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采用紫外可见光谱作为检测2,4-二硝基苯酚的方法,pH6或pH3时,2,4-二硝基苯酚的特征吸收峰分别为370 nm及260 nm处;在pH 3~6之间,两特征峰共存。文章提出一种简单的归一拟合方法,首先推导出260 nm处的吸收值与浓度的线性关系,再将pH不同的2,4-二硝基苯酚在370 nm处的吸收值校正到260 nm处。开发了一种简单快捷无需调节pH测定2,4-二硝基苯酚浓度的方法。 相似文献
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(I) 引言α-二硝基苯酚学名2, 4-二硝基苯酚〔2,4-C_6H_3OH(NO_2)_2〕,是一种淡黄到黄色的粉状結晶,熔点112.9℃,通常用2,4-二硝基氯化苯經碱性水解而成,工业品主要用于制造硫化染料,4-硝基,2-氨基苯酚和盐酸2,4-二氨基苯酚等。β-二硝基苯酚学名2,6-二硝基苯酚〔2,6-C_6H_3OH(NO_2)_2〕,系黄色至亮黄色結晶,熔点63~64℃,在比色法测定中用为单色pH指示剂,其顔色变化由无色至黄色, 相似文献
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近年来针对痕量2,4-二硝基苯酚的检测,出现了很多新的方法,本文筛选其中比较实用并有独创性的方法.进行对比总结. 相似文献
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系统地研究了以4,6-二硝基间二氯苯(DCDNB)为原料经单水解后氨解两步反应制备聚对亚苯基苯并咪口恶二唑(PBIO)的关键中间体5-氨基-2,4-二硝基苯酚(ADNP)的合成新路线及其优化条件。结果表明:采用NaOH在水溶剂中100℃回流下进行两个氯基的选择单水解反应,制得纯度98%以上的高收率5-氯-2,4-二硝基苯酚(CDNP);以1,4-二氧六环为溶剂,在150℃下使用氨水压力氨解另一个氯基合成ADNP,经精制后获得纯度98.5%以上、总收率达73.6%(以DCDNB计)的产品。产品经IR、1HNMR、13CNMR及MS等定性确认,合成过程已呈现有机污染少、操作方便、产品质量优异、经济性良好及易于产业化等特色,为进一步研发合成新型高性能材料PBIO及其新单体提供技术基础及中间体来源。 相似文献
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以KMnO4和MnSO4·H2O为原料,在常温常压和水热条件下制备新生态MnO2,借助XRD、TEM、低温N2吸附-脱附等手段对材料进行表征,比较不同制备方法对产物结构和吸附性能的影响。结果表明,反应温度和压力对新生态MnO2的形貌和吸附性能有较大影响,常温常压下合成产物均为短棒状,水热合成产物为介孔纤维,对2,4-二硝基苯酚的吸附效果优于常温常压合成产物。新生态MnO2对2,4-二硝基苯酚的等温吸附和吸附动力学分别符合Langmuir等温式(R2>0.99)和准二级吸附动力学方程(R2>0.99),说明2,4-二硝基苯酚在新生态MnO2上为单分子层吸附和化学吸附。溶液pH值能显著影响2,4-二硝基苯酚在新生态MnO2上的吸附,在pH=7时最大吸附量为2.539 mg/g。 相似文献
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提出了经氨氧化法制得 2 ,4 二氯苯腈 ,然后水解得到 2 ,4 二氯苯甲酸的合成路线。 2 ,4 二氯甲苯在合适的催化剂和反应条件下 ,2 ,4 二氯苯腈的产率为 89 5 % ,经简单水洗后 ,产品纯度为 98 9%。 2 ,4 二氯苯腈在硫酸中较温和条件水解得到 2 ,4 二氯苯甲酸 ,产率为 95 5 %。 相似文献
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以取代苯甲醛为原料,采用醇醛缩合反应和珀金反应完成了反,反-2,4-二甲基-5(对硝基苯基)戊-2,4-二烯酸和反,反-2,4-二甲基-5-(间硝基苯基)戊-2,4-二烯酸的有效全合成,并确定了最佳反应条件,化合物3b为尚未见文献报道的新化合物,其结构经红外光谱,核磁共振证实。 相似文献
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Adsorption characteristics of 2,4-Dichlorophenoxyacetic acid (2,4-D) and 2,4-Dinitrophenol (2,4-DNP) onto granular activated
carbon (GAC) were studied to obtain basic information on their removal from aqueous solution. Single component adsorption
equilibria of 2,4-D and 2,4-DNP dissolved in water have been measured for three kinds of GACs (F400, SLS103, and WWL). In
case of 2,4-D, the magnitude of adsorption capacity was in the order of F400> SLS103>WWL, and that for 2,4-DNP was SLS103>
F400> WWL. The influence of temperature and initial pH of aqueous solution on adsorption has been discussed in detail by using
the Sips equation. 相似文献
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通过实验室小试,研究了一体式膜生物反应器(MBR)对微污染湖水中的微量2,4-二氯酚(2,4-DCP)的去除效果。64 d的连续试验证实,当进水2,4-DCP浓度在2~200 μg·L-1时,MBR对2,4-DCP的平均去除率达936%。出水2,4-DCP浓度平均为428 μg·L-1,满足《城市供水水质标准》的要求。同时采用间歇试验对MBR去除2,4-DCP的机理进行了研究,证实生物作用在2,4-DCP的去除中起主要作用,MBR对2,4-DCP的去除符合零级动力学过程,降解速率常数为106 μg·L-1·min-1。此外,试验证实MBR对DCP的去除是基于二级基质原理,而向反应器内投加葡萄糖并不能促进MBR对2,4-DCP的去除。 相似文献
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《分离科学与技术》2012,47(16):2329-2336
Adsorption experiments were conducted to study the removal of 2,4-dichlorophenol (2,4-DCP) from aqueous solution by a new low-cost adsorbent-activated bamboo charcoal. The results showed that acidic pH was favorable for the adsorption and removal of 2,4-DCP. Higher initial 2,4-DCP concentrations led to higher adsorption capacity. Most of the adsorption of 2,4-DCP occurred within the first 5 min, and about 90% of 2,4-DCP were removed from solution. After 5 min, the adsorption capacity increased slowly with contact time and the adsorption reached equilibrium in less than 100 min. As the adsorbent dose was increased, the removal of 2,4-DCP was increased, while the equilibrium time was slightly affected. Adsorption kinetics could be best described by the pseudo-second-order model, independent of adsorbent dosages. The adsorption behavior of 2,4-DCP onto bamboo charcoal fitted both Langmuir and Freundlich isotherms well, but followed Freundlich isotherm more precisely. This study demonstrated for the first time that activated bamboo charcoal could be used for the removal of 2,4-DCP in water treatment. 相似文献
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废水中较高浓度的2,4-二氯酚(2,4-DCP)以溶解态和胶体2种形态存在。研究了间歇式电辅助微生物体系(IEMS)和连续式电辅助微生物体系(CEMS)对较高浓度2,4-DCP的还原降解效果。结果表明CEMS对溶解性2,4-DCP的降解符合零级反应动力学特征,动力学常数为0.245 h-1,对2,4-DCP降解中间产物邻氯酚(2-CP)和对氯酚(4-CP)的降解也为零级反应,动力学常数分别为0.048、0.081 5 h-1。IEMS在停止电辅助期间对胶体态2,4-DCP的水解效率远高于CEMS,2个体系均为零级反应,动力学常数分别为0.083 4、0.027 1 h-1。较高浓度的2,4-DCP宜采用IEMS处理。 相似文献
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Katsuhiko Saido Shigeyasu Motohashi Takeshi Kuroki Tadashi Ikemura Makoto Kirisawa 《应用聚合物科学杂志》1984,29(11):3261-3268
Bis(2,4-diphenylbutyl) phathalate, a plasticizer for poly(vinyl chloride) (PVC), was synthesized from 2,4-diphenyl-1-butene obtained by a thermal decomposition under reduced pressure of waster polystyrene. The heat stability of bis(2,4-diphenylbutyl) phthalate was determined by thermogravimetric analysis and compared with typical plasticizers. It was recognized that bis(2,4-diphenylbutyl) phthalate showed high heat resistant. A test sheet of plasticized PVC with bis(2,4-diphenylbutyl) phthalate and bis(2-ethylhexyl) phthalate was prepared. The test sheet was used for determination of the plasticizing performance of bis(2,4-diphenylbutyl) phthalate. Although the effect of bis(2,4-diphenylbutyl) phthalate imparting flexibility to PVC is poorer than that of bis(2-ethylehexyl) phthalate, the former phthalate is well compatible with PVC and exceedingly heat-resistant. 相似文献
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Nor Azah Yusof Nor Dyana Zakaria Nor Amirah Mohd Maamor Abdul Halim Abdullah Md. Jelas Haron 《International journal of molecular sciences》2013,14(2):3993-4004
Molecularly imprinted polymers (MIPs) were prepared by bulk polymerization in acetonitrile using 2,4-dinitrophenol, acrylamide, ethylene glycol dimethacrylate, and benzoyl peroxide, as the template, functional monomer, cross-linker, and initiator, respectively. The MIP membrane was prepared by hybridization of MIP particles with cellulose acetate (CA) and polystyrene (PS) after being ground and sieved. The prepared MIP membrane was characterized using Fourier transform infrared spectroscopy and scanning electron microscopy. The parameters studied for the removal of 2,4-dinitrophenol included the effect of pH, sorption kinetics, and the selectivity of the MIP membrane. Maximum sorption of 2,4-nitrophenol by the fabricated CA membrane with MIP (CA-MIP) and the PS membrane with MIP (PS-MIP) was observed at pH 7.0 and pH 5.0, respectively. The sorption of 2,4-dinitrophenol by CA-MIP and PS-MIP followed a pseudo–second-order kinetic model. For a selectivity study, 2,4-dichlorophenol, 3-chlorophenol, and phenol were selected as potential interferences. The sorption capability of CA-MIP and PS-MIP towards 2,4-dinitrophenol was observed to be higher than that of 2,4-dichlorophenol, 3-chlorophenol, or phenol. 相似文献