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《工程塑料应用》2021,49(5)
采用热塑性弹性体苯乙烯–乙烯–丁烯–苯乙烯嵌段共聚物(SEBS)对丙烯腈–丁二烯–苯乙烯塑料(ABS)进行改性,制备3D打印ABS/SEBS复合材料,研究了SEBS的用量对3D打印ABS/SEBS复合材料流动性能、力学性能与热降解行为的影响。结果表明,随SEBS用量的增加,ABS/SEBS复合材料的熔体流动速率先增加后降低;随SEBS用量增加,ABS/SEBS复合材料的冲击强度增加,SEBS能提高ABS/SEBS复合材料的断裂伸长率,但同时也使拉伸强度和弯曲强度降低;随SEBS用量的增加,ABS/SEBS复合材料的热稳定性增加;当SEBS质量分数为15%时,ABS/SEBS复合材料在3D打印中的综合性能最好。 相似文献
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用苯乙烯-丁二烯-苯乙烯嵌段共聚物(SBS)改性苯乙烯-丁二烯-丙烯腈共聚物(ABS),制备3D打印用ABS改性复合材料,研究了SBS的用量对ABS复合材料性能的影响。采用熔体流动速率仪表征了复合材料的熔体流动速率,万能力学试验机和悬壁梁冲击试验机测试了复合材料的力学性能。研究结果表明,随SBS用量增加,复合材料的熔体流动速率增加,5%SBS的加入能使复合材料的熔体流动速率增加42.1%;随SBS用量增加,复合材料的冲击强度增加,弯曲强度降低;SBS能提高复合材料的断裂伸长率,增加其韧性,但同时也使拉伸强度降低。 相似文献
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以氯化聚乙烯(CPE)为增韧剂,用双螺杆挤出机共混制备丙烯腈-丁二烯-苯乙烯塑料(ABS)/聚氯乙烯(PVC)合金。研究了PVC及CPE用量对ABS/PVC合金的拉伸强度、弯曲强度、缺口冲击强度、维卡软化温度、氧指数和熔体流动性的影响。结果表明,随着PVC用量的增加,ABS/PVC合金的拉伸强度略有增加,弯曲强度基本不变,冲击强度呈现先略增加然后显著降低的趋势,维卡软化温度降低,氧指数增加;随着CPE用量增加,ABS/PVC合金的缺口冲击强度增加,拉伸强度和弯曲强度降低,氧指数和维卡软化温度变化很小,当ABS/PVC/CPE为40/60/15时,合金的拉伸强度为39.8 MPa、弯曲强度为60.8 MPa、缺口冲击强度为18.3 kJ/m2,氧指数为29.7%。 相似文献
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研究了废纸浆、马来酸酐接枝苯乙烯-乙烯/丁烯-苯乙烯(SEBS-g-MAH)用量以及发泡对废纸浆/丙烯腈-丁二烯-苯乙烯(ABS)复合材料的力学性能和吸水率的影响;通过扫描电镜SEM分析了SEBS-g-MAH对未发泡和发泡废纸浆/ABS复合材料的增容效果.结果表明:废纸浆用量为30份和SEBS-g-MAH用量为20份时,未发泡和发泡复合材料的拉伸性能和缺口冲击强度都达到最佳;吸水率随纸浆用量的增加而增加,SEBS-g-MAH用量为20份时,未发泡和发泡材料吸水率都达到最低.发泡后的复合材料的拉伸强度降低,冲击性能和吸水率升高.SEBS-g-MAH能有效地改善ABS和纸浆的界面相容性. 相似文献
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研究了氯化聚乙烯(CPE)、乙烯醋酸乙烯酯共聚物(EVA)、甲基丙烯酸甲酯-丁二烯-苯乙烯共聚物(MBS)和丁腈橡胶(NBR)4种相容剂对聚氯乙烯/丙烯腈-丁二烯-苯乙烯共聚物(PVC/ABS)合金注塑料性能的影响。研究结果表明,4种相容剂均会降低PVC/ABS合金注塑料的弯曲性能和阻燃性;CPE和EVA综合性能较好,有利于注塑料的加工和使用;MBS和NBR对合金注塑料流动性的不利影响较大,不适用于PVC/ABS合金注塑料。 相似文献
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ABS/Nano-ATH复合材料性能研究 总被引:2,自引:2,他引:0
采用熔融共混法制备出了丙烯腈-丁二烯-苯乙烯共聚物(ABS)/纳米氢氧化铝(nano-ATH)复合材料,研究了nano-ATH的用量对复合材料力学性能和阻燃性能的影响,并利用扫描电镜分析了nano-ATH在ABS基体中的分散情况。结果表明:随着nano-ATH用量的增加,ABS/nano-ATH复合材料的冲击强度和拉伸强度均是先升后降,分别在nano-ATH含量为10%和5%时达到最大值;nano-ATH的加入可以提高ABS复合材料的阻燃性能和弯曲模量,但随其用量的增加,nano-ATH在ABS基体中的分散性逐渐变差。 相似文献
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利用聚甲基丙烯酸甲酯(PMMA)及丙烯腈-苯乙烯共聚物(AS)对丁二烯-苯乙烯-丁二烯(SBS)增韧的回收丙烯腈-丁二烯-苯乙烯塑料(ABS)进行改性以提高其表面硬度.研究结果表明,PMMA及AS在提高共混物表面硬度的同时还可以提高其拉伸强度、弯曲强度及硬度,而冲击强度则呈下降趋势;此外,添加PMMA的共混体系的各项力... 相似文献
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Silvia Schicker Daniel E. García Igor Gorlov Rolf Janssen Nils Claussen 《Journal of the American Ceramic Society》1999,82(10):2607-2612
Wet milling of Al2 O3 -aluminide alloy (3A) precursor powders in acetone has been investigated by milling Fe/Al/Al2 O3 and Fe2 O3 /Al/Al2 O3 powder mixtures. The influence of the milling process on the physical and chemical properties of the milled powders has been studied. Particle refinement and homogenization were found not to play a dominant role, whereas plastic deformation of the metal particles leads to the formation of dislocations and a highly disarranged polycrystalline structure. Although no chemical reactions among the powder components in Fe2 O3 /Al/Al2 O3 powder mixtures were observed, the formation of a nanocrystalline, ordered intermetallic FeAl phase in Fe/Al/Al2 O3 powder mixtures caused by mechanical alloying was detected. Chemical reactions of Fe and Al particle surfaces with the atmosphere and the milling media lead to the formation of highly porous hydroxides on the particle surfaces. Hence the specific surface area of the powders increases, while the powder density decreases during milling. The fraction of Fe oxidized during milling was determined to be 0.13. The fraction of Al oxidized during milling strongly depends on the metal content of the powder mixture. It ranges between 0.4 and 0.8. 相似文献
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A new ampholytic homopolypeptide, , which has one tertiary amino and two carboxyl groups in the side chain has been derived from a hydrochloride salt of poly(L-lysine). The polymer in aqueous solution seems to be in the coil form with locally extended structure (LES) at neutral pH. In both the acidic and alkaline regions, the molar ellipticity of the polymer changes as a result of change in net charge on the side chain. The conformational changes may be from the coil with LES to other coiled forms. 5–7 M NaClO4 and 80% aqueous methanol induce the α-helix in the polymer at neutral pH. Divalent cations, Cu2+ and Ca2+, do not induce any remarkably ordered structures such as α-helix or β-structure in the polymer in aqueous solution at any pH. Ultraviolet absorption studies show an absorption peak of the polymer-Cu2+ complex near 240 nm. Dependence of the peak intensity on pH at various q values () indicates the two steps of the complex formation. At q less than 0.64, the formation is described only with the first step. An average coordination number for Cu2+ at the first step was calculated to be about 2 by the method of Mandel and Leyte. The association constant of Cu2+ with the residue at the step was determined from the absorption data to be far smaller than that for the Cu2+-EDTA complex. The second step of the formation occurs in the case of large q but the absorption data for the second step cannot be obtained exactly due to precipitation. 相似文献
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Sintering kinetics of the system Si3 N4-Y2O3 -Al2 O3 were determined from measurements of the linear shrinkage of pressed disks sintered isothermally at 1500° to 1700°C. Amorphous and crystalline Si3 N4 were studied with additions of 4 to 17 wt% Y2 O3 and 4 wt% A12 O3 . Sintering occurs by a liquid-phase mechanism in which the kinetics exhibit the three stages predicted by Kingery's model. However, the rates during the second stage of the process are higher for all compositions than predicted by the model. X-ray data show the presence of several transient phases which, with sufficient heating, disappear leaving mixtures of β ' -Si3 N4 and glass or β '-Si3 N4 , α '-Si3 N4 , and glass. The compositions and amounts of the residual glassy phases are estimated. 相似文献
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Won-Hyuk Lee Yoshihiro Abe Eikichi Inukai 《Journal of the American Ceramic Society》1993,76(4):849-856
Ag2 O-doped superconducting Bi2 Sr2 Ca1 Cu2 O x ceramics were prepared by a melt-quenching–reheating method. It is found that the Ag2 O-doped, as-cast specimens exhibit superconductivity ( T c = around 80 K) by heat treatment at temperatures around 800°C even in an evacuated and sealed silica glass tube, while the undoped specimens do not and vaporize by the corresponding heat treatment. Conversion of the Ag2 O-doped, as-cast specimens into superconducting ceramics when heated in an evacuated vessel is explained in terms of the oxygen donor of Ag2 O in the specimen. This finding enables us to fabricate a desired shape of superconducting Bi2 Sr2 Ca1 Cu2 O x ceramics sealed in metals or glasses. The addition of Ag2 O to Bi2 Sr2 Ca1 Cu2 O x melt, however, had deleterious influences on the superconducting properties ( T c and J c ) of the resultant ceramics when obtained by heat treatment in air. 相似文献
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Akira Akimoto 《Polymer》1974,15(4):216-218
The polymerization of vinyl chloride has been investigated using an catalyst system in the presence of various Lewis bases. Effective Lewis bases are γ-butyrolactone, diglyme and diethylenetriamine which are multidentate. The rate of polymerization is dependent not only on the basicity of the Lewis base used but also on a coordination number of one. The latter is the predominant factor. For the effect of polymeric amines, a tentative hypothesis is discussed. 相似文献
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Subsolidus phase relations were established in the system Si3 N4 -SiO2 -Y2 O3 . Four ternary compounds were confirmed, with compositions of Y4 Si2 O7 N2 , Y2 Si3 O3 N4 , YSiO2 N, and Y10 (SiO4 )6 N2 . The eutectic in the triangle Si3 N4 -Y2 Si2 O7 -Y10 (SiO4 )6 N2 melts at 1500°C and that in the triangle Si2 N2 O-SiO2 -Y2 Si2 O7 at 1550°C. The eutectic temperature of the Si3 N4 -Y2 Si2 O7 join was ∼ 1520°C. 相似文献