稀土元素La对AZ91D镁合金低周疲劳行为的研究

研究了AZ91D＋0．3％La镁合金在总应变幅△εt／2为0.2％～1.2％范同内循环加载时的低周疲劳行为。结果表明,在较大应变幅下,AZ91D＋0．3％La镁合金的循环滞后回线上分别出现捌点、拉压不对称和锯齿现象;镁合金的低周疲劳寿命随应变幅值的提高而下降,并且符合Manson—Coffin关系式;镁合金的循环应力响应行为和循环应力应变行为均呈现明显的循环硬化现象;疲劳断口上出现了多疲劳源现象,且随应变幅的增加越来越凹凸不平。     

AZ91合金的压缩行为

Z91合金的压缩行为研究表明 ,在室温和 350℃下 ,选取应变速率在 5 .6× 1 0 - 3～ 1 .8× 1 0 - 2 s- 1 之间变化时 ,真应力 -真应变曲线变化规律呈现一致性 ,真应力值差距不明显 ,压缩屈服强度σ0 .2 比较接近 ;在 2 50℃下 ,真应力值因应变速率的不同差距比较明显 ,随着应变的增加 ,真应力趋向稳定值。压缩后的试样形貌从室温到 350℃之间的变化规律为 :剪切破碎 -部分饼状 -完全饼状。观察变形组织发现 ,变形后的AZ91合金中出现了大量的动态再结晶晶粒。     

添加稀土提高AZ91镁合金力学性能研究进展

简要分析了添加稀土元素提高AZ91镁合金力学性能的强化机理,着重介绍了不同稀土元素强化AZ91镁合金力学性能的最新研究进展,并指出了高性能AZ91镁合金的发展方向。     

Preparation and Corrosion Resistance of Rare Earth Conversion Coatings on AZ91 Magnesium Alloy

The feasibility of forming Ce-containing rare earth conversion coating (short for RECCs),which is nonpoisonous and green to the environment,onto the AZ91 magnesium alloy surface in order to increase the corrosion resistance was studied. And the optimum technological conditions, such as the appropriate concentrations of the components in the solution,temperature and duration of the coatings formation were also settled. The protection of conversion coatings on magnesium alloy surface was evaluated by moisture/heating test, anodie polarization, etc.     

双螺旋搅拌法制浆工艺参数对AZ91D合金半固态组织的影响

双螺旋搅拌工艺制备了AZ91D合金半固态浆料,获得金属半固态加工要求的细小、等轴分布均匀的非枝晶组织。研究了熔体温度、搅拌速度和剪切时间对该组织的影响规律。结果表明:采用合适的搅拌工艺,可获得金属半固态加工要求的细小、等轴分布均匀的非枝晶组织。即降低降体温度、搅拌速度及适当剪切时间有利于细小球形晶粒的形成。加大搅拌速度及合理搅拌时间可以细化晶粒,主要是由于是高剪切作用下熔体获得一个非常均匀温度场,从而增加有效形核的缘故。     

Study on Ignition Proof AZ91D Magnesium Alloy Chips with Cerium Addition

The effect of Ce on ignition point of AZ91D magnesium alloy chips was studied. For the AZ91D and the AZ91D-xCe magnesium alloys, changing the sizes of the chips in the range of 58 - 270 μm has a limited influence on ignition point, however, the shift of the content of Ce has much effect on ignition point. Increasing the Ce content, x from 0.15 to 0.25, the ignition point increases with increasing of Ce; however, x from 0.25 to 0.45, the ignition point decreases with increasing of Ce. By the addition of Ce of 0.25 %. the ignition point is raised by 43℃.     

Effect of ErCl3 Addition on Microstructures and Properties of AZ91 Magnesium Alloy

Effect of ErCl_3 Addition on Microstructures and Properties of AZ91 Magnesium Alloy     

新型复合熔剂对AZ91镁合金组织和力学性能的影响

利用金相显微镜、X-射线衍射仪、SEM、EDAX、数字显微硬度计和电子万能试验机,对采用传统覆盖剂和自制覆盖剂制备的AZ91镁合金的显微组织和力学性能进行了分析。结果表明,自制覆盖剂制备的AZ91镁合金,Mg17Al12相得到改善,晶内出现Al4C3形核质点,晶粒得到显著细化,抗拉强度、屈服强度和延伸率都得到较大的提高,综合性能是实验合金中最高的,且拉伸断口形貌呈现河流花样,韧窝较深,这与合金的组织更细小有关。     

新型复合熔剂对AZ91镁合金组织和力学性能的影响

利用金相显微镜、X-射线衍射仪、SEM、EDA、数字显微硬度计和电子万能试验机,对采用传统覆盖剂和自制覆盖剂制备的AZ91镁合金的显微组织和力学性能进行了分析。结果表明。自制覆盖剂制备的AZ91合金、Mg17Al12相得到改善,晶内出现Al4C3形核质点,晶粒得到显著细化,抗拉强度、屈服强度和延伸率都得到较大的提高。     

稀土钡镁硅铁合金物相和显微组织分析

在成分（ｗｔ％）为ＲＥ２．９１、Ｂａ３．８５、Ｍｇ９．７０：Ｃａ２．２、Ａｌ１．５，余量为Ｆｅ的范围内，运用Ｘ－射线衍射分析及电子探针分析手段对ＲＥＢａＭｇＳｉＦｅ合金的物相和显微组织进行了分析。发现了稀土和碱土金属之间在硅基中的互溶现象并对其进行了初步鉴别。     

Effect of Microalloying on Wettability, Oxidation and Solidification Morphology of Sn-9Zn Alloy

EutecticorcloseneareutecticSn Pballoysare extensivelyusedinelectronicinterconnectionand packagingbecauseoftheirlowmeltingtemperatures, excellentwettabilitytocoppersubstratesandlow cost.Existingproductionlinesaredesignedonbasis ofSn Pbsolders.Withtheaccele…     

A Comprehensive Study of Diffusion Bonding of Mg AZ31 to Al 5754, Al 6061 and Al 7039 Alloys

In the present study, microstructural and mechanical properties of diffusion bonding of AZ31–Mg with Al 5754, Al 6061, and Al 7039 alloys were compared under same conditions. The vacuum diffusion processes were performed at a temperature of 440 °C, the pressure of 29 MPa, and a vacuum of 1?×?10^?4 torr for 60 min. The microstructural characterizations were investigated using optical microscopy and scanning electron microscopy equipped with EDS analysis and linear scanner. The XRD analysis was performed to study phase figures near the interface zone. The results revealed the formation of brittle intermetallic compounds like Al₁₂Mg₁₇, Al₃Mg₂, and their other combinations at bonding interfaces of all samples. Additionally, the hardness of Al alloys seemed to play a key role in increasing diffusion rate of magnesium atoms toward the aluminum atoms, with Al 6061 alloy having the highest diffusion rate. It consequently led to an increase in diffusion rate and thus formation of a strong diffusion bonding between magnesium and aluminum alloys. The highest strength was about 42 MPa for the diffusion bonding between Mg AZ31 and Al 6061. Further investigations on surfaces indicated that the brittle phases especially Al₃Mg₂ caused brittle fracturing.     

喷射沉积Al-12Si-0.6Mg合金的微观组织与性能

共晶合金具有良好的激光焊接性能,为提高电子封装盖板用Al-12Si合金的强度并保持良好的热物理性能,采用喷射沉积与热压烧结技术制备Al-12Si合金,研究添加0.6% Mg对合金微观组织、力学性能和热物理性能的影响。结果表明,喷射沉积/热压烧结Al-12Si合金中Si相呈近球形颗粒,平均直径为（4.5±0.2）μm,均匀分布于Al基体中;添加Mg未对Si相尺寸和形貌产生显著影响,但是在Al基体中形成Mg₂Si相。相对于Al-12Si合金,Al-12Si-0.6Mg合金的热导率降幅仅为4.2%,但是抗拉强度从154.1 MPa提高到190.1 MPa,增幅达到23.4%,该强度改善主要归因于固溶强化和析出强化作用。      

新型Al-1Mg-0.8Si-xCu铝合金均匀化工艺研究

Al-1Mg-0.8Si-xCu铝合金是汽车轻量化首选材料之一。采用光学显微镜、DTA分析、X射线衍射等分析检测手段,研究了Al-1Mg-0.8Si-xCu这一新型铝合金的均匀化工艺。结果表明,Cu元素含量为0.5%的Al-1Mg-0.8Si-xCu合金理想均匀化工艺为450℃×4 h+550℃×12 h,该工艺适用于Cu元素含量不大于1.05%的合金。     

Microstructure and Properties of Mg-10%Al-(0～3%)Di Alloys

The effects of didymium(Nd:Pr=3:1)on the microstructure and mechanical properties of Mg-10%Al alloy were studied with the additions of 0～3%Di. The small block-like Al2(Nd,Pr) phase appears in 1%Di alloy, the block-like Al2(Nd,Pr) and needle-like Al11(Nd,Pr)3 phases appear synchronously in 2%Di and 3%Di alloys, while the network of (Mg17Al12) β phase is broken up. The tensile properties can be improved with the addition of didymium. When the addition of didymium in Mg-10%Al alloy reaches 2%, the alloy exhibits the best combination of strength and ductility, but the strength and ductility drop at the addition of 3%Di due to the obvious increase of the size and quantity of the needle-like Al11(Nd,Pr)3 phase.     

Effect of rare-earth element additions on high-temperature mechanical properties of AZ91 magnesium alloy

The present article focuses on the high-temperature mechanical properties of the magnesium alloy AZ91. The addition of rare-earth (RE) elements up to 2 wt pct improves both yield and tensile strengths at 140 °C by replacing the Mg₁₇Al₁₂ phase with RE-containing intermetallic compounds. This intermetallic phase is thermally and metallurgically stable and is expected to boost the grain-boundary strengthening. It also increases the resistance of grain boundaries to flow at high temperatures. Further increases of RE additions reduce strength and ductility due to growth of the Al₁₁RE₃ brittle phase, which has sharp edges. Still, at a 3 wt pct RE addition, the strength of the alloy at high temperatures is more than that of AZ91.     

Wear-Resistance Performance of ZA-27 Alloys Reinforced by Rare Earth Compounds

In order to further improve wear-resistanceof the ZA-27 alloy and widen its applieationfields, St phase is added in the alloy[' '21. ButSt phase seriously cuts apart the alloy matrix.It not only decreases high toughness of the alloy, but also is harmful to its wear-resistance.On the basis of the researches in foregoing periodical on Zn-based alloy reinforced by Stphase and the inLfluence of RE on the high temperature mechanical properties of the ZA-27 alloy["'j, this paper deals with the e…     

Effect of Compositional Variation on the Microstructural Evolution and the Castability of Al–Mg–Si Ternary Alloys

This study examined the microstructural evolution and castability of Al–Mg–Si ternary alloys with varying Si contents. Al–6Mg–xSi alloys (where x = 0, 1, 3, 5, and 7; all compositions in mass pct) were examined, with Al–6 mass pct Mg as a base alloy. The results showed that in the ternary alloys with Si ≤ 3 pct, the solidification process ended with the formation of eutectic α-Al–Mg₂Si phases generated by a univariant reaction. However, in the case of ternary alloys with Si > 3 pct, solidification was completed with the formation of α-Al–Mg₂Si–Si ternary eutectic phases generated by a three-phase invariant reaction. In addition to the eutectic Mg₂Si phases, the primary Mg₂Si phases formed in each of the ternary alloys, and the size of both sets of phases increased with increasing Si content. The two-phase eutectic α-Al–Mg₂Si nucleated from the primary Mg₂Si phases. The inoculated Al–6Mg–1Si alloy had the smallest grain size. Moreover, the grain-refining efficacy of the Al–5Ti–B master alloy in the ternary alloys decreased with increasing Si content in the alloys. Despite the poisoning effect of Si on the potency of TiB₂ compounds in the inoculated Al–6Mg–1Si alloy, the grain size of the alloy was slightly smaller than that of the Al–6Mg binary alloy. This resulted from the increasing growth restriction factor (induced by Si addition) of the Al–6Mg–1Si alloy. In terms of the castability, the examined alloys showed different levels of susceptibility to hot tearing. Among the alloys, the ternary Al–6Mg–5Si alloy exhibited the highest susceptibility to hot tearing, whereas the Al–6Mg–7Si exhibited the lowest. The severity of hot tearing initiated by the unraveling of the bifilm was determined by the freezing range, grain size, and the amount of eutectic phases at the end of the solidification process.

     

Effect of Rare Earth on Microstructure of Vacuum Melting Ni-Based Self-Fluxing Alloy Coatings

The Ni-based self-fluxing alloy coating containing RE was acquired by the technique of vacuum melting on the hypoeutectoid steel (Fe-0.45% C) matrix. By X-ray diffraction, SEM and EDX, the microstructure and phase structure of section of coating and the microstructure near the interface between coating and matrix were investigated, and the effect of RE on microstructure of coating was also discussed. The results show that the microstructure of the NiCrBSi alloy coating is composed of Ni-based solid solution and a lot of massive, globular and needle secondary phases CrB, Ni3B, Cr7C3, Cr23C6 among the solid solution. The metallurgical binding between steel matrix and coating is realized. RE makes needle phase of alloy coating vanish. New phases of NiB and Cr6.5Ni2.5Si are precipitated from alloy coating, and secondary phases of alloy coating are sphericized. Consequently, RE also hinders the diffusion of Ni, Cr and Si atoms from coating to matrix and Fe atoms from matrix to coating, holds back the dilution of Fe for NiCrBSi alloy coating, and assures the chemical composition of the alloy coating.