytic performances of the catalysts were evaluated in direct epoxidation of propylene(DPO) using molecular oxygen under atmospheric pressure and without adding hydrogen. Adding 5 wt%La to the Na/Ag/Mo/SiO_2 catalyst improves both the catalysts electivity in DPO and its stability over 20h of time-on-stream.The characterization results show that La_2O_3 species interact strongly with silver particles on the silica surface which result in significant improvement in the dispersion profile of silver and marked decrease in the size of silver nanoparticles(AgNPs). The estimated mean diameter of AgNPs is ca. 4.0 nm in Na/Ag/Mo/5 wt%La_2O_3-SiO_2, which is smaller than that(53.9 nm) found in Na/Ag/SiO_2. The presence of subnanometer AgNPs on Ag/La_2O_3-SiO_2 prior addition of MoO_3 and NaCl to the sample can enhance the mutual electronic synergism between Ag, MoO_3 and Na for selective production of propylene oxide. 相似文献
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采用熔盐电解法研究了La2O3电脱氧反应过程。由电位阶越实验及取样电流电位分析和对电解产物进行X衍射分析表明La2O3的电脱氧反应是可以进行的,La2O3得电子还原为低价脱氧产物LaO,接着LaO作为中间产物与阳极气体Cl结合生成氯氧镧。 相似文献
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用溶胶-凝胶法制备了复合光催化剂CdS/TiO2和CdS/Eu3+-TiO2。利用XRD、UV-Vis漫反射光谱对样品进行了表征。以可见光分解水制氢为探针反应考察了催化剂的活性。结果发现Eu3+掺杂TiO2后抑制了TiO2晶粒生长,提高了光生电子和空穴的分离,从而提高了复合光催化剂的活性。 相似文献
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《中国稀土学报(英文版)》2017,(11)
14%REO_x-2.5%La_2 O_3-33.5%ZrO_2-50%Al_2 O_3(RE = Ce, Y, Pr) composites were prepared by a coprecipitation method. The Pd catalysts were obtained by an aqueous solution of Pd(NO_3)_2 loaded on the rare earths modified composites with an initial wet impregnated method. The experiment results show that catalytic activity of the rare earths modified Pd/La_2 O_3-ZrO_2-Al_2 O_3 catalysts is better than bare sample for methane oxidation. The structural characterization results reveal that the rare earths modified Pd catalysts increase amounts of surface active oxygen species by X-ray photoelectron spectroscopy(XPS) analysis and improve the dispersion of active component from H2-temperature programmed reduction(H2-TPR) measurement compared with bare sample. Especially,Pd/14%Y_2 O_3-2.5%La_2 O_3-33.5%ZrO_2-50%Al_2 O_3 sample exhibits highly active stability, it is related to the Pd particles highly dispersion,which was observed by transmission electron microscope(TEM) images. 相似文献
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Photocatalystic Oxidation Degradation of Polyethylene by Nano-TiO_2 Doped Rare Earth Ion 相似文献
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《中国稀土学报(英文版)》2020,38(2):195-202
Corundum porous materials of particle-packing type with different contents of in situ formed LaAl_(11)O_(18)were prepared using tabular corundum,reactive alumina and La_2O_3 powder as raw materials.The effects of the introduction of LaAl_(11)O_(18) on the microstructure.phase composition and properties of the porous materials were investigated.The specimens were characterized by scanning electron microscopy.X-ray diffraction and mercury porosimetry.Results show that platelet-like LaAl_(11)O_(18) is formed in situ by the reactions of La_2O_3 and Al_2O_3.With a certain amount of La_2O_3 added.the cold crushing strength,cold modulus of rupture and hot modulus of rupture(1400 x 0.5 h) of the specimens are increased,and the air permeability is improved simultaneously.However.upon further increasing the amount of La_2O_3 added,the mechanical properties and air permeability of the porous materials then decrease gradually owing to the increased numbers of pores and cracks in the bonding phase.The enhanced mechanical properties of the specimens with La_2O_3 added are attributed to the strengthening effects of plate-like LaAl_(11)O_(18) in the bonding phase and to the activated sintering of both Al_2O_3 powder and corundum coarse aggregate for the diffusion of La~(3+)in Al_2O_3 lattice.In addition,the improved air permeability of the specimens should be related to the decreased content of pores in the bonding phase and the reduced number of interfacial cracks. 相似文献
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采用正交设计优化法研究了硫酸 焦硫酸钾湿法熔融(化学法)分解碳氮化钛,以较少的实验次数确定了蒸馏分离和试样分解的最佳分析条件,通过条件实验,建立了相应的分析方法,测定结果与惰气熔融热导法一致。 相似文献
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《中国稀土学报(英文版)》2020,38(1):100-107
The lack of thermodynamic information,such as primary phase fields and liquidus temperatures,in the CaO-SiO_2-Nb_2O_5-La_2O_3 quaternary system phase diagram has restricted the comprehensive utilization of the niobium(Nb) and rare earth(RE) resources.In this work,the phase equilibria in low basicity region(w(CaO)/w(SiO_2)1) of CaO-SiO_2-Nb_2O_5-(0-15 wt%)La_2O_3 system at 1373-1873 K were experimentally studied by thermodynamic equilibrium experiment,and then,the results were analyzed by X-ray diffraction(XRD),scanning electron microscopy(SEM),and energy dispersive spectrometry(EDS).Additionally,an optimized method was proposed to process the compositions of equilibrium liquid phases at different temperatures.According to the experimental results,the univariate line between CaNb_2O_6,SiO_2 and LaNbO_4 primary phase fields,interface between CaNb_2O_6 and SiO_2 primary phase fields and isothermal liquidus surfaces in SiO_2 primary phase field were determined.Finally,the spatial phase diagram of CaO-SiO_2-Nb_2O_5-La_2O_3 within specific region was constructed,and furthermore,the phase diagram was also presented in CaO-SiO_2-Nb_2O_5 pseudo-ternary system with w(La_2O_3)=5 wt%,10 wt% and 15 wt%.The research results have guiding significance for the improvement of related phase diagram and the comprehensive utilization of Nb and RE resources. 相似文献
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This article describes kinetic modeling of titania reduction and carburization by methane-containing gas, based on experimental
data reported previously by Zhang and Ostrovski. A sequence of titania reduction to titanium oxycarbide,
which was observed experimentally, is represented by the following two reactions:
where ss designates a solid solution and f is the molar fraction of TiC in the solid solution. A two-interface shrinking-core model and a crackling-core model are employed
for the kinetic modeling of the reduction and carburization process. The rates of Reactions [1] and [2] are both controlled
by the chemical-reaction stage. For the intrinsic chemical-reaction control, the extent of the reaction as a function of reaction
time is well described analytically. The two models give close results that are consistent with experimental data obtained
at 1473 to 1773 K and a methane partial pressure up to 8 kPa. Reaction [1] is of the first order with respect to methane and
of one-half to first order with respect to hydrogen. The apparent activation energy of reaction [1] is 124 kJ/mol for the
two-interface shrinking-core model and 126 kJ/mol for the crackling-core model. Reaction [2] is of the first order with respect
to methane and is independent of hydrogen concentration. Nevertheless, hydrogen plays an important role in the reduction/carburization
process, as it suppresses the decomposition of methane and deposition of solid carbon. The apparent activation energy of the
reaction is 161 kJ/mol for the two-interface shrinking-core model and 191 kJ/mol for the crackling-core model. 相似文献
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A Study on La_2O_3-Y_2O_3-Mo Secondary Emission Material 总被引:1,自引:0,他引:1
Thephenomena ,mechanismandtheapplicationofsecondaryemissionofmanykindsofmaterialshavebeenstudiedsincethesecondaryemissionphenomenawasdiscoveredbyCompellin 1899.Withthedevel opmentofelectronictechnologythephenomenaofsec ondaryemissionhavebeenincreasinglyappliedinmanyfields[1,2 ] ,especiallyinhighpowermagnetrontube .Nowadays ,thecathodesofhighpowermag netrontubeusedinthefieldsofbroadcast,correspon denceandnationaldefensearemainlyBa Wcath odes[3] andsomeTh Wcathodes .However ,Ba Wcathodeishard… 相似文献