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水性紫外光固化环氧丙烯酸酯涂料 总被引:9,自引:0,他引:9
合成了水性紫外光固化涂料用环氧丙烯酸酯预聚物,测定了固化膜的固化时间、硬度、附着力、杨氏模量和伸长率等性能.讨论了预聚物对固化膜性能的影响,并考察了涂料的流变性能. 相似文献
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紫外光固化环氧丙烯酸酯涂料 总被引:2,自引:0,他引:2
本文主要介绍了紫外光固化环氧丙烯酸酯涂料的树脂合成,涂料制备,测试性能,涂料的成膜机理以及应用领域。树脂的合成,主要是将丙烯酸基因引入环氧树脂中,使得环氧大分子两端接上丙烯酸酯基,从而具备光固化的特性。紫外光固化环氧丙烯酸酯涂料的主要成分为环氧丙烯酸酯树脂,光敏剂和活性稀释剂,其中活性稀释剂的选择使用对涂料的施工性能与涂膜性能都有一定的影响。环氧丙烯酸酯涂料添加光敏剂后,用紫外光照射,光敏剂分解产生游离基,然后通过游离基聚合反应,线型的环氧丙烯酸酯树脂与活性稀释剂交联生成体型的高聚物,涂层便固化成膜。紫外光固化环氧丙烯酸酯涂料在测试性能方面,表现为突出的光泽度及硬度,另外,冲击强度和附着力也比较理想,因此,其用途十分广泛。特别适用于塑料制品,纸张、木材、皮革、织物、玻璃、印刷线路板等不能烘烤的产品的涂装,也适用于金属制品,标牌等产品作表面保护装饰涂层。 相似文献
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通过聚氨酯丙烯酸酯(PUA)预聚物中的端-NCO与双酚F型环氧丙烯酸酯(BPF-EA)低聚物中的侧-OH反应,制备了一种光活性聚氨酯改性环氧丙烯酸酯(PMEA)低聚物。将两种低聚物与活性稀释剂以及光引发剂均匀混合并进行了UV固化。研究了EA和PMEA低聚物及固化膜的性能。结果表明,制备的BPF-EA低聚物与自制的双酚A型环氧丙烯酸酯低聚物相比黏度大幅下降。EA和PMEA固化膜具有高的交联密度、良好的附着力以及优异的耐化学品性能。由于PUA预聚物的引入,聚合物链中具有一定量的柔性基团,PMEA固化膜的铅笔硬度、热稳定性和拉伸强度略有下降,断裂伸长率明显增加。固化膜的柔韧性变好。其中,以20%(质量分数)TPGDA为稀释剂配制的UV固化涂料,固化膜的综合性能最好。 相似文献
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SiO_2消光剂(UV55C)对环氧豆油丙烯酸酯性能的影响 总被引:3,自引:0,他引:3
考察了 Si O2 消光剂 (UV5 5 C)对环氧豆油丙烯酸酯及其涂膜性能的影响。试验结果表明 :Si O2 消光剂 (UV5 5 C)的加入 ,降低了环氧豆油丙烯酸酯的固化速率和其涂膜的光泽度 ,但提高了其涂膜的硬度、耐磨性和附着力 相似文献
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Dandan Zhang Hongbo Liang Jiang Bu Lei Xiong Shengmei Huang D. D. Zhang H. B. Liang J. Bu L. Xiong S. M. Huang 《应用聚合物科学杂志》2015,132(24)
In this study, epoxidized soybean oil was modified to prepare acrylated epoxidized soybean oil (AESO) and vinyl/acrylate ended soybean oil (VASO), which were blended with mercaptopropyl polyhedral oligomericsilsequioxane (POSS‐SH) to prepare UV curable thiol‐acrylate and thiol‐ene‐acrylate hybrid coatings. Photopolymerization processes of the coatings were measured and the results showed that addition of POSS‐SH obviously increased the conversion of double bond. The physical and mechanical properties of all cured samples were investigated, which indicated that the pencil hardness, tensile strength, and fracture toughness were significantly improved by POSS‐SH. Moreover, with increasing POSS‐SH content, the water contact angles of cured samples were increased, and the water resistance was greatly improved. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 42095. 相似文献
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Stefan Oprea 《Polymer-Plastics Technology and Engineering》2015,54(4):342-349
Synthetic and natural acrylate oligomers blends and their blends with different ratios of crude soybean oil were studied as environmentally degradable and eco-compatible materials. Two of the components acrylated epoxidized soybean oil (AESO) and crude soybean oil are bio-sourced oligomers. Their biodegradability under soil burial in natural condition was characterized by FT-IR and mechanical properties and was further confirmed by SEM analyses. A high content of modified and crude soybean oil present in the sample composition had enhanced the adhesion of microorganism onto the polymer surface, which in turn resulted in high biodegradation rates under soil burial conditions. 相似文献
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Sukanya Pradhan Smita Mohanty Sanjay K. Nayak 《Journal of Coatings Technology and Research》2018,15(3):515-526
The present work addresses the critical requirements for the coating industry such as developing the sustainability of biobased materials and simultaneously achieving a balanced combination of coating properties. In this study, acrylated epoxidized soybean oil (AESO) has been successfully synthesized from epoxidized soybean oil and acrylic acid. Subsequently, AESO was modified using a biobased long chain diacid (Pripol-1009) with the assistance of a water/ethanol blend to form waterborne epoxy acrylate (WBEA). The properties of the cured WBEA with 2,5-bis(tert-butylperoxy)-2,5-dimethylhexane as initiator were studied through spectral analysis, coating properties evaluation, corrosion resistance, and morphological and thermal analysis. The results revealed that WBEA exhibited relatively better mechanical, thermal and corrosion resistance characteristics over cured waterborne epoxy. 相似文献
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Minghui He Shun Jiang Ruixin Xu Jianwen Yang Zhaohua Zeng Guangxue Chen 《Progress in Organic Coatings》2014
Nowadays biosource-based materials have received revitalized interest for their ability to substitute for petrochemical-based materials. In this paper, we report a facile synthetic method of soybean oil-based polyfunctional acrylate (PFA) for UV-curable materials. Specifically, rapid and highly efficient side-chain functionalization of soybean oil was achieved via photoclick thiol-ene reaction, soybean oil-based polycarboxylic acid (PCA) was thus obtained. Next, by DCC (N,N′-dicyclohexylcarbodiimide) catalyzed esterification reaction with hydroxypropyl acrylate, polyfunctional acrylate (PFA) was synthesized at room temperature. Real-FTIR result indicated that almost 100% conversion of double-bond within vegetable oil was observed within 16.7 min, yielding the soybean oil-based polycarboxylic acid quantitatively. Furthermore, the structure of PFA was confirmed by 1H NMR and FTIR. Finally, the excellent UV-curing rate of PFA was revealed by real-FTIR. 相似文献
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Bio-based coating materials have emerged as an environmentally friendly alternative to petrochemical based ones due to their sustainability, lower carbon footprint and often lower cost. Acrylated vegetable oils and their derivatives are increasingly preferred for advanced photo-curable “green” coatings due to a number of technical and commercial benefits. We report a novel family of acrylate-functional monomers/oligomers derived from epoxidized soybean oil (ESO) and epoxidized soy-methyl ester (EME), using 2-hydroxyethyl acrylate (HEA) as an acrylating agent. Using super-acid catalyzed etherification, acrylated soy-monomers and oligomers with lower viscosity and high acrylate content have been synthesized. Soy-acrylate products are characterized for their chemical structures and functionality using chemical, physical and spectroscopic methods. 相似文献
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Organic–inorganic hybrid coating based on methacrylated/phosphorylated epoxidized soybean oil were obtained by combining photopolymerization and sol–gel process. A series of novel methacrylated and phosphorylated epoxidized soybean oil/silica coating materials were prepared from tetraethoxysilane (TEOS), and acrylated soybean oil via sol–gel technique. Acrylated epoxidized soybean oil (AESO) is obtained by reacting epoxidized soybean oil (ESO) with methacrylic acid and vinyl phosphonic acid. The characterization of AESO was performed by NMR and IR spectroscopy. 相似文献