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锡偶联型溶聚丁苯胶性能评价 总被引:7,自引:0,他引:7
本文研究了具有适宜的苯乙烯、乙烯基含量及其配比的15立升釜聚合的锡偶联型溶聚丁苯橡胶(S-SBR)的硫化及力学性能、古德里奇疲劳温升、动态力学及摩擦性能,并与低温乳聚丁苯橡胶(E-SBR)进行了平行对比。结果表明,锡偶联型S-SBR是一种集较佳的静态性能、优异的动态性能、令人满意的安全及低能耗性为一体的新型胎面材料。 相似文献
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增韧SMA的制备及与PC的共混改性 总被引:9,自引:2,他引:7
研究了SBS增韧SMA树脂体系,采用二次共混工艺,用15%(质量)的SBS可以很好地增韧SMA树脂;用增韧的SMA树脂与PC进行共混,考察了体系的力学性能和微观相结构,制备出综合力学性能良好、加工性能优于纯PC的共混材料。当增韧SMA/PC为20/80时,共混材料的力学性能与纯PC相近,达到了预期改性PC的目的。 相似文献
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超细Al(OH)3对聚氨酯弹性体性能的影响 总被引:3,自引:0,他引:3
以端羟基聚丁二烯和甲苯二异氰酸酯等为主要基材,以超细A1(OH)3作为阻燃消烟剂,制备了聚氨酯弹性体,研究了A1(OH)3粒度和含量对弹性体的物理力学性能和阻燃性能的影响,测试了材料的物理力学性能、可见光的透过率和燃烧性能。结果表明,通过改变填料的粒度和含量,可以大幅度提高材料的物理力学性能和阻燃消烟性能,当粒度(50%填料粒子的粒径)为7.12μm,含量为15份时,聚氨酯材料可以获得较佳的阻燃消烟效果和物理力学性能。 相似文献
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相容剂对PS/PP共混合金混容形态和性能的影响 总被引:3,自引:0,他引:3
研制了马来酸酯接枝聚丙烯相容剂,并将其用于聚苯乙烯/聚丙烯的共混改性;通过力学性能测试、透射电镜分析、差示扫描量热分析等方法研究了相容剂对PS/PP合金的混容形态和力学性能的影响。结果表明:相容剂的加入,使PS/PP由不相容的独立聚集的两相变为相畴很小的细分散相,共混高分子的链段运动也表现为趋于均相结构的运动方式。加入相容剂后共混材料的冲击强度有明显提高,拉伸强度也有所上升。相容剂的含量对性能也有较大影响,相容剂用量为8%时,力学性能最好,从DSC测试中可以看到此时共混物趋向均相体系;继续增大相容剂用量,合金的力学性能反而下降。 相似文献
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本文对LCF/PSU颅骨修补材料及颅骨的耐95%酒精和生理盐水老化性能进行了研究。研究发现LCF/PSU材料与颅骨有着相似的耐95%酒精老化性能,但LCF/PSU材料比频骨有着更为优良的耐生理盐水老化性能,当LCF含量超过10wt%时,LCF/PSU颅骨修补材料耐生理盐水老化性能优于耐95%酒精老化性能。 相似文献
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常压烧结莫来石/氧化锆/碳化硅复相陶瓷的研究 总被引:2,自引:1,他引:2
本文对莫来石/氧化锆/碳化硅复相陶瓷进行了N2气氛中常压烧结的研究。实验结果表明:SiC粒子添加量≤20vol%,材料均可致密烧结并可获得均匀的微观结构。SiC粒子的加入使材料人力学性能较莫来石/氧化锆陶瓷有明显的提高,并在SiC含量为10vol%时达到峰值,室温强度和断裂韧性分别为601MPa和5.8MPa^C2,接近热压材料。 相似文献
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《Ceramics International》2020,46(9):13695-13703
Manganese–copper ferrite (MCFO) and dysprosium (Dy)-doped manganese–copper ferrite nanocomposites (Mn0.5Cu0.5DyxFe2−xO4) (x = 0, 0.05, 0.10, and 0.15) were synthesized by sonochemical method. Crystal structure and the structural parameters of the MCFO were analyzed based on the doping concentration of Dy ion. It was observed that the average crystalline size of the synthesized nanocomposite decreases when the concentration of Dy increases. The existing spherical surface morphology of the MCFO and Dy-doped MCFO nanocomposites were obtained through scanning electron microscopy. In the UV spectrum, the pristine MCFO sample showed an absorbance peak at 743 nm whereas the absorbance values of Dy-doped ferrite nanocomposite considerably shifted (blue) toward a lower wavelength (231–222 nm). The dielectric parameters of all ferrite nanocomposites were studied in the frequency range of 100 Hz to 5 MHz. The dielectric spectrum revealed that dielectric constant and loss tangent decreased with increased doping concentration of Dy ion. The saturation magnetization also changed with Dy doping in MCFO. The impact of Dy on manganese–copper ferrite changed the optical, dielectric and magnetic properties of the prepared binary ferrite nanocomposite, which can be used for microwave-absorbing material applications. 相似文献
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E. S. Zainudin S. M. Sapuan K. Abdan M. T. M. Mohamad 《Polymer-Plastics Technology and Engineering》2013,52(1):97-101
Mechanical strengths of a banana pseudo-stem (BPS) fiber and unplasticized polyvinyl chloride (UPVC) composite were evaluated to assess the possibility of using it as a new material in engineering applications. Samples were fabricated by the compression molding process with reference to the effect of filler loading. The samples were submitted to mechanical tests to measure tensile, flexural, and impact properties of the composites. The nature of adhesion between the matrix and the reinforcement and information relating the structure of mechanical properties can be obtained by scanning electron microscopy (SEM) assessment of the composite fracture surface. The mechanical properties show that the composites did not have good adhesion between filler and matrix; on the other hand, the filler insertion improved the flexural modulus and the material rigidity. 相似文献
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核壳纳米粒子作为复合纳米粒子一个重要的分支,由于其光、磁和催化等方面的优异性能,近年来引起了人们广泛的关注.本文主要介绍了核壳纳米粒子的制备方法及诸多性能,并对核壳纳米粒子的发展进行了展望. 相似文献
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Effects of support and additive on oxidation state and activity of Pt catalyst in propane combustion 总被引:1,自引:0,他引:1
The effects of support and additive on the oxidation state and catalytic activity of Pt catalyst in the low temperature propane combustion were systematically investigated on Pt/MgO, Pt/Al2O3 and Pt/SiO2–Al2O3. The catalytic activity varied much with both support materials and additives. The catalyst on the more acidic support showed higher activity, and the catalytic activity on every support materials increased as the electronegativity of additives increased, while some additives decreased the activity. The oxidation state of platinum, estimated by white line intensity of Pt LIII-edge XANES spectrum, also varied with the support and additives, and additives with higher electronegativity greatly prevented the platinum from its oxidation under oxidising atmosphere. Among almost all the catalysts with various supports and various additives, a clear relationship was observed between the oxidation state of platinum and the catalytic activity; the more metallic platinum showed higher activity. Thus, it was concluded that the total electrophilic/electrophobic property derived from those of the support and additive controls the oxidation state of platinum, which intensively affects the catalytic activity; i.e. higher electrophilic property provides less oxidised platinum, resulting in high catalytic activity. The mechanism of this effect was also discussed on the basis of thermochemical data, and it was proposed that the electrophobic materials promote the noble metal oxidation since the noble metal oxo-anion such as PtOδ− is more stabilised with electrophobic cation. 相似文献
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丁腈橡胶的伏安特性与功率特性的研究 总被引:1,自引:0,他引:1
本文对乙炔碳黑填充丁腈橡胶(NBR)的伏安特性及其功率特性进行了研究,分析了丁腈橡胶在交、直流电场下的导电机理,并对环境温度变化时的丁腈橡胶的功率及功率与电压的变化规律提出了相应的关系式,同时对导电丁腈橡胶的物理机械性能进行了研究与测定。 相似文献
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