喷射成形高硅铝合金填补国内空白

国内材料学科研究十余年的新型电子封装材料——喷射成形高硅铝合金，现已走出实验室，实现产业化。率先迈出这一步是位于国家级镇江经济技术开发区的江苏豪然喷射成形合金有限公司：     

快速凝固硅铝合金材料的组织与性能

为了探究硅铝合金材料应用需求,采取热压致密化和喷射成形法,制备硅铝合金,并利用热膨胀仪、金相显微镜等设备对材料的热物理性能、力学性能及显微组织进行研究。结果发现,在铝基体中分布较为均匀、弥散;热压致密化能够改善喷射成形存在的弊端,促进材料致密度的提升,材料具备良好的力学及物理性能。     

喷射成形过共晶AlSiFeCuMgRE合金的性能

喷射成形技术是在传统快速凝固/粉末冶金工艺基础上发展起来的一种全新的材料制备、成形与加工技术,用喷射成形技术来制备过共晶铝硅合金可有效改善合金的组织和性能.本文在低真空下用氮气作为雾化介质制备过共晶AlSiFeCuMgRE合金沉积坯,通过热挤压对其进行致密化,并利用时效工艺对挤压坯进行热处理,研究了不同状态合金材料的性能.     

新型高硅铝合金电子封装复合材料的研究进展

微电子集成技术的快速发展对封装材料提出了更高的要求。具有低膨胀系数、轻质化、较高导热率的新型Al-Si复合材料受到了广泛的重视。文章详细介绍了高硅铝合金电子封装材料的性能特点、制备方法以及研究现状，指出了高硅铝合金电子封装材料的发展方向。     

喷射成形制备Al-Zn-Mg-Cu系高强高韧铝合金的研究

采用喷射成形技术制备了Al Zn Mg Cu系高强高韧铝合金 ,对喷射成形工艺参数进行了优化 ,对沉积坯件的热挤压工艺、热处理工艺进行了探索 ,对材料的组织进行了分析并对不同状态的材料性能进行了比较。结果表明 :当喷射成形工艺参数合理时 ,沉积坯件具有良好的成形性与致密度 ,在随后的热挤压过程中 ,通过较低的挤压比即可使材料达到全致密 ;沉积坯件热挤压温度的降低有利于使材料获得更高的力学性能 ;同时 ,通过对合金热处理的优化 ,可以获得加工和使用性能更加优良的Al Zn Mg Cu系高强高韧铝合金材料     

喷射成形7055铝合金搅拌摩擦焊的焊缝组织与力学性能

采用全自动控制的往复喷射成形工艺批量生产大规格的7055铝合金锭坯,对喷射成形7055铝合金板材进行搅拌摩擦焊.通过对搅拌摩擦焊塑性连接时的焊缝成形、焊缝组织及力学性能进行研究,实验结果证实:用搅拌摩擦焊焊接4mm厚的7055铝合金板材,选用合适的工艺参数,可获得外形美观、组织无缺陷、无变形的焊缝.焊缝各区域的组织有明...     

喷射成形钛铝合金的研究

喷射成形是一种快速凝固近终成形材料制坯技术，利用该技术制备的材料具有优异的性能，喷射成形技术产品在特定的领域正在逐步取代一些传统材料。简要阐述了喷射成形技术制备钛铝合金的研究发展现状，并指出制备喷射成形钛铝合金未来的方向。     

铝及铝合金电镀研究进展

铝及铝合金电镀层具有优良的防腐性能及装饰性能,广泛应用金属防护和表面装饰等领域。本文针对铝和铝合金电镀研究及发展状况,在电镀基体、电镀层成分、电镀体系、电镀添加剂等几个方面进行文献综述,其中主要对熔盐电镀金属铝及合金的发展作重点论述,并对近年来发展的一些新的电镀技术进行了介绍。本文在文献综述的基础上,结合我们在熔盐电镀领域的研究经验,对熔盐电镀铝的方法及研究成果进行分析总结,旨在推动铝与铝合金电镀技术的发展。     

豪然喷射成形7055铝合金顺利通过超强抗弹性测试

正6月22日,江苏豪然喷射成形合金有限公司采用喷射成型工艺生产的15mm和13mm厚的7055铝合金板材顺利通过抗弹性测试。喷射成形7055铝合金装甲板具有良好的机械加工性能,可以在7055铝合金装甲板上钻孔攻丝,实现披挂装甲或其零部件与装甲板的连接。此外,喷射成形7055铝合金装甲板强度可以达700兆帕级,不需镶嵌钢质螺套,自身的强度就可以满钻孔攻丝实现与其他零部件连接的目的;还可以采用焊接、铆接等多种方法进行拼接,也可以进折弯、变形加工。喷     

喷射成形工艺的发展现状及其对先进铝合金产业的影响

对喷射成形技术的发展现状及其对先进铝合金产业结构的影响作了综述和分析。认为喷射成形工艺是一种新型的快速凝固近形材料制备方法,其产品具有组织精细、合金含量高、力学性能优越、生产效率高、产品规格大的优点,填补了传统铸造和粉末冶金工艺的产品空白,将对铝合金性能升级和产业结构产生深远影响,推动我国先进铝合金产业的发展。     

Si-Al合金电子封装材料性能及显微组织研究

采用热压烧结法制备了70%Si-Al和90%Si-Al两种合金,测量了两种合金的典型热性能和力学性能,并观察和对比了两种合金的显微组织。结果表明:随着Si含量从70%升高到90%,在各测量温度下,合金材料的线膨胀系数都降低。热压烧结制备的材料Si相细小,致密度高,界面结合力好,热导率高。随着Si相含量的增加,热压的Si-Al合金热导率逐渐降低。烧结的Si-Al合金的抗弯强度和弹性模量随Si相含量的增加逐渐降低,材料的断裂主要以Si相的脆性断裂为主。     

Boron removal by titanium addition in solidification refining of silicon with Si-Al melt

In order to effectively remove B from Si for its use in solar cells, a process involving B removal by solidification refining of Si using a Si-Al melt with Ti addition was investigated. For clarifying the effect of Ti addition on B removal from the Si-Al melt, TiB₂ solubilities in Si-64.6 at. pct Al melt at 1173 K and Si-60.0 at. pct Al melt at 1273 K were determined by measuring the equilibrium concentrations of B and Ti in the presence of TiB₂ precipitates. The small solubilities of TiB₂ in the Si-Al melt indicate the effective removal of B from the Si-Al melt by Ti addition. Further, solidification experiments of Si-Al alloys containing B by Ti addition were performed, and the effect of Ti addition on the solidification refining of Si with the Si-Al melt was successfully confirmed.     

Effects of Rare Earths on Properties of Ti-Zr-Cu-Ni Base Brazing Filler Alloys

The effects of the addition of rare earths on the properties of Ti-Zr-Cu-Ni base brazing filler alloys and the mechanical microstructure and properties were studied for the brazed-joints in the vacuum brazing of TC4 by comparing synthetical properties of two kinds of filler metals.The results indicate that the filler metals added with rare earths have lower melting point, better wettability and higher mechanical properties in the brazing joints.     

硅含量对喷射成形铝硅复合材料显微组织与力学性能的影响

利用双喷嘴扫描喷射成形技术制备27%SiAl、42%SiAl、50%SiAl等3种Si-Al合金电子封装材料,并对该材料进行热等静压致密化处理。研究合金沉积态和热等静压态的显微组织,测定合金的热膨胀系数、抗拉强度及抗弯强度,利用扫描电镜研究其断裂机制。结果表明:沉积态Si-Al合金的硅相呈均匀弥散分布。随含硅量增加,合金凝固区间增大,初生硅相的数量增多,平均尺寸增大,由全部颗粒状分布逐渐演化为呈部分颗粒、部分骨架状分布,这种均匀弥散分布的结构有利于降低合金的热膨胀系数。27%SiAl、42%SiAl、50%SiAl合金的热膨胀系数连续可控,室温至200℃分别为14.76×10 6、9.75×10 6、9.29×10 6/K。随硅含量升高,材料的抗弯强度和抗拉强度呈下降趋势。27%SiAl合金的平均抗拉强度和抗弯强度分别达到196 MPa和278 MPa,伸长率为9.5%。42%SiAl与50%SiAl的平均抗拉强度与抗弯强度都接近,分别达到140 MPa及220 MPa,伸长率小于1%。断裂方式由以铝相的韧性断裂为主逐渐转变为以硅相的脆性裂为主。     

Liquid Film Migration in Warm Formed Aluminum Brazing Sheet

Warm forming has previously proven to be a promising manufacturing route to improve formability of Al brazing sheets used in automotive heat exchanger production; however, the impact of warm forming on subsequent brazing has not previously been studied. In particular, the interaction between liquid clad and solid core alloys during brazing through the process of liquid film migration (LFM) requires further understanding. Al brazing sheet comprised of an AA3003 core and AA4045 clad alloy, supplied in O and H24 tempers, was stretched between 0 and 12 pct strain, at room temperature and 523K (250 °C), to simulate warm forming. Brazeability was predicted through thermal and microstructure analysis. The rate of solid–liquid interactions was quantified using thermal analysis, while microstructure analysis was used to investigate the opposing processes of LFM and core alloy recrystallization during brazing. In general, liquid clad was consumed relatively rapidly and LFM occurred in forming conditions where the core alloy did not recrystallize during brazing. The results showed that warm forming could potentially impair brazeability of O temper sheet by extending the regime over which LFM occurs during brazing. No change in microstructure or thermal data was found for H24 sheet when the forming temperature was increased, and thus warm forming was not predicted to adversely affect the brazing performance of H24 sheet.

     

Effect of strontium and SmO on the microstructure and fracture mode of AlSi-Mg_2Si brazing filler metal

An AlSi-Mg_2Si self-fluxing brazing filler metal was obtained by activating Al Si brazing filler metal with the Mg_2Si phase and applying a metamorphism treatment of Mg_2Si and Si crystals with Sr and Sm O. A good wetting performance between the modified AlSi-Mg_2 Si and 3003 Al alloys was achieved in the vacuum brazing without Mg vapour as the activator. The melting point of the brazing filler was measured by STA409 Pc differential scanning calorimetry. A scanning electron microscope was used to analyse the microstructure and the component distribution of the brazing filler. The results indicated that the change in morphology of the Mg_2 Si phase was remarkable after metamorphism. The analyses of the microstructure indicated that the Mg_2 Si and Si phases presented small needle-type and granular morphologies. The follows were found to occur: intergranular penetration of Mg and Si on the base metal, a large amount of granular eutectic structure, and a significant grain boundary effect. The shear fracture of the lap joint presented cleavage fracture; in addition, with the decrease of the Mg_2 Si phases, the fracture morphology transformed from a rock candy shape to a steam shape, and cleavage steps appeared. The rock candy-shaped fracture areas enlarged after metamorphism treatment.     

Microstructural control in an aluminum core alloy for brazing sheet applications

The use of aluminum alloys for automotive heat exchangers has increased considerably in the last 15 to 20 years, and in parallel, new alloys have been developed to meet the increased demand for higher strengths and improved corrosion resistance. An Al-Mn alloy, X800, has been developed by Alcan to significantly increase the corrosion resistance of radiator tubes when subjected to typical service environments. Conventional alloy tubes, 3xxx or 6xxx, fail by intergranular attack, whereas X800 utilizes the diffusion of Si during brazing to form a sacrificial layer between core and cladding and thus prevent penetration through the core. The Si penetrates up to a depth of 70 μm into the core alloy and combines with both the Mn in solid solution and the coarse constituent particles to form theα-AlMnSi phase. In contrast to the core, the interface layer exhibits a high dispersoid density, a modified coarse particle chemistry, and a lower Mn level in solid solution after brazing. Three layers remain after brazing; anα-Al residual cladding, the interface layer with a band of dense precipitates (BDP), and the X800 core. Free corrosion potential measurements confirmed the lowering of the potential within the BDP by about 30 mV compared to —710 mV for the brazed X800 core.     

Development of a Novel Ni-Based Multi-principal Element Alloy Filler Metal,Using an Alternative Melting Point Depressant

Brazing is a crucial joining technology in industries where nickel-superalloy components must be joined. Nickel-based brazing filler metals are extensively employed, possessing excellent mechanical properties, corrosion resistance, and retained strength at elevated temperatures. To function as a filler metal, the alloy melting point must be reduced to below that of the materials being joined, but the addition of melting point depressants (MPDs) such as boron, silicon, and phosphorus can, however, lead to the formation of brittle intermetallics, potentially compromising the joint performance. In the present work, a novel multi-principal element brazing alloy (in the style of a high entropy alloy), utilizing Ge as an alternative MPD along with a reduced B addition, is investigated. The design process considered binary phase diagrams and predictions based on Thermo-Calc software and empirical thermodynamic parameters. The alloy was used to vacuum braze nickel-superalloy Inconel-718, and microstructural and mechanical investigations are reported. The maximum shear strength achieved was 297 MPa with a brazing temperature of 1100 °C and 60-minute hold time, with isothermal solidification completed. Shear strength was only slightly reduced with increased joint width. Assessments are made of the ability to accurately predict properties of multi-principle element alloys using Thermo-Calc software and empirical thermodynamic parameters.