共查询到19条相似文献,搜索用时 184 毫秒
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针对FCC汽油重馏分加氢精制后的硫醇(称为重硫醇)的脱除开发了一种自制脱臭催化剂,考察了反应温度、催化剂质量分数、硫醇类型等对催化剂体系脱除硫醇效果的影响,并实际考察了催化剂体系对加氢精制汽油中重硫醇的脱除效果。实验结果表明,一定范围内,温度越高,硫醇脱除效果越好; 催化剂浓度越大,硫醇脱除效果越好;异构硫醇比正构硫醇难脱除,高碳数硫醇比低碳数硫醇难脱除;该催化剂体系可以将油品中100ug/g的硫醇硫降至5ug/g以下,博士试验合格。 相似文献
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从终点电位设定、滴定溶剂、试验样品、取样量四个方面探讨了自动电位滴定法测定汽油硫醇性硫对分析结果的影响,通过试验,找到影响汽油硫醇性硫测定的主要影响因素,提高了分析精确度,得到满意的结果。 相似文献
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阐述了瑞士万通848型自动硫醇硫分析仪的分析原理和实验方法,从试剂和对分析仪器操作两个方面,对汽油硫醇硫分析过程中的影响因素进行探讨,提出具体措施和操作注意事项. 相似文献
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开发可降硫的催化剂和助剂,既可以降低汽油中硫化物含量,又不损失汽油收率、不降低汽油辛烷值已成为新的研究思路。作者以Ce改性的HZSM-5沸石为催化剂,在固定床微型反应器中研究了丁硫醚的催化转化反应。结果表明:Ce改性后的HZSM-5对丁硫醚的脱除具有较高的活性及稳定性;硫化氢的量得到上升,并趋于稳定;丁硫醚转化率明显提高,在350℃下,Ce3 交换量为1.51%时,丁硫醚基本完全转化;而丁硫醚的裂解副产物四氢噻吩(THT)的量有增大趋势。同时探讨了丁硫醚的反应历程,认为烷基硫醚类化合物裂解过程中,碳硫键的断裂生成类硫醇物种的一步是其裂解关键步骤。 相似文献
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国内外对车用汽油硫含量的限制日趋严格,采用有效的技术手段降低催化裂化汽油硫含量是关键。针对FCC汽油中含硫化合物的特点,本文综述了国内外开发的一系列FCC汽油脱硫技术的特点及发展现状,并针对国内成品汽油现状,提出了一种具有低辛烷值损失、高液收、低硫的FCC汽油脱硫新工艺。 相似文献
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FCC汽油脱硫工艺及发展现状 总被引:3,自引:0,他引:3
国内、外对车用汽油硫含量的限制日趋严格,采用有效的技术手段降低催化裂化汽油硫含量是关键。针对FCC汽油中含硫化合物的特点,本文综述了国内外开发的一系列FCC汽油加氢脱硫、吸附脱硫以及一些其他脱硫技术特点和发展现状,并对今后脱硫方法的发展方向加以预测。 相似文献
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通过比较改性镁铝尖晶石与FCC催化剂在不同装填方式时产品汽油中的硫含量,考察改性镁铝尖晶石对不同烃油馏分硫化物的吸附性能。结合物化表征,探讨催化裂化过程中改性镁铝尖晶石对烃油中硫化物的吸附作用。结果表明,镁铝尖晶石经过渡金属改性后,弱酸比例提高,中孔分布集中,可增强尖晶石对硫化物尤其是较大分子硫化物的吸附能力,吸附原料油和裂化产物中的硫化物,将其转化成焦炭或焦炭前驱物沉积于尖晶石表面,是改性尖晶石降低汽油产物硫含量的重要途径之一。镁铝尖晶石中引入适当的过渡金属,可以实现降低催化裂化汽油硫含量的目标。 相似文献
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催化裂化汽油降硫剂的制备与应用 总被引:1,自引:0,他引:1
为降低汽油硫含量,以锌和镧为有效元素合成了催化裂化汽油脱硫钝化剂,在催化裂化装置上进行了工业应用试验。结果表明,当加入量为300×10^-6时,汽油中总硫可以从204×10^-6降低到140×10^-6,脱硫率达36.37%;当加入量为(500~600)×10^-6时,脱硫率可达到50%以上。汽油中的噻吩硫主要以硫化氢形态转移至干气、液化气中。脱硫钝化剂对平衡催化剂的主要性质和FCC产品分布没有明显影响,亦有良好的金属钝化效果。 相似文献
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Behavior of sulfur species present in atmospheric residue in fluid catalytic cracking 总被引:1,自引:0,他引:1
The selective removal of sulfur species in atmospheric residue (AR) is strongly wanted since the species of the hydrodesulfurized AR (HDS-AR) define the sulfur content of the product gasoline in the subsequent fluid catalytic cracking (FCC). Hence, the correlations between sulfur species in HDS-AR and FCC gasoline were explored in the present study. HDS-AR was fractionated into vacuum gas oil (VGO) and vacuum residue (VR) by distillation. Reactivities of HDS-AR (S = 3000 mass ppm) and its VGO (S = 900 mass ppm) were measured by micro activity test to clarify which fractions and sulfur compounds in HDS-AR were converted into gasoline and its sulfur species. The yields and sulfur contents of the product gasoline were 45.0 mass% and 52 mass ppm from HDS-AR and 47.7 mass% and 14 mass ppm from VGO, respectively. The sulfur content of the gasoline from HDS-AR was markedly higher than that from HDS-VGO. The saturate and aromatic fractions in HDS-AR are mainly converted to the gasoline in the FCC process, providing similar gasoline yields from HDS-VGO and HDS-AR. Thiophene, methylthiophenes, and benzothiophenes were major sulfur species in both gasolines from HDS-AR and HDS-VGO. Such sulfur species are concluded to be derived from benzothiophenes in VGO and dibenzothiophenes in VR fractions, respectively through hydrogen transferring ring opening and dealkylation during FCC. Sulfur compounds are also produced from H2S and olefins in FCC, increasing the sulfur content in the product gasoline. The larger sulfur content in the gasoline from HDS-AR than that from HDS-VGO is ascribed to more H2S being produced during the FCC process as well as dibenzothiophenes being present in the feed. 相似文献