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1.
Polymer/filler composites have been widely used in various areas. One of the keys to achieve the high performance of these composites is good interfacial interaction between polymer matrix and filler. As a relatively new approach, the possibility to enhance polymer/filler interfacial interaction via crystallization of polymer on the surface of fillers, i.e., interfacial crystallization, is summarized and discussed in this paper. Interfacial crystallization has attracted tremendous interest in the past several decades, and some unique hybrid crystalline structures have been observed, including hybrid shish-kebab and hybrid shish-calabash structures in which the filler served as the shish and crystalline polymer as the kebab/calabash. Thus, the manipulation of the interfacial crystallization architecture offers a potential highly effective route to achieve strong polymer/filler interaction. This review is based on the latest development of interfacial crystallization in polymer/filler composites and will be organized as follows. The structural/morphological features of various interfacial crystallization fashions are described first. Subsequently, various influences on the final structure/morphology of hybrid crystallization and the nucleation and/or growth mechanisms of crystallization behaviors at polymer/filler interface are reviewed. Then recent studies on interfacial crystallization induced interfacial enhancement ascertained by different research methodologies are addressed, including a comparative analysis to highlight the positive role of interfacial crystallization on the resultant mechanical reinforcement. Finally, a conclusion, including future perspectives, is presented.  相似文献   

2.
A core–shell hybrid nanostructure, possessing a hard backbone of multiwalled carbon nanotubes (MWNTs) and a soft shell of brush‐like poly(methyl methacrylate), has been successfully prepared via a reversible addition–fragmentation chain transfer (RAFT) process using a RAFT agent immobilized on MWNTs. Polymer‐modified MWNTs are easily dispersed in good solvents for the grafted polymer, such as toluene, tetrahydrofuran and CHCl3. This observation has been confirmed by transmission electron microscopy analysis. The content of polymer in the functionalized MWNTs can be well controlled by the feed ratio. It is believed that realizing these hybrid structures, on the basis of such simple grafting, will pave the way for the design, fabrication, optimization and eventual application of more functional carbon nanotube‐related nanomaterials. Copyright © 2007 Society of Chemical Industry  相似文献   

3.
有机-无机分子印迹杂化材料的研究进展   总被引:1,自引:0,他引:1  
分子印迹技术是制备选择性识别特定分子的聚合物的方法,因其制备简单、稳定性好且具有特异分子识别功能使其在色谱分离、固相萃取、化学传感和模拟酶催化等方面都有广泛的应用。有机-无机杂化分子印迹聚合物集有机和无机聚合物的优点,不仅机械强度高,而且耐溶剂性好,是分子印迹技术的一个崭新领域。在介绍有机-无机杂化分子印迹聚合物基本概况的基础上,综述了有机-无机杂化分子印迹聚合物制备的原理、方法和特点,并对未来的发展提出了展望。  相似文献   

4.
This paper provides a rigorous literature review in a field of glass-fiber composites. Glass-fiber composite is a type of fiber-reinforced polymer composites. Glass-fiber composite holds good properties such as low density, high strength, and easy processing, so widely used in aerospace, automotive, and construction. Fabrication of glass-fiber composite has been discussed in the present study. Combining the glass-fiber with other fibers into a single polymer matrix results in the development of hybrid glass-fiber composites. The hybridization in glass-fiber composites raised new ideas for future in the field of composites.  相似文献   

5.
利用溶胶凝胶法制备高分子梯度玻璃前体 ,在这个体系中加入钛酸丁酯 ,形成高分子梯度玻璃。采用X射线散射能谱 (EDAX)、吸收光谱仪、隧道扫描电子显微镜 (SEM)、射线衍射仪 (XRD)对产品进行了表征 ,发现在样品(棒状 )中钛离子浓度由中心向边缘逐渐降低 ,呈梯度分布 ,样品在可见光范围内无明显的吸收峰 ,说明样品有较好的光学透明性 ,材料的颗粒分布均匀 ,粒径的大小为 40~ 6 0nm ,说明其有机相和无机相是均匀混合的 ,材料中没有明显的晶态物质  相似文献   

6.
A review on the mechanical properties of hybrid fibers-reinforced polymer composite is presented in this article. Fiber-reinforced polymer composite has a lot of advantages such as high strength, low density, and ease of processing. Fiber-reinforced polymer composite has been used in many areas such as aerospace, automotive, and construction. Incorporation of two or more fibers into a single polymer matrix leads the development of hybrid composite. Hybridization can improve the mechanical properties of single fiber-reinforced polymer composite. This study shows that mechanical properties of natural fiber-reinforced polymer composite increase due to incorporation of comparably high elongation fibers.  相似文献   

7.
A novel polymerizable pigment based on polymerizable surfactant-encapsulated polyoxometalate complexes has been developed. While retaining the intrinsic colors of polyoxometalates, the complexes are organically compatible and are readily incorporated into polymer matrices by means of copolymerization. During the copolymerization process, the complexes can covalently graft onto polymer chains, creating a molecular hybrid between the complexes and polymer matrices, thereby effectively avoiding phase separation between the two components which results in high transparency of the colored polymer. In addition, the complexes exhibit good coloration efficacy, provide stable colors and have little effect on polymer processibility.  相似文献   

8.
高分子阻尼材料作为一类环保功能材料,将向高性能、宽温域的方向发展。传统的阻尼改性方法(如共混、共聚、无机杂化等)及近年来发展起来的互穿聚合物网络和添加压电陶瓷等研究手段都存在一定的局限性。新近开发的利用有机小分子与极性高聚物形成杂化体的方法所得到的阻尼材料的性能非常突出,是一种很有前途的阻尼改性新方法。本文在对现有的二元、三元杂化体系进行分析对比的基础上,对影响有机杂化阻尼材料动态力学性能的因素进行了探讨,为今后该领域的研究工作提供参考。  相似文献   

9.
Boron nitride (BN) is an eminent inorganic compound having many interesting characteristics such as improved oxidation resistance, mechanical strength, good thermal conductivity (TC), higher bandgap, high chemical stability, thermal stability, high hydrophobicity, and electrical insulation. The use of BN as a filler in polymers is a well-established strategy to tailor the properties of polymer composites. Recent studies depict an interesting urge to reap the synergistic effect of various nanofillers with BN in the form of hybrids. Hence the consolidation of the works on BN based hybrid fillers would definitely attract researchers so that these new filler systems could be transformed into useful polymer nanocomposites in future. This review article focuses on the synthesis and characterization of various boron nitride based hybrids in detail. Moreover, the review also throws light on different BN hybrid reinforced polymer nanocomposites (PNCs) and their thermal, electrical, electronic as well as biomedical applications in a detailed manner. Thus the review anticipates serving as a tool toward understanding the recent trends in the field of boron nitride hybrid based ternary polymer composites.  相似文献   

10.
The bacterium Pseudomonas oleovorans was utilized to produce a novel natural-synthetic hybrid block copolymer. This hybrid biomaterial consists of the natural hydrophobic polymer polyhydroxyoctanoate (PHO) end-capped with hydrophilic synthetic diethylene glycol (DEG). The addition of the synthetic component, in the form of PEG106, to the bioprocessing stage significantly affected polymer yield and properties compared to its non-hybridized counterpart. Compared to PHO polymer, the PHO-DEG hybrid possessed a significantly higher C8 component and reduced molecular mass. In contrast, thermal and crystalline properties were similar in both polymer types. While the molecular weight ratio of the natural and synthetic blocks is approximately 1000:1, the small hydrophilic component exerted a powerful influence during polymer processing. Under conditions of high humidity, solvent cast films of the PHO-DEG hybrid self-assembled into ordered microporous arrays. Thus, a novel natural-synthetic hybrid comprized of biocompatible components has been produced.  相似文献   

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