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泡沫浮选法处理含氰废水 总被引:1,自引:0,他引:1
本文研究了在含氰废水中按化学计量比加入Fe~(2+)和Fe~(3+)离子以生成无毒的亚铁氰化铁絮状物沉淀,然后采用泡沫浮选进行分离的除氰方法。操作过程中拟加入一定量的阳离子表面活性剂,采用5~#烧结玻璃板作气体分布器,在pH值为4.0~6.5之间,能获得较高的分离效率。操作宜在阳光直射不到的阳暗处进行以避免亚铁氰化铁沉淀的光解反应发生。 相似文献
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采用SiO_2纳米颗粒分别与阴离子表面活性剂十二烷基硫酸钠(SDS)、阳离子表面活性剂十六烷基三甲基溴化铵(CTAB)、非离子表面活性剂十二烷基醇聚氧乙烯(3)醚(AEO-3)复配制备水相泡沫,研究了发泡体积、半衰期和微观结构的变化规律,以揭示SiO_2纳米颗粒对水相泡沫稳定性的影响机理。结果表明,在表面活性剂质量分数一定的条件下,随着纳米颗粒质量分数的增加,泡沫稳定性逐渐增强,当纳米颗粒质量分数为0.3%时,发泡体积达最大值,含气率分别为78.9%,78.4%和78.8%。与单组分质量分数分别为0.3%,0.3%和15%的SDS、CTAB、AEO-3体系相比,发泡体积未受影响,半衰期分别为9.0,8.2和360?min,提高了20%,28.1%和71.4%,泡沫的稳定性得到了不同程度的改善。 相似文献
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采用胶团强化超滤(MEUF)-泡沫分离(FF)组合工艺,对含镉重金属废水进行深度处理.探讨了两种技术联用对分离效果的影响.结果表明,表面活性剂SDS和金属Cd2 离子浓度对分离效果有很大的影响.MEUF-FF联用后,大大降低了表面活性剂SDS用量,节省了经济成本.相比于单一的MEUF,MEUF-FF联用后能降低出水中SDS浓度,显著提高Cd2 分离效率.经过组合工艺处理后,Cd2 出水的浓度小于0.1mg/L,满足国家污水综合排放标准(GB8978-1996). 相似文献
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采用泡沫分离-Fenton氧化工艺进行处理某炼油公司含SDBS和Brij30废水,研究了气体流速、废水流速、塔内液体高度、pH和Fenton试剂用量对处理效果的影响。得到了优化后的工艺条件为:Fenton试剂用量0.05 mol/L,气体流速0.054~0.072 m3/h,分离塔内液体量为1.8~1.9 L,废水流速2.0~2.2 L/h,Fenton氧化处理pH=3~4。在此最佳工艺基础上进行了工业侧线实验,实验表明,采用泡沫分离-Fenton氧化工艺可将废水中SDBS和Brij30分别降至2 mg/L和5 mg/L以下。 相似文献
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Fe^3+掺杂纳米TiO2光催化剂的制备及其光催化性能研究 总被引:1,自引:0,他引:1
以十六烷基三甲基溴化铵(CTAB)为表面活性剂,正丁醇为助表面活性剂,环己烷为油相,采用微乳液法制备出Fe3+掺杂纳米TiO2,用X-射线衍射(XRD)对纳米TiO2粒径、物相等方面进行了表征.通过光催化降解甲基橙溶液考察了TiO2的光催化性能.甲基橙降解实验结果表明,溶液的pH=2时降解率可达100%;掺杂Fe3+会影响TiO2光催化性能,n(Ti4+):n(Fe3+)=1:0.000 4的TiO2在前10 min降解率高达54.50%,60 min降解率可达93.33%,掺杂浓度增大到一定程度后,降解率反而下降,说明存在较佳掺杂浓度.另外,溶液初始浓度对TiO2光催化性能有一定的影响. 相似文献
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利用3-氨基丙基三乙氧基硅烷(APTES)对SiO2纳米粒子进行改性,得到改性SiO2纳米粒子,通过FTIR和接触角分析对其进行了表征,并通过静态实验考察了十二烷基硫酸钠(SDS)溶液、SiO2-SDS纳米流体、改性SiO2-SDS纳米流体在有、无氯化镁存在下对CO2泡沫的起泡性、发泡性和稳定性的影响。结果表明,经改性SiO2纳米粒子表面改性的聚甲基丙烯酸甲酯(PMMA)表面在油-水体系中更亲油,在空气-水体系中更亲气;与SDS溶液(质量浓度0.236%,半衰期80 min)相比,SiO2(质量浓度0.06%)-SDS纳米流体、改性SiO2(质量浓度0.05%)-SDS纳米流体的泡沫半衰期均有所延长,分别延长至120 min、140 min;当SDS质量浓度从0.236%增至0.472%时,改性SiO2-SDS纳米流体的泡沫半衰期从140 min延长至270 min;在氯化镁存在下,改性Si... 相似文献
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In order to recover cadmium ion from wastewater, a process based on enhanced ultrafiltration was finalised. The originality of the solution here proposed lies on the coupled use of ceramic membranes and of a surfactant added to the water to be treated. This paper deals with the study of the influence of experimental conditions upon permeation flux and selectivity of the separation. The process is efficient and flexible since a single stage treatment allows to reduce the concentration of cadmium in the effluent by a factor of about 750; this high performance in selectivity is on a par with high fluxes of permeate (roughly 170 L.h.?1.m?2 at 25°C and 3 × 105 Pa). 相似文献
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Hayriye Kula T
þRker Gürkan H. nder zbelge 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1983,33(5):237-244
In the industrial production of aluminium by the electrolysis of alumina, electrolyte froth, which is a mixture of carbon and cryolite is obtained at a rate of 50 kg of froth per ton of aluminium produced. Cryolite can be recovered from this mixture by flotation. In this study, the effects of the following parameters on flotation were experimentally investigated: particle size, type, combination, dosage and ratio of reagents, and conditioning time. It is found that it is possible to decrease the carbon content of cryolite below 1% by suitably choosing the operating parameters. Electrolyte froth must be ground to —100 mesh size for the liberation of carbon particles captured in the cryolite matrix. Any combination of two of the reagents, kerosene, fuel oil, creosote and terebenthene yield good results if used together with pine oil. Pine oil is found to be a more effective frother compared to Pril, a commercial detergent. Satisfactory separations are obtained when a kerosene-fuel oil mixture (50:50, v/v) is used as the collector with a dosage of 3.7 kg per ton of feed together with pine oil, the frother, with a dosage of 0.095 kg per ton of feed. 相似文献
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Celin Acharya Gedela V Rao Irena Twardoska Rabi N Kar Lala B Sukla 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1999,74(10):945-948
Reduction of sulfur by bacterial leaching from a high sulfur‐bearing coal sample from Assam was attempted. Flotation of the sample with light diesel oil could not depress the pyrite and also the Thiobacillus ferrooxidans was found to be ineffective in leaching the sulfur from the flotation concentrate. Conditioning of the same coal sample with Thiobacillus ferrooxidans was found to assist in selectively depressing the pyrite, thereby reducing nearly 60% of the pyritic sulfur present in the sample. © 1999 Society of Chemical Industry 相似文献
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Amine-based carbon capture (ABCC) is an advanced and cost-effective technology used to reduce the effects of climate change by capturing emitted from different sources. Although it has been demonstrated commercially, amine degradation poses a significant threat to humans and aquatic life. Amine degradation produces a wide variety of complex products such as nitrosamines and some organic acids. Some of these products are carcinogenic and mutagenic in nature and have demonstrated acute toxicity for laboratory animals. In order to mitigate the adverse impact of these compounds on human health and aquatic life, heterogeneous photocatalysis, an advanced oxidation process which can degrade a wide variety of chemical species with potent reactive hydroxyl radicals, was considered for the degradation of these compounds. The photocatalytic degradation of N-nitrosodiethylamine (NDEA), acetic acid, and formic acid were tested using TiO2 and metal-impregnated TiO2 catalysts such as Fe, Co, Ni, and Cu. Various techniques, such as thermogravimetric analysis (TGA), UV–Vis, X-ray diffraction (XRD), Brunauer–Emmett–Teller (BET), scanning electron microscopy (SEM), and X-ray fluorescence (XRF) were used to characterize these catalysts. The operational parameters for the photocatalytic degradation process were chosen as solution pH, catalyst dose, and metal impregnation percentage (imp%), and they were optimized using response surface methodology (RSM). pH was found as an important factor, and its impact on the photocatalytic degradation efficiency was more significant than the other operational parameters. The average degradation efficiency of the compounds reached 93.1% for Fe-TiO2, 92.08% for Co-TiO2, 89.09% for Ni-TiO2, 88.81% for Cu-TiO2, and 86.3% for TiO2 at the optimum conditions. 相似文献
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二氧化钛在解决环境污染问题方面有着广阔的应用前景。将二氧化钛负载固定于非金属矿物载体之上,能够更好地提高二氧化钛的催化和应用性能。简单介绍了二氧化钛的催化机理,综述了非金属矿物材料负载二氧化钛的研究进展,并就未来的发展趋势进行了展望。 相似文献
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聚合物强化超滤过程处理含Hg~(2+)废水 总被引:2,自引:0,他引:2
研究聚丙烯酸钠(PAASS)与Hg2+络合反应动力学,当PAASS大量过剩及pH值恒为5时,络合反应达到平衡时间为25 m in,反应行为可用拟一级速率方程描述。测定PAASS对Hg2+络合能力,pH=5时每mg PAASS络合容量为1.0 mg。考察pH值、盐浓度和竞争络合剂对Hg2+截留系数的影响,可得:pH=5及负载比LR=1时适宜截留Hg2+;当C l-和SO42-浓度增大时,Hg2+截留系数逐渐降低;酒石酸钠和三乙醇胺不干扰PAASS与Hg2+的络合。进一步研究超滤浓缩行为,结果表明:当pH=5,PAASS及Hg2+初始质量浓度均为100 mg/L时,原料液浓缩15倍,膜通量仅衰减15.0%,浓缩液及渗透液汞质量浓度分别为1499.6,0.03 mg/L。 相似文献
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鉴于水体中工程纳米颗粒(ENP)的环境毒性与潜在价值,高效富集/回收ENP是其资源化处理的重要课题。为了突破浮选ENP中富集程度低且后续分离难度大的技术瓶颈,本文基于强化泡沫排液建立了富集/回收ENP的浮选法。以TiO2纳米颗粒(TNP)为研究对象、十六烷基三甲基溴化铵(CTAB)为捕收剂和起泡剂,构筑了正八边形中空棱台(RHP)构件强化泡沫排液,分别从持液率、气泡直径和富集比等方面探讨了RHP强化排液的效果,分析了其机理。实验结果表明,在RHP构件安装于泡沫相中部、pH9.0、CTAB浓度100mg/L和气速250mL/min的条件下,TNP的富集比和回收率分别达到48.3±2.4和98.2%±4.9%;与不添加RHP相比,浮选过程中持液率降低了72.1%,TNP富集比升高了68.9%。综上,本文开发的浮选法为有效治理ENP水污染提供了重要的理论指导和技术支持。 相似文献
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The effect of single frothers and their blends on bubble size, froth stability, and unburned carbon (UC) flotation performance was studied. Methyl isobutyl carbinol that produces smaller bubbles is efficient in floating ultrafine particles and producing concentrate. DF-250 that gives higher froth stability is effective for recovering coarse particles and improving recovery. The presence of DF-250 in the blend increases bubble size and significantly enhances froth stability, and hence the optimal flotation performance is achieved with 75% DF-250. It indicates that the frother giving high froth stability is better in UC flotation due to the little effect of UC on froth stability. 相似文献