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采用原位聚合法,以三聚氰胺-甲醛(MF)为壁材分别制备了包覆环氧树脂与硫醇的微胶囊,并将两种微胶囊混合制备成单组分环氧压敏胶。当外力使微胶囊囊壁破裂后,由于两种芯材具有良好的互溶性,有利于其释放后的相互扩散和均质化,实现快速均匀固化。对微胶囊的微观形貌、尺寸分布、化学结构、热稳定性进行了表征,并研究了单组分压敏胶的固化放热过程与粘接性能。研究结果表明:所制备的微胶囊都呈规则球形,表面光滑,平均粒径在8~10μm左右,包封率都在70%以上;所制备的微胶囊具备良好的储存稳定性,室温下可长期储存而不发生质变,升温到150℃时皆能高效适用;将活性组分进行微胶囊化包覆不会破坏芯材的反应活性,且该胶粘剂在室温甚至低温下都有较好的固化效果;将两种微胶囊混合制备成单组分胶粘剂,并对其进行粘接强度测试,结果表明该微胶囊型单组分室温固化压敏胶十分具有发展潜力。 相似文献
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采用原位聚合法制备了以异丙苯过氧化氢为芯材、脲醛树脂为壁材的微胶囊。研究了稳定剂类别和芯壁比对微胶囊化过程的影响。结果表明,稳定油滴的形成是能得到微胶囊产品的前提条件,而稳定剂对油滴的稳定效果越好,壁材越倾向于形成囊壁;芯壁比的增加会使微胶囊产率下降,芯含量增加;改变芯材或壁材用量调节芯壁比会影响壁材利用率。 相似文献
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以自制沸石分子筛为载体,通过水热法将二甲酸钾负载形成芯材,海藻酸钠、壳聚糖为壳材,以复凝聚法制备出缓释微胶囊。通过FTIR、XPS对微胶囊进行了结构表征,通过缓释及抑菌率测试对其性能进行表征。结果表明:沸石分子筛与二甲酸钾之间可形成复配效应,构成微胶囊的芯材;壳聚糖和海藻酸钠发生静电作用,形成聚电解质膜,构成微胶囊的壳材;制备的微胶囊在pH=2.0的模拟胃环境中稳定,在pH=7.2的模拟肠道环境中二甲酸钾得到了释放,并在3 h内可释放完全;微胶囊包封率为68.33%,二甲酸钾的释放量为137.50 mg/g。微胶囊对大肠杆菌的生长具有一定的抑制作用,并随着微胶囊浓度的增大对大肠杆菌的抑制率呈现增长的趋势,最高抑菌率可以达到85%。 相似文献
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乙烯酮(双乙烯酮)是十分重要的化工中间体,其下游产品较多。江苏某化工厂开发生产乙烯酮(双乙烯酮)下游产品三十多个,年生产规模三万多吨,是国内以乙烯酮(双乙烯酮)为中间体生产精细化学品的综合骨干企业。针对乙烯酮(双乙烯酮)下游产品废水特点,该厂结合企业实际,开展了产品优化,结构调整,清洁生产,资源循环利用,节水降耗等工作,从源头削减了污染物的生产。同时投资二千多万元新建预处理装置三套,6000m3/d废水生化处理装置一套,使全厂乙烯酮(双乙烯酮)下游产品的废水得到了有效的治理。 相似文献
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D. G. Gordeev L. F. Gudarenko M. V. Zhernokletov V. G. Kudel’kin M. A. Mochalov 《Combustion, Explosion, and Shock Waves》2008,44(2):177-189
A semi-empirical equation of state for metals is described. Its capabilities are demonstrated by the example of the equation
of state for aluminum. New experimental data are presented on the location of the isentrope of aluminum for unloading from
the state at p = 229.71 GPa on the shock adiabat to an aerogel (SiO2) of density 0.08 g/cm3.
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Translated from Fizika Goreniya i Vzryva, Vol. 44, No. 2, pp. 61–75, March–April, 2008. 相似文献
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Jorge Marcelo Romero Soledad Bustillo Hugo Enrique Ramirez Maisuls Nelly Lidia Jorge Manuel Eduardo Gómez Vara Eduardo Alberto Castro Alicia H. Jubert 《International journal of molecular sciences》2007,8(7):688-694
A thermochemical rather simple experimental technique is applied to determine the enthalpy of formation of Diperoxide of ciclohexanone. The study is complemented with suitable theoretical calculations at the semiempirical and ab initio levels. A particular satisfactory agreement between both ways is found for the ab initio calculation at the 6–311G basis This set level. Some possible extensions of the present procedure are pointed out. 相似文献
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The objective of the study was to explore the effect of the degree of deacetylation (DD) of the chitosan used on the degradation rate and rate constant during ultrasonic degradation. Chitin was extracted from red shrimp process waste. Four different DD chitosans were prepared from chitin by alkali deacetylation. Those chitosans were degraded by ultrasonic radiation to different molecular weights. Changes of the molecular weight were determined by light scattering, and data of molecular weight changes were used to calculate the degradation rate and rate constant. The results were as follows: The molecular weight of chitosans decreased with an increasing ultrasonication time. The curves of the molecular weight versus the ultrasonication time were broken at 1‐h treatment. The degradation rate and rate constant of sonolysis decreased with an increasing ultrasonication time. This may be because the chances of being attacked by the cavitation energy increased with an increasing molecular weight species and may be because smaller molecular weight species have shorter relaxation times and, thus, can alleviate the sonication stress easier. However, the degradation rate and rate constant of sonolysis increased with an increasing DD of the chitosan used. This may be because the flexibilitier molecules of higher DD chitosans are more susceptible to the shear force of elongation flow generated by the cavitation field or due to the bond energy difference of acetamido and β‐1,4‐glucoside linkage or hydrogen bonds. Breakage of the β‐1,4‐glucoside linkage will result in lower molecular weight and an increasing reaction rate and rate constant. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 3526–3531, 2003 相似文献
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醋酸纤维素取代基分布与性质的关系 总被引:9,自引:0,他引:9
分析了以吡啶为溶剂的醋酸纤维素的13C-NMR核磁共振谱,得出了三种不同位置羟基的取代度。结合X—射线和DSC分析,初步说明具有相同取代度但未经水解和经过水解的醋酸纤维素(CA) 性质上的差异是由于三个羟基上的取代度分布不同及消晶程度差异所致。 相似文献
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1 INTRODUCTIONBecause of importance of equations of state (EOS)in science and industry,hundreds forms of EOS havebeen presented since latter 19th century.It seems impossible to develop a general equation covering vari-ous kinds of EOS.But for cubic EOS,several generalequations have been reported already. Martin presented the first general equation whichis following p=RT/V-α(T)/(υ β)(υ γ) δ(T)/υ(υ β)(υ γ) (1) Kumar et a1.presented an equation called the most general form of a density-cubic or, alterna tively,volume-cubic mathematical equation,the form of which is as follows 相似文献