冷轧压下率对CSP流程SPCC钢板退火组织和织构的影响

采用某钢厂生产的低碳铝镇静钢进行了CSP流程SPCC钢板不同冷轧压下率的工业试验,研究了退火过程中冷轧压下率对冷轧钢板组织性能的影响规律。结果表明：对于碳含量为0．043％的低碳铝镇静钢,试验条件下冷轧压下率对其力学性能和n影响不明显,对r影响则非常显著;冷轧压下率为75％时,可获得最大rm,综合力学性能也达到最佳;△r则随冷轧压下率的提高而单调减小;铁素体晶粒饼形度随冷轧压下率的提高而增加;冷轧压下率为75％时,{111}织构的强度明显高于冷轧压下率为60％时的对应值。     

大厚度耐候高建钢轧制性能分析

建筑用高强钢应用广泛,生产流程相对较为成熟,但单道次压下率普遍不高.为寻求提高道次压下率是否可以成为工艺突破口,本文分别采用不同压下率对钢板进行轧制,对比分析了其力学性能.结果表明,小压下率钢板心部性能与边部性能差别较大,边部拉伸性能、冲击性能较好,心部较差,且大压下率钢板心部性能与边部性能差别较小,拉伸性能和冲击性能...     

压下率对316L/EH40复合板界面微观形貌的影响

 为确定制备316L/EH40不锈钢复合板所需压下率,采用MSC.Marc有限元软件模拟研究了316L/EH40不锈钢复合板在不同压下率下的轧制过程,通过对变形区结合界面处应力场与应变场的综合分析,确定不锈钢复合板实现有效黏合的最小压下率为55%。基于有限元仿真结果,采用Gleeble-3800热模拟试验机制备了不同变形率下的复合样件,并对复合样件结合界面处的微观组织形貌进行了观测。通过分析得出结论,样件压下率达到30%后,结合界面处孔隙基本闭合,但仍有部分夹杂物和微孔存在;当压下率超过50%后,结合界面处微孔完全消失,夹杂物数量减少并且尺寸减小;低合金钢侧组织由铁素体和珠光体组成,靠近结合面处存在脱碳层,随着压下率的提高,脱碳层厚度逐渐降低;不锈钢侧由奥氏体组织组成,奥氏体晶粒尺寸随着压下率的提高得到不同程度的细化;显微硬度值随着压下率提高逐渐增大。     

冷轧压下率对低碳铝镇静钢冷轧板深冲性能的影响

采用攀钢热轧板厂生产的低碳铝镇静钢热轧卷,在实验室进行了不同压下率对冷轧风板深冲性能的影响试验。结果表明：冷轧压下率对学性能和ｎ值无明显影响,而对ｒ值影响显著。对于含碳量０．０５９％的低碳铝镇静钢,获得最大ｒ值的冷轧压下率为７３％,而△ｒ值随冷轧压下率的提高单调减小。     

中厚板轧制厚度方向上不均匀变形

通过对中厚板轧制过程中厚度方向变形的有限元计算,分析了不同压下率下的厚度方向变形特点,并对不同工艺参数对中厚板心部变形的影响进行了研究。计算结果表明,压下率变化显著影响钢板厚度方向上的变形分布,当压下率小于5%时,变形主要集中于表层,钢板内层变形较小,心部变形最小。当压下率大于5%小于25%时,金属内层变形最大,表层变形小于内层变形,心部变形更小。当压下率大于25%时,表层变形最大,其次是内层,最后是心部区域。合理的提高压下率对增大中厚板心部的压缩变形是最根本的,也是最有效的。本研究的意义在于,从轧钢工序提高中心变形,来改善中心质量缺陷问题,指导生产实践,制定合理的轧制工艺。     

连铸板坯轻压下过程压下率参数的理论分析

通过分析连铸板坯的轻压下过程,提出了铸坯压下率的理论模型,考察了不同拉速、不同铸坯断面下板坯压下率的变化规律.结果表明,压下率与压下速率沿拉坯方向呈近似线性减少关系;压下速率的取值不受拉速影响;压下率与铸坯厚度呈线性减少关系,厚度每增加10%,压下率减小10%;铸坯宽度对压下率的影响很小;压下总量不随拉速的变化而变化.     

冷轧压下率对DQ级深冲带钢组织和性能的影响

研究了60%～80%冷轧压下率对3.5 mm CSP热轧板轧制的1.4～0.7 mm冷轧深冲带钢力学性能、组织和织构的影响。结果表明,随冷轧压下率由60%提高至80%,冷轧带钢的再结晶开始温度由560℃降至520℃,成品带钢组织细化;当冷轧压下率为74.3%时,成品DQ级带钢的深冲性能最佳。随冷轧压下率提高,成品深冲带钢△r值逐渐减小,这与成品带钢中{112}〈110〉织构取向函数值f(g)升高有关。     

冷轧低碳钢连续退火生产工艺优化

针对低碳钢DC01在使用过程中的屈服强度高和开裂问题,通过研究炼钢成分、热轧轧制工艺、冷轧压下率以及退火温度等工艺参数对低碳钢力学性能的影响,制定了工艺优化方案。炼钢方面降低碳含量,提高铝含量,控制氮含量;热轧通过提高卷取温度,冷轧工序对不同规格压下率进行设计,稳定规格压下率;连退提高退火的均热温度。生产实践证明,制定的工艺优化方案行之有效,产品满足了用户使用要求。     

IF钢平面各向异性与制耳效应的研究

分析了提高IF钢的冷轧压下率、调整Ti和Nb含量等方式对IF钢平面各向异性性能及后续深冲过程制耳的影响。结果表明,冷轧压下率从70%提高至82%,IF钢的各向异性性能得到改善;在冷轧压下率为82%时,加入适量Nb元素代替部分Ti,Δr和r值下降的同时制耳指数增加;制耳是塑性应变比和平面各向异性度综合作用的结果。     

卷取温度和冷轧压下率对高强度IF钢力学性能的影响

以不同卷取温度(分别为670℃和710℃)工业生产的高强度IF钢热轧板为研究材料,进行了不同冷轧压下率(分别为55%、65%、75%和85%)的实验室冷轧试验,结合连续热镀锌线的工艺特点进行了盐浴退火试验,采用金相和力学性能测试方法,研究了热轧卷取温度和冷轧压下率对高强度IF钢力学性能的影响。结果表明,较低温度卷取时,热轧卷晶粒尺寸较细,冷轧退火态晶粒尺寸相对较粗,rm值相对较低。冷轧退火态仍具有较细小的晶粒,但屈服强度明显降低,这与间隙碳原子在退火过程通过NbC粗化被大量清除有关。卷取温度对试验钢冷轧退火态的强度、断后伸长率和nm值几乎没有影响。随着冷轧压下率从55%增加到75%时,退火后铁素体晶粒尺寸变化不明显,当冷轧压下率进一步增加到85%时,铁素体晶粒尺寸有所减小。冷轧压下率对强度和断后伸长率影响较小,对nm值没有影响,而rm值随着冷轧压下率的提高而提高。     

Study on the Shaft-Direct Reduction Process with Cold Bound Pellet

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The Effect of Reduction Parameters on Iron Nugget Production From Composite Pellets

Composite pellets which contain a reducing agent and are produced only by cold bonding process are improved instead of traditionally hardened pellets by sintering. The new ironmaking technologies that are able to utilize these pellets have been developed from pilot plant to commercial scale. Iron nuggets which have a similar composition to pig iron can be produced by using composite pellets at high temperatures (1350–1400°C) and in a short reduction time (15–20 min) by smelting reduction process. In this study, the effect of reduction parameters and basicity of composite pellets on the reduction properties and product quality are investigated. Composite pellets containing magnetite concentrate with a reducing agent (coke) and a flux are processed at different temperature and at times by smelting reduction process. The increasing temperature and time has a positive effect on reduction and melting of the pellets. Excessive carbon prevents the metal droplets from coalescing. The iron nugget that is produced from the sample with the basicity (CaO/SiO₂) of 0.68 has the optimal physical and chemical properties. It is also determined that a decrease or increase of basicity has a negative effect on the properties of the iron nuggets.     

氟钽酸钾钠还原制备工艺对钽粉性能的影响

为制备出大比表面积的高性能钽粉,根据钠还原氟钽酸钾制备钽粉的过程分析,对其主要影响因素(还原温度、稀释剂比例、还原速度、搅拌转速)对钽粉性能的影响进行了研究。结果表明,随着还原温度降低,还原的钽粉比表面积增大;还原温度提高会增加还原过程中反应容器的腐蚀,造成金属杂质增加。稀释剂比例增加,有利于生成大比表面积钽粉,但会降低钽粉收率,且杂质含量增加。注钠速度、搅拌转速不是主要影响钽粉比表面积的关键因素。     

真空碳热还原制备Mg-Sr合金的反应热力学

介绍了真空碳热还原制备Mg-Sr合金新思路,研究了其还原反应的反应式、吉布斯自由能及临界还原温度。结果表明,真空碳热还原MgO,SrO的混合物可以得到Mg-Sr合金;其他因素不变的情况下,还原反应吉布斯自由能随反应温度的提高而减小,随系统气压的降低而减小,随反应生成的Sr,Mg混合蒸气中Sr摩尔分数的减小而减小;反应温度的提高、系统气压的降低和Sr摩尔分数的减小均有利于还原反应的进行;当系统气压为10 Pa,Sr摩尔分数为0.1时,临界反应温度为1353 K;相同系统气压下,碳热还原制备Mg-Sr合金的临界反应温度低于真空碳热炼锶、炼镁的临界温度,反应更易于进行;常规真空硅热还原制备金属镁(皮江法)的反应温度1473 K,气压13.3 Pa下,无论反应生成的Sr,Mg混合蒸气中Mg,Sr相对比例如何,真空碳热还原制备Mg-Sr合金的反应均具备热力学可行性。     

30CrMo精冲钢连铸板坯高温力学性能研究

利用Gleeble-3800 热模拟机测试了30CrMo精冲钢连铸坯从1350 °C以5°C/s和15°C/s冷却至600~900°C拉伸的高温力学性能,通过扫描电镜对拉伸试样的断口形貌和显微组织进行了观察分析,讨论了各温度区域变形断裂的机理。结果表明,冷却速度增大,铸坯整体的断面收缩率减小,铸坯的热塑性降低。30CrMo精冲钢的第Ⅲ脆性温度区间在650~750°C。将二冷区矫直点入口处的铸坯角部温度提升至800°C以上可以有效避免角部裂纹发生。     

Effects of CaO on Precipitation Morphology of Metallic Iron in Reduction of Iron Oxides Under CO Atmosphere

 Growth process of iron whiskers and mechanism of CaO influence on precipitation morphology of metallic iron at the gas-solid interfaces was studied. Analytical reagents of Fe(NO3)3 and Ca(NO3)2 aqueous solution were used to prepare sheet film sample of Fe2O3-CaO by thermal decomposition at high temperature. In-situ observation was conducted using a stereo optical microscope and a hot-stage. And reduction kinetics of samples was studied by thermo gravimetric (TG) method. Some samples after reduction were analyzed by using the scanning electron microscope (SEM), energy dispersive spectrometer (EDS) and fourier transform infrared (FT-IR) spectrometer. Results indicate that during the reduction of iron oxides with CO, metallic iron is mostly precipitated as whisker and the precipitation behavior mainly depends on reduction rate. Doping CaO can significantly increase the reduction rate and effectively change the precipitation morphology of metallic iron after the reduction. When CaO doping concentration is less than 4% (mass percent), CaO can promote whisker formation of reduced iron; as it reaches 6% (mass percent), CaO inhibits iron whiskers growth; as it is more than 8% (mass percent), no whiskers could be observed. Therefore, controlling the quantity of Ca2+ is effective to control the formation and growth of iron whiskers during gaseous reduction and thus eliminating ore grain sticking caused by intertexture of iron whiskers.     

现代炼铁技术进展

评述了国际上发展较快的几种主要非高炉炼铁工艺流程.COREX、FINEX和HISMELT等熔融还原流程可以避免炼焦工艺引发的环境污染.成熟的竖炉气基还原工艺是COREX流程工业化的重要保障,粉体流化床由于粘结等问题尚未完全解决和铁浴炉二次燃烧与炉衬侵蚀之间的固有矛盾注定了FINEX和HISMELT实现的难度远高于COREX流程.气基还原流程(MIDREX、HYL-Ⅲ、FINMET)目前都要使用天然气资源,很难在我国得到发展.转底炉可使用低强度的含碳球团,给煤基直接还原流程注入新的活力,但其能耗高、生产效率低、产品质量差将会制约它的发展.我国自主研发的炼铁新工艺,即低温快速还原工艺,目前仍处于研究开发阶段,它能够实现低温快速还原反应,是一种能耗低、污染少、资源利用率高的新型绿色冶金工艺流程,具有良好的发展前景.     

铜还原钼酸盐实验研究

基于钨钼的电化学性质差异,以铜为还原剂,在添加EDTA络合剂和无络合剂作用的条件下,研究了EDTA用量、pH值、还原时间、反应温度对钼还原率的影响。结果表明,添加EDTA络合剂不利于钼还原率的提高;反应可采用铜直接还原,选择pH=1.0～1.5、反应温度60℃及延长还原时间,利于钼还原率的提高。     

Study on Properties of Alumina‐Based Mould Fluxes for High‐Al Steel Slab Casting

During the continuous casting of high‐Al steel, the dynamic reduction of silica‐based mould fluxes by the aluminium in the steel leads to changes in their composition and physical properties. The alumina‐based mould flux has been suggested as an alternative to alleviate this reduction problem. However, until now, the smooth running of high‐Al steel continuous casting has been impeded by the lack of systematic investigation of properties of this slag. In this paper, the effects of typical components on the properties of alumina‐based mould fluxes are discussed. The experimental results show that: (a) an increase in F^? can reduce the viscosity while increasing the melting and break temperatures; (b) with increasing Li₂O, the viscosity, melting temperature, and break temperature first decrease and then increase; (c) with the addition of BaO, the viscosity, melting temperature, and break temperature remain at a low level, while a further increase in BaO causes a decrease in viscosity, an increase in melting temperature, and the stabilization of the break temperature; (d) BaO is favorable to stabilize the properties of mould fluxes for the dissolution of additional Al₂O₃; (e) the crystalline phases of the mould fluxes mainly contain 12CaO · 7Al₂O₃ and 11CaO · 7Al₂O₃ · CaF₂, and 12CaO · 7Al₂O₃ has great potential as a substitute for cuspidine.