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Cu-Al合金内氧化及Cu氧化行为的热力学分析 总被引:12,自引:1,他引:11
对Cu-Al合金的内氧化及冷却过程中Cu的氧化行为进行了热力学分析和实验室,据此确立了Cu2O粉末和氮基气氛共同作为内氧化介质的新工艺。结果表明,内氧化区是择优氧化区中上限氧分压下方的一个很小区域,其中上限氧分压由下式计算,lgPo2上=17611/T+12.91;内氧化介质,氧分压和温度是实际内氧化控制的三要素;内氧化过程中晶内生成了均匀弥用分布的纳米γ-Al2O3粒子,其平均尺雨和颗粒间距分别为7nm和30nm。降温过程中Cu的氧化不容忽视。通H2 急冷可明显提高材料性能。 相似文献
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TiAl合金表面阴极微弧制备的Al_2O_3膜结构与性能 总被引:1,自引:0,他引:1
以Al(NO3)3乙醇溶液为电解液,采用阴极微弧放电沉积方法,在TiAl合金表面制备连续的Al2O3薄膜,并对膜的结构与性能进行研究.利朋扫描电镜(SEM)观察到样品表面分布着熔融状颗粒,颗粒的平均直径约20μm,颗粒中间有小孔存在.X射线衍射(XRD)分析表明氧化膜的相成分主要为α-Al2O3和γ-Al2O3相,还有少量的ε-Al2O3相;氧化膜中α-Al2O3和γ-Al2O3的相对含量随着制备电压改变而变化.显微划痕实验测得膜与TiAl基体之间结合力大于20 N,表明制得的氧化膜与基体有良好的结合力.900℃的高温氧化实验表明氧化膜能够有效地提高基体的抗氧化性能. 相似文献
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采用反应热压(RHP)工艺,利用Ti、Al、TiO2及Nb2O5之间的放热反应,在较低温度下制备了Nb2O5强化Al2O3/TiAl复合材料.借助XRD、OM及SEM等手段,考察了Nb2O5对Al2O3/TiAl复合材料的相分布及组织结构的影响.结果表明:材料产物由γ-TiAl、α2-Ti3Al、Al2O3和NbAl3相构成,Al2O3颗粒分布于基体交界处,存在一定的偏聚.Nb2O5的引入,使得γ-TiAl相含量减少,α2-Ti3Al相含量增大;基体晶粒有所细化,且分布逐渐趋于均匀.当Nb2O5的引入量(质量分数)为6%时,组织主要由α2-Ti3Al/γ-TiAl层片状晶团组成,出现了较完整的γ-TiAl晶粒,属于近片层(NL)组织结构,层片状晶团的尺寸小于50μm,γ晶粒尺寸小于5μm.力学性能测试表明,当Nb2O5的引入量(质量分数)为6%时,材料的抗弯强度达到最大值,约为593MPa,硬度为4.77 GPa;断裂韧度达到最大值,为8.93MPa·m1/2,具有可接受的力学性能. 相似文献
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Al2O3/Cu复合材料内氧化粉末的制备 总被引:6,自引:0,他引:6
通过引入高能球害,为Al2O3/Cu复合材料的内氧化工艺提供了新的粉末制备途径。高能球窘可制备亚稳态的Cu-Al预合金粉末,使用该粉末进行内氧化,既可避免复杂的雾化制粉装置,又可使Al的脱溶氧化变得容易,缩短内氧化的周期;Cu2O粉末与Cu-Al预合金粉末一起进行球磨。一方面改善了粉末内氧化的动力学条件,另一方面避免了Cu2O分解后产生的富铜相。球磨过程适宜的酒精加入量为15mL/100g粉料。Cu-Al系粉末在经过96h的球窘后合金已经形成,合金粉末向层片结构发展,此时粒子已经细化。X射线衍射图谱中Al的衍射峰的消失是Cu-Al系粉末形成合金的标志,并不是晶粒细化所致。Cu-2.0%Al比Cu-0.8%Al的合金更容易细化,层片结构更突出。 相似文献
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研究了两种不同Cr含量的常规熔炼Ni-Cr-Al合金在1000℃空气中的氧化行为.合金氧化动力学遵循抛物线规律,Ni-20Cr-2.5Al合金在1000℃的氧化增重略小于Ni-15Cr-2.5Al合金,二者的氧化增重都明显小于Ni-20Cr合金.Ni-20Cr-2.5Al合金1000℃氧化后形成了外层的Cr2O3及内层极薄的Al2O3型氧化膜,在Ni-Cr合金中加入Al,由于Cr、Al的相互作用,降低了形成Cr2O3和Al2O3外氧化膜所需的Cr或Al的临界含量,促进了保护性Al2O3或Cr2O3膜的生成. 相似文献
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利用拟薄水铝石胶粒聚集行为制备了三维梯次结构的球形Al2O3:Eu3 荧光颗粒.AlOOH/Eu(NO3)3复合胶体喷雾过程形成雾滴,雾滴中的拟薄水铝石胶粒在范德华力和毛细管力作用下聚集,自组装形成三维梯次结构干凝胶颗粒.干凝胶颗粒经900℃灼烧获得纳米微晶组成的Al2O3:Eu3 荧光颗粒,Eu3 以部分取代Al3 的形式进入γ-Al2O3晶格.578mm,588nm(593nm)和616nm发射峰分别来自Eu3 基态5D0到7F0,7F1和7F2的跃迁.其中616nm对应的5D0→7F2跃迁发射峰值与Eu3 掺杂α-Al2O3纳米颗粒中Eu3 发射峰相同. 相似文献
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正Last month,Chinalco signed framework agreement for strategic cooperation with Harbin Municipal Government in Harbin Xiong Weiping,Chairman of Chinalco,said that based on the strategic deployment to build world top-class mining company with the highest growth potential,Chinalco was now concentrating all efforts on making strategic transition and structural adjustment,strategic cooperation with the local governments where 相似文献
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《China Nonferrous Metals Monthly》2014,(12)
<正>According to the latest info from Jiangxi Province State-owned Assets Supervision and Administration Commission,Jiangxi Copper Corporation was approved to become the first pilot enterprise for deepening reform.Contents of the pilot work is"Three Self"(self expansion,self decision-making,self 相似文献
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《Baosteel Technical Research》2014,8(4)
正Baosteel Technical Research,a quarterly journal,which is issued domestically and abroad,is run and sponsored by Baosteel Group Corporation.Baosteel Technical Research mainly reports the achievements in technological innovation,academic research,new product development and industrial equipment improvement by Baosteel.It will continue to follow up on hot topics and serve the company’s technological development and progress.Its readers include experts in 相似文献
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《China Nonferrous Metals Monthly》2014,(1):9-10
【正】According to the Ministry of Industry and Information Technology,the Ministry has released the 2013 Operation Report on China’s Industrial Communication Indu... 相似文献
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正Recently,Chinalco and Gansu Provincial People’s Government signed"Framework Agreement for Strategic Cooperation on Reform,Restructuring and Transition Development of Chinalco’s Electrolytic Aluminum Enterprises in Gansu",signifying that the strategic cooperation between Chinalco and Gansu Province had made new substantive progress. 相似文献
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《China Nonferrous Metals Monthly》2014,(12)
正Owing to continual downturn in real estate and bulk commodity markets,a number of traditional industries in China suffered unfavorable impact in performance.With the progressive disclosure of third quarter report,the no-pleasant-surprise performance of 相似文献
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正The High Performance Magnetic Material Phase II Project,an industry upgrading project implemented by Inner Mongolia Baotou IronSteel Rare Earth(Group)Hi-tech Co.,Ltd,recently basically finished equipment commissioning,signifying that the enterprise had developed the production capacity of15000 t/a Nd-Fe-B strip casting alloy and 5000t/a Nd-Fe-B magnet,thus becoming the world’s 相似文献
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正With the signing of"Letter of intention for Propelling Integration of Shandong Rare Earth Enterprises"between Shandong Province Commission Of Economy and Informatization,China IronSteel Research Institute Group("China Steel Institute"),and China Rare MetalsRare Earth Co.,Ltd("China Rare Earth"),the"Shandong Rare Earth Group"jointly set up by the 3 units thus broke surface.On August 9,reporters of the China Economic Herald learned from Shandong Province 相似文献