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天然气制甲醇合成气工艺及进展 总被引:2,自引:0,他引:2
论述了国内外天然气制甲醇合成气各工艺的研究现状,进展及发展方向。天然气制合成气的典型工艺是水蒸气催化转化法,其技术成熟,但投资大,能耗高,生产的合成气不适于直接用来合成甲醇。天然气与CO2催化转化工艺可制得富含CO的合成气,解决蒸气转化法氢过剩的问题,实现CO2的减排,目前对该法的研究主要集中在开发新型催化剂和优化反应条件等。两段转化法即一段炉采用蒸气转化,两段炉用富氧或纯氧转化,无需经转化炉前或炉后添加二氧化碳,就可达到合成甲醇原料气成分的要求。甲烷部分氧化法能耗低,反应易控制,可制得符合比例要求的甲醇合成气,但尚未见到该技术工业化的相关报道。甲烷自热转化工艺是在反应器中耦合了放热的甲烷部分氧化反应和强吸热的甲烷蒸气转化反应,反应体系本身可实现自供热,该工艺一般采用富氧空气或氧气,因此需氧气分离装置,增加了投资,这是制约其发展和应用的主要障碍。 相似文献
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《精细化工原料及中间体》2015,(9)
<正>一种煤制液化天然气的工艺本发明公开了一种煤制液化天然气(LNG)的工艺,该工艺具体为:煤制合成气甲烷化前仅精脱硫,CO2仍留在合成气中,甲烷化后再进行脱除CO2至50×10-6(vol%)送去液化,生产LNG。本发明采用无循环气的甲烷化工艺,脱CO2采用低温分离与低温甲醇洗相结合的工艺。在压力2.4MPa~2.6MPa,温度-50℃~-60℃。先进行低温分离CO2,塔釜得到液 相似文献
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针对合成气中含有的甲烷气体,提出了采用变压吸附和低温冷箱相结合的分离工艺对合成气中的甲烷进行分离的工业试验研究方案。该方法可减少了工业废气排放,使合成气资源得到综合利用,具有显著的经济与社会效益。 相似文献
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合成甲醇的原料气中,主要含有一氧化碳、氢气和二氧化碳,还含有少量的氮气、氩气、甲烷等惰性气体,由于甲醇合成是反复循环的反应过程,循环气中还应考虑到未完全分离的甲醇蒸汽及生成的甲烷对合成的影响。合成气成分对甲醇合成反应影响很大,本文中探讨循环比对甲醇合成过程影响对甲醇合成的控制有着特别重要的意义。 相似文献
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《精细化工原料及中间体》2015,(11)
<正>在一个合成回路中反应合成气制甲醇的方法,碳氧类原料(1)被裂化后转换成合成气,合成回路中反应生成合成气,获得粗甲醇更进一步获得高规格甲醇,以及在粗甲醇中溶解的二氧化碳被回收到裂化部分,以调节合成气的化学计量比。在一个优选实施比例中,闪蒸气体(9)从粗甲醇分离(8)和轻烃(10)来自蒸馏过程被压缩机循环到裂化炉中,进而 相似文献
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Three schemes of the gas turbine cycle have been analyzed from the point of view of the second law of thermodynamics: the conventional gas turbine cycle, where natural gas (methane) is oxidized by air; a closed gas turbine cycle, in which methane is oxidized by oxygen; and a proposed gas turbine cycle, in which the methane is first converted to synthesis gas (a mixture of carbon oxide and hydrogen), then part of the synthesis gas is oxidized by oxygen for electric energy generation while the rest is withdrawn from the power cycle for production of methanol, ether, synthetic fuel, etc. It has been shown that the third integrated scheme of natural gas usage provides minimum entropy increase as well as suppression of toxic nitrogen oxides generation in combustion products. Therefore, it could be considered as a prospective energy‐saving technology. 相似文献
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M. A. Vannice 《Catalysis Reviews》1976,14(1):153-191
The increasing demand for energy, coupled with the uncertainty and expense of crude oil imports, has renewed interest in the production of fuels and chemicals from hydrogen-deficient materials. These energy sources such as coal, residua, oil shale, and tar sands can be gasified with steam and oxygen to produce a gas containing large quantities of carbon monoxide and hydrogen. Once methane is removed from this CO/H2 mixture it is purified to remove S poisons and then reacted over a catalyst to produce a variety of organic products. The synthesis of hydrocarbon products, with the exception of methane, is commonly referred to as the Fischer-Tropsch synthesis reaction. 相似文献
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Partial oxidation of methane to synthesis gas over some titanates based perovskite oxides 总被引:1,自引:0,他引:1
Takashi Hayakawa Arnfinn G. Andersen Masao Shimizu Kunio Suzuki Katsuomi Takehira 《Catalysis Letters》1993,22(4):307-317
Ca1–x
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TiO3-based mixed oxide catalysts containing chromium, iron, cobalt or nickel were prepared and used in the oxidation of methane. The catalyst containing cobalt or nickel showed high activity for the synthesis gas production from methane. In the case of nickel containing catalyst, nickel oxide originally separated from the perovskite structure was easily reduced to nickel metal, which showed synthesis gas production activity. In the case of the cobalt containing catalyst, pretreatment with methane was required for high activity. Reduced metallic cobalt was formed from the perovskite structure, which revealed relatively high selectivity for the oxidative coupling of methane, and afforded synthesis gas production. Both the catalysts also catalyzed carbon dioxide reforming of methane and especially both high activity and selectivity were observed over the nickel containing catalyst. 相似文献
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联合两段氧化制合成气/F-T合成的GTL工艺和催化剂 总被引:1,自引:0,他引:1
A novel process for catalytic oxidation of methane to synthesis gas (syngas),which consists of two consecutive fixed-bed reactors with air introduced into the reactors,integrated Fischer-Tropsch synthesis,was investigated.At the Same time,a catalytic combustion technology has been investigated for utilizing the F-T offgas to generate heat or powr energy.The results show that the two-stage fixed reactor process keep away from explosion of CH4/O2.The integrated process is fitted to produce diesel oil and lubricating oil in remote gas field. 相似文献
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Carbon dioxide reforming of methane to syngas is one of the primary technologies of the new poly-generation energy system
on the basis of gasification gas and coke oven gas. A free energy minimization is applied to study the influence of operating
parameters (temperature, pressure and methane-to-carbon dioxide ratio) on methane conversion, products distribution, and energy
coupling between methane oxidation and carbon dioxide reforming methane. The results show that the methane conversion increases
with temperature and decreases with pressure. When the methane-to-carbon dioxide ratio increases, the methane conversion drops
but the H2/CO ratio increases. By the introduction of oxygen, an energy balance in the process of the carbon dioxide reforming methane
and oxidation can be realized, and the CO/H2 ratio can be adjusted as well without water-gas shift reaction for Fischer-Tropsch or methanol synthesis.
This work was presented at the 6
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Korea-China Workshop on Clean Energy Technology held at Busan, Korea, July 4–7, 2006. 相似文献
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天然气储量丰富,日益成为重要的清洁能源之一,而从其主要成分甲烷合成高附加值化合物更是研究前沿。由于甲烷结构稳定,CH键能很高,因而活化甲烷需要的条件非常苛刻。本文首先介绍了普通光催化氧化甲烷合成化合物的反应原理、研究进展、催化反应器和存在不足,然后综述了激光催化氧化甲烷合成化合物的反应原理、研究进展和催化反应器。指出激光光源具有提高光催化剂量子效率和缩短催化反应时间等诸多优势,接下来在深入研究激光催化反应机理的基础上,通过设计科学合理的激光反应体系,并遴选高效的光催化剂,有望显著提升包括甲烷氧化在内的激光催化反应性能,从而具有重要的学术意义和实践价值。今后的重点研究方向是通过激光催化氧化的方法使甲烷在温和的条件下活化,并合成高附加值化合物。 相似文献
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Production of synthesis gas 总被引:5,自引:0,他引:5
The state-of-the-art for the production of synthesis gas from the steam reforming of methane is reviewed and discussed. Particular attention is given to the design of the tubular reformer and carbon formation on the nickel catalyst. Improvements in syngas technology are discussed, including: CO2 reforming, autothermal reforming and heat exchange reforming, and the energy efficiencies of direct and indirect methane conversion are compared and contrasted. 相似文献