改进型移动床生物膜反应器处理有机废水的试验

改进型移动床生物膜反应器(CMCBR)是在普通移动床生物膜反应器中引入导流板,使填料在全池循环移动,消除了普通移动床生物膜反应器的死角。在CMCBR处理模拟生活污水的试验中,研究了有机物的去除效果,考察了容积负荷、水力停留时间、冲击负荷等参数对处理效果的影响。试验发现,在填料填充比例为50%(体积比),进水COD质量浓度为320~550mg/L,水力停留时间为3 h的条件下,出水COD质量浓度小于100 mg/L,达到国家污水综合排放标准的一级标准。反应器具有较强的抗冲击负荷能力,出水水质稳定。     

Effect of organic loading rate on a wastewater treatment process combining moving bed biofilm and membrane reactors.

The effect of moving bed biofilm reactor (MBBR) loading rate on membrane fouling rate was studied in two parallel units combining MBBR and membrane reactor. Hollow fiber membranes with molecular weight cut-off of 30 kD were used. The HRTs of the MBBRs varied from 45 min to 4 h and the COD loading rates ranged from 4.1 to 26.6 g COD m(-2) d(-1). The trans-membrane pressure (TMP) was very sensitive to fluxes for the used membranes and the experiments were carried out at relatively low fluxes (3.3-5.6 l m(-2) h(-1)). Beside the test with the highest flux, there were no consistent differences in fouling rate between the low- and high-rate reactors. Also, the removal efficiencies were quite similar in both systems. The average COD removal efficiencies in the total process were 87% at 3-4 h HRT and 83% at 0.75-1 h HRT. At high loading rates, there was a shift in particle size distribution towards smaller particles in the MBBR effluents. However, 79-81% of the COD was in particles that were separated by membranes, explaining the relatively small differences in the removal efficiencies at different loading rates. The COD fractionation also indicated that the choice of membrane pore size within the range of 30 kD to 0.1 microm has very small effect on the COD removal in the MBBR/membrane process, especially with low-rate MBBRs.     

Fluidised pellet bed bioreactor: a promising technology for onsite wastewater treatment and reuse.

A pilot-scale fluidised pellet bed (FPB) bioreactor, which combines chemical coagulation, biological degradation, particle pelletisation and separation in one unit, was applied for onsite wastewater treatment and reuse. As a result of rational use of inorganic coagulant and organic polymer and moderate mechanical agitation, spherical particles were generated in the upflow column and a well-fluidised bed was formed. With a continuous supply of dissolved oxygen through a recycling loop, an aerobic condition was kept in the bottom section of the FPB column. Under such conditions the pellets in the FPB column showed the following characteristics: (1) compact structure and high density; (2) rich in microorganisms; and (3) high MLSS and MLVSS concentrations. Therefore, the FPB bioreactor achieved more than 90% removal of SS, COD, BOD and TP from raw domestic wastewater within a total hydraulic retention time (HRT) of only about 30 minutes. It also showed nitrification and denitrification ability and the TN removal could be about 50% as the recycling ratio was increased to 1:1. The treated water quality is generally competitive with the secondary effluent from a conventional activated sludge process. With these advantages the FPB bioreactor is recommendable as a compact system for onsite wastewater treatment and reuse.     

底层泥沙交换和状态概率及推悬比研究

本文首先论述了床面层泥沙静止、推移(滚动与跳跃)和悬浮三种运动状态及它们转移的临界条件，四种基本转移概率和由它们构成的九种状态转移概率。接着利用数字计算结果，给出了四种基本转移概率，并分析了它们的特性。在这个基础上计算了泥沙在床面层处于静止(床沙)、推移(推移质)、悬浮(悬移质)的状态概率。最后作为状态概率的应用给出了推悬比的公式。     

Modelling and dynamic simulation of a pilot-scale moving bed bioreactor for the treatment of municipal wastewater: model concepts and the use of respirometry for the estimation of kinetic parameters.

A model for the simulation of a moving bed bioreactor (MBBR) used for the treatment of municipal wastewater is proposed. The model includes attachment of particulates to the biofilm and detachment of biofilm into the bulk liquid. The growth kinetics are modelled with the activated sludge model no. 1 (ASM1). Respirometry was used for the estimation of kinetic parameters. The resulting respirograms featured the typical endogenous and exogenous respiration phases and the respirogram shapes were as expected from analogous respirometry with activated sludge. The estimated parameter set was used for modelling and simulation of the pilot-scale MBBR. The main proportion of biomass in the MBBR was found to be attached as biofilm on the carrier elements (4.1 -4.6 g dm-3) and only a small amount was suspended in the bulk liquid (0.15gdm(-3)). Attachment and detachment rates were estimated to be 4.8-7.5g m(-2) d(-1) 1for attachment and 6.5-7.5g m(-2) d(-1) for detachment. The biofilm age was estimated to be 1.8-2.7d. The model was used to predict effluent quality parameters and a good fit of the simulated data to the measured data originating from a four-days-long measurement campaign was obtained.     

溶解氧浓度对硅藻土移动床复合生物反应器处理城市污水的影响

利用硅藻土移动床复合生物反应器处理城市污水。以复配硅藻土作为微生物的载体,在连续流小试中,考察溶解氧浓度对反应器处理城市污水效果的影响。当溶解氧浓度为1.85～2.38 mg/L时,处理出水TN为13～16mg/L,满足《城镇污水处理厂污染物排放标准》(GB 18918—2002)一级B标准,其他出水指标如COD_(Cr)为12～22mg/L,NH_3—N为0.5～2.6mg/L;出水TP为0.2～0.9mg/L,都满足GB 18918—2002一级A标准。表明该反应器在中小规模污水处理方面是一个有前途的污水处理工艺单元。     

一体式膜生物反应器处理焦化废水

介绍了用一体式膜生物反应器(M BR)处理焦化废水的技术,讨论了对焦化废水中的COD,NH3-N和浊度的去除效果及影响因素。实验结果表明,一体式膜生物反应器用于处理焦化废水在技术上是可行的,调整合适的操作参数,其对焦化废水中的COD,NH3-N和浊度的平均去除率分别达到80%、95%、90%以上,操作简单,出水水质好,稳定,且优于国家一级排放标准,有一定的推广意义。     

Tracking particle size distributions in a moving bed biofilm membrane reactor for treatment of municipal wastewater.

A study has been conducted to investigate the effect of loading rates on membrane fouling in a moving bed biofilm membrane reactor process for municipal wastewater treatment, especially analysing the fate of submicron colloidal particles and their influence on membrane fouling. Two operating conditions defined as low and high organic loading rates were tested where the development and fate of the particulate material was characterised analysing the particle size distributions throughout the process. Analysis of the membrane performance showed higher fouling rates for the high-rate conditions. The fraction of colloidal submicron particles was higher in the membrane reactor indicating that fouling by these particles was a dominant contribution to membrane fouling.     

Baffled membrane bioreactor (BMBR) for advanced wastewater treatment: easy modification of existing MBRs for efficient nutrient removal.

In this study, a novel membrane bioreactor (MBR) in which nitrification and denitrification simultaneously proceed in a single reaction chamber is proposed for advanced municipal wastewater treatment. Anoxic/aerobic environments are alternatively created in the proposed MBR by inserting baffles inside the membrane chamber. The performance of the proposed baffled membrane bioreactor (BMBR) was examined at an existing municipal wastewater treatment facility based on long-term operation. Although the procedure was simple, insertion of the baffles actually created the alternative anoxic/aerobic environments in the chamber at a constant interval and showed a great improvement in the nutrient removal. The insertion did not cause any adverse effect on membrane permeability. In this study, almost complete elimination of NH4+-N was observed while around 8 mg/L of NO(3-)-N was detected in the treated water. The modification proposed in this study can immediately be applied to most existing MBRs and is highly recommended for more efficient wastewater treatment.     

推移质动床模型变率的选择与比降变态的研究

根据模型沙起动相似和水流阻力相似要求,推导出推移质动床模型变率应满足的条件,当模型实际采用的变率不能满足要求时,或因选沙不当不能满足水流阻力相似条件时,可采用比降变态方法调整模型水流,在推导出调整后的比降比尺计算式的基础上,分比降变陡和变缓两种情形进行了说明。     

ICEAS 工艺污水处理厂设计与运行

介绍了瓦房店污水处理厂ICEAS工艺的设计流程,各构筑物的技术参数.对该工艺的污泥培养、运行情况进行了分析,结果表明ICEAS工艺适用于北方中小城市.     

Evaluation of a long-term operation of a submerged nanofiltration membrane bioreactor (NF MBR) for advanced wastewater treatment.

Nanofiltration (NF) is considered as one of the most promising separation technologies to obtain a very good-quality permeate in water and wastewater treatment. A submerged NF membrane bioreactor (NF MBR) using polyamide membranes was tested for a long-term operation and the performance of the NF MBR was compared with that of a microfiltration MBR (MF MBR). Total organic carbon (TOC) concentration in the permeate of the NF MBR ranged from 0.5 to 2.0 mg/L, whereas that of the MF MBR showed an average of 5 mg/L. This could be explained by the tightness of the NF membrane. Although the concentration of organic matter in the supernatant of the NF MBR was higher than that in the permeate due to high rejection by the NF membrane, the NF MBR showed excellent treatment efficiency and satisfactory operational stability for a long-term operation.     

焦化废水处理工程的调试与运行

以实际运行中的焦化废水处理站为例,介绍了其调试、运行过程,指出焦化废水调试及稳定运行的控制条件,并对调试运行过程中可能出现的问题及解决措施进行了总结,为同类废水的调试和运行提供了参考。     

Biolak工艺处理城市污水的设计及运行

山东诸城市污水处理厂采用Biolak工艺,一期设计处理能力6.6万m3/d。其进水包含40%生活污水和60%工业废水,设计进水CODCr450mg/L,BOD5200mg/L,SS230mg/L,NH3-N40mg/L,TP5mg/L,设计出水达到《污水综合排放标准》(GB8976-1996)一级标准。介绍了工艺流程,主要设计参数以及Biolak工艺的特点。运行结果表明,该工艺占地小,处理效率高,出水水质达到设计要求。     

一体式厌氧平板膜生物反应器处理酒厂废水的研究

研究了容积负荷、水力停留时间对一体式厌氧平板膜生物反应器处理高浓度酒厂废水效果的影响。试验结果表明,CODCr负荷为5．2～8 kg／(m3·d),水力停留时间3～5 d时,CODCr平均去除率为95％。正常运行时的碱度与VFA的比为2．5～4．5。当CODCr负荷超过10 kg／(m3·d),系统 VFA出现累积,COD去除率下降。水力停留时间对一体式厌氧平板膜生物反应器处理效果有重要影响,水力停留时间应大于70 h。     

Effect of temperature and salinity on the wastewater treatment performance of aerobic submerged fixed bed biofilm reactors.

The influence of temperature (5-35 C) and salinity (up to 20 g/l NaCl) on the wastewater purification process in completely mixed and aerated submerged fixed bed biofilm reactors (SFBBRs) was studied. C- and N-conversion in SFBBRs designed according to the DWA (German Association for Water, Wastewater and Waste) rules for carbon removal was investigated for several months on synthetic wastewater. The DOC degradation rate was even at, according to the DWA, high DOC/BOD loading rates not much affected by temperatures between 5-35 degrees C and salt contents up to 20 g/L NaCl. At these high DOC loadings an appreciable ammonium conversion could also be observed. The ammonium conversion proved to be sensitive to temperature and salinity. At 5 degrees C the ammonium removal rate decreased by a factor of five compared to 25-35 degrees C. Under many operation conditions investigated more than 50% of the converted ammonium was transformed into gaseous nitrogen. The addition of 20 g/L NaCl caused a strong inhibition of the ammonium removal rate over the whole temperature range investigated.     

Removal of ibuprofen from wastewater: comparing biodegradation in conventional, membrane bioreactor, and biological nutrient removal treatment systems.

Pharmaceuticals are continually being introduced into the influent of municipal wastewater treatment plants (WWTPs). Developing a better understanding of pharmaceutical removal mechanisms within the different treatment processes is vital in preventing downstream contamination of our water resources. In this study, ibuprofen, a popular over-the-counter pain reliever, was monitored by taking wastewater samples throughout the City of Guelph municipal WWTP. Greater than 95% of ibuprofen was found to be removed in the aeration tank, with aerobic biodegradation being the dominant mechanism. For comparison, first-order kinetics were used to quantify ibuprofen biodegradation in a conventional WWTP aeration tank and in a membrane bioreactor (MBR) pilot plant. The rate constants, k biol, for the conventional tank and the MBR were determined to be (-6.8+/-3.3) L/g SS*d and (-8.4+/-4.0) L/g SS*d, respectively. These two rate constants were found to be statistically similar. Preliminary study of a biological nutrient removal pilot system also suggests that ibuprofen can be anaerobically degraded.     

盐酸盐金霉素废水处理工程的设计与运行

盐酸盐金霉素废水有机物和氨氮浓度都很高,难以处理。工程实践表明,采用ABR—3级A/O—铁碳微电解组合工艺,在进水CODCr5120～15040mg/L、氨氮650～1078mg/L时,出水CODCr和氨氮分别为80～98mg/L、1～10mg/L,达到《污水综合排放标准》(GB8979—1996)一级标准。     

印染废水处理改造工程设计及运行实例

某印染废水处理改造工程设计规模1440m3/d,采用混凝—水解酸化—两级接触氧化—过滤处理工艺。工程实践表明,在进水CODCr2356mg/L、SS294mg/L、色度481倍时,出水CODCr70mg/L、SS36mg/L、色度37倍,达到《纺织染整工业水污染物排放标准》(GB4287—92)的一级标准。     

The effect of public or private structures in wastewater treatment on the conditions for the design, construction and operation of wastewater treatment plants.

Organised in public or private structures, wastewater services have to cope with different framework conditions as regards planning, construction, financing and operation. This leads quite often to different modes of management. In recent years there has been a push for privatisation on the water sector in general, the reasons for which are manifold, ranging from access to external know-how and capital to synergistic effects through integration of wastewater treatment into other tasks of similar or equal nature. Discussed are various models of public/private partnership (PPP) in wastewater treatment, encompassing for example the delegation of partial tasks or even the proportional or entire transfer of ownership of treatment facilities to private third parties. Decisive for high performance and efficiency is not the legal or organisational form, but rather the clear and unmistakable definition of tasks which are to be assigned to the different parties, customers and all other partners involved, as well as of clear-cut interfaces. On account of the (of course legitimate) profit-oriented perspective of the private sector, some decision-making processes in relation to project implementation (design and construction) and to operational aspects will differ from those typically found on the public sector. This does apply to decisions on investments, financing and on technical solutions too. On the other hand, core competencies in wastewater treatment should not be outsourced, but remain the public bodies' responsibility, even with 'far-reaching' privatisation models. Such core competencies are all efforts geared to sustainable wastewater treatment as life-supporting provision for the future or as contribution to the protection of health and the environment and to the development of infrastructure. Major areas of wastewater treatment and other related tasks are reviewed. The paper concludes with a list of questions on the issue of outsourcing.