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《丙烯酸化工与应用》2004,17(4):44-45
我国对丙烯酸酯反倾销期中复审调查;天津建丙烯酸乳液装置;上海华谊丙烯酸装置投产;沈化13万吨丙烯酸及酯项目签约;聚乙烯纤维粘合涂层用水乳型聚丙烯酸酯微乳液的合成;丙烯酸高级酯共聚物组成与其无皂乳液稳定性研究 相似文献
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以甲基丙烯酸丁酯、丙烯酸为原料合成的齐聚物为乳化剂合成了聚丙烯酸酯无皂乳液.研究了单体配比、链转移剂、pH值对齐聚物的影响,以及反应温度、单体配比、齐聚物用量、引发剂对聚丙烯酸酯无皂乳液性能的影响.并对聚丙烯酸酯无皂乳液进行了红外光谱和透射电镜的表征. 相似文献
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《精细化工》2016,(11)
以可逆加成断裂链转移(RAFT)聚合合成的聚甲基丙烯酸-N,N-二甲氨基乙酯-b-聚丙烯酸六氟丁酯(PDMAEMA-b-PHFBA)为稳定剂,通过无皂乳液聚合技术合成了阳离子型含氟聚丙烯酸酯无皂乳液。用FTIR、1HNMR、TEM、DLS对乳胶粒子和聚合物的结构进行了表征。结果表明,当PDMAEMA-b-PHFBA的用量为总加料质量的2.4%时,乳液的稳定性好,Zeta电位达+57.8 m V,转化率达97.6%,乳胶粒具有明显的核壳结构,粒径分布指数为0.058。将阳离子型含氟聚丙烯酸酯无皂乳液用于皮革涂饰后,随着丙烯酸六氟丁酯用量的增加,涂饰后的皮革对水和二碘甲烷的接触角逐渐增加,当丙烯酸六氟丁酯用量为总单体质量的10%时,涂饰后的皮革对水的接触角为125°,对二碘甲烷的接触角为81.5°。 相似文献
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以可逆加成-断裂链转移(RAFT)聚合合成的聚甲基丙烯酸N,N-二甲氨基乙酯-b-丙烯酸六氟丁酯(PDMAEMA-b-PHFBA)为稳定剂,通过无皂乳液聚合技术合成了阳离子型含氟聚丙烯酸酯无皂乳液。采用红外光谱(FT-IR)、核磁共振氢谱(1H-NMR)、透射电子显微镜(TEM)、动态光散射(DLS)对乳胶粒子和聚合物的结构进行了表征。结果表明,当PDMAEMA-b-PHFBA用量为2.4%时,乳液的稳定性好,转化率高,乳胶粒具有明显的核壳结构,且粒径分布窄。将阳离子型含氟聚丙烯酸酯无皂乳液用于皮革涂饰后,皮革表面的防水防油性得到明显提高,随着丙烯酸六氟丁酯用量的增加,涂饰后的皮革对水和二碘甲烷的接触角逐渐增加,当丙烯酸六氟丁酯用量为10%时,涂饰后的皮革对水的接触角为125?,对二碘甲烷的接触角为81.5?。 相似文献
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以甲基丙烯酸十二氟庚酯(FM)、丙烯酸丁酯(BA)、苯乙烯(St)、甲基丙烯酰氧乙基三甲基氯化铵(DAC)、丙烯酸十八酯(ODA)为原料,采用无皂乳液聚合,制得了阳离子含氟丙烯酸酯多元共聚物乳液,并对聚合物的结构、组成进行了表征,研究了引发剂、FM的用量对乳液耐水性和稳定性的影响。单独使用含氟乳液对纤维类织物进行表面涂敷,水和油滴在织物上所成的接触角最大可分别达到135°和87°,同时织物的抗张强度、耐折度、平滑度分别提高13.45%、15.38%和60.52%。 相似文献
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本文研究了以甲基丙烯酸环氧丙酯作为活性单体,采用种子乳液聚合制备四元体系的共聚物乳液,对其稳定性,流变性等性能进行了表征测试,考察了甲基丙烯酸环氧丙酯及其含量对乳液性能的影响. 相似文献
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以3-甲基丙烯酰氧丙基三甲氧基硅烷(MPTS)为功能改性单体,丙烯酸酯及少量的丙烯酸为主要共聚单体,采用离子型/非离子型复合乳化剂,过硫酸钾(KPS)为引发剂,制备了有机硅改性的丙烯酸酯共聚物乳液(SAE)。考察了MPTS用量、甲基丙烯酸-β-羟丙酯(HPMA)用量、引发剂用量及聚合温度对乳液稳定性的影响。采用IR、TG对SAE进行了表征。共聚物乳液SAE为成膜物,硅藻土、膨润土等为颜填料,制备了有机硅改性丙烯酸酯共聚物调湿涂料(SAE-C)。在测定共聚物乳液膜、SAE-C涂料基本性能的基础上,进一步测定了涂料SAE-C调湿功能。结果表明,MPTS能提高SAE乳液膜的附着力和涂料的耐水性;SAE乳液与SAE-C涂料均能达到国家内墙涂料和建筑涂料相关标准。同时,具有较好的增/降湿性能,可用作具有调湿功能的内墙涂料。 相似文献
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Methyl methacrylate, butyl acrylate, acrylic acid, and various amounts of glycidyl methacrylate (GMA) were copolymerized by a semicontinuous seeded emulsion copolymerization to be a four-component copolymer emulsion; the copolymers were characterized using swelling capacity, transmission electron microscopy (TEM), etc. The effect of glycidyl methacrylate and its content on the properties of emulsion and copolymer films was studied. The self-crosslinking reaction of the copolymer was investigated by FTIR and DSC. It was found that the swelling capacity of the crosslinked copolymer films decreased with increase of the glycidyl methacrylate content, the morphology showed a core–shell structure, and the copolymer emulsion possessed a self-crosslinking property. © 1995 John Wiley & Sons, Inc. 相似文献
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Using silicylacrylate (SPMA: 3-(trimethoxysilyl)propyl methacrylate) and acrylic acid as functional monomers, silicylacrylate copolymer core–shell emulsion (SiA-CSE) was prepared by emulsion polymerization. The relationships between stability of SiA-CSE and contents of SPMA, emulsifier, initiator and copolymerization temperature were investigated. Moreover, the structure of SiA-CSE was characterized by FTIR, TEM and TGA techniques. The SiA-CSE was applied to prepare the silicylacrylate copolymer humidity coatings (SiA-CSE-C) by compositing with pigments and porous fillers. Based on measuring the basic performance of copolymer emulsion film and SiA-CSE coatings, the humidifying function of SiA-CSE coatings was investigated. In conclusion, SPMA could improve the adhesion of SiA-CSE film and water resistance of the coatings. The obtained coatings showed excellent humidity-sensitivity and humidity retention, which could be used as the interior walls coatings in the building. 相似文献
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以丙烯酸丁酯(BA)和丙烯酸-2-乙基己酯(2-EHA)为软单体、甲基丙烯酸甲酯(MMA)为硬单体、丙烯酸(AA)为功能单体、甲基丙烯酸羟乙酯(HEMA)为交联单体和十二烷基硫酸钠(SDS)/乳化剂(OP-10)为阴/非离子型复合乳化剂,采用核/壳种子乳液聚合法制备了丙烯酸酯共聚乳液;然后在壳层聚合时寸加入HEMA,并用乙烯基有机硅进行改性,制得硅丙乳液。结果表明:当m(SDS):m(OP-10)=3:2、w(复合乳化剂)=3.4%、w(引发剂)=0.82%、w(HEMA)=3.5%、聚合温度为80℃以及聚合中期加入6.8%乙烯基硅油至壳单体中时,硅丙乳液及其胶膜的稳定性、耐水性和力学性能俱佳。 相似文献
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《Journal of Industrial and Engineering Chemistry》2014,20(5):3195-3200
Pressure sensitive adhesives (PSAs) with higher thermal stability were synthesized by crosslinking acrylic copolymer with naphthyl curing agent. The acrylic copolymer was synthesized for a base resin of PSAs by solution polymerization of 2-ethylhexyl acrylate, ethyl acrylate, and acrylic acid with N,N′-azobisisobutyronitrile as an initiator. The acrylic copolymer was further modified with glycidyl methacrylate to have the vinyl groups available for UV curing. Thermal stability of acrylic PSAs was improved noticeably with increasing naphthyl curing agent content and UV dose mainly due to the extensive formation of crosslinked structure in the polymer matrix. Although the peel strength decreased with UV curing of acrylic polymer, a proper balance between the thermal stability and the adhesion performance of PSAs was obtained by controlling the UV curing with naphthyl curing agent content and UV dose. 相似文献
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A two‐layer film consisting of a tacky layer (air side) and a porous nontacky layer (release‐paper side) was prepared by casting blend emulsion on a release paper, in which 150‐nm 2‐ethylhexyl acrylate–2‐methoxyethyl acrylate–acrylic acid terpolymer particles having high storage stability and 542‐nm ethyl acrylate–methyl methacrylate copolymer particles having low storage stability were dispersed. Both emulsion particles were produced by emulsifier‐free emulsion copolymerizations. The difference of tackiness between both surfaces increased with increases in the film‐formation time and the concentration of electrolytes in the blend emulsion, and resulted in the two‐layer film. The film had a high water vapor permeability, which is also needed for medical adhesive tape. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 2027–2033, 2003 相似文献