国内商情

今年化工市场预测偏紧品种铜、硫酸铜、浓硝酸、液氯、硝酸钠、亚硝酸钠、粗苯、纯苯、甲苯、混合二甲苯、间二甲苯、苯酐、甲醇、丁醇、辛醇、萘、丙酮、环已酮、已内酰胺、苯胺、甲酸、冰醋酸、丙酸、PE、PP、PS、EPS、对硝基氯化苯、对苯二甲酸、丙烯腈、N66盐、氯丁胶、丁腈胶、顺丁胶、三元乙丙胶、天然胶乳、椰子油、合成盐酸、硝基苯、片基涤纶树脂、增塑剂、尿素、硫酸钾。持平品种硫酸、氧化锌、无水芒硝、硫化碱、金红石型钛白粉、氰化钾、氧化铜、氧化亚铜、氯化亚铜、氰化亚     

香水化妆品在中国发展分析

芳香化妆品是指在化妆品中配入香味,以及配加香味的生活环境改善的产品,统称为芳香化妆品。它包括雪花膏、冷霜、护肤霜（蜜）、清洁霜、粉底霜、营养霜、润肤油、按摩油、发油、发蜡、发胶、摩丝、生发水、剃须膏、洗发精、护发素、洗面奶、牙膏、牙粉、含漱水、香粉、爽身粉、各种香水、花露水、唇膏（口红）、胭脂、眉笔、眼黛、指甲油、染发剂、脱毛剂、抑汗剂、祛斑霜、粉刺霜、面膜、浴油、浴盐、泡沫浴、SPA用香薰产品、香皂、除臭剂、空气清新剂等     

2011上海卫浴精品厨房设施展览会

展出内容：厨房设施及配套五金件整体厨房、橱柜、壁柜门、隔断、人造石台面、微晶石板、防火板、厨房家具、整体衣柜、书柜、移门、鞋柜及家具制品。家用净水设备、厨房卫生间家用电器、厨房设施、燃气灶、炉灶系列、抽油烟机、热水器产品、操作台系列产品、洗刷设备、厨房水槽、换气扇水处理卫生洁具、龙头花洒、休闲健康设备、整体浴室、按摩浴缸、淋浴房、桑拿泳池设备、卫生问浴室设施、洗面器、洗涤槽、便器、洁身器、水箱配件、感应器、烘手器、浴室镜、浴室柜卫浴挂件、旋转衣架、水暖五金、蒸汽浴房、各类卫生陶瓷及相关设备。     

发展精细化工原料的市场分析

(1)已得到或已安排生产能力、不宜再重复建设的品种是:甲胺、乙胺、丙烯酰胺、乙醇胺、双氰胺、三聚氰胺、氯乙烷、氯乙酸、乙二醛、季戊四醇、新戊二醇、丙烯酸酯、二甘醇、氯化苯、二氯苯、硝基氯苯、十二烷基苯、甲酚、壬基酚、氯化苄、苯甲酸、苯乙酸、柠檬酸等。     

化妆品添加剂

七十年代以来,国外化妆品采用动植物的添加剂增长的极快。来自动物的有胎盘油、蛋黄油、骨胶原、蜂王浆、骨髓、血浆等。来自植物的有人参、银耳、七叶树、金盏花、白芷、当归、桔梗、麻黄、颠茄、欧芹、飞帘、升麻、甘菊、大麦壳、西门木、指甲花、芦荟、芝麻、旱金莲、杏仁等多种药用植物,以及昆布、胡萝卜、葱、蒜、苹果、杨梅、鳄梨、佛手、黄瓜、甜瓜、西瓜、野生梨等。由昆布、蓝藻、绿藻等萃取物制的洗发剂,可促进头发生长;用芝麻、芦荟、昆布、大麦芽     

JDK系列电动机固态节能控制器

·适用范围: 可广泛用于石油、化工、冶金、煤矿、油田、纺织、机械、印刷、塑料、食品、码头、装卸、给排水、粮油加工等各类行业交流异步电动机拖动设备。如:抽油机、液体泵、空压机、破碎机、球磨机、皮带运输机、轧钢机、锻床、冲床、铣床、钻床、磨床、纺织机、炼塑机、流水作业线电机拖动设备等。     

8月份30城市乘用车轮胎热销型号市场价格

注：按品牌中文首字母排序;30城市为：北京、上海、广州、深圳、杭州、成都、沈阳、西安、武汉、青岛、哈尔滨、合肥、呼和浩特、兰州、连云港、洛阳、南昌、南宁、攀枝花、秦皇岛、曲靖、厦门、太原、泰安、重庆、乌海、乌鲁木齐、泰州、大庆、运城     

几种新型化工设备的研制与应用（下）

DTB结晶器应用广泛,国外用于氯化钾、硝酸钾、硫酸铵、磷酸氢二铵、硫酸钠、硫代硫酸钠、硫酸镁、硫酸钾、溴化钠、氯酸钠、重铬酸钠、十水碳酸钠、磷酸钠、硼砂、硼酸、氯化钡、氯化镁、氯化铵、碳酸锂、硝酸银、磷酸铵、尿素等溶液的结晶操作。     

硼肥在农业上的应用(二)

硼泥制造硼肥的试验通过广大贫下中农在十多个省市,一百多万亩大面积土地上使用的结果,证明硼肥肥效很好,对粮、棉、油、蔬菜、瓜果都有显著的增产效果。一、硼肥的增产效果硼肥能使以下作物获得增产。计有:水稻、小麦、大麦、荞麦、玉米、高粱、马铃薯、甘薯、蓖麻、麻类、油菜籽、花生、豆类、棉花、向日葵、甜菜、西红柿、黄瓜、芜菁、根油菜、菜豆角、胡萝卜、白萝卜、甘兰、菜花、芹菜、青菜、莴苣、茴香、白皮葱、阿尔巴尼亚甜椒、茄子、烟叶、苹果、     

国外动态

▲一些国家限制使用的部分化学品 45、硫丹 阿根廷、保加利亚、加拿大、丹麦、芬兰、以色列、匈牙利、新西兰、菲律宾、瑞典限制或禁止使用。 46、氯丹 阿根廷、加拿大、哥伦比亚、塞浦路斯、德国、丹麦、芬兰、以色列、日本、挪威、新西     

2004～2005年国外塑料工业进展

收集了2004年7月-2005年6月国外塑料工业的相关资料，介绍了2004年～2005年国外塑料工业的发展情况。提供了世界几大区域塑料的产量、增长率及所占份额；美国、德国、日本、韩国、法国、比利时、印度、西班牙、中国台湾、加拿大、巴西、英国等国家和地区的不同树脂的产量及消费量；各国、各地区塑料原料的产量、进出口量、国内消费量和人均消费量；日本塑料原料的生产情况。按通用热塑性树脂（聚乙烯、聚丙烯、聚苯乙烯、聚氯乙烯、ABS树脂）、工程塑料（聚酰胺、聚碳酸酯、聚甲醛、热塑性聚酯、聚苯醚）、通用热固性树脂（酚醛、聚氨酯、不饱和树脂、环氧树脂）、特种工程塑料（聚苯硫醚、液晶聚合物、聚醚醚酮、聚砜）的品种顺序，对树脂的产量、消费量、供需状况及合成工艺、产品开发、树脂品种的延伸及应用的扩展作了详细的介绍。     

Recent Advances in Catalytic Conversion of Glycerol

The article underlines and discusses the state-of-the-art accomplishments in the catalytic conversion of glycerol (1,2,3-propanetriol) to fuels and value-added chemicals in the past five years (2008–2012). The reactions include steam reforming, aqueous-phase reforming, hydrogenolysis, oxidation, dehydration, esterification, etherification, carboxylation, acetalization, and chlorination. Typical products are hydrogen, propanediols, dihydroxyacetone, glyceric acid, acrolein, glyceride, polyglycerol, glycerol carbonate, acetals, ketals, and epichlorohydrine. Recent studies on the catalysts, reaction conditions, and possible pathways are primarily discussed. They indicate that major breakthroughs are achieved by the use of multifunctional catalysts, process intensification and integrated reactions. Literature survey suggests that future work on the catalytic conversion of glycerol for commercial goals particularly requires new catalysts, innovative reactor engineering, and close multidisciplinary partnership.     

Mechanisms Governing Anaphylaxis: Inflammatory Cells,Mediators, Endothelial Gap Junctions and Beyond

Anaphylaxis is a severe, acute, life-threatening multisystem allergic reaction resulting from the release of a plethora of mediators from mast cells culminating in serious respiratory, cardiovascular and mucocutaneous manifestations that can be fatal. Medications, foods, latex, exercise, hormones (progesterone), and clonal mast cell disorders may be responsible. More recently, novel syndromes such as delayed reactions to red meat and hereditary alpha tryptasemia have been described. Anaphylaxis manifests as sudden onset urticaria, pruritus, flushing, erythema, angioedema (lips, tongue, airways, periphery), myocardial dysfunction (hypovolemia, distributive or mixed shock and arrhythmias), rhinitis, wheezing and stridor. Vomiting, diarrhea, scrotal edema, uterine cramps, vaginal bleeding, urinary incontinence, dizziness, seizures, confusion, and syncope may occur. The traditional (or classical) pathway is mediated via T cells, Th2 cytokines (such as IL-4 and 5), B cell production of IgE and subsequent crosslinking of the high affinity IgE receptor (FcεRI) on mast cells and basophils by IgE-antigen complexes, culminating in mast cell and basophil degranulation. Degranulation results in the release of preformed mediators (histamine, heparin, tryptase, chymase, carboxypeptidase, cathepsin G and tumor necrosis factor alpha (TNF-α), and of de novo synthesized ones such as lipid mediators (cysteinyl leukotrienes), platelet activating factor (PAF), cytokines and growth factors such as vascular endothelial growth factor (VEGF). Of these, histamine, tryptase, cathepsin G, TNF-α, LTC₄, PAF and VEGF can increase vascular permeability. Recent data suggest that mast cell-derived histamine and PAF can activate nitric oxide production from endothelium and set into motion a signaling cascade that leads to dilatation of blood vessels and dysfunction of the endothelial barrier. The latter, characterized by the opening of adherens junctions, leads to increased capillary permeability and fluid extravasation. These changes contribute to airway edema, hypovolemia, and distributive shock, with potentially fatal consequences. In this review, besides mechanisms (endotypes) underlying IgE-mediated anaphylaxis, we also provide a brief overview of IgG-, complement-, contact system-, cytokine- and mast cell-mediated reactions that can result in phenotypes resembling IgE-mediated anaphylaxis. Such classifications can lead the way to precision medicine approaches to the management of this complex disease.     

Genotype and growing location effects on phytosterols in canola oil

There is little information available about phytosterols in canola (Brassica napa L.) oil and the effects of genotype and growing locations from Virginia and the mid-Atlantic region of the United States, a potential area for the establishment of domestic production to provide edible oil. Our objectives were to characterize the phytosterols, phospholipids, unsaponifiable matter, and FA in oil from Virginia-grown canola. Among 11 canola genotypes grown at two locations during 1995–1996 significant variations existed for oil content and FA profiles, but not for contents of phospholipids, unsaponifiable matter, total phytosterols, campesterol, stigmasterol, and β-sitosterol, Total phytosterol content in the oil of Virginia-grown canola varied from 0.7 to 0.9% with a mean of 0.8%. This concentration compared favorably with oil from Canadian canola, which typically contains 0.5 to 1.1% total phytosterols. The mean contents of brassicasterol, campesterol, stigmasterol, β-sitosterol, Δ⁵-avenasterol, and Δ⁷-stigmatenol as percentages of total phytosterols in Virginia-grown canola were: 9.7, 32.0, 0.6, 49.3, 4.99, and 3.5%, respectively. Growing location did not affect phytosterols in Virginia-grown canola oil but had significant effects on contents of phospholipids, and saturated (myristic, stearic, and arachidic) and unsaturated (palmitoleic, linoleic, linolenic, eicosenoic, and erucic) FA.     

Hydrocarbon components of the yellowheaded spruce sawfly sex pheromone

The primary sex pheromone of the yellowheaded spruce sawfly,Pikonema alaskensis (Rohwer) (Hymenoptera: Tenthredinidae), was found to include a series of straight-chain hydrocarbon dienes, all with the double bonds in the 9 and 19 positions and all with the (Z, Z) configuration. The major components, of 29, 31, 33, 35, and 37 carbon atoms, were synthesized. In the field and the greenhouse, the synthetic dienes were far above control levels in activity but, at least during the first hours of bioassay, were somewhat less active than the female-derived materials on a weight basis. In the field, a mixture of all five synthetic dienes, in the proportions found in the females, was more attractive than any single one, on a mole basis. In addition, (Z, Z)-9,19 dienes of 28, 30, 32, 34, 36, 38, and 39 carbons have been detected in females in minor amounts. The first five were bioassayed, and each was found to be similar in activity to the 35-carbon component when compared on a weight basis. The synthetic dienes, while active by themselves, were strongly synergized by two, more polar, Florisil fractions derived from females. Experimental design considerations are discussed.     

抗菌防腐剂（Ⅰ）—抗菌防腐剂的历史、定义与分类

简要回顾了抗菌防腐剂的发展历程,进一步明确了杀菌剂,抑菌剂,抗菌剂,防腐剂,防霉剂,消毒剂,杀生剂,保鲜剂,抗生素的概念。同时,结合抗菌防腐剂的发展在对抗菌防腐剂按无机物,有机物和天然物分类的基础上,进一步又按化学结构和官能团将抗菌剂分为有机金属,有机卤代物,醇,酚,醚,醛,酮,醌,酸,酯,含氮类,含硫类,有机磷,有机砷类以及杂环类等。     

典型过程强化技术在纳米材料制备中的应用进展

纳米材料被誉为21世纪的新材料,广泛应用于化工、电子、国防、陶瓷等领域。传统的纳米材料制备方法面临粒径控制较困难、批次间重复性差,存在放大效应等不足。过程强化技术是化学工程学科的研究前沿和热点方向之一,旨在通过在生产过程中采用新工艺、新设备等手段,实现缩减操作单元、减小设备体积、提高生产能力及能量利用效率的目的,是实现化工过程安全、高效、绿色的重要途径。过程强化技术不仅在制备时间和能源利用效率等方面明显优于常规方法,还可以得到特殊形态和性能的纳米材料。过去二十年中,过程强化技术广泛应用于纳米材料的小试和规模化制备,并取得了良好的经济及社会效益,引起越来越多科学研究者的重视。本工作以超重力、微化工、微波、超声、等离子体技术、离子液体为代表,综述了过程强化技术在纳米材料制备领域中的应用及相关研究的最新进展,结合实例对不同领域进行了概述,分析总结了各领域的优势和特点,讨论了在快速发展的纳米材料制备领域中存在的机遇和挑战,并展望了其未来的应用前景。     

Low-molecular weight organic compositions of acid waters from vegetable oil soapstocks

Alkaline extracts (soapstocks) from canola, corn, cottonseed, peanut, soybean, and sunflower oil refining were acidified, and identities and concentrations of the low-molecular weight organic components of the resulting acid waters were determined by gas chromatography, followed by mass spectroscopy, and by high-performance liquid chromatography. The main components of each acid water sample, in order of decreasing concentration and after omitting the fermentation product lactic acid, were phosphoric acid, α-glycerophosphate, and glycerol from canola;myo-inositol, phosphoric acid, α-glycerophosphate andmyo-inositol-1-phosphate from corn; glycerol, α-glycerophosphate,myo-inositol-1-phosphate, and β-glycerophosphate from cottonseed; phosphoric acid, glycerol, andmyo-inositol from peanut; α-glycerophospho-1-myo-inositol,myo-inositol-1-phosphate, α-glycerophosphate, and glycerol from soybean; and α-glycerophosphate, glycerol,myo-inositol-1-phosphate, and β-glycerophosphate from sunflower.     

树脂基复合材料成型工艺研究进展

主要综述了树脂基复合材料的几种成型工艺,包括RTM、VARTM、CRTM、LRTM、RFI、VARI、SCRIMP、SRIM、TERM,各自的发展现状、成型原理、特点等.     

The variation of element contents in triticale during vegetative growth

The variation of N, P, K, Ca, Mg, Fe, Mn, Zn, Cu, B, Ba, Be, Bi, Sn, Sr, Sb, Ti, Te, V, Se, As and Hg concentrations was studied under field conditions in triticale. The samples were collected every 10 days from tillering to full ripening stage using plant material from 0.5 m² per plot. The concentrations generally decreased from early growth to harvest. The elemental concentrations in triticale differed from the other cereals, but the variation's trend was similar.

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Zusammenfassung Es wurden die Schwankungen in den Konzentration von N, P, K, Ca, Mg, Fe, Mn, Zn, Cu, B, Ba, Be, Bi, Sn, Sr, Sb, Ti, Te, V, Se, As und Hg in Triticale unter Feldbedingungen untersucht. Von der Bestockung bis zur Vollreife wurden alle 10 Tage von je 0.5 m² pro Parzelle Pflanzenproben genommen.In allgemeinen haben die Konzentrationen von Frühjar bis zur Ernte abgenommen.Der elementengehalt in Triticale war demjenigen der übrigen Getreidearten verschieden, aber der Trend der Änderungen war ähnlich.